Arsenic in shallow groundwater of Bangladesh: investigations from three different physiographic settings   总被引：1，自引：0，他引：1  

M. Aziz Hasan  K. Matin Ahmed  Ondra Sracek  Prosun Bhattacharya  Mattias von Brömssen  Sandra Broms  Johan Fogelström  M. Lutful Mazumder  Gunnar Jacks 《Hydrogeology Journal》2007,15(8):1507-1522

Occurrences of arsenic (As) in the Bengal Basin of Bangladesh show close relationships with depositional environments and sediment textures. Hydrochemical data from three sites with varying physiography and sedimentation history show marked variations in redox status and dissolved As concentrations. Arsenic concentration in groundwater of the Ganges Flood Plain (GFP) is characteristically low, where high Mn concentrations indicate redox buffering by reduction of Mn(IV)-oxyhydroxides. Low DOC, \( {\text{HCO}}^{ - }_{3} \), \( {\text{NH}}^{ + }_{4} \) and high \( {\text{NO}}^{ - }_{3} \) and \( {\text{SO}}^{{2 - }}_{4} \) concentrations reflect an elevated redox status in GFP aquifers. In contrast, As concentration in the Ganges Delta Plain (GDP) is very high along with high Fe and low Mn. In the Meghna Flood Plain (MFP), moderate to high As and Fe concentrations and low Mn are detected. Degradation of organic matter probably drives redox reactions in the aquifers, particularly in MFP and GDP, thereby mobilising dissolved As. Speciation calculations indicate supersaturation with respect to siderite and vivianite in the groundwater samples at MFP and GDP, but groundwater in the GFP wells is generally supersaturated with respect to rhodochrosite. Values of log P_CO2 at MFP and GDP sites are generally higher than at the GFP site. This is consistent with Mn(IV)-redox buffering suggested at the GFP site compared to Fe(III)-redox buffering at MFP and GDP sites.  相似文献   

Assessment of Potential Alkali Aggregate Reactivity for Siliceous and Carbonate Aggregates: A Case Study     

M. Ahmad  M. K. Ansari  Rajesh Singh  L. K. Sharma  T. N. Singh  Sandra Pires 《Journal of the Geological Society of India》2018,91(4):467-474

Alkali-aggregate reactivity (AAR) involves a reaction between the pore solution of concrete and certain minerals found in some aggregates. To assess the potential AAR various physical and chemical tests are available and extensively used. The petrographic examination is the initial assessment that decides the further investigation for potential reactivity of an aggregate. A chemical approach is another option to assess the aggregate for potential AAR. The accelerated mortar bar method and concrete prism tests are other very important tests for determination of potential AAR of aggregates samples. However, a combination of the results of all the techniques provides most reliable results for potential AAR in aggregates. Moreover, each test represents the stepwise investigation and provides the decision for the test of next approach. Petrographic examination and chemical test methods are the quick decision-making methods for the estimation of potential AAR. In some cases, by these two methods, the aggregate can be selected and rejected confidently. However, for critical values or doubtful aggregates, further tests are necessary to develop a higher confidence level of the results. The present study comprises of the assessment of the alkali-reactivity of siliceous and carbonate aggregates using petrographic and chemical approaches. X-ray diffraction analysis was used as a complementary method to the petrographic evaluation. Moreover, under chemical approach, two separate test methods were used for siliceous and carbonate aggregates. The study also included a comparison between the petrographic examination and chemical analysis for the same aggregate samples and found significant results.  相似文献   

Reducing landscape heterogeneity for improved land use and land cover (LULC) classification across the large and complex Ethiopian highlands     

Tibebu Kassawmar  Sandra Eckert  Kaspar Hurni  Gete Zeleke  Hans Hurni 《国际地球制图》2018,33(1):53-69

This paper presents a land use and land cover (LULC) classification approach that accounts landscape heterogeneity. We addressed this challenge by subdividing the study area into more homogeneous segments using several biophysical and socio-economic factors as well as spectral information. This was followed by unsupervised clustering within each homogeneous segment and supervised class assignment. Two classification schemes differing in their level of detail were successfully applied to four landscape types of distinct LULC composition. The resulting LULC map fulfills two major requirements: (1) differentiation and identification of several LULC classes that are of interest at the local, regional, and national scales, and (2) high accuracy of classification. The approach overcomes commonly encountered difficulties of classifying second-level classes in large and heterogeneous landscapes. The output of the study responds to the need for comprehensive LULC data to support ecosystem assessment, policy formulation, and decision-making towards sustainable land resources management.  相似文献   

Interaction of chemical and physical processes during deformation at fluid-present conditions: a case study from an anorthosite–leucogabbro deformed at amphibolite facies conditions     

Henrik Svahnberg  Sandra Piazolo 《Contributions to Mineralogy and Petrology》2013,165(3):543-562

