Spatial and temporal distribution of cadmium and copper in water and zooplankton in the Bahía Blanca estuary,Argentina     

Melisa Daiana Fernández Severini  Sandra Elizabeth BottéMónica Susana Hoffmeyer  Jorge Eduardo Marcovecchio 《Estuarine, Coastal and Shelf Science》2009

Cadmium and copper in the dissolved and particulate phase and in zooplankton were determined in the Bahía Blanca estuary during six surveys from March to December 2005. Temperature, pH, salinity, dissolved oxygen, suspended particulate matter, particulate organic matter and chlorophyll-a were also considered. Dissolved Cd was below the detection limit (0.2 μg L⁻¹) for almost the entire study period whereas Cu concentrations (0.5–2.4 μg L⁻¹) indicated a continuous dissolved Cu input. Particulate Cd concentrations ranged from below the detection limit (<0.01) to 28.6 μg g⁻¹ d.w. while particulate Cu ranged from below the detection limit (<0.04) to 53.5 μg g⁻¹ d.w. Cd in mesozooplankton ranged from below the detection limit (<0.01) to 37.4 μg g⁻¹ d.w. Some of the Cd levels were higher than those reported for other aquatic ecosystems. Cu in the mesozooplankton ranged from 1.3 to 89.3 μg g⁻¹ d.w., values which were within the reported values or higher than other studies. The log of the partition coefficients (log (K_d)) of Cd was 0.04, while log (K_d) for Cu ranged from −0.39 to 2.79. These values were lower than both those calculated for other estuaries and the typical coefficients for marine environments. The log of the bioconcentration factor (log BCF) of Cd was 1.78, indicating that Cd concentration was higher in the zooplankton than in the dissolved phase. Log BCF of Cu ranged from 1.15 to 3. The logs of the biomagnification factors (log BMF) of Cd were low, with a range between −3.45 and 2.21 and those for Cu ranged from −0.1 to 3.35. Positive values indicate biomagnification while negative values indicate biodiminution. In general, no significant dissolved Cd concentration appeared to be present in the Bahía Blanca estuary and Cu values did not indicate a critical environmental status. The particulate phase seemed to be the major carrier for Cd and Cu and TPCu values were within the normal values for an anthropogenically stressed estuary but not for a strongly polluted system. This fraction was the most important metal source for the mesozooplankton. Moreover, the highest metal concentrations were in the mesozooplankton since most of the bioconcentration and biomagnification factors were positive, especially for Cu.  相似文献   

Recruitment of flatfish species to an estuarine nursery habitat (Lima estuary, NW Iberian Peninsula)     

Sandra Ramos  Pedro R  Adriano A. Bordalo 《Journal of Sea Research》2010,64(4):473-486

One of the present concerns of fish biologists involves defining and identifying nursery habitats in the context of conservation and resource management strategies. Fish nursery studies usually report upon nursery occupation during the latter juvenile stages, despite the fact that recruitment to nurseries can start early in life, during the larval phase. Here we investigated the use of a temperate estuarine nursery area, the Lima estuary (NW Portugal), by initial development stages of flatfish species before and after metamorphosis, integrating the larval and juvenile phases. The Lima estuarine flatfish community comprised twelve taxa, seven of which were present as pelagic larvae, six as juveniles and three as adults. There was a general trend of increasing spring–summer abundance of both larvae and juveniles, followed by a sharp winter decrease, mainly of larval flatfishes. The Lima estuary was used by Solea senegalensis, Platichthys flesus and Solea solea as a nursery area, with direct settlement for the two first species. In contrast, indirect settlement was suggested for S. solea, with metamorphosis occurring outside the estuarine area. Estuarine recruitment of S. senegalensis varied between years, with young larvae occurring in the estuary throughout a prolonged period that lasted 6–9 months, corroborating the protracted spawning season. P. flesus, the second most abundant species, exhibited a typical spring estuarine recruitment, without inter-annual variations. Developed larvae arrived in the estuary during spring, whereas the 0-group juveniles emerged in the following summer period. The present study contributes new insight to our understanding of the economically important S. senegalensis, and highlights the importance of integrating the planktonic larval phase into traditional flatfish nursery studies.  相似文献   

Late quaternary evolution of a subantarctic paleofjord, Tierra del Fuego     

Sandra Gordillo  Andrea M.J. Coronato  Jorge O. Rabassa 《Quaternary Science Reviews》1993,12(10)

