Heavy metals pollution of aquatic ecosystems in the vicinity of a recently closed underground lead-zinc mine (Basque Country, Spain)   总被引：3，自引：0，他引：3  

M. Marqués  E. Martínez-Conde  J. Rovira  S. Ordóñez 《Environmental Geology》2001,40(9):1125-1137

A presentation is made of the study of an underground polymetallic sulphide mine and the pollution caused by this in the adjoining aquatic ecosystems. Troya Mine is in the Basque Cantabrian region (northern Spain). The annual production of the ore deposit of over 3.7 million tons of Pb (0.9%), Zn (11.2%) and Cu (0.2%) was 300,000 t. It was open and producing from 1986-1993. The mineralization was made up of pyrite, marcasite, sphalerite, galena, chalcopyrite and arsenopyrite. Only the Zn and the Pb were mined. We studied the distribution and behaviour of the heavy metals Zn, Pb, Fe, Mn, Cu, Cr and Cd in the water column, dissolved and suspended fractions, and in the sediments of Estanda Stream and of Gezala Creek. Zn, Cd and Mn tend to be found in the water; Fe, Pb, Cu and Cr appear as an adsorbed fractionin the solid phases. Those of the second group are significantly linked to the fluvial sediments and present very high levels. The concentrations of the metals are conditioned by the waters from the mine galleries, by the leached waste, by the surface runoff, and by overflow from the spillway of the tailings pond. Our observations provide knowledge on the extent of the polluting power of the metals, the physico-chemical effects in play and the subsequent chances of recovering these highly affected environments.  相似文献   

Petrographic and geochemical evidence for the formation of primary, bacterially induced lacustrine dolomite: La Roda 'white earth' (Pliocene, central Spain)   总被引：1，自引：0，他引：1  

M. Angeles García Del Cura  Jose P. Calvo  Salvador Ordóñez  Blair F. Jones  & Juan C. Cañaveras 《Sedimentology》2001,48(4):897-915

Upper Pliocene dolomites (‘white earth’) from La Roda, Spain, offer a good opportunity to evaluate the process of dolomite formation in lakes. The relatively young nature of the deposits could allow a link between dolomites precipitated in modern lake systems and those present in older lacustrine formations. The La Roda Mg‐carbonates (dolomite unit) occur as a 3·5‐ to 4‐m‐thick package of poorly indurated, white, massive dolomite beds with interbedded thin deposits of porous carbonate displaying root and desiccation traces as well as local lenticular gypsum moulds. The massive dolomite beds consist mainly of loosely packed 1‐ to 2‐μm‐sized aggregates of dolomite crystals exhibiting poorly developed faces, which usually results in a subrounded morphology of the crystals. Minute rhombs of dolomite are sparse within the aggregates. Both knobbly textures and clumps of spherical bodies covering the crystal surfaces indicate that bacteria were involved in the formation of the dolomites. In addition, aggregates of euhedral dolomite crystals are usually present in some more clayey (sepiolite) interbeds. The thin porous carbonate (mostly dolomite) beds exhibit both euhedral and subrounded, bacterially induced dolomite crystals. The carbonate is mainly Ca‐dolomite (51–54 mol% CaCO₃), showing a low degree of ordering (degree of ordering ranges from 0·27 to 0·48). Calcite is present as a subordinate mineral in some samples. Sr, Mn and Fe contents show very low correlation coefficients with Mg/Ca ratios, whereas SiO₂ and K contents are highly correlated. δ¹⁸O‐ and δ¹³C‐values in dolomites range from ?3·07‰ to 5·40‰ PDB (mean=0·06, σ=1·75) and from ?6·34‰ to ?0·39‰ PDB (mean=?3·55, σ=1·33) respectively. Samples containing significant amounts of both dolomite and calcite do not in general show significant enrichment or depletion in ¹⁸O and ¹³C between the two minerals. The correlation coefficient between δ¹⁸O and δ¹³C for dolomite is extremely low and negative (r=?0·05), whereas it is higher and positive (r=0·47) for calcite. The lacustrine dolomite deposit from La Roda is interpreted mainly as a result of primary precipitation of dolomite in a shallow, hydrologically closed perennial lake. The lake was supplied by highly saturated HCO₃^?/CO₃^2? groundwater that leached dolomitic Mesozoic formations. Precipitation of dolomite from alkaline lake waters took place under a semi‐arid to arid climate. However, according to our isotopic data, strong evaporative conditions were not required for the formation of the La Roda dolomite. A significant contribution by bacteria to the formation of the dolomites is assumed in view of both petrographic and geochemical evidence.  相似文献   

