Regional metamorphism of some Dalradian pelites in the Buchan area,N.E. Scotland     

Neil F. C. Hudson 《Contributions to Mineralogy and Petrology》1980,73(1):39-51

Regional metamorphic zones, based on mineral assemblages in pelites, are presented for the Dalradian rocks of Aberdeenshire and Banffshire, in the type area of Buchan metamorphism; electron microprobe analyses of cordierite (C), staurolite (S), chlorite (Chl), biotite (B) and white mica (Ms) are reported for rocks from the classic sections of the Banffshire coast and the valley of the Ythan.A low grade biotite zone, separates two NE-SW trending sets of higher grade zones, in which the sequence s defined by the entry of cordierite, andalusite (A) and (in the west only) staurolite. The zones are characterised by the assemblages (with quartz and muscovite) B-Chl, C-B-Chl, A-C-B and S-A-B.The western sequence contains a transition towards higher pressure, Barrovian type, metamorphism. The isograds arise from continuous reactions affecting rocks of restricted bulk composition (M/FM). With increasing grade, there is a regular trend towards more magnesian ranges of composition for the assemblages C-B-Chl, A-C-B and finally (as P increases in the west), S-A-B. The isograds form when these assemblages intersect the most Fe⁺⁺-rich rock compositions present which occurs in each case when the biotite M/FM=40. A complex of divariant equilibria, derived for the system KFMASH, is used to model the natural reactions.  相似文献   

Crystallization of chromite from nickel-iron sulphide melts     

W. E. Ewers  J. Graham  D. R. Hudson  J. M. Rolls 《Contributions to Mineralogy and Petrology》1976,54(1):61-64

An experiment, in which an iron-nickel-copper sulphide melt was heated with synthetic chromite and then cooled, showed that substantial quantities of chromite had dissolved in the melt and had then recrystallized as euhedral crystals rimmed with magnetite. This experiment suggests that the unusual chromite (low in Mg and Al) which is associated with the sulphide phase in Western Australian nickel ores may have formed in a similar way.J.M.R. carried out the experimental part of this investigation as a post-graduate student at Flinders University, South Australia, working under a CSIRO extramural grant.  相似文献   

Differential-Head–Lake-Level Relationships in the Middle-Gulf Area, Florida     

H. E. Hudson  Jr 《Ground water》1976,14(5):278-282

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Late Pleistocene glaciation of Páramo de La Culata,north-central Venezuelan Andes     

Dr. Carlos Schubert  Mr. Sam Valastro 《International Journal of Earth Sciences》1974,63(2):516-538

Late Pleistocene glacial features in the Páramo de La Culata region, north-central Venezuelan Andes, include: 1. depositional features: morainic till and fluvio-glacial deposits (terrace gravels); 2. sculptured features: glaciated valleys, cirques, horns, and arêtes; and 3. erosional features: striation and grooving, polished rock, roches moutonnées and whaleback forms, and erratic boulders. Two main levels of moraines were found, an older one at 2600 m elevation, and a younger one between 3000 and 3500 m. The difference in age is reflected by the higher degree of weathering, erosion, and vegetation cover of the lower level, as compared with the higher level. Radiocarbon dating, and a comparison and correlation of these glacial features with those of adjacent regions, indicates that the lower morainic level (2600 m) is probably the result of the main glacial advance of the Late Wisconsin Glaciation. The main morainic level (3000 to 3500 m) was probably formed by the latest Wisconsin glacial advance. The Late Pleistocene snow-line depression reached approximately 1200 m below the present snow-line (i. e., down to approximately 3500 m).  相似文献   

The formation and stability of carbonic acid on outer Solar System bodies     

Z. Peeters  R.L. Hudson  M.H. Moore 《Icarus》2010,210(1):480-487

The radiation chemistry, thermal stability, and vapor pressure of solid-phase carbonic acid (H₂CO₃) have been studied with mid-infrared spectroscopy. A new procedure for measuring this molecule’s radiation stability has been used to obtain intrinsic IR band strengths and half-lives for radiolytic destruction. We report, for the first time, measurements of carbonic acid’s vapor pressure (0.290-2.33 × 10⁻¹¹ bar for 240-255 K) and its enthalpy of sublimation (71 ± 9 kJ mol⁻¹). We also report the first observation of a chemical reaction involving solid-phase carbonic acid. Possible applications of these findings are discussed, with an emphasis on the outer Solar System icy surfaces.  相似文献   

ENSO,the IOD and the intraseasonal prediction of heat extremes across Australia using POAMA-2     

Christopher J. White  Debra Hudson  Oscar Alves 《Climate Dynamics》2014,43(7-8):1791-1810

The simulation and prediction of extreme heat over Australia on intraseasonal timescales in association with the El Niño–Southern Oscillation (ENSO) and the Indian Ocean Dipole (IOD) is assessed using the Bureau of Meteorology’s Predictive Ocean Atmosphere Model for Australia (POAMA). The analysis is based on hindcasts over 1981–2010 and focuses on weeks 2 and 3 of the forecasts, i.e. beyond a typical weather forecast. POAMA simulates the observed increased probabilities of extreme heat during El Niño events, focussed over south eastern and southern Australia in SON and over northern Australia in DJF, and the decreased probabilities of extreme heat during La Niña events, although the magnitude of these relationships is smaller than observed. POAMA also captures the signal of increased probabilities of extreme heat during positive phases of the IOD across southern Australia in SON and over Western Australia in JJA, but again underestimates the strength of the relationship. Shortcomings in the simulation of extreme heat in association with ENSO and the IOD over southern Australia may be linked to deficiencies in the teleconnection with Indian Ocean SSTs. Forecast skill for intraseasonal episodes of extreme heat is assessed using the Symmetric Extremal Dependence Index. Skill is highest over northern Australia in MAM and JJA and over south-eastern and eastern Australia in JJA and SON, whereas skill is generally poor over south-west Western Australia. Results show there are windows of forecast opportunity related to the state of ENSO and the IOD, where the skill in predicting extreme temperatures over certain regions is increased.  相似文献   

