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41.
Analía V. Serra Sandra E. Botté Diana G. Cuadrado Noelia S. La Colla Vanesa L. Negrin 《Environmental Earth Sciences》2017,76(6):254
In this study, we measured the concentrations of metals (Cd, Cu, Pb, Ni, Cr, Zn, Hg, Mn, and Fe) and assessed the characteristics of tidal flats (grain size and organic matter content) in sediments and their overlying microbial mats fractions to evaluate the anthropogenic impact within the Bahía Blanca Estuary (BBE). Puerto Rosales (PR) and Almirante Brown (AB), located in the middle and inner zone of the estuary, respectively, were used as sampling sites. Sediments were composed mainly of silt–clay in AB, whereas first fine-grained particles were coarser in depth in PR. Regarding the concentration of metals in both fractions, we found differences between sites: There were higher concentrations of overall metals in AB relative to PR. In addition, higher concentrations of Cu were recorded in the first centimeters of AB tidal flats, whereas higher concentration of Cd were recorded in microbial mats of PR. Considering that the grain size was similar between sites, these results are consistent with the high concentration of organic matter found in AB, probably because this site is close to a former municipal dump and sewage discharges. Also, the higher Cd content found in PR site would highlight both the influence of untreated urban discharges and port anthropogenic activities. In conclusion, this study allowed identifying high values of some metals in the presence of microbial mats in the BBE, thus suggesting a possible interaction between both, at least for metals like Cu or Cd. 相似文献
42.
Characterizing the pore space of rock samples using three‐dimensional (3D) X‐ray computed tomography images is a crucial step in digital rock physics. Indeed, the quality of the pore network extracted has a high impact on the prediction of rock properties such as porosity, permeability and elastic moduli. In carbonate rocks, it is usually very difficult to find a single image resolution which fully captures the sample pore network because of the heterogeneities existing at different scales. Hence, to overcome this limitation a multiscale analysis of the pore space may be needed. In this paper, we present a method to estimate porosity and elastic properties of clean carbonate (without clay content) samples from 3D X‐ray microtomography images at multiple resolutions. We perform a three‐phase segmentation to separate grains, pores and unresolved porous phase using 19 μm resolution images of each core plug. Then, we use images with higher resolution (between 0.3 and 2 μm) of microplugs extracted from the core plug samples. These subsets of images are assumed to be representative of the unresolved phase. We estimate the porosity and elastic properties of each sample by extrapolating the microplug properties to the whole unresolved phase. In addition, we compute the absolute permeability using the lattice Boltzmann method on the microplug images due to the low resolution of the core plug images. In order to validate the results of the numerical simulations, we compare our results with available laboratory measurements at the core plug scale. Porosity average simulations for the eight samples agree within 13%. Permeability numerical predictions provide realistic values in the range of experimental data but with a higher relative error. Finally, elastic moduli show the highest disagreements, with simulation error values exceeding 150% for three samples. 相似文献
43.
Sandra Hochscheid Andrea Travaglini Fulvio Maffucci Graeme C. Hays Flegra Bentivegna 《Marine Ecology》2013,34(3):321-333
Understanding the role that consumers play in an ecosystem requires knowledge about food selection and intake rates. However, such basic data are often difficult to obtain, particularly for marine animals that are not easy to observe. To overcome this problem, a beak movement sensor was employed on a free‐ranging loggerhead turtle in a neritic foraging habitat at the Domitian littoral (SW Italy). In combination with gastrointestinal content analysis from six turtles found dead in the same area we sought to identify which beak movement patterns were associated with which prey type, and to quantify the ingestion of the various prey types. Brachyuran crabs (100% occurrence), in particular Liocarcinus vernalis, and small molluscs (66% occurrence) were found most frequently in the stomach and intestine of the turtles. Beak movements revealed average ingestion rates of (mean ± SE) 0.27 ± 0.13 food items per minute and that feeding occurred predominantly during dives >4 m and during early morning and evening. Interestingly, the time spent feeding amounted to only 2.2% of the total observation time, whereas feeding‐associated dives added up to just above 10% of the total time. We thus established that loggerhead turtles in this area are specialised on brachyuran crabs, on which they prey with high success during the short time dedicated to foraging. This information strengthens our knowledge about turtle–prey and turtle–habitat interactions, which are essential data to delineate the role that turtles play in this and similar marine ecosystems. Moreover, since the same area is also intensively used by the regional bottom trawl fishery, our results have important conservation implications, because they clearly show the time of day and water depths for which fishing activity should be regulated to reduce the number of turtles that are currently being incidentally caught in this area. 相似文献
44.