Analyzing ice dynamics using Sentinel-1 data at the Solheimajoküll Glacier,Iceland     

Diego Gómez  Pablo Salvador  Julia Sanz  Mikhail Urbazaev  José Luis Casanova 《地理信息系统科学与遥感》2020,57(6):813-829

ABSTRACT

The climate in southern Iceland has warmed over the last 70 years, resulting in accelerated glacier dynamics at the Solheimajoküll glacier. In this study, we compare glacier terminus locations from 1973 to 2018, to changes in climate across the study area, and we derive ice-surface velocities (2015–2018) from satellite remote-sensing imagery (Sentinel-1) using the offset-tracking method. There have been two regional temperature trends in the study period: cooling (1973–1979) and warming (1980–2018). Our results indicate a time lag of about 20 years between the onset of glacier retreat (?53 m/year since 2000) and the inception of the warming period. Seasonally, the velocity time series suggest acceleration during the summer melt season since 2016, whereas glacier velocities during accumulation months were constant. The highest velocities were observed at high elevations where the ice-surface slope is the steepest. We tested several scenarios to assess the hydrological time response to glacier accelerations, with the highest correlations being found between one and 30 days after the velocity estimates. Monthly correlation analyses indicated inter-annual and intra-annual variability in the glacier dynamics. Additionally, we investigate the linkage between glacier velocities and meltwater outflow parameters as they provide useful information about internal processes in the glacier. Velocity estimates positively correlate with water level and negatively correlate with water conductivity between April and August. There is also a disruption in the correlation trend between water conductivity and ice velocity in June, potentially due to a seasonal release of geothermal water.  相似文献   

Dispersion measure variations and their effect on precision pulsar timing     

X. P. You  G. Hobbs  W. A. Coles  R. N. Manchester  R. Edwards  M. Bailes  J. Sarkissian  J. P. W. Verbiest  W. van Straten  A. Hotan  S. Ord  F. Jenet  N. D. R. Bhat  A. Teoh 《Monthly notices of the Royal Astronomical Society》2007,378(2):493-506

We present an analysis of the variations seen in the dispersion measures (DMs) of 20-ms pulsars observed as part of the Parkes Pulsar Timing Array project. We carry out a statistically rigorous structure function analysis for each pulsar and show that the variations seen for most pulsars are consistent with those expected for an interstellar medium characterized by a Kolmogorov turbulence spectrum. The structure functions for PSRs J1045−4509 and J1909−3744 provide the first clear evidence for a large inner scale, possibly due to ion–neutral damping. We also show the effect of the solar wind on the DMs and show that the simple models presently implemented into pulsar timing packages cannot reliably correct for this effect. For the first time we clearly show how DM variations affect pulsar timing residuals and how they can be corrected in order to obtain the highest possible timing precision. Even with our presently limited data span, the residuals (and all parameters derived from the timing) for six of our pulsars have been significantly improved by correcting for the DM variations.  相似文献   

Labour and residential accessibility: a Bayesian analysis based on Poisson gravity models with spatial effects   总被引：1，自引：1，他引：0  

M. P. Alonso  M. A. Beamonte  P. Gargallo  M. J. Salvador 《Journal of Geographical Systems》2014,16(4):409-439

In this study, we measure jointly the labour and the residential accessibility of a basic spatial unit using a Bayesian Poisson gravity model with spatial effects. The accessibility measures are broken down into two components: the attractiveness component, which is related to its socio-economic and demographic characteristics, and the impedance component, which reflects the ease of communication within and between basic spatial units. For illustration purposes, the methodology is applied to a data set containing information about commuters from the Spanish region of Aragón. We identify the areas with better labour and residential accessibility, and we also analyse the attractiveness and the impedance components of a set of chosen localities which allows us to better understand their mobility patterns.  相似文献   

Influence of olive mill waste application on the role of soil as a carbon source or sink     

