Preliminary Interlaboratory Trial for ISO/DIS 12010: Determination of Short Chain Polychlorinated Alkanes (SCCP) in Water     

Sabine Geiß  Nicole Lettmann  Aurélien Rey  Herbert Lepper  Birgit Körner  Silvio Mais  Theodor Prey  Bettina Hilger  Moana Engelke  Stephan Lebertz  Claudine Chatellier  George Sawal  Dirk Löffler  Tom Schillings 《洁净——土壤、空气、水》2011,39(6):537-542

A first preliminary interlaboratory trial was planned to prepare ISO/DIS 12010: Water quality – determination of short chain polychlorinated alkanes (SCCP) in water – method using GC/MS and electron capture negative ionisation (ECNI). The task was to determine the sum of short chain polychlorinated n‐alkanes with carbon chain lengths of C₁₀–C₁₃ and a chlorine content between 49 and 67% in water by GC‐ECNI‐MS and quantification by multiple linear regression described in ISO/DIS 12010 as the compulsory method. Distributed samples were obtained from a real water extract spiked with a target concentration of 0.4 µg/mL sum of SCCP, i.e. the environmental quality target level according to the Water Framework Directive. The interlaboratory trial included the calibration, a column chromatographic clean up, a concentration step and an integration of chromatographic unresolved humps as well as the quantification with multiple linear regression. Reproducibility standard deviations between 21.5 and 22.9% were achieved by 17 participating laboratories from four countries. The method outlined no significant difference of the results between the standard solution and a real water matrix extract. On the basis of this succeeded preliminary interlaboratory trial the final interlaboratory trial for validation of ISO 12010 was prepared in autumn 2010.  相似文献   

Sex-specific biochemical and histological differences in gonads of sea urchins (Psammechinus miliaris) and their response to phenanthrene exposure     

Schäfer S  Abele D  Weihe E  Köhler A 《Marine environmental research》2011,71(1):70-78

Female and male individuals of the same species often differ with respect to their susceptibility to toxicant stress. In the present study, sea urchins (Psammechinus miliaris) of both sexes were exposed to high (150 μg L?1) and environmentally relevant (5 μg L?1) concentrations of phenanthrene over 10 days. While food intake was significantly decreased following exposure to 150 μg L?1 phenanthrene, histological indices (lipofuscin accumulation, fibrosis, oocyte atresia), energetic status (energy charge, sum adenylates, AMP/ATP ratio) as well as ascorbate levels in the gonads showed either little or no effect upon phenanthrene exposure. However, most parameters (vitamin C, energy charge, sum adenylates, AMP/ATP ratio, ATP and ADP concentrations, lipofuscin content, fibrosis) significantly differed between male and female animals. This study illustrates the difficulties to identify toxic injury in reproductive tissue as it may be superimposed by gametogenesis and spawning of gametes.  相似文献   

Nutrient Inputs, Phytoplankton Response, and CO2 Variations in a Semi-Enclosed Subtropical Embayment, Kaneohe Bay, Hawaii     

Patrick Drupp  Eric Heinen De Carlo  Fred T. Mackenzie  Paul Bienfang  Christopher L. Sabine 《Aquatic Geochemistry》2011,17(4-5):473-498

The marine shelf areas in subtropical and tropical regions represent only 35% of the total shelf areas globally, but receive a disproportionately large amount of water (65%) and sediment (58%) discharges that enter such environments. Small rivers and/or streams that drain the mountainous areas in these climatic zones deliver the majority of the sediment and nutrient inputs to these narrow shelf environments; such inputs often occur as discrete, episodic introductions associated with storm events. To gain insight into the linked biogeochemical behavior of subtropical/tropical mountainous watershed-coastal ocean ecosystems, this work describes the use of a buoy system to monitor autonomously water quality responses to land-derived nutrient inputs and physical forcing associated with local storm events in the coastal ocean of southern Kaneohe Bay, Oahu, Hawaii, USA. The data represent 2.5 years of near-real time observations at a fixed station, collected concurrently with spatially distributed synoptic sampling over larger sections of Kaneohe Bay. Storm events cause most of the fluvial nutrient, particulate, and dissolved organic carbon inputs to Kaneohe Bay. Nutrient loadings from direct rainfall and/or terrestrial runoff produce an immediate increase in the N:P ratio of bay waters up to values of 48 and drive phytoplankton biomass growth. Rapid uptake of such nutrient subsidies by phytoplankton causes rapid declines of N levels, return to N-limited conditions, and subsequent decline of phytoplankton biomass over timescales ranging from a few days to several weeks, depending on conditions and proximity to the sources of runoff. The enhanced productivity may promote the drawing down of pCO₂ and lowering of surface water column carbonate saturation states, and in some events, a temporary shift from N to P limitation. The productivity-driven CO₂ drawdown may temporarily lead to air-to-sea transfer of atmospheric CO₂ in a system that is on an annual basis a source of CO₂ to the atmosphere due to calcification and perhaps heterotrophy. Storms may also strongly affect proximal coastal zone pCO₂ and hence carbonate saturation state due to river runoff flushing out high pCO₂ soil and ground waters. Mixing of the CO₂-charged water with seawater causes a salting out effect that releases CO₂ to the atmosphere. Many subtropical and tropical systems throughout the Pacific region are similar to Kaneohe Bay, and our work provides an important indication of the variability and range of CO₂ dynamics that are likely to exist elsewhere. Such variability must be taken into account in any analysis of the direction and magnitude of the air?Csea CO₂ exchange for the integrated coastal ocean, proximal and distal. It cannot be overemphasized that this research illustrates several examples of how high frequency sampling by a moored autonomous system can provide details about ecosystem responses to stochastic atmospheric forcing that are commonly missed by traditional synoptic observational approaches. Finally, the work exemplifies the utility of combining synoptic sampling and real-time autonomous observations to elucidate the biogeochemical and physical responses of coastal subtropical/tropical coral reef ecosystems to climatic perturbations.  相似文献   

