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51.
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Fossil shark teeth and coprolites from three major phosphorite occurrences in the Gafsa Basin (southwestern Tunisia) were investigated for their geochemical compositions to improve local stratigraphy and to better assess paleoenvironmental conditions. 87Sr/86Sr isotope ratios of shark teeth from the Early Maastrichtian El Haria Formation and from the Early Eocene Métlaoui s.s. Formation yielded Sr isotope ages of 68 ± 1 and 47.9 ± 1.3 Ma, respectively, which accord with the expected stratigraphic positions of these sediments. Conversely, shark teeth from the Paleocene–Eocene Chouabine Formation have large variation in Sr isotope ratios even within individual layers. After statistical treatment and then elimination of certain outlier samples, three age-models are proposed and discussed. The most reasonable solution includes three subsequent Sr ages of 61.8 ± 2.2 Ma, 57.2 ± 1.8 and 54.6 ± 1.6 for layer IX, layers VIII–V and layers IV–0, respectively. Three scenarios are discussed for explanation of the presence of the outliers: (1) diagenesis, (2) re-working and (3) locally controlled seawater Sr isotope ratio. The most plausible account for the higher 87Sr/86Sr ratios relative to the global ocean in some fossils is enhanced intrabasinal re-working due to low sea level. Conversely, the sample with lower 87Sr/86Sr than the global seawater may link to diagenesis or to seawater influenced by weathering of Late Cretaceous marine carbonates, which latter is supported by model calculation as well. The εNd values of these fossils are very similar to those reported for Paleogene and Late Cretaceous Tethyan seawater and are compatible with the above interpretations. The relatively low oxygen isotope values in shark teeth from the topmost phosphate bed of the Chouabine Formation, together with the Sr isotope results, point toward recovering better connections with the open sea. These δ18O data reflect elevated ambient temperature, which may link to the Early Eocene Climatic Optimum.  相似文献   
53.
In southern Hodna, an arid region of Algeria, the extension of irrigated agriculture and overexploitation of groundwaters have led to a rupture with traditional land use by pastoralism. Due to the arid conditions, groundwaters are the only water resources for man and irrigation. This study focuses on nitrate contamination of groundwaters and its increase since the last 40 years, on the basis of two archives and recent analyses. The chemical facies of waters is sulphate-chloride, the risk of salinity is moderate to large. The sodicity risk, as estimated by the SAR, is low due to the large salinity and the sandy soil texture. Nitrate contamination of deep groundwater is a clear evidence when recent data are compared to the historical data. From 1996 to 2008, the proportion of samples with NO 3 ? concentrations larger than 50 mg/L increases from 24 to 61 %, the proportion of samples with NO 3 ? concentrations larger than 100 mg/L increases from 12 to 27 %. The study points at a general contamination of aquifers from anthropic origin: phreatic water was already contaminated when pastoralism was dominant (1967); as population increased and irrigation agriculture developed with large use of N-fertilizers and organic amendments, contamination extended spatially and vertically to deep aquifer. To remediate this contamination, fertilizers should be fractionated and limited to plant requirements on the basis of soil and plant analyses. Excess of irrigation should be avoided. Soil surface should be continuously covered to prevent nitrate leaching. Secondly, more efficient irrigation techniques, such as localized irrigation, should be implemented, with adaptation of crop systems and fertilizer inputs to arid conditions. Farmers should then be trained; simultaneously, local agronomic references that are presently lacking should be acquired.  相似文献   
54.
The main objective of this paper was the characterization of the reservoir (Abu Roash G dolomite) in terms of acoustic impedance from surface seismic data complemented by available well logs. To reach our target, a two-step procedure was followed: first, identification of the reservoir signatures using synthetic seismogram using Strata program in Hampson–Russell software and second, applying inversion technique to the post-stack seismic data using Strata program in Hampson–Russell software to obtain acoustic impedance profiles and maps. This procedure was applied to 12 3D seismic lines (six cross-lines, and six in-lines) from Horus field in Western Desert in Egypt after converting them from analog state to SEGY format by vectorization. Five wells had been used in this study. The outcome of this paper is an improved subsurface image of seismic data and achieving the reservoir characterization in a good way.  相似文献   
55.
