Anthropogenic influence on trace element geochemistry of healing mud (peloid) from Makirina Cove (Croatia)     

S. Miko  G. Koch  S. Mesić  M. Šparica-Miko  M. Šparica  R. Čepelak  A. Bačani  P. Vreča  T. Dolenec  S. Bergant 《Environmental Geology》2008,55(3):517-537

Due to their balneotherapeutic features, the organic-rich sediments in Makirina Cove are an important source of healing mud. An environmental geochemistry approach using normalization techniques was applied to evaluate the anthropogenic contribution of trace metals to sediments used as healing mud. Sediment geochemistry was found to be associated with land-use change and storm events, as well as with proximity of a road with heavy traffic in the summer months. Local valley topography preferentially channels lithogenic and pollutant transport to the cove. Concentrations and distribution of trace metals indicate lithogenic (Ni, Cr, Co) and anthropogenic (Pb, Cu, Zn and Se) contributions to the sediments. The calculation of enrichment factors indicates a moderate (EFs between 2–3.5) input of anthropogenic Cu and Pb in surficial sediments to a depth of 10 cm. Patients using the Makirina Cove sediments as healing mud could be to some extent exposed to enhanced uptake of metals from anthropogenic sources via dermal contact.  相似文献   

The relationship between hydrodynamic properties and weathering of soils derived from volcanic rocks,Galapagos Islands (Ecuador)     

M. Adelinet  J. Fortin  N. d’Ozouville  S. Violette 《Environmental Geology》2008,56(1):45-58

The aim of this interdisciplinary study is to examine a component of the hydrological cycle in Galapagos by characterizing soil properties. Nine soil profiles were sampled on two islands. Their physical and hydrodynamic properties were analyzed, along with their mineralogical composition. Two groups of soils were identified, with major differences between them. The first group consists of soils located in the highlands (>350 m a.s.l.), characterized by low hydraulic conductivity (<10⁻⁵ m s⁻¹) and low porosity (<25%). These soils are thick (several meters) and homogeneous without coarse components. Their clay fraction is considerable and dominated by gibbsite. The second group includes soils located in the low parts of the islands (<300 m a.s.l.). These soils are characterized by high hydraulic conductivity (>10⁻³ m s⁻¹) and high porosity (>35%). The structure of these soils is heterogeneous and includes coarse materials. The physical properties of the soils are in good agreement with the variations of the rainfall according to the elevation, which appears as the main factor controlling the soil development. The clayey alteration products constrain soils physical and hydrodynamic properties by reducing the porosity and consequently the permeability and also by increasing water retention.  相似文献   

Mineralogy and geochemistry of the Texeo Cu–Co mine site (NW Spain): screening tools for environmental assessment     

J. Loredo  R. Álvarez  A. Ordóñez  T. Bros 《Environmental Geology》2008,55(6):1299-1310

The Cu–Co–Ni Texeo mine has been the most important source of Cu in NW Spain since Roman times and now, approximately 40,000 m³ of wastes from mine and metallurgical operations, containing average concentrations of 9,263 mg kg⁻¹ Cu, 1,100 mg kg⁻¹ As, 549 mg kg⁻¹ Co, and 840 mg kg⁻¹ Ni, remain on-site. Since the cessation of the activity, the abandoned works, facilities and waste piles have been posing a threat to the environment, derived from the release of toxic elements. In order to assess the potential environmental pollution caused by the mining operations, a sequential sampling strategy was undertaken in wastes, soil, surface and groundwater, and sediments. First, screening field tools were used to identify hotspots, before defining formal sampling strategies; so, in the areas where anomalies were detected in a first sampling stage, a second detailed sampling campaign was undertaken. Metal concentrations in the soils are highly above the local background, reaching up to 9,921 mg kg⁻¹ Cu, 1,373 mg kg⁻¹ As, 685 mg kg⁻¹ Co, and 1,040 mg kg⁻¹ Ni, among others. Copper concentrations downstream of the mine works reach values up to 1,869 μg l⁻¹ and 240 mg kg⁻¹ in surface water and stream sediments, respectively. Computer-based risk assessment for the site gives a carcinogenic risk associated with the presence of As in surface waters and soils, and a health risk for long exposures; so, trigger levels of these elements are high enough to warrant further investigation.  相似文献   