Optimal water depth management on river-fed National Wildlife Refuges in a changing climate     

Sam Nicol  Brad Griffith  Jane Austin  Christine M. Hunter 《Climatic change》2014,124(1-2):271-284

The prairie pothole region (PPR) in the north-central United States and south-central Canada constitutes the most important waterfowl breeding area in North America. Projected long-term changes in precipitation and temperature may alter the drivers of waterfowl abundance: wetland availability and emergent vegetation cover. Previous studies have focused on isolated wetland dynamics, but the implications of changing precipitation on managed, river-fed wetlands have not been addressed. Using a structured decision making (SDM) approach, we derived optimal water management actions for 20 years at four river-fed National Wildlife Refuges (NWRs) in North and South Dakota under contrasting increasing/decreasing (+/?0.4 %/year) inflow scenarios derived from empirical trends. Refuge pool depth is manipulated by control structures. Optimal management involves setting control structure heights that have the highest probability of providing a desired mix of waterfowl habitat, given refuge capacities and inflows. We found optimal seasonal control structure heights for each refuge were essentially the same under increasing and decreasing inflow trends of 0.4 %/year over the next 20 years. Results suggest managed pools in the NWRs receive large inflows relative to their capacities. Hence, water availability does not constrain management; pool bathymetry and management tactics can be greater constraints on attaining management objectives than climate-mediated inflow. We present time-dependent optimal seasonal control structure heights for each refuge, which are resilient to the non-stationary precipitation scenarios we examined. Managers can use this information to provide a desired mixture of wildlife habitats, and to re-assess management objectives in reserves where pool bathymetry prevents attaining the currently stated objectives.  相似文献   

Quality assessment and hydrogeochemical characteristics of groundwater in Agastheeswaram taluk,Kanyakumari district,Tamil Nadu,India     

Y. Srinivas  Oliver D. Hudson  Raj A. Stanley  N. Chandrasekar 《中国地球化学学报》2014,33(3):221-235

The present study investigates the hydrogeochemical characteristics of groundwater quality in Agas- theeswaram taluk of Kanyakumari district, Tamil Nadu, India. A total of 69 groundwater samples were collected during pre- and post-monsoon periods of 2011-2012. The groundwater quality assessment has been carried out by evaluating the physicochemical parameters such as pH, EC, TDS, HCO3, Cl, SO42-, Ca2＋, Mg2＋, Na＋ and K＋ for both the seasons. Based on these parameters, groundwater has been assessed in favor of its suitability for drinking and irrigation purpose. Dominant cations for both the seasons are in the order of Na＋〉 Ca2＋〉 Mg2＋ 〉 K＋ while the dominant anions for post monsoon and pre monsoon have the trends of CI 〉 HCO3 〉 SO42- and HCO3- 〉 CI 〉 SO42-, respectively. Analytical results observed from various indices reveal that the groundwater quality is fairly good in some places. Analytical results of few samples show that they are severely polluted and incidentally found to be near the coasts, estuaries and salt pans in the study area. The Gibbs plot indicates that the majority of groundwater samples fall in rock dominant region, which indicates rock water interaction in the study area. The United States salinity （USSL） diagram shows that the groundwater is free from sodium hazards but the salinity hazard varies from low to very high throughout the study area. This reveals that the groundwater is moderately suitable for agricultural activities. The observed chemical variations in pre-monsoon and post-monsoon seasons may be the effect to rock-water interactions, ion-exchange reactions, and runoff of fertilizers from the surrounding agricultural lands.  相似文献   

A comparison of local Type Ia supernovae with the IRAS PSCz gravity field     

D. J. Radburn-Smith  J. R. Lucey  M. J. Hudson 《Monthly notices of the Royal Astronomical Society》2004,355(4):1378-1382

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Reactions of nitriles in ices relevant to Titan, comets, and the interstellar medium: formation of cyanate ion, ketenimines, and isonitriles     

R.L. Hudson  M.H. Moore 《Icarus》2004,172(2):466-478

Motivated by detections of nitriles in Titan's atmosphere, cometary comae, and the interstellar medium, we report laboratory investigations of the low-temperature chemistry of acetonitrile, propionitrile, acrylonitrile, cyanoacetylene, and cyanogen (CH₃CN, CH₃CH₂CN, CH₂CHCN, HCCCN, and NCCN, respectively). A few experiments were also done on isobutyronitrile and trimethylacetonitrile ((CH₃)₂CHCN and (CH₃)₃CCN, respectively). Trends were sought, and found, in the photo- and radiation chemical products of these molecules at 12-25 K. In the absence of water, all of these molecules isomerized to isonitriles, and CH₃CN, CH₃CH₂CN, and (CH₃)₂CHCN also formed ketenimines. In the presence of H₂O, no isonitriles were detected but rather the cyanate ion (OCN⁻) was seen in all cases. Although isonitriles, ketenimines, and OCN⁻ were the main focus of our work, we also describe cases of hydrogen loss, to make smaller nitriles, and hydrogen addition (reduction), to make larger nitriles. HCN formation also was seen in most experiments. The results are presented in terms of nitrile ice chemistry on Titan, in cometary ice, and in the interstellar medium. Possible connections to prebiotic chemistry are briefly discussed.  相似文献