Sandra Freiboth Holger Class Rainer Helmig Tobias Graf Wolfgang Ehlers Viktoria Schwarz Christos Vrettos 《Computational Geosciences》2009,13(3):281-300
Multiphase flow processes in unsaturated cohesive soils are often affected by deformation due to swelling and shrinking as
a result of varying water contents. This paper presents a model concept which is denoted ‘phenomenological’ in terms of the
processes responsible for soil deformation, since the effects of deformation on flow and transport are only considered by
constitutive relations that allow an adaptation of the hydraulic properties. This new model is validated in a detailed intercomparison
study with two state-of-the-art models that are capable of explicitly describing the processes relevant for the deformation.
A ‘numerical experiment’ with a state-of-the-art reference model is used to produce ‘measurement data’ for an inverse-modelling-based
estimation of the model input parameters for the phenomenological concept. 相似文献
45.
Color removal was evaluated in anaerobic assays using synthetic (SE) and real (RE) effluents containing the dye Direct Black 22 (DB22). The focus was on the individual influence of two electron donors (EDs), sucrose and ethanol; and their combination with two redox mediators (RMs), lawsone and riboflavin. In addition to SE assays, the EDs were combined with sulfate which was present in the RE. Distinct behavior was observed with both assays. In the case of SE, using the EDs sucrose and ethanol resulted in DB22 removal efficiency of 93 and 83%, respectively; but only 27% in the control. The respective removal rates were 27.8‐ and 4.4‐fold higher than that of the control. Using the EDs with the RM lawsone resulted in color removal higher than that with riboflavin. Interestingly, in the ethanol + sulfate assay, late release of the last was observed, possibly due to the desulfonation reaction of the aromatic structures during the DB22 molecule breakdown. In the case of RE, no improvement was observed with either EDs; and some combinations with the RMs even resulted in decreased color removal. Therefore, the used EDs and RMs showed positive effect on color removal in SEs; but unexpectedly not in REs. 相似文献
46.
Brittle-plastic deformation in initially dry rocks at fluid-present conditions: transient behaviour of feldspar at mid-crustal levels 总被引:1,自引:0,他引:1
Linus Brander Henrik Svahnberg Sandra Piazolo 《Contributions to Mineralogy and Petrology》2012,163(3):403-425
We present detailed microstructural and chemical analyses from an initially dry anorthositic rock deformed during wet amphibolite
facies conditions. Three different domains representing the microstructural variation of the deformed samples are investigated
in detail in terms of fracture morphology and mode, grain characteristics and chemistry of present phases. Results show transient
deformational behaviour where a close interaction between brittle, plastic and fluid-assisted deformation mechanisms can be
observed. Our analysis allows us to describe the succession, interrelationships and effects of active mechanisms with progressively
increasing strain in three so-called stages. In Stage 1, initial fracturing along cleavage planes promoted fluid influx that caused fragmentation and chemical reactions, producing
fine-grained mineral assemblages in the fractures. Deformation twins and dislocations developed in clast pieces due to stress
relaxation. Passive rotation of conjugate fracture sets and interconnection of intracrystalline fractures formed micro-shear-zones,
constituting Stage 2. Microstructures and grain relationships indicate the activity and fluctuation between fracturing, dissolution-precipitation
creep, grain boundary sliding and locally dislocation creep, reflecting the transient behaviour of brittle and plastic deformation
mechanisms. Further rotation and widening of fractures into overall foliation parallel shear-bands (Stage 3) promoted strain partitioning into these areas through increased fluid influx, influence of fluid-assisted grain boundary
sliding, phase mixing and presence of weak phases such as white mica. We suggest that local differences in fluid availability,
volume fraction of weak phases produced by fluid present metamorphic reactions coupled with volume increase and local variations
in stress concentration induced transient brittle-plastic behaviour. The studied shear-zone represents an example of the transformation
of a rigid dry rock to a soft wet rock during deformation through syntectonic fracturing. 相似文献
47.