Numerical modeling assessment of three-gate structures for capturing contaminated groundwater     

Paul F. Hudak 《Environmental Geology》2008,55(6):1311-1317

This modeling study evaluated the capability of alternative funnel-and-gate structures with three gates for capturing contaminated groundwater in a hypothetical unconfined aquifer. Simulated interceptor structures were linear and 45 m wide, consisting of three gates and two funnels (walls). One gate occupied the center and two gates occupied the ends of the interceptor structures. The structures, positioned perpendicular to regional groundwater flow, traversed the entire thickness of the aquifer. A total of four structures were evaluated (numbers designate widths of end, center, and end gates, respectively, in meters): 3-3-3, 2-5-2, 1-7-1, and 4-1-4. Particle tracking and zonal water budgets identified shapes of capture zones and discharge patterns for each interceptor structure. A mass transport model, accounting for advection and hydrodynamic dispersion, tested the capability of each structure for capturing a contaminant plume. Results suggest that: time-dependent capture zones underestimate the amount of time to capture a contaminant plume, wide center gates facilitate plume capture, and wide end gates facilitate lateral containment of contaminants. Of the structures simulated, the 2-5-2 configuration was relatively efficient at processing and containing the simulated contaminant plume.  相似文献   

Regional distribution pattern of groundwater heavy metals resulting from agricultural activities   总被引：18，自引：0，他引：18  

J. Nouri  A. H. Mahvi  G. R. Jahed  A. A. Babaei 《Environmental Geology》2008,55(6):1337-1343

Contaminations of groundwater by heavy metals due to agricultural activities are growing recently. The objective of this study was to evaluate and map regional patterns of heavy metals (Cd, Zn and Cu) in groundwater on a plain with high agricultural activities. The study was conducted to investigate the concentration of heavy metals and distribution in groundwater in regions of Shush Danial and Andimeshk aquifers in the southern part of Iran. Presently, groundwater is the only appropriate and widely used source of drinking water for rural and urban communities in this region. The region covers an area of 1,100 km² between the Dez and Karkhe rivers, which lead to the Persian Gulf. For this study, the region was divided into four sub-regions A, B, C and D. Additionally, 168 groundwater samples were collected from 42 water wells during the earlier months of 2004. The flame atomic absorption spectrometry (AAS-Flame) was used to measure the concentration of heavy metals in water samples and the Surfer software was used for determination of the contour map of metal distribution. The results demonstrated that in all of the samples, Cd and Zn concentrations were below the EPA MCLG and EPA secondary standard, respectively. However, the Cu contents of 4.8 % of all samples were higher than EPA MCL. It is also indicated that the concentrations of metals were more pronounced at the southern part of the studied region than at the others. The analysis of fertilizers applied for agricultural activities at this region also indicated that a great majority of the above-mentioned heavy metals were discharged into the environment. Absence of confining layers, proximity to land surface, excess agricultural activities in the southern part and groundwater flow direction that is generally from the north to the southern parts in this area make the southern region of the Shush plain especially vulnerable to pollution by heavy metals than by other contaminants.  相似文献   

Groundwater recharge of carbonate aquifers of the Silesian-Cracow Triassic (southern Poland) under human impact     

Andrzej Kowalczyk  Andrzej J. Witkowski 《Environmental Geology》2008,55(2):235-246

A Triassic carbonate unit has been intensively drained by zinc and lead ore mines and numerous borehole fields since the nineteenth century. Its groundwater recharge has increased due to: pumping of water from boreholes, mining activity, and urbanization. An approach to determine the amounts of the recharge at a variety of spatial scales is presented in the paper. Different methods were used to identify and quantify recharge components on a regional and local scale: mathematical modelling was performed for four aquifers included in an aquifer system, an analytical estimation based on the assumption that an average recharge is equal to the average discharge of the hydrogeological system—for six man-made drainage centres, and the method of water level fluctuation (WLF) was applied in one observation borehole. Results of modelling have been supplemented by observation of environmental tracers (δ¹⁸O, δ²H, ³H), noble gases temperatures, and ⁴He_exc in groundwater. The regional aquifer’s current recharge according to estimations performed by means of modelling varies from 39 to 101 mm/year on average. Depending on the aquifer site the average precipitation ranges from 779 to 864 mm/year. In the confined part of the aquifer average recharge ranges from 26 to 61 mm/year. Within outcrops average recharge varies from 96 to 370 mm/year. Current recharge estimated by the analytical method for man-made drainage centres varies from 158 up to 440 mm/year. High values are caused by different recharge sources like precipitation, induced leakage from shallow aquifers, and water losses from streams, water mains and sewer systems. Pumping of water, mining and municipal activities constitute additional factors accounting for the intensified recharge.  相似文献   

