Influence of Redox Mediators and Electron Donors on the Anaerobic Removal of Color and Chemical Oxygen Demand from Textile Effluent     

Sandra M. Amorim  Mario T. Kato  Lourdinha Florencio  Sávia Gavazza 《洁净——土壤、空气、水》2013,41(9):928-933

Color removal was evaluated in anaerobic assays using synthetic (SE) and real (RE) effluents containing the dye Direct Black 22 (DB22). The focus was on the individual influence of two electron donors (EDs), sucrose and ethanol; and their combination with two redox mediators (RMs), lawsone and riboflavin. In addition to SE assays, the EDs were combined with sulfate which was present in the RE. Distinct behavior was observed with both assays. In the case of SE, using the EDs sucrose and ethanol resulted in DB22 removal efficiency of 93 and 83%, respectively; but only 27% in the control. The respective removal rates were 27.8‐ and 4.4‐fold higher than that of the control. Using the EDs with the RM lawsone resulted in color removal higher than that with riboflavin. Interestingly, in the ethanol + sulfate assay, late release of the last was observed, possibly due to the desulfonation reaction of the aromatic structures during the DB22 molecule breakdown. In the case of RE, no improvement was observed with either EDs; and some combinations with the RMs even resulted in decreased color removal. Therefore, the used EDs and RMs showed positive effect on color removal in SEs; but unexpectedly not in REs.  相似文献   

Brittle-plastic deformation in initially dry rocks at fluid-present conditions: transient behaviour of feldspar at mid-crustal levels   总被引：1，自引：0，他引：1  

Linus Brander  Henrik Svahnberg  Sandra Piazolo 《Contributions to Mineralogy and Petrology》2012,163(3):403-425

We present detailed microstructural and chemical analyses from an initially dry anorthositic rock deformed during wet amphibolite facies conditions. Three different domains representing the microstructural variation of the deformed samples are investigated in detail in terms of fracture morphology and mode, grain characteristics and chemistry of present phases. Results show transient deformational behaviour where a close interaction between brittle, plastic and fluid-assisted deformation mechanisms can be observed. Our analysis allows us to describe the succession, interrelationships and effects of active mechanisms with progressively increasing strain in three so-called stages. In Stage 1, initial fracturing along cleavage planes promoted fluid influx that caused fragmentation and chemical reactions, producing fine-grained mineral assemblages in the fractures. Deformation twins and dislocations developed in clast pieces due to stress relaxation. Passive rotation of conjugate fracture sets and interconnection of intracrystalline fractures formed micro-shear-zones, constituting Stage 2. Microstructures and grain relationships indicate the activity and fluctuation between fracturing, dissolution-precipitation creep, grain boundary sliding and locally dislocation creep, reflecting the transient behaviour of brittle and plastic deformation mechanisms. Further rotation and widening of fractures into overall foliation parallel shear-bands (Stage 3) promoted strain partitioning into these areas through increased fluid influx, influence of fluid-assisted grain boundary sliding, phase mixing and presence of weak phases such as white mica. We suggest that local differences in fluid availability, volume fraction of weak phases produced by fluid present metamorphic reactions coupled with volume increase and local variations in stress concentration induced transient brittle-plastic behaviour. The studied shear-zone represents an example of the transformation of a rigid dry rock to a soft wet rock during deformation through syntectonic fracturing.  相似文献   

The recognition of multiple magmatic events and pre-existing deformation zones in metamorphic rocks as illustrated by CL signatures and numerical modelling: examples from the Ballachulish contact aureole, Scotland     

Helena Bergman  Sandra Piazolo 《International Journal of Earth Sciences》2012,101(5):1127-1148

The combination of cathodoluminescence (CL) analysis, temperature and temperature–time calculations, and microstructural numerical modelling offers the possibility to derive the time-resolved evolution of a metamorphic rock. This combination of techniques is applied to a natural laboratory, namely the Ballachulish contact aureole, Scotland. Analysis of the Appin Quartzite reveals that the aureole was produced by two distinct magmatic events and infiltrated by associated fluids. Developing microstructures allow us to divide the aureole into three distinct regions. Region A (0–400?m, 663°C?<?T _max?<?714°C) exhibits a three-stage grain boundary migration (GBM) evolution associated with heating, fluid I and fluid II. GBM in region B (400–700?m, 630°C?<?T _max?<?663°C) is associated with fluid II only. Region C (>700?m of contact, T _max?<?630°C) is characterised by healed intragranular cracks. The combination of CL signature analysis and numerical modelling enables us to recognise whether grain size increase occurred mainly by surface energy-driven grain growth (GG) or strain-induced grain boundary migration (SIGBM). GG and SIGBM result in either straight bands strongly associated with present-day boundaries or highly curved irregular bands that often fill entire grains, respectively. At a temperature of ~620°C, evidence for GBM is observed in the initially dry, largely undeformed quartzite samples. At this temperature, evidence for GG is sparse, whereas at ~663°C, CL signatures typical for GG are commonplace. The grain boundary network approached energy equilibrium in samples that were at least 5?ka above 620°C.  相似文献   

