Distribution of As, Cr and V species in the Po-Adriatic mixing area, (Italy)   总被引：1，自引：0，他引：1  

M. Pettine  D. Mastroianni  M. Camusso  L. Guzzi  W. Martinotti 《Marine Chemistry》1997,58(3-4)

The distribution of dissolved and participate concentrations of As, Cr and V was investigated in the mixing area of the Po river in five surveys over the period March 1992-March 1995. The data obtained indicate noticeable contamination of coastal waters of the northern Adriatic with Cr but not As or V. Total dissolved concentrations for As and V were comparable with oceanic levels but were higher by a factor of 4 for Cr. These results suggest either low anthropogenic inputs of As and V, from terrigenous and atmospheric sources, or efficient removal mechanisms. The investigated metals had low reactivity during freshwater-seawater mixing and the distribution of concentrations in the dissolved and solid phases suggests that the dilution process is the main factor controlling the transport of these metals to the sea in low-to-medium solid transport conditions. Further investigations are required to elucidate the behavior of these metals during high solid transport conditions. Significant changes in the speciation of As occurred during the transition between the two end-member matrices. In the coastal waters of the northern Adriatic, the arsenite fraction in winter, and the arsenite and dimethylarsinate fractions in summer increased with respect to riverine waters. Changes in the speciation of chromium were minor, but also showed a small increase in reduced species in marine waters.  相似文献   

A residual analysis method for quantitative comparison of spatial data from the Iceland-Faeroes Front     

S. Aranuvachapun  S.J. Maskell 《Ocean Engineering》1997,24(8):721-741

A spatial statistical method has been developed from the well-known Kriging technique in geostatistics, as a way of providing quantitative comparison between a pair of spatial data sets, and a measure for such a comparison. This residual analysis method is applied to oceanographic data in order to compare Iceland-Faeroes Front (IFF) model predictions against appropriate field observations, with an aim to assess the IFF model performance and its prediction accuracy. The method is also used to evaluate the model-generated dynamical variability within the model predictions, as well as the natural variability within the frontal observations. From the results, it has been found that the IFF model is highly robust, and gives better predictions at depth 150–350 m than elsewhere. Within such a depth (i.e. 250–350 m), there is also evidence to suggest that the main frontal region is most active above the IF Ridge. The natural variability obtained from the observations appears to be comparable to the model-generated dynamical variability after 20 days of integration, indicating a certain degree of accuracy in the model predictions. The method reported in this paper could also be extended for further use in model data assimilation. Thus, the work not only demonstrates how spatial statistics can be applied to oceanographic data, but also opens up new statistical tools for data handling in ocean modelling.  相似文献   

Environmental overview of Eckernförde Bay,northern Germany     

T. H. Orsi  F. Werner  D. Milkert  A. L. Anderson  W. R. Bryant 《Geo-Marine Letters》1996,16(3):140-147

This environmental overview of Eckernförde Bay (northern Germany) summarizes the results of previous studies relevant to the Office of Naval Research's Coastal Benthic Boundary Layer (CBBL) Baltic field exercise conducted during 1993–1994. Significant environmental characteristics include the following: (1) surface sediment distribution is related to water depth, dictated primarily by hydrodynamic reworking of older glacial deposits; (2) the origin and characteristics of small-scale sedimentary structures depend on storm-generated waves and currents; (3) the proximity of the sea surface and sediment —water interface results in a pelagic—benthic coupling that drives biogeochemical processes and produces organicrich, acoustically turbid sediments; and (4) the bay floor is complicated topographically by pockmarks and manmade sedimentary structures.  相似文献   

The synchronous coupling of a third-generation wave model and a two-dimensional storm surge model     

M.Y. Zhang  Y.S. Li 《Ocean Engineering》1996,23(6):533-543

The interaction of waves and currents is studied by the dynamical coupling of a third generation wave model and a two-dimensional storm surge model. The coupling process of the two models is implemented synchronously. To estimate the effects of waves on the generation of storm surges, the theory of Janssen is used. The effects of the wave radiation stress on surge levels and the effects of storm-induced currents on waves are also investigated.The coupled wave and storm surge models have been tested by hindcasting two storm events in the northern South China Sea. The use of the Simth and Banke stress relation underestimates the surges by 10%. The inclusion of the radiation stress improves the accuracy of the computed results slightly by 2%. The introduction of a wave-dependent surface drag gives a significant improvement. The storm-induced currents clearly affect the wave characteristics at the peak stage. However, as far as the prediction of wave height is concerned, it is better not to consider the wave radiation stress in the storm surge model unless this is accompanied by a wave-dependent surface drag.  相似文献   

Three-dimensional visualization of mission planning and control forthe NPS autonomous underwater vehicle   总被引：1，自引：0，他引：1  

Zyda  M.J. McGhee  R.B. Kwak  S. Nordman  D.B. Rogers  R.C. Marco  D. 《Oceanic Engineering, IEEE Journal of》1990,15(3):217-221

The Naval Postgraduate School (NPS) is constructing a small autonomous underwater vehicle (AUV) with an onboard mission control computer. The mission controller software for this vehicle is a knowledge-based artificial intelligence (AI) system requiring thorough analysis and testing before the AUV is operational. The manner in which rapid prototyping of this software has been demonstrated by developing a controller code on a LISP machine and using an Ethernet link with a graphics workstation to simulate the controller's environment is discussed. The development of a testing simulator using a knowledge engineering environment (KEE) expert system shell that examines AUV controller subsystems and vehicle models before integrating them with the full AUV for its test environment missions is discussed. This AUV simulator utilizes an interactive mission planning control console and is fully autonomous once initial parameters are selected  相似文献   