We present microstructural and chemical analyses of chemically zoned and recrystallized plagioclase grains in variably strained samples of a naturally deformed anorthosite–leucogabbro, southern West Greenland. The recorded microstructures formed in the presence of fluids at mid-crustal conditions (620–640 °C, 7.4–8.6 kbar). Recrystallized plagioclase grains (average grain size 342 μm) with a random crystallographic orientation are volumetrically dominant in high-strain areas. They are characterized by asymmetric chemical zoning (An₈₀ cores and An₆₄ rims) that are directly associated with areas exhibiting high amphibole content and phase mixing. Analyses of zoning indicate anisotropic behaviour of bytownite plagioclase with a preferred replacement in the $ \left\langle {0 10} \right\rangle $ direction and along the (001) plane. In areas of high finite strain, recrystallization of plagioclase dominantly occurred by bulging recrystallization and is intimately linked to the chemical zoning. The lack of CPO as well as the developed asymmetric zoning can be explained by the activity of grain boundary sliding accommodated by dissolution and precipitation creep (DPC). In low-strain domains, grain size is on average larger and the rim distribution is not related to the inferred stress axes indicating chemically induced grain replacement instead of stress-related DPC. We suggest that during deformation, in high-strain areas, pre-existing phase mixture and stress induced DPC-caused grain rotations that allowed a deformation-enhanced heterogeneous fluid influx. This resulted in local plagioclase replacement through interface-coupled dissolution and precipitation and chemically induced grain boundary migration, accompanied by bulging recrystallization, along with neocrystallization of other phases. This study illustrates a strong interaction and feedback between physical and chemical processes where the amount of stress and fluids dictates the dominant active process. The interaction is a cause of deformation and external fluid infiltration with a result of strain localization and chemical re-equilibration at amphibolite facies conditions.  相似文献   

Pink manganian phengite in a high P/T meta-conglomerate from northern Syros (Cyclades, Greece)     

Rainer Altherr  Christian Soder  Sandra Panienka  Daniel Peters  Hans-Peter Meyer 《Contributions to Mineralogy and Petrology》2013,166(5):1323-1334

A new occurrence of Mn-rich rocks was discovered within the high-pressure/low-temperature metamorphic rocks on the Palos peninsula of Syros (Greece). Near the summit of Mount Príonas, a meta-conglomerate consists of calcite (~63 wt%), pink manganian phengite, blue–purple manganian aegirine–jadeite, microcline, albite and quartz. In addition, it contains abundant braunite-rich aggregates (up to ~1.5 cm in diameter) that include hollandite [(Ba_0.98–1.02K_<0.01Na_<0.02Ca_<0.03) (Mn _1.02–1.52 ³⁺ Fe _0.38–0.88 ³⁺ Ti_0.29–0.92Mn _5.11–5.76 ⁴⁺ )O₁₆], barite and manganian hematite. Due to metamorphic recrystallization and deformation, the contacts between clasts and matrix are blurred and most clasts have lost their identity. In back-scattered electron images, many aegirine–jadeite grains appear patchy and show variable jadeite contents (Jd_10–67). These pyroxenes occur in contact with either quartz or albite. Manganian phengite (3.41–3.49 Si per 11 oxygen anions) is of the 3T type and contains 1.4–2.2 wt% of Mn₂O₃. At the known P–T conditions of high-pressure metamorphism on Syros (~1.4 GPa/ 470 °C), the mineral sub-assemblage braunite + quartz + calcite (former aragonite) suggests high oxygen fugacities relative to the HM buffer (+7 ≤ ?f_O2 ≤ + 17) and relatively high CO₂ fugacities. The exact origin of the conglomerate is not known, but it is assumed that the Fe–Mn-rich and the calcite-rich particles originated from different sources. Braunite has rather low contents of Cu (~0.19 wt%) and the concentrations of Co, Ni and Zn are less than 0.09 wt%. Hollandite shows even lower concentrations of these elements. Furthermore, the bulk-rock compositions of two samples are characterized by low contents of Cu, Co and Ni, suggesting a hydrothermal origin of the manganese ore. Most likely, these Fe–Mn–Si oxyhydroxide deposits consisted of ferrihydrite, todorokite, birnessite, amorphous silica (opal-A) and nontronite. Al/(Al + Fe + Mn) ratios of 0.355 and 0.600 suggest the presence of an aluminosilicate detrital component.  相似文献   

The role of fire on soil mounds and surface roughness in the Mojave Desert     

Christopher E. Soulard  Todd C. Esque  David R. Bedford  Sandra Bond 《地球表面变化过程与地形》2013,38(2):111-121