The combination of cathodoluminescence (CL) analysis, temperature and temperature–time calculations, and microstructural numerical modelling offers the possibility to derive the time-resolved evolution of a metamorphic rock. This combination of techniques is applied to a natural laboratory, namely the Ballachulish contact aureole, Scotland. Analysis of the Appin Quartzite reveals that the aureole was produced by two distinct magmatic events and infiltrated by associated fluids. Developing microstructures allow us to divide the aureole into three distinct regions. Region A (0–400?m, 663°C?<?T max?<?714°C) exhibits a three-stage grain boundary migration (GBM) evolution associated with heating, fluid I and fluid II. GBM in region B (400–700?m, 630°C?<?T max?<?663°C) is associated with fluid II only. Region C (>700?m of contact, T max?<?630°C) is characterised by healed intragranular cracks. The combination of CL signature analysis and numerical modelling enables us to recognise whether grain size increase occurred mainly by surface energy-driven grain growth (GG) or strain-induced grain boundary migration (SIGBM). GG and SIGBM result in either straight bands strongly associated with present-day boundaries or highly curved irregular bands that often fill entire grains, respectively. At a temperature of ~620°C, evidence for GBM is observed in the initially dry, largely undeformed quartzite samples. At this temperature, evidence for GG is sparse, whereas at ~663°C, CL signatures typical for GG are commonplace. The grain boundary network approached energy equilibrium in samples that were at least 5?ka above 620°C. 相似文献
48.
Costa PM Caeiro S Lobo J Martins M Ferreira AM Caetano M Vale C DelValls TÁ Costa MH 《Marine pollution bulletin》2011,62(1):55-65
Juvenile Senegalese soles were exposed through 28-day laboratory and field (in situ) bioassays to sediments from three sites of the Sado estuary (W Portugal): a reference and two contaminated by metallic and organic contaminants. Fish were surveyed for ten hepatic histopathological alterations divided by four distinct reaction patterns and integrated through the estimation of individual histopathological condition indices. Fish exposed to contaminated sediments sustained more damage, with especial respect to regressive changes like necrosis. However, differences were observed between laboratory- and field-exposed animals, with the latest, for instance, exhibiting more pronounced fatty degeneration and hepatocellular eosinophilic alteration. Also, some lesions in fish exposed to the reference sediment indicate that in both assays unaccounted variables produced experimental background noise, such as hyaline degeneration in laboratory-exposed fish. Still, the field assays yielded results that were found to better reflect the overall levels of contaminants and physico-chemical characteristics of the tested sediments. 相似文献
49.
Encarni Montoya Valentí Rull Nathan D. Stansell Mark B. Abbott Sandra Nogué Broxton W. Bird Wilmer A. Díaz 《Quaternary Research》2011,76(3):335-344
The southern Gran Sabana (SE Venezuela) holds a particular type of neotropical savanna characterized by the local occurrence of morichales (Mauritia palm swamps), in a climate apparently more suitable for rain forests. We present a paleoecological analysis of the last millennia of Lake Chonita (4°39′N–61°0′W, 884 m elevation), based on biological and physico-chemical proxies. Savannas dominated the region during the last millennia, but a significant vegetation replacement occurred in recent times. The site was covered by a treeless savanna with nearby rainforests from 3640 to 2180 cal yr BP. Water levels were higher than today until about 2800 cal yr BP. Forests retreated since about 2180 cal yr BP onwards, likely influenced by a higher fire incidence that facilitated a dramatic expansion of morichales. The simultaneous appearance of charcoal particles and Mauritia pollen around 2000 cal yr BP supports the potential pyrophilous nature of this palm and the importance of fire for its recent expansion. The whole picture suggests human settlements similar to today – in which fire is an essential element – since around 2000 yr ago. Therefore, present-day southern Gran Sabana landscapes seem to have been the result of the synergy between biogeographical, climatic and anthropogenic factors, mostly fire. 相似文献