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Natural Resources Research - 相似文献
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Chun-Chan Kung Ryoichi Hayatsu Martin H. Studier Robert N. Clayton 《Earth and Planetary Science Letters》1979,46(1):141-146
Nitrogen isotope fractionations have been measured in Fischer-Tropsch and Miller-Urey reactions in order to determine whether these processes can account for the large15N/14N ratios found in organic matter in carbonaceous chondrites. Polymeric material formed in the Fischer-Tropsch reaction was enriched in15N by only 3‰ relative to the starting material (NH3). The15N enrichment in polymers from the Miller-Urey reaction was 10–12‰. Both of these fractionations are small compared to the 80–90‰ differences observed between enstatite chondrites and carbonaceous chondrites. These large differences are apparently due to temporal or spatial variations in the isotopic composition of nitrogen in the solar nebula, rather than to fractionation during the production of organic compounds. 相似文献
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在热液条件下合成了板状的和高度结晶的三八面体蒙脱石。用淬冷玻璃与脱水的钠基蒙脱石分别在(a)500°C,100MPa下1天和11天;(b)300°C,100MPa下7天的条件下进行反应。产物的结晶度和颗粒大小取决于初始玻璃的化学组成,合成温度和热液改性的时间。XRD尖锐的峰和一定相对湿度下水合作用证明了产物结构的高度有序和大尺寸。透射电镜也被用来表征产物颗粒尺寸。通过改变初始材料的化学成分,产物的颗粒大小可以在10nm到几个微米之间变化。有序度最高和尺寸最大的产物是在500°C,100MPa的条件下用Na0.33(Mg1.83Al0.67)Si4O11成分的玻璃反应… 相似文献
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Surface Acidity of Amorphous Aluminum Hydroxide 总被引：3，自引：0，他引：3
K. FUKUSHI K. TSUKIMURA H. YAMADA 《《地质学报》英文版》2006,80(2):206-211
The surface acidity of synthetic amorphous AI hydroxide was determined by acid/base titration with several complementary methods including solution analyses of the reacted solutions and XRD characterization of the reacted solids. The synthetic specimen was characterized to be the amorphous material showing four broad peaks in XRD pattern. XRD analyses of reacted solids after the titration experiments showed that amorphous AI hydroxide rapidly transformed to crystalline bayerite at the alkaline condition （pH〉10）. The solution analyses after and during the titration Ksp=^aAl^3＋/aH^＋^3 ,was 10^10.3. The amount of consumption of added acid or base during the titration experiment was attributed to both the protonation/deprotonation of dissolved AI species and surface hydroxyl group. The surface acidity constants, surface hydroxyl density and specific surface area were estimated by FITEQL 4.0. 相似文献
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Probabilistic Estimates of Number of Undiscovered Deposits and Their Total Tonnages in Permissive Tracts Using Deposit Densities 总被引：2，自引：0，他引：2
Empirical evidence indicates that processes affecting number and quantity of resources in geologic settings are very general
across deposit types. Sizes of permissive tracts that geologically could contain the deposits are excellent predictors of
numbers of deposits. In addition, total ore tonnage of mineral deposits of a particular type in a tract is proportional to
the type’s median tonnage in a tract. Regressions using size of permissive tracts and median tonnage allow estimation of number
of deposits and of total tonnage of mineralization. These powerful estimators, based on 10 different deposit types from 109
permissive worldwide control tracts, generalize across deposit types. Estimates of number of deposits and of total tonnage
of mineral deposits are made by regressing permissive area, and mean (in logs) tons in deposits of the type, against number
of deposits and total tonnage of deposits in the tract for the 50th percentile estimates. The regression equations (R
2 = 0.91 and 0.95) can be used for all deposit types just by inserting logarithmic values of permissive area in square kilometers,
and mean tons in deposits in millions of metric tons. The regression equations provide estimates at the 50th percentile, and
other equations are provided for 90% confidence limits for lower estimates and 10% confidence limits for upper estimates of
number of deposits and total tonnage. Equations for these percentile estimates along with expected value estimates are presented
here along with comparisons with independent expert estimates. Also provided are the equations for correcting for the known