Estuarine ecological risk based on hepatic histopathological indices from laboratory and in situ tested fish     

Costa PM  Caeiro S  Lobo J  Martins M  Ferreira AM  Caetano M  Vale C  DelValls TÁ  Costa MH 《Marine pollution bulletin》2011,62(1):55-65

Juvenile Senegalese soles were exposed through 28-day laboratory and field (in situ) bioassays to sediments from three sites of the Sado estuary (W Portugal): a reference and two contaminated by metallic and organic contaminants. Fish were surveyed for ten hepatic histopathological alterations divided by four distinct reaction patterns and integrated through the estimation of individual histopathological condition indices. Fish exposed to contaminated sediments sustained more damage, with especial respect to regressive changes like necrosis. However, differences were observed between laboratory- and field-exposed animals, with the latest, for instance, exhibiting more pronounced fatty degeneration and hepatocellular eosinophilic alteration. Also, some lesions in fish exposed to the reference sediment indicate that in both assays unaccounted variables produced experimental background noise, such as hyaline degeneration in laboratory-exposed fish. Still, the field assays yielded results that were found to better reflect the overall levels of contaminants and physico-chemical characteristics of the tested sediments.  相似文献   

Polychaete/amphipod ratio as an indicator of environmental impact related to offshore oil and gas production along the Norwegian continental shelf     

Andrade H  Renaud PE 《Marine pollution bulletin》2011,62(12):2836-2844

Benthic faunal data is regularly collected worldwide to assess the ecological quality of marine environments. Recently, there has been renewed interest in developing biological indices able to identify environmental status and potential anthropogenic impacts. In this paper we evaluate the performance of a general polychaete/amphipod ratio along the Norwegian continental shelf as an environmental indicator for offshore oil and gas impacts. Two main trends are apparent: first, a contamination gradient is discernible from where production takes place compared to stations 10,000 m away. Second, the quality of the marine environment has improved over time. These results are consistent with monitoring reports employing a combination of uni- and multi-variate statistics. Thus, we consider this ratio as a relatively simple, useful and potentially cost-effective complement to other more demanding assessment techniques. Because of its strong theoretical basis, it may also be useful for detecting ecological change as a result of other activities.  相似文献   

Forest–savanna–morichal dynamics in relation to fire and human occupation in the southern Gran Sabana (SE Venezuela) during the last millennia     

Encarni Montoya  Valentí Rull  Nathan D. Stansell  Mark B. Abbott  Sandra Nogué  Broxton W. Bird  Wilmer A. Díaz 《Quaternary Research》2011,76(3):335-344

The southern Gran Sabana (SE Venezuela) holds a particular type of neotropical savanna characterized by the local occurrence of morichales (Mauritia palm swamps), in a climate apparently more suitable for rain forests. We present a paleoecological analysis of the last millennia of Lake Chonita (4°39′N–61°0′W, 884 m elevation), based on biological and physico-chemical proxies. Savannas dominated the region during the last millennia, but a significant vegetation replacement occurred in recent times. The site was covered by a treeless savanna with nearby rainforests from 3640 to 2180 cal yr BP. Water levels were higher than today until about 2800 cal yr BP. Forests retreated since about 2180 cal yr BP onwards, likely influenced by a higher fire incidence that facilitated a dramatic expansion of morichales. The simultaneous appearance of charcoal particles and Mauritia pollen around 2000 cal yr BP supports the potential pyrophilous nature of this palm and the importance of fire for its recent expansion. The whole picture suggests human settlements similar to today – in which fire is an essential element – since around 2000 yr ago. Therefore, present-day southern Gran Sabana landscapes seem to have been the result of the synergy between biogeographical, climatic and anthropogenic factors, mostly fire.  相似文献   

Improving the description of the suspended particulate matter concentrations in the southern North Sea through assimilating remotely sensed data     

Ghada Y. El Serafy  Marieke A. Eleveld  Meinte Blaas  Thijs van Kessel  Sandra Gaytan Aguilar  Hendrik J. Van der Woerd 《Ocean Science Journal》2011,46(3):179-204

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Water relations and hydraulic architecture of two Patagonian steppe shrubs: Effect of slope orientation and microclimate     

Patricia A. Iogna  Sandra J. Bucci  Fabián G. Scholz  Guillermo Goldstein 《Journal of Arid Environments》2011,75(9):763-772