Environmental risk evaluation of the use of mine spoils and treated sewage sludge in the ecological restoration of limestone quarries     

M. M. Jordán  S. Pina  F. García-Orenes  M. B. Almendro-Candel  E. García-Sánchez 《Environmental Geology》2008,55(2):453-462

The ecologic restoration criteria in areas degraded from extraction activities require making use of their mine spoils. These materials do not meet fertility conditions to guarantee restoration success and therefore, need the incorporation of organic amendments to obtain efficient substratum. Reducing the deficiencies in the organic material and restoration material nutrients with the contribution of treated sewage sludge is proposed in this work. This experiment was based on a controlled study using columns. The work was conducted with two mine spoils, both very rich in calcium carbonate. The first mineral, of poor quality, came from the formation of aggregates of crushed limestone (Z). The other residual material examined originated in limestone extraction, formed by the levels of interspersed non-limestone materials and the remains of stripped soils (D). Two treatments were undertaken (30,000 and 90,000 kg/ha of sewage sludge), in addition to a control treatment. The water contribution was carried out with a device that simulated either short-duration rain or a flooding irrigation system in order to cover the surface and then percolate through the soil. The collection of leached water took place 24 h after the applications. Different parameters of the leached water were determined, including pH, electrical conductivity, nitrate anions, ammonium, phosphates, sulphates and chlorides. The values obtained for each irrigation application are discussed, and the nitrate values obtained were very elevated.  相似文献   

Spatial data for landslide susceptibility, hazard, and vulnerability assessment: An overview   总被引：30，自引：0，他引：30  

Cees J. van Westen  Enrique Castellanos  Sekhar L. Kuriakose 《Engineering Geology》2008,102(3-4):112

The aim of this paper is to discuss a number of issues related to the use of spatial information for landslide susceptibility, hazard, and vulnerability assessment. The paper centers around the types of spatial data needed for each of these components, and the methods for obtaining them. A number of concepts are illustrated using an extensive spatial data set for the city of Tegucigalpa in Honduras. The paper intends to supplement the information given in the “Guidelines for Landslide Susceptibility, Hazard and Risk Zoning for Land Use Planning” by the Joint ISSMGE, ISRM and IAEG Technical Committee on Landslides and Engineered Slopes (JTC-1). The last few decades have shown a very fast development in the application of digital tools such as Geographic Information Systems, Digital Image Processing, Digital Photogrammetry and Global Positioning Systems. Landslide inventory databases are becoming available to more countries and several are now also available through the internet. A comprehensive landslide inventory is a must in order to be able to quantify both landslide hazard and risk. With respect to the environmental factors used in landslide hazard assessment, there is a tendency to utilize those data layers that are easily obtainable from Digital Elevation Models and satellite imagery, whereas less emphasis is on those data layers that require detailed field investigations. A review is given of the trends in collecting spatial information on environmental factors with a focus on Digital Elevation Models, geology and soils, geomorphology, land use and elements at risk.  相似文献   

Transient deterministic shallow landslide modeling: Requirements for susceptibility and hazard assessments in a GIS framework   总被引：12，自引：0，他引：12  

J.W. Godt  R.L. Baum  W.Z. Savage  D. Salciarini  W.H. Schulz  E.L. Harp 《Engineering Geology》2008,102(3-4):214

  相似文献   

Age of the Earth’s crust and the Nd isotopic composition of the mantle sources of East Antarctic complexes     

E. V. Mikhalsky 《Geochemistry International》2008,46(2):168-174

  相似文献