well-explored deposits in a tract. These deposit-density models require internally consistent grade and tonnage models and
delineations for arriving at unbiased estimates. 相似文献
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Most regional geochemistry data reflect processes that can produce superfluous bits of noise and, perhaps, information about the mineralization process of interest. There are two end-member approaches to finding patterns in geochemical data—unsupervised learning and supervised learning. In unsupervised learning, data are processed and the geochemist is given the task of interpreting and identifying possible sources of any patterns. In supervised learning, data from known subgroups such as rock type, mineralized and nonmineralized, and types of mineralization are used to train the system which then is given unknown samples to classify into these subgroups.To locate patterns of interest, it is helpful to transform the data and to remove unwanted masking patterns. With trace elements use of a logarithmic transformation is recommended. In many situations, missing censored data can be estimated using multiple regression of other uncensored variables on the variable with censored values.In unsupervised learning, transformed values can be standardized, or normalized, to a Z-score by subtracting the subset's mean and dividing by its standard deviation. Subsets include any source of differences that might be related to processes unrelated to the target sought such as different laboratories, regional alteration, analytical procedures, or rock types. Normalization removes effects of different means and measurement scales as well as facilitates comparison of spatial patterns of elements. These adjustments remove effects of different subgroups and hopefully leave on the map the simple and uncluttered pattern(s) related to the mineralization only.Supervised learning methods, such as discriminant analysis and neural networks, offer the promise of consistent and, in certain situations, unbiased estimates of where mineralization might exist. These methods critically rely on being trained with data that encompasses all populations fairly and that can possibly fall into only the identified populations. 相似文献
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A new SPH-based approach to simulation of granular flows using viscous damping and stress regularisation 总被引：2，自引：1，他引：1
Cuong T. Nguyen Chi T. Nguyen Ha H. Bui Giang D. Nguyen Ryoichi Fukagawa 《Landslides》2017,14(1):69-81
The smoothed particle hydrodynamics (SPH) method was recently extended to simulate granular materials by the authors and demonstrated to be a powerful continuum numerical method to deal with the post-flow behaviour of granular materials. However, most existing SPH simulations of granular flows suffer from significant stress oscillation during the post-failure process, despite the use of an artificial viscosity to damp out stress fluctuation. In this paper, a new SPH approach combining viscous damping with stress/strain regularisation is proposed for simulations of granular flows. It is shown that the proposed SPH algorithm can improve the overall accuracy of the SPH performance by accurately predicting the smooth stress distribution during the post-failure process. It can also effectively remove the stress oscillation issue in the standard SPH model without having to use the standard SPH artificial viscosity that requires unphysical parameters. The predictions by the proposed SPH approach show very good agreement with experimental and numerical results reported in the literature. This suggests that the proposed method could be considered as a promising continuum alternative for simulations of granular flows. 相似文献
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采用同位素稀释ICP-MS测定法,对中国东海陆架及日本冲绳海槽的6个沉积物芯中U和Th的同位素地球化学行为进行了研究,以了解氧化还原敏感元素U在近海次氧化性沉积物中的蓄积行为,并评价其在全球海洋铀平衡中的意义。东海沉积物芯中,238U浓度及238U/232Th比值随深度变化不明显。但是在冲绳海槽沉积物芯中,238U浓度及238U/232Th比值在沉积芯表层氧化带显示较低值,然后在次氧化层随深度增加而增加。230Th和232Th浓度在所有沉积物芯中基本不随深度变化。这些结果说明,冲绳沉积物中有“自生铀”的蓄积过程发生,蓄积速率约为(47±5)～(90±8)ng/(cm2·a),与文献报道的世界其他海域次氧化性沉积区大致相当。进一步证明了U在近海次氧化性沉积区的蓄积对于全球海洋铀平衡有重要意义。“自生铀”的主要蓄积机制是海水U(Ⅵ)向沉积物迁移,在还原条件下被还原为惰性的U(Ⅳ)并被吸附在沉积物固体相上。 相似文献