Bacterial sulphate reduction in sediments of a european salt marsh: Acid-volatile and tin-reducible products     

D. B. Nedwell  S. Takii 《Estuarine, Coastal and Shelf Science》1988,26(6)

The products of ³⁵S-sulphate reduction by sedimentary bacteria were measured at two sites in a salt marsh on the east coast of England. Non-acid-volatile products were measured, after acid-volatile sulphide was removed, by their reduction to sulphide by digestion with tin. The proportion of the sulphate reduced to tin-reducible products varied between 25% in a salt marsh pan and 61% in creek sediment, over a 0–25 cm depth profile. There were also variations with depth at each site in the proportions of sulphate reduced to tin-reducible products. Further examination revealed differences in the proportions of sulphate which were reduced to free sulphide, acid-volatile sulphide, sulphur or pyrite at the two sites. The data suggest that previous work which did not measure non-acid-volatile products underestimated sulphate reduction rates by three-fold in the creek site, but by only one third in the pan.  相似文献   

Histopathological changes in the liver of dab (Limanda limanda) from a contamination gradient in the North sea     

Michael G. Simpson 《Marine environmental research》1992,34(1-4)

As part of a joint workshop organised by the International Council for the Exploration of the Sea (ICES) and the Intergovernmental Oceanographic Commission (IOC) on biological effects monitoring techniques. dad (Limanda limanda) were examined from six spaced stations along a 200 km transect extending from near the mouth of the Elbe River out to the Dogger Bank in the North Sea. Based on historical data, differences in contaminant concentrations in sediments exist along the transect (lipophilic organic xenobiotics at the inshore sites and heavy metals offshore over the Dogger Bank). The most contaminated site sampled was the most inshore, the least contaminated was approximately midway along the transect, with contamination building up again over the farthest point along the transect, over the Dogger Bank. Multiple organs and tissues were examined for full pathology from each fish sampled. Only liver data are presented here (11–20 livers per station). The most significant lesions were considered to be well-developed foci of cellular alteration, high mitotic activity and high neutral lipid accumulation in livers from dab sampled from the most inshore site examined. Livers from the least-contaminated station showed minimal evidence of such changes. Foci of cellular alteration and neutral lipid accumulation were also seen in dab liver sampled from fish from the Dogger Bank site. Thus far, the hepatic changes seen correlate well with the most contaminated sites along the transect. The value of comprehensively examining the histopathology of an organ of toxicological significance, such as the liver in a European species of flatfish, is demonstrated.  相似文献   

Species composition and biomasses of fishes in tropical seagrasses at Groote Eylandt, northern Australia     

S.J.M. Blaber  D.T. Brewer  J.P. Salini  J.D. Kerr  C. Conacher 《Estuarine, Coastal and Shelf Science》1992,35(6)

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Circulation and water properties of the southwest Indian Ocean, Spring 1987     

M.L. Gründlingh  R.A. Carter  R.C. Stanton 《Progress in Oceanography》1991,28(4)

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The distributions of particulate atmospheric trace metals and mineral aerosols over the Indian Ocean     

R. Chester  A. S. Berry  K. J. T. Murphy 《Marine Chemistry》1991,34(3-4)

Data are presented for the concentrations of Al, Fe, Mn, Ni, Co, Cr, V, Cu, Zn, Pb and Cd in aerosols collected over two contrasting regions of the Indian Ocean. These are: (1) the northern Arabian Sea (AS), from which samples were collected in the northeast monsoon, during which the region receives an input of crustal material from the surrounding arid land masses; and (2) the Tropical Southern Indian Ocean (TSIO), a remote region from which samples were collected from air masses for which there were no large-scale up-wind continental aerosol sources. The TSIO samples can be divided into two populations: Population I aerosols, collected from air masses which have probably impinged on Madagascar, and Population II aerosols, which have been confined to open-ocean regions to the south of the area.The data indicate that there are strong latitudinal variations in the chemical signatures of aerosols over the Indian Ocean. The input of crustal material to the Arabian Sea gives rise to an average Al concentration of about 1000 ng m⁻³ of air in the northeast monsoon regime. As a result, the concentrations of all trace metals are relatively high, and the values of crustal enrichment factors are less than 10 for most metals, in the AS aerosols. In contrast, TSIO Population II ‘open-ocean southern air’ sampled during the southwest monsoon season, has an average Al concentration of only about 10 ng m⁻³ of air. Trace metal concentrations in the TSIO ‘open-ocean southern air’ during the southwest monsoon season are representative of ‘clean’ remote marine air and are generally similar to those reported over the central North Pacific.Mineral dust concentrations over the Indian Ocean decrease in a north to south direction, from about 15–20 μg m⁻³ of air in the extreme north to about 0.01–0.25 μg m⁻³ of air in the far south. The deposition of mineral dust over the northern Arabian Sea can account for approximately 75% of the non-carbonate material incorporated into the underlying sediments.In the Arabian Sea the dissolved atmospheric inputs of all the trace metals, with the exception of Cu and Co, exceed those from fluvial run-off by factors which range from 9.6 for Pb to 1.6 for Cr.  相似文献