Reviews on books,internet and scientific media     

Sabine Tesch 《Environmental Earth Sciences》2011,62(4):897-898

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Deciphering an Archean mantle plume: Abitibi greenstone belt,Canada     

Jaroslav Dostal  Wulf U. Mueller 《Gondwana Research》2013,23(2):493-505

The 2724–2722 Ma Stoughton-Roquemaure Group (SRG) of the Abitibi greenstone belt (the Archean Superior Province, Canada) is a ≤ 2 km thick komatiite–basalt succession intermittently exposed for about 50 km along strike. The ultramafic and mafic rocks occur mainly as pillowed, brecciated, and massive flows with well preserved spinifex textures in the komatiites. Volcanological, comparative stratigraphic and geochemical studies of the group along a volcanic marker horizon at the base of the succession allow the assessment of magma emplacement processes and mantle source rocks. Major feeder channels, secondary distributary tubes surrounded by pillowed flows with minor breccias and hyaloclastites display facies architecture of small volume flow fields (1–2 km³). Within the SRG, Al-depleted (ADK; Barberton-type) and Al-undepleted (AUK; Munro-type) komatiitic lavas are intercalated with tholeiitic basalt flows at a m- to 10s of m scale. Basalts and komatiites are inferred to be mantle plume-related; both rock types form two groups with characteristics of ADK and AUK including Al₂O₃/TiO₂ ~ 9–12 for ADK versus 17–22 for AUK, as well as (Gd/Yb)_n with > 1.3 versus ~ 1, respectively. The interdigitation of compositionally different flow units, limited extent of SRG volcanic rocks and facies architecture with the prevalence of small volume flows argue for a relatively small, heterogeneous mantle plume during the incipient stage of the evolution of the Archean Abitibi belt. Assuming that the scale of heterogeneities is comparable to the field expression of compositional changes and stratigraphy, it can be suggested that geochemical plume ‘layering’ is on 10s to 100s of m-scale. The evolution of this Archean mantle plume from inception to demise compares favorably with the Yellowstone hotspot which is assumed to have developed over 17 m.y. and had a diameter of about 300 km.  相似文献   

The last 40 ka tephrostratigraphic record of Lake Ohrid,Albania and Macedonia: a very distal archive for ash dispersal from Italian volcanoes     

B. Wagner  R. Sulpizio  G. Zanchetta  S. Wulf  M. Wessels  G. Daut  N. Nowaczyk 《Journal of Volcanology and Geothermal Research》2008

A 1075 cm long core (Lz1120) was recovered in the south-eastern part of the Lake Ohrid (Republics of Macedonia and Albania) and sampled for identification of tephra layers. Magnetic susceptibility investigations show rather high magnetic values throughout the core, with peaks unrelated to the occurrence of tephra layers but instead to the relative abundance of detrital magnetic minerals in the sediment. Naked-eye inspection of the core allowed us to identify of two tephra layers, at 896–897 cm and 1070–1075 cm. Laboratory inspection of the grain-size fraction > 125 μm allowed for the identification of a third cryptotephra at 310–315 cm. Major element analyses on glass shards of the tephra layers at 896–897 cm and 1070–1075 cm show a trachytic composition, and indicate a correlation with the regionally dispersed Y-3 and Y-5 tephra layers, dated at ca 30 and 39 cal ka BP. The cryptotephra at 310–315 cm has a mugearitic–benmoreitic composition, and was correlated with the FL eruption of Mt. Etna, dated at 3370 ± 70 cal yr BP. These ages are in agreement with five ¹⁴C AMS measurements carried out on plant remains and macrofossils from the lake sediments at different depths along the core.  相似文献   

The Y-3 tephra: A Last Glacial stratigraphic marker for the central Mediterranean basin     