On a local scale, topography influences microclimate, vegetation structure and the morpho-physiological attributes of plants. We studied the effects of microclimatic differences between NE- and SW-facing slopes on the water relations and hydraulic properties of two dominant shrubs of the Patagonian steppe in Argentina (Retanilla patagonica and Colliguaja integerrima). The NE-facing slope had higher irradiance and air saturation deficits and lower soil water availability and wind speed than the SW-facing slope. Predawn and midday Ψ_L and osmotic potentials were significantly lower in shrubs on the NE-facing slope. Osmotic adjustment and more elastic cell walls helped the plants to cope with a more xeric environment on NE-facing slope. Higher water deficits on NE-facing slope were partially compensated by a higher leaf and stem water storage. While stem hydraulic efficiency did not vary between slopes, leaf hydraulic conductance was between 40% and 300% higher on the NE-facing slope. Changes observed in leaf size and in SLA were consistent with responses to mechanical forces of wind (smaller and scleromorphic leaves on SW-facing slope). Morpho-physiological adjustments observed at a short spatial scale allow maintenance of midday Ψ_L above the turgor loss point and demonstrate that leaves are more responsive to microclimatic selective pressures than stems.  相似文献   

Effect of a broad shallow sill on tidal circulation and salt transport in the entrance to a coastal plain estuary (Mira—Vila Nova de Milfontes, Portugal)     

J. O. Blanton  M. A. Ferreira  F. A. Andrade 《Estuaries and Coasts》2000,23(3):293-304

We describe the tidal circulation and salinity regime of a coastal plain estuary that connects to the ocean through a flood tide delta. The delta acts as a sill, and we examine the mechanisms through which the sill affects exchange of estuarine water with the ocean. Given enough buoyancy, the dynamics of tidal intrusion fronts across the sill and selective withdrawal (aspiration) in the deeper channel landward appear to control the exchange of seawater with estuarine water. Comparison of currents on the sill and stratification in the channel reveals aspiration depths smaller than channel depth during neap tide. During neap tide and strong vertical stratification, seawater plunges beneath the less dense estuarine water somewhere on the sill. Turbulence in the intruding bottom layer on the sill promotes entrainment of fluid from the surface layer, and the seawater along the sill bottom is diluted with estuarine water. During ebb flow, salt is effectively trapped landward of the sill in a stagnant zone between the aspiration depth and the bottom where it can be advected farther upstream by flood currents. During spring tide, the plunge point moves landward and off the sill, stratification is weakened in the deep channel, and aspiration during ebb extends to the bottom. This prevents the formation of stagnant water near the bottom, and the estuary is flooded with high salinity water far inland. The neapspring cycle of tidal intrusion fronts on flood coupled with aspiration during ebb interacts with the sill to play an important role in the transport and retention of salt within the estuary.  相似文献   

Spatiotemporal patterns of burned areas,fire drivers,and fire probability across the equatorial Andes     

Xavier ZAPATA-ROS  Carmen LOPEZ-FABARA  Abigail NAVARRETE  Sandra TORRES-PAGUAY  Miguel FLORES 《山地科学学报》2021,(4):952-972

Field-based fire studies in the equatorial Andes indicate that fires are strongly associated with biophysical and anthropogenic variables. However, fire controls and fire regimes at the regional scale remain undocumented. Therefore, this paper describes spatial and temporal burned-area patterns, identifies biophysical and anthropogenic fire drivers, and quantifies fire probability across 6° of latitude and 3° of longitude in the equatorial Andes. The spatial and temporal burned-area analysis was carried out based on 18 years(2001-2018) of the MCD64 A1 MODIS burned-area product. Climate, topography, vegetation, and anthropogenic variables were integrated in a logistic regression model to identify the significance of explanatory variables and determine fire occurrence probability. A total of 5779 fire events were registered during the 18 years of this study, located primarily along the western cordillera of the Andes and spreading from North to South. Eighty-eight percent of these fires took place within two fire hotspots located in the northwestern and southwestern corners of the study area. Ninety-nine percent occurred during the second part of the year, between June and December. The largest density of fires was primarily located on herbaceous vegetation and shrublands. Results show that mean monthly temperature, precipitation and NDVI during the prefire season, the location of land cover classes such as forest and agriculture, distance to roads and urban areas, slope, and aspect were the most important determinants of spatial and temporal fire distribution. The logistic regression model achieved a good accuracy in predicting fire probability(80%). Probability was higher in the southwestern and northern corners of the study area, and lower towards the north in the western and eastern piedmonts of the Andes. This analysis contributes to the understanding of fires in mountains within the tropics. The results here presented have the potential to contribute to fire management and control in the region.  相似文献