Lago Roca-Lapataia valley (54°50′S, 68°34′W) is a paleofjord that was occupied by a valley-glacier system during the glacial maximum of the late Pleistocene (estimated ca. 18–20 ka BP). Deglaciation began before 10,080 ± 270 BP. The marine fauna in several marine terraces found in the area shows that early-middle Holocene climatic conditions were basically the same as at present. Species found are characteristic of cold and shallow waters, although minor temperature fluctuations cannot be ruled out for this period. A recent radiocarbon date of 7518 ± 58 BP on Chlamys patagonica (NZ # 7730) confirms that Lago Roca was transformed into a fjord ca. 7500–8000 BP. The sea reached its maximum level of 8–10 m a.s.l. around 6000 BP and at 4000–4500 BP was at least above 6 ± 1 m a.s.l. Later, when sea level fell, Lago Roca was occupied by fresh water and was no longer tidal. The relative land-sea positions during this period are a consequence of combined eustatic and neotectonic processes.  相似文献   

A simple photometer for precise determination of dissolved oxygen concentration by the Winkler method with recommendations for improving respiration rate measurements in aquatic organisms     

Sandra L. Vargo  R. Ken Forcé 《Estuaries and Coasts》1981,4(1):70-74

A simple inexpensive photometer designed for Winkler titration end-point detection is described. The precision of replicate dissolved oxygen measurements using this instrument was 0.06–0.22%. This high precision is needed to measure the small changes in dissolved oxygen concentration for determining the respiration rate of small aquatic organisms. Other recommendations for improving precision are also presented.  相似文献   

The stable isotopic composition of coral skeletons: control by environmental variables   总被引：1，自引：0，他引：1  

Sandra M. Weil  Robert W. Buddemeier  Stephen V. Smith  Peter M. Kroopnick 《Geochimica et cosmochimica acta》1981,45(7):1147-1153

The reef corals Pocillopora damicornis and Montipora verrucosa were cultured under various controlled temperature and light conditions. The corals were analyzed for growth rate, tissue pigment content and skeletal ¹³C and ¹⁸O. Coral skeletal δ¹³C values varied with light dose and correlated with changes in zooxanthellar pigment. The δ¹³C values of skeletal aragonite seem to be modified by oxidation of photosynthetically produced organic matter.Functionally significant relationships between coral skeletal δ¹⁸O values and temperature have been determined. The temperature coefficients of the δ¹⁸O values [?4.4°C (%.)^?1] are similar to the first order coefficient in the equilibrium paleotemperature equation, but the δ¹⁸O values have taxonomically consistent offsets from equilibrium. The offsets may be attributed to the coral metabolism with slight but statistically significant differences between the two genera. Environmental and metabolic variables other than temperature have little or no effect on skeletal δ¹⁸O.  相似文献   

Diffusion of ions in sea water and in deep-sea sediments   总被引：3，自引：0，他引：3  

Sandra Gregory 《Geochimica et cosmochimica acta》1974,38(5):703-714

The tracer-diffusion coefficient of ions in water, D_j⁰, and in sea water, $\text{D}{}_{\mathrm{j}}{}^1$, differ by no more than zero to 8 per cent. When sea water diffuses into a dilute solution of water, in order to maintain the electro-neutrality, the average diffusion coefficients of major cations become greater but of major anions smaller than their respective $\text{D}{}_{\mathrm{j}}{}^1$ or D_j⁰ values. The tracer diffusion coefficients of ions in deep-sea sediments, D_j,sed., can be related to $\text{D}{}_{\mathrm{j}}{}^1$ by $\text{D}{}_{\mathrm{j,sed.}}\text{= D}{}_{\mathrm{j}}{}^1\text{·}\text{α}\text{θ}{}^2$, where θ is the tortuosity of the bulk sediment and a a constant close to one.  相似文献   

Bimodal early proterozoic volcanism in the Grythytte field and associated volcano-plutonic complexes,Bergslagen, Central Sweden     

Willem van der Velden  James Baker  Sandra de Maesschalck  Thea van Meerten 《International Journal of Earth Sciences》1982,71(1):171-181

The Grythytte field sequence forms a NNW belt of acid-basic metavolcanic and metasedimentary rocks. The geology shows characteristics of a dynamic process of trough-forming and infilling which to a large extent post-dates the Hjulsjö volcanoplutonic complex situated to the east. In the latter complex acid metapyroclastics strike around a centre of granite and granophyre, which cut and are cut by basic sills and dykes. Field and petrochemical evidence points to a distinct bimodal magmatism that ist manifested during one short phase of a rifting period.

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Zusammenfassung Die Grythytte Schichtenfolge bildet einen NNW verlaufenden Gürtel aus sauren und basischen Metavulkaniten und Metasedimenten. Die geologischen Befunde weisen auf einen dynamischen Entstehungsprozeß von Grabenbildung und Füllung hin. Im weiter östlich gelegenen vulkanisch-plutonischen Hjulsjö-Komplex streichen älteren metamorphen pyroklastischen Gesteine rund ein Granit-Granophyr Zentrum. Dieser Komplex durchschneidet und wird durchschnitten von basischen Sills und Gängen. Feldgeologische und geochemische Untersuchungen weisen deutlich auf einen bimodalen Magmatismus hin, der während einer kurzen Phase der Grabenbildung stattfand.