R. Carbonell-Bojollo  R. Ordóñez-Fernández  A. Rodríguez-Lizana 《Climatic change》2010,102(3-4):625-640

Organic matter (OM) is involved in the enhancement of soil quality since it acts on soil structure, nutrient storage and biological activity. Organic carbon (OC), the dominant element constituent of OM, and related soil properties are probably the most widely acknowledged indicator of soil quality. The typically Mediterranean climate of the South of Spain promotes low yields on crops and low organic carbon in soil. The present work was carried out to evaluate the effect of the application of alperujo, olive oil waste difficult to eliminate, on the fixation or emission of carbon on soil in an olive grove situated in Montoro (Córdoba, Spain). In the study three treatments were considered: 15 kg (A), 7.5 kg (B), 0 kg (C) of alperujo per tree and the implementation of the amendment has been made for three consecutive years. The results confirm the benefits of the amendment on the carbon content organic soil with a fixation with respect to control of 4.8 and 6.1 t ha^???1 for the first year and 8.7 and 6.8 t ha^???1 for the second in treatments A and B, respectively. Of the different climatic agents considered in the study, it was the temperature which had a major influence on the emissions of CO₂ into the atmosphere and the flow of gas presented the highest values in soils treated with the highest dose.  相似文献   

Chemical and biological transport in deforming porous media     

A. Ord  G. Metcalfe  M. Trefry  D. Lester  P. Kulkarni  S. Kesari  B. Hobbs  M. Rudman  P. Hornby 《Journal of Geochemical Exploration》2009

  相似文献   

Emergence in crustal plumbing systems     

Bruce E. Hobbs  Alison Ord  Chongbin Zhao 《Journal of Geochemical Exploration》2009

  相似文献   

MSC certification in Argentina: Stakeholders’ perceptions and lessons learned     

Mónica Pérez-Ramírez  Salvador Lluch-Cota  Mario Lasta 《Marine Policy》2012

Marine Stewardship Council (MSC) certification is a market-based incentive program recognizing well-managed fisheries. Currently, four Argentine fisheries are involved in the MSC program. Using in-depth, semi-structured interviews with fishery stakeholders, the study surveys their perceptions regarding MSC certification. MSC certification is positively perceived because stakeholders focus on knowledge of the process. Most respondents consider certification as encouraging effective fishery stakeholders’ participation: access to information, increased communication, and reaching consensus. Market/political/social realities will prove whether a more intense participation of Argentine fisheries in the certification initiative is useful. Because some markets in the EU and USA are demanding MSC certified products, there is a need to work towards a governance structure that helps link certification with policy market outcomes to ensure exportation of Argentine fish. MSC certification may suggest improved management of participatory bottom-up planning. This bottom-up approach provides an opportunity to establish feedback mechanisms and organizational changes.  相似文献   

Shaking‐table tests of flat‐bottom circular silos containing grain‐like material          下载免费PDF全文

Stefano Silvestri  Salvador Ivorra  Laura Di Chiacchio  Tomaso Trombetti  Dora Foti  Giada Gasparini  Luca Pieraccini  Matt Dietz  Colin Taylor 《地震工程与结构动力学》2016,45(1):69-89

According to Eurocode 8, the seismic design of flat‐bottom circular silos containing grain‐like material is based on a rough estimate of the inertial force imposed on the structure by the ensiled content during an earthquake: 80% of the mass of the content multiplied by the peak ground acceleration. A recent analytical consideration of the horizontal shear force mobilised within the ensiled material during an earthquake proposed by some of the authors has resulted in a radically reduced estimate of this load suggesting that, in practice, the effective mass of the content is significantly less than that specified. This paper describes a series of laboratory tests that featured shaking table and a silo model, which were conducted in order to obtain some experimental data to verify the proposed theoretical formulations and to compare with the established code provisions. Several tests have been performed with different heights of ensiled material – about 0.5 mm diameter Ballotini glass – and different magnitudes of grain–wall friction. The results indicate that in all cases, the effective mass is indeed lower than the Eurocode specification, suggesting that the specification is overly conservative, and that the wall–grain friction coefficient strongly affects the overturning moment at the silo base. At peak ground accelerations up to around 0.35 g, the proposed analytical formulation provides an improved estimate of the inertial force imposed on such structures by their contents. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献