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941.
942.
An intercomparison study of voltammetric and atomic absorption spectrometric methods for determining cadmium, lead and copper in seawater samples was conducted. The voltammetric approach utilizes differential pulse anodic stripping voltammetry using a rotating, glassy carbon, mercury film electrode under conditions developed to minimize contamination sources and to enhance sensitivity for seawater matrices. The atomic absorption approach involves a concentration step using either an organic solvent extraction of metal dithiocarbamate chelates or a Chelex-100 column with detection by graphite furnace atomic absorption spectrometry. Similar and consistent results were obtained using both methods for the three trace metals studied on a wide range of natural seawater samples. Both methods are comparable in sensitivity for cadmium and copper, however the voltammetric method is better suited for the analysis of lead in seawater because of its enhanced sensitivity and low blank. An advantage of the voltammetric approach is its amenability towards real-time shipboard analysis.  相似文献   
943.
Geomorphic, stratigraphic, and faunal observations of submarine slide scars that occur along the flanks of Monterey Canyon in 2.0–2.5 km water depths were made to identify the processes that continue to alter the surface of a submarine landslide scar after the initial slope failure. Deep-sea chemosynthetic biological communities and small caves are common on the sediment-free surfaces of the slide scars, especially along the headwall. The chemosynthetic organisms observed on slide scars in Monterey Canyon undergo a faunal succession based in part on their ability to maintain their access to the redox boundaries in the sediment on which they depend on as an energy source. By burrowing into the seafloor, these organisms are able to follow the retreating redox boundaries as geochemical re-equilibration occurs on the sole of the slide. As these organisms dig into the seafloor on the footwall, they often generate small caves and weaken the remaining seafloor. While chemosynthetic biological communities are typically used as indicators of fluid flow, these communities may be supported by methane and hydrogen sulfide that are diffusing out of the fresh seafloor exposed at the sole of the slide by the slope failure event. If so, these chemosynthetic biological communities may simply mark sites of recent seafloor exhumation, and are not reliable fluid seepage indicators.  相似文献   
944.
Mesoscale eddies are frequently observed in the Greenland and Barents Seas' marginal ice zone (MIZ). The objective of this study was to investigate the hypothesis that acoustic hotspots along the ice-edge region are due to mesoscale eddy currents interacting with the broken-up ice floes in the MIZ. To test this hypothesis, ambient-noise case studies were carried out during the MIZEX 85-87 and SIZEX 89 field experiments. In each experiment, ice-edge eddies were localized visually from aircraft and by use of satellite remote-sensing data obtained in near real time. Sonobuoys were, thereafter, deployed by fix-wing aircraft and helicopters in selected eddy areas. Ambient-noise data, recorded over several hours by aircraft, were analyzed estimating averaged ambient-noise levels at four selected frequencies: 40, 100, 315, and 1000 Hz. The analysis showed high mean levels and large gradients in ambient noise near ice-edge eddies and during strong wind and wave forcing against the ice edge. The conclusion of this study is that mapping of the ice edge and localization of mesoscale ocean processes using remote sensing from space will provide important input to ambient-noise prediction in the MIZ.  相似文献   
945.
This study presents the results of the decoupling of a free-roll decay test by wavelet transforms. A free-roll decay test was performed to determine the coefficients of damping terms in equations of motion. No motion of the model was restricted during the experiment. A slight yaw motion was found while the model was in the free-roll decay motion. It was necessary to extract a pure roll motion from the experimental data. Wavelet transforms were applied to the signals to extract the pure roll motion. The results were compared to those found through the Fourier transform. Discrete wavelet transforms were able to efficiently decouple the test signals, while the continuous wavelet transform and the Fourier transform could not.  相似文献   
946.
Cadmium, lead and copper have been determined in both dissolved and particulate phases for 130 surface-water samples from the coastal zone of Scotland and England in the western North Sea. The concentrations reported are, in general, lower than those published previously for the same area.The distribution of total metal concentration between the dissolved and particulate phases varies for the three elements. The lead distribution is dominated by its associations with particulate material while cadmium shows the reverse behaviour, existing almost totally in the dissolved phase. Copper is intermediate in behaviour, with the dissolved phase generally being dominant.An inverse relationship between salinity and dissolved copper concentration suggests a freshwater origin for this element. It is suggested that sedimentary and/or anthropogenic sources affect dissolved copper concentrations in coastal waters. The dissolved lead distribution reveals plumes of contaminated coastal water. The lead distribution is, however, dominated by associations with particulate material and sediments which produce a sharp concentration gradient close to the coast. The Humber estuary is identified as a significant source of cadmium to the North Sea.  相似文献   
947.