G. Zanchetta  R. Sulpizio  B. Giaccio  G. Siani  M. Paterne  S. Wulf  M. D'Orazio 《Journal of Volcanology and Geothermal Research》2008

The paper reviews the existing data on the Y-3 tephra layer, first recognised in the Ionian Sea (Mediterranean basin). The collection and collation of old and new data on distal tephra occurrences in terrestrial, marine and lacustrine successions indicate that the Y-3 layer is dispersed over a wide area of the central Mediterranean basin. The peculiar homogeneous chemical composition of this layer makes its recognition rather straightforward and permits it being distinguished from other stratigraphically adjacent tephras. The best age estimate for the Y-3 layer of ca 30–31 cal ka BP, its peculiar stratigraphic position close to the Marine Isotope Stage 3/2 transition or Heinrich Event 3 onset, as well as its wide dispersion makes this layer an important marker to link and date late Pleistocene terrestrial and marine archives of the central Mediterranean basin.  相似文献   

Towards a detailed distal tephrostratigraphy in the Central Mediterranean: The last 20,000 yrs record of Lago Grande di Monticchio     

Sabine Wulf  Michael Kraml  Jörg Keller 《Journal of Volcanology and Geothermal Research》2008

A detailed compilation of distal tephrostratigraphy comprising the last 20,000 yrs is given for the Central Mediterranean region. A total of 47 distinct ash layers identified in the maar lake sediments of Lago Grande di Monticchio (Basilicata, Southern Italy) are compared with proximal and distal terrestrial-marine tephra deposits in the circum-central Mediterranean region. The results of these studies provide valuable information for reconstructing the Late Pleistocene and the Holocene dispersal of pyroclastic deposits from south Italian explosive volcanoes, in particular Somma-Vesuvius, the Campi Flegrei caldera, Ischia Island and Mount Etna. Prominent tephras are discussed with respect to their reliability as dating and correlation tools in sedimentary records. Ashes from Plinian eruptions of Somma-Vesuvius (i.e. Avellino, Mercato, Greenish, Pomici di Base), for instance, are well-defined by their distribution patterns and their unique composition. The widespread Y-1 tephra from Mount Etna, on the other hand, derived most likely from two distinct Plinian events with changing wind conditions, and therefore becomes a less reliable stratigraphic marker. Statistical–numerical calculations are presented in order to discriminate between Holocene tephras from the Campi Flegrei caldera (i.e. Astroni 1–3, Agnano Monte Spina, Averno 1, Lagno Amendolare), since these ashes are characterized by an almost indistinguishable chemical fingerprint. As a highlight, numerous Campanian eruptions of proposed low-intensity have been identified in the distal site of Monticchio suggesting a revision of existing tephra dispersal maps and re-calculation of eruptive conditions. In summary, the tephra record of Monticchio is one of the key successions for linking both, terrestrial records from Central-southern Italy and marine sequences from the Tyrrhenian, Adriatic and Ionian Seas.  相似文献   

Late Quaternary lake response to climate change and anthropogenic impact: biomarker evidence from Lake Constance sediments     

Sabine Hanisch  Martin Wessels  Frank Niessen  Antje Schwalb 《Journal of Paleolimnology》2009,41(3):393-406

This study used organic matter in oligotrophic Lake Constance (southern Germany) to reconstruct lake environment and to disentangle the multiple factors, such as climate change and human impacts, which influence sedimentation in large lakes. A sediment core from Upper Lake Constance, which represents 16,000 years of Late Glacial and Holocene lake history, was analysed for organic biomarkers, hydrogen index and elements calcium, strontium, and magnesium. Magnetic susceptibility was measured to establish a high-resolution stratigraphic framework for the core and to obtain further information about changes with respect to relative allochthonous versus autochthonous sedimentation. Dinosterol—a biomarker for dinoflagellates—and calcium have low concentrations in Younger Dryas sediments and consistently high concentrations between 10,500 and 7,000 cal. years BP. These variations are attributed to changes in lake productivity, but are not reflected in the proportion of total organic carbon within the sediment. During the Younger Dryas and between 6,000 and 2,800 cal. years BP, concentrations and accumulation rates of land-plant-derived C₂₉-steroids (β-sitosterol, stigmastanol and stigmasterol), in combination with a relatively low HI, indicate periods of enhanced terrigenous input to the lake. For the Younger Dryas, higher runoff can be attributed to a cold climate, leading to decreased vegetation cover and increased erosion. After 6,000 cal. years BP, high terrestrial input may be explained by enhanced precipitation. Biomarker and HI results, in combination with archaeological studies, raise the question as to whether lakeshore settlements affected sedimentation in Upper Lake Constance between 6,000 and 2,800 cal. years BP.  相似文献   

Competition between benthic and pelagic microalgae for phosphorus and light – long-term experiments using artificial substrates     

Annika Pasternak  Helmut Hillebrand  Sabine Flöder 《Aquatic Sciences - Research Across Boundaries》2009,71(2):238-249

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