A fundamental question in arid land management centers on understanding the long‐term effects of fire on desert ecosystems. To assess the effects of fire on surface topography, soil roughness, and vegetation, we used terrestrial (ground‐based) LiDAR to quantify the differences between burned and unburned surfaces by creating a series of high‐resolution vegetation structure and bare‐earth surface models for six sample plots in the Grand Canyon‐Parashant National Monument, Arizona. We find that 11 years following prescribed burns, mound volumes, plant heights, and soil‐surface roughness were significantly lower on burned relative to unburned plots. Results also suggest a linkage between vegetation and soil mounds, either through accretion or erosion mechanisms such as wind and/or water erosion. The biogeomorphic implications of fire‐induced changes are significant. Reduced plant cover and altered soil surfaces from fire likely influence seed residence times, inhibit seed germination and plant establishment, and affect other ecohydrological processes. Published in 2012. This article is a US Government work and is in the public domain in the USA.  相似文献   

New method for estimating reference evapotranspiration and comparison with alternative methods in a fruit-producing hub in the semi-arid region of Brazil     

de Souza  Luciana Sandra Bastos  Silva  Maiara Tatiane Lima  Alba  Elisiane  de Moura  Magna Soelma Beserra  da Cruz Neto  José Francisco  de Souza  Carlos André Alves  da Silva  Thieres George Freire 《Theoretical and Applied Climatology》2022,149(1-2):593-602

Theoretical and Applied Climatology - Analysing alternative methods for estimating reference evapotranspiration (ET0) is essential for improving the management of water resources, especially where...  相似文献   

Aram Chaos and its constraints on the surface heat flux of Mars     

Sandra Schumacher  Tanja E. Zegers 《Icarus》2011,211(1):305-315

The surface heat flux of a planet is an important parameter to characterize its internal activity and to determine its thermal evolution. Here we report on a new method to constrain the surface heat flux of Mars during the Hesperian. For this, we explore the consequences for the martian surface heat flux from a recently presented new hypothesis for the formation of Aram Chaos (Zegers, T.E., Oosthoek, J.H.P., Rossi, A.P., Blom, J.K., Schumacher, S. [2010]. Earth Planet. Sci. Lett. 297, 496-504. doi:10.1016/j.epsl.2010.06.049.). In this hypothesis the chaotic terrain is thought to have formed by melting of a buried ice sheet. The slow sedimentation and burial of the ice sheet led to an increased thermal insulation of the ice and subsequently to a temperature increase high enough to trigger melting and the formation of the subsurface lake. As these processes highly depend on the thermal properties of the subsurface and especially on the surface heat flux, it is possible to constrain the latter by using numerical simulations. Based on the hypothesis for the formation of Aram Chaos, we conducted an extensive parameter study to determine the parameter settings leading to sufficient melting of the buried ice sheet. We find that the surface heat flux in the Aram Chaos region during the Hesperian was most likely between 20 and 45 mW m⁻² with a possible maximum value of up to 60 mW m⁻².  相似文献   

SUMMER DIURNAL WIND PATTERNS AT 3,000 m SURFACE LEVEL,FRONT RANGE,COLORADO, U.S.A.     

Anthony J. Brazel  Sandra W. Brazel 《自然地理学》2013,34(1):53-60

Observations of hourly wind speeds and directions were taken over a 56-day period in summer 1978, at the 3,000 m ground level near an INSTAAR mountain research site on the east slope of the Front Range, Colorado Rockies. During nearly calm weather, which persisted for longer periods than normal in summer 1978, the pattern of diurnal wind variations resembles results from other mountain studies of wind along high mountain slopes. However, timing of high wind speeds during the daily cycle is not readily explainable, although hypotheses can be offered. Results of this study can assist in interpretations of forest clearing microclimates at high elevations in the mountains and in important air quality questions (e.g., precipitation pH) in the Rocky Mountains.  相似文献   

Establishing the wave climate influence on the morphodynamics of a coastal lagoon inlet     

Sandra Plecha  Paulo A. Silva  Anabela Oliveira  João M. Dias 《Ocean Dynamics》2012,62(5):799-814

The morphologic changes in estuaries and coastal lagoons are very complex and constitute a challenging task in coastal research. The bathymetric changes result from the combined action of tides, waves, rivers discharge and wind stress in the area of interest. Additionally, an accurate knowledge of the sediment transport is essential to achieve a good morphological characterization. This work establishes the influence of the wave climate on the morphodynamics of the Ria de Aveiro lagoon inlet by analysing the numerical results of the morphodynamic modelling system MORSYS2D. The numerical simulations considered a realistic coupled forcing of tidal currents and waves. The computed sediment fluxes and bathymetric changes are analysed and compared with the erosion and accretion trends obtained from the numerical simulations forced only by tidal currents, in order to establish the wave climate influence. The final bathymetry and the corresponding changes are compared with bathymetric data collected through surveys. It is concluded that: (a) the morphodynamics of the study area is dominated by the wave regime in the lagoon inlet and nearshore areas, while in the inner areas is tidally dominated; and (b) the inclusion of the wave regime forcing constitutes an improvement in order to accurately reproduce the local morphodynamics.  相似文献