We study the problem of determination of the sound field of a point harmonic source in the coastal zone and the influence of a cylindrical body floating above the source on the sound field formed in the marine medium. A numerical-analytic method is proposed for the determination of the velocity potential. According to this method, the unknown coefficients in the general solution of the problem are determined from the corresponding infinite system of linear algebraic equations by the method of reduction. We present results of numerical calculations for a special case of a waveguide whose parameters are typical of the coastal part of the sea and perform the comparative analysis of the data obtained as a result of variation of the indicated parameters.  相似文献   
948.
Several mechanisms have been proposed to account for the rotation of the nearly north-south abyssal hill fabric formed on the East Pacific Rise north of the Easter Microplate to the nearly east-west trends in the northern microplate interior. Proposed mechanisms include rigid microplate rotation, transform fault – parallel shear, and bookshelf faulting during the transfer of lithosphere from the Nazca Plate to the microplate. We used a submersible magnetometer on a NAUTILE dive program to measure the magnetic vector rotation of a pillow basalt and dike spur near Pito Deep, the present location of the tip of the propagating rift system that created the microplate. Our results, although too limited to draw strong conclusions from, suggest clockwise rotations of the seafloor magnetic vectors inconsistent with the transform-parallel shear model, and larger than can be explained solely by rigid microplate rotation.  相似文献   
949.
Abundance and distribution of phytoplankton in seawater at southwestern East/Japan Sea near Gampo were investigated by HPLC analysis of photosynthetic pigments during summer of 1999. Detected photosynthetic pigments were chlorophyll a, b, c1+2 (Chl a, Chl b, Chl c1+2), fucoxanthin (Fuco), prasinoxanthin (Pras), zeaxanthin (Zea), 19’-butanoyloxyfucoxanthin (But-fuco) and beta-carotene (β-Car). Major carotenoid was fucoxanthin (bacillariophyte) and minor carotenoids were Pras (prasinophyte), Zea (cyanophyte) and But-fuco (chrysophyte). Chl a concentrations were in the range of 0.16-8.3/land subsurface chlorophyll maxima were observed at 0-10m at inshore and 30–50 m at offshore. Thermocline and nutricline tilted to the offshore direction showed a mild upwelling condition. Results from size-fraction showed that contribution from nano+picoplankton at Chl a maximum layer was increased from 18% at inshore to 69% at offshore on average. The maximum contribution from nano+picoplankton was found as 87% at St. E4. It was noteworthy that contribution from nano+picoplanktonic crysophytes and green algae to total biomass of phytoplankton was significant at offshore. Satellite images of sea surface temperature indicated that an extensive area of the East/Japan Sea showed lower temperature (<18 °C) but the enhanced Chl a patch was confined to a narrow coastal region in summer, 1999. Exceptionally high flux of low saline water from the Korea/Tsushima Strait seemed to make upwelling weak in summer of 1999 in the study area. Results of comparisons among Chl a from SeaWIFs, HPLC and fluorometric analysis showed that presence of Chl b cause underestimation of Chl a about 30% by fluorometric analysis but overestimation by satellite data about 30-75% compared to HPLC data.  相似文献   
950.
The extensive intertidal flats along Eighty-mile Beach in North-western Australia appear to be monotonous and homogeneous and seem ideally suited to study tidal zonation in macrozoo-benthic communities and their possible correlates with characteristics of the sediment. In October 1999, we sampled benthic invertebrates and sediments at a total of 895 sampling stations distributed over six different locations, each location separated by 15 km of unsampled foreshore along Eighty-mile Beach. To test for the presence or absence of patterns of tidal zonation (distinct height-related zones of specific sediment grain sizes or zoobenthic taxonomic groups) or patchiness (distinct patches of specific sediment grain sizes or zoobenthic taxonomic groups not related to tidal height) each location was divided into three along-shore sections and each section (transect) was examined at two or three tidal heights. Zonation was observed for sediment grain sizes. Sediments were coarser at the highest intertidal level and finer towards the low water line. Benthic assemblages also differed among tidal heights, but in terms of species-composition the differences were not consistent among the locations. Each location supported a unique collection of benthic invertebrates. Therefore the hypothesis of the presence of distinct zones of specific species or zoobenthic taxonomic groups was rejected; the presence of benthic patches was confirmed. The distribution of sediments and the composition of benthic assemblages were surprisingly poorly correlated compared to those reported in 12 previous quantitative studies around the world. One possible explanation might be that super-cyclone Vance, which hit the study-area only six months before this study, contributed to this poor correlation. Alternatively, the poor correlation may indicate that biotic interactions are more important than the assumed abiotic structuring.  相似文献   
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