Gulf of Suez consists mainly of three tectonic provinces that are separated by two accommodation zones. The southern edge of the gulf is bordered by N–S faults which mark the transition between the shallow water, Suez Basin and the deep northern Red Sea Basin. The sensitivity of coda Q measurements with respect to geological differences in the crust is demonstrated in three regions with a large variety of tectonic and geologic properties. The estimation of coda Q (Qc) is performed for 370 local earthquakes recorded at 12 digital seismic stations during the period from 2000 to 2007. The magnitudes of the earthquakes between 1.5 and ~4.5 have been used at central frequencies 1.5, 3, 6, 9, 12, 15, 18, and 24 Hz through three lapse time windows 10, 20, 30 s starting at once and twice the time of the primary S wave from the origin time. The time domain coda decay method of the single isotropic scattering model is employed to calculate frequency-dependent values of coda Q. The Qc values are frequency dependent in the range 1–25 Hz, and are approximated by a least squares fit to the power law [Qc(f) = Qo(f/fo]. The observed coda Q indicates that the area is seismically and tectonically active with high heterogeneities. The variation of the quality factor Qc has been estimated at different regions to observe the effect of different tectonic province. The average frequency-dependent estimated relations of Qc vary from 65f1.1 to 96f0.9 at 10 to 30 s window length, respectively. The decreasing value of the frequency parameter with increasing lapse time shows that the crust acquires homogeneity with depth. The variation of Qc with the variations in the geologic and tectonic properties of the crust was investigated. The frequency exponent η might be larger in active tectonic areas and smaller in more stable regions. In the northern region of the Gulf of Suez, the obtained value of η?=?0.8?±?0.011, which might indicate a low level of tectonic activity compared with η?=?1.1?±?0.005 and 1.3?±?0.009 for the central and southern regions of the gulf.  相似文献   
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Catechol is one of the most abundant phenolic components of olive mill wastewaters. In this article, the mineralization of this compound in synthetic aqueous solutions by the Fenton and photo‐Fenton processes is studied. It has been found that for 1.44 mM catechol, the total organic carbon of solutions is reduced about 94.4% at best after 60 min of Fenton treatment at optimized conditions of pH 3.0, 0.2 mM Fe2+, 7.09 mM H2O2, and 25°C. A faster and overall mineralization is attained by applying photo‐Fenton with UVA irradiation. o‐Benzoquinone, 1,2,3‐trihydroxybenzene and 1,2,4‐trihydroxybenzene were identified by GC–MS as primary quinonic and polyhydroxylated derivatives. Small amounts of generated carboxylic acids like muconic, maleic, malonic, acetic, oxalic, and formic acids were detected by ion‐exclusion chromatography. The Fe(III) complexes of these acids persist in the medium under Fenton conditions, while their photolysis by UVA light and that of other by‐products account for by the faster degradation and total mineralization achieved in the photo‐Fenton process. A reaction sequence for catechol mineralization by Fenton and photo‐Fenton involving all intermediates detected is proposed.  相似文献   
58.
Stepwise extraction and molecular analysis of non-recoverable oil from intact reservoir core plugs is used to provide constraints on the accumulation history of petroleum in the Permo-Carboniferous Unayzah reservoirs at the Ghazal Field, Saudi Arabia. When integrated with existing tools such as oil geochemistry, gas geochemistry, stable carbon isotopes, fluid inclusions and thermal modeling, the sequential extraction approach helped decode a previously unrecognized component of the hydrocarbon accumulation history. In particular, it indicates that the region received early petroleum charges that were less mature than currently produced light oil and gas condensates, possibly from the prolific Early Silurian Qusaiba shale source rock and other sources. This has significant implications for prospecting for additional oil, particularly in the north/northwest of the Ghazal region where paleo-oil accumulations may have been displaced or spilled. The lower portion of the Unayzah reservoir (Unayzah-C) remained water-wet during early filling of the upper reservoir unit (Unayzah-A) and appears to have been filled only by a late oil charge. Anomalous molecular and carbon isotopic behavior of residual oil extracts from the uppermost segment of the Unayzah reservoir, where the free oil (first of the sequential extracts) is less mature (0.95% Rc) and isotopically lighter (δ13C?31.15‰) than the adsorbed oil (last sequential extract, 1.05% Rc; δ13C?29.65‰), suggests a late oil contribution or bitumen contamination from the overlying Khuff Formation.  相似文献   
59.
A new geomatics-based approach for flood prediction was developed and used to model the magnitude and spatial extent of a future Red River flood in southern Manitoba. This approach combines the statistical modelling capabilities of Markov (non-spatial) analysis and logistic regression (spatial) within a geographic information system (GIS) environment, utilizing modelling inputs derived from remotely sensed RADARSAT imagery and other digital geographic data. The 1997 Red River flood was the second largest in recorded history, and the largest for which accurate data are available. The results indicate: (i) a flood “one time interval-in terms of 3 days time unit measurement- larger in area” than the 1997 flood is expected to affect 17.6% more land (an additional 47.6 km2) within the study area compared to 1997 levels based on Markovian probability derived from observations from the 1997 event; and (ii) the majority of this excess flooding will take place on agricultural land; no additional communities are expected to be at risk. Quantitative assessment verified the capability of this modelling approach for producing statistically significant results. The methodology used in this research would be easily transferable to other areas, and may provide the basis for a viable alternative to conventional hydrologic-based flood prediction approaches This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   
60.
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