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Résumé La séquence de Grythytte forme une ceinture de roches métavolcaniques et métasédimentaires de direction NNO. La géologie fait apparaître les caractéristiques d'un processus dynamique de formation de fosse et de remplissage, qui s'est produit, pour la plus grande partie, après la formation du complexe volcano-plutonique de Hjulsjö situé à l'Est. Dans ce dernier complexe des produits pyroclastiques acides sont disposés autour d'un centre granitoïde et granophyrique, qui à son tour recoupe et est recoupé par des sills et des dykes basiques. Les observations de terrain et les faits pétrochimiques indiquent un procèssus magmatique distinctement bimodal qui s'est manifesté pendant une phase courte dans une période de «rifting».

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Grythytte , NNW . . Hjulsj -- . . , , .

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Statistical analysis of the largest possible earthquake magnitudes on the Ecuadorian coast for selected return periods     

Sandra García-Bustos  Jimmy Landín  Ricardo Moreno  A.S.E. Chong  Maurizio Mulas  Mónica Mite 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2020,14(1):56-68

ABSTRACT

In this work, we have studied the largest earthquake magnitudes on the Ecuadorian coast by using the principles of Extreme Value Analysis based on its two approaches: Block Maxima and Peaks-over-Threshold. First, before modelling the recorded earthquakes, the K-means clustering technique was applied to determine a classification according to the level of magnitude of the earthquakes. Then, models based on the Extreme Value theory of earthquake magnitudes were developed for each of the four clusters that were found, and finally, the best-fitted models were those known as Fréchet and Gumbel ones. The zone with the greatest earthquake magnitudes on the Ecuadorian coast is located between the north of the province of Manabí and the south of the province of Esmeraldas, with a return period of 50 years for an earthquake with magnitude greater than 7.7 M_W.  相似文献   

The carbon isotopic distribution of Murchison amino acids     

Sandra Pizzarello  Yongsong Huang 《Geochimica et cosmochimica acta》2004,68(23):4963-4969

The δ¹³C values of thirty-four individual amino acids and two pyridine carboxylic acids have been obtained fromthe Murchison meteorite. They were found to range from +4.9 to +52.8‰, with statistically significant differences observed both within and between amino acid subgroups. The ¹³C content of α-amino acids declines with increasing chain length, a trend similar to the ones previously observed for carboxylic acids and alkanes. Also 2-methyl-2-amino acids were found to be heavier in ¹³C than the corresponding 2-H homologues. The3-, 4-, and 5-amino acids do not show a comparable declining trend in δ¹³C values and neither do the amino dicarboxylic acids. This variability in δ ¹³C values can be interpreted as to indicate that the synthetic histories of soluble organics in meteorites may have been diverse even within groups of compounds with very similar functional group composition.  相似文献   

Coarse sediment transport in mountain streams in Colorado and Wyoming,USA     

Sandra E. Ryan  Laurie S. Porth  C. A. Troendle 《地球表面变化过程与地形》2005,30(3):269-288

Since the early 1990s, US Forest Service researchers have made thousands of bedload measurements in steep, coarse‐grained channels in Colorado and Wyoming, USA. In this paper we use data from 19 of those sites to characterize patterns and rates of coarse sediment transport for a range of channel types and sizes, including step–pool, plane‐bed, pool–riffle, and near‐braided channels. This effort builds upon previous work where we applied a piecewise regression model to (1) relate flow to rates of bedload transport and (2) define phases of transport in coarse‐grained channels. Earlier, the model was tested using bedload data from eight sites on the Fraser Experimental Forest near Fraser, Colorado. The analysis showed good application to those data and to data from four supplementary channels to which the procedure was applied. The earlier results were, however, derived from data collected at sites that, for the most part, have quite similar geology and runoff regimes. In this paper we evaluate further the application of piecewise regression to data from channels with a wider range of geomorphic conditions. The results corroborate with those from the earlier work in that there is a relatively narrow range of discharges at which a substantial change in the nature of bedload transport occurs. The transition from primarily low rates of sand transport (phase I) to higher rates of sand and coarse gravel transport (phase II) occurs, on average, at about 80 per cent of the bankfull (1·5‐year return interval) discharge. A comparison of grain sizes moved during the two phases showed that coarse gravel is rarely trapped in the samplers during phase I transport. Moreover, the movement and capture of the D₁₆ to D₂₅ grain size of the bed surface seems to correspond with the onset of phase II transport, particularly in systems with largely static channel surfaces. However, while there were many similarities in observed patterns of bedload transport at the 19 studied sites, each had its own ‘bedload signal’ in that the rate and size of materials transported largely reflected the nature of flow and sediment particular to that system. Published in 2005 by John Wiley & Sons, Ltd.  相似文献