Fate and biodegradability potential of an emerging micropollutant diclofenac in subsurface environment     

D. O. Tas  S. Sari  E. Aydın  E. Topuz  E. Pehlivanoğlu-Mantaş 《International Journal of Environmental Science and Technology》2018,15(6):1201-1210

The present study deals with the assessment of the fate of an emerging contaminant (diclofenac), present in the subsurface environment at specific concentration levels, and its biodegradation potential under different environmental configurations. Diclofenac is a widely consumed nonsteroidal anti-inflammatory drug used as a painkiller prescribed as pills or ointments and among the most frequently detected pharmaceuticals in wastewater treatment plants’ effluents. Fermentative/methanogenic cultures were enriched from previously contaminated sediment samples. Although partial biodegradation was achieved in all enrichment cultures, complete degradation was not observed. The results reflected that less than 6% of the diclofenac sorbed on the solid phase and the rest was either biotransformed (25–40%) or remained in the liquid phase (55–70%) at the end of 45-day incubation period. Although partial cometabolic degradation of diclofenac occurred in the presence of glucose, biodegradation was not observed in the presence of readily biodegradable carbon source (i.e., acetate). Diclofenac concentration up to 1000 µg/L did not affect the methanogenic activity of the enriched culture. The results of this study will have a significant impact in the designation of the permitted concentration limits of diclofenac before the discharge through wastewater treatment plants.  相似文献   

Why do we see the man in the Moon?     

Oded Aharonson  Peter Goldreich  Re’em Sari 《Icarus》2012,219(1):241-243

Numerical simulations and analysis show that the Moon locks into resonance with a statistical preference of facing either the current near-side or far-side toward Earth. The near-side is largely covered by dense, topographically low, dark mare basalts, the pattern of which to some, resembles the image of a man’s face. Although the Moon is locked in this configuration at present, the opposite one, with the current far-side facing Earth, is of lower potential energy and hence might be naively expected. Instead, we find that the probability of selecting each configuration depends upon the ratio of the asymmetry of the potential energy maxima, dominated by the octupole moment of the Moon, to the energy dissipated per tidal cycle within the Moon. If this ratio is small, the two configurations are equally likely. Otherwise, interesting dynamical behavior ensues. In the Moon’s present orbit, with the best-estimated geophysical parameters and dissipation parameter Q = 35, trapping into the current higher-energy configuration is preferred. With Q = 100 in analogy with the solid Earth, the current configuration is nearly certain. The ratio of energies and corresponding probabilities were different in the past. Relative crater counts on the leading and trailing faces indicate an impact may have unlocked the Moon before it settled into the present configuration. Our analysis constrains the geophysical parameters at the time of the last such event.  相似文献   

Stratigraphy of Upper Cretaceous–Palaeogene sequences in the southern and eastern Menderes Massif (western Turkey)     

Sacit Özer  Hasan Sözbilir  İzver Özkar  Vedia Toker  Bilal Sari 《International Journal of Earth Sciences》2001,89(4):852-866

The stratigraphy of the uppermost levels of the Menderes Massif is controversial and within its details lie vital constraints to the tectonic evolution of south-western Turkey. Our primary study was carried out in four reference areas along the southern and eastern Menderes Massif. These areas lie in the upper part of the Menderes metamorphic cover and have a clear stratigraphic relationship and contain datable fossils. The first one, in the Akbük-Milas area, is located south-east of Bafa Lake where the Milas, then KLzLla<aç and KazLklL formations are well exposed. There, the Milas formation grades upwards into the KLzLla<aç formation. The contact between the KLzLla<aç and the overlying KazLklL formation is not clearly seen but is interpreted as an unconformity. The Milas and KLzLla<aç formations are also found north of Mu<la, in the region of Yata<an and KavaklLdere. In these areas, the Milas formation consists of schists and conformably overlying platform-type, emery and rudist-bearing marbles. Rudists form the main palaeontological data from which a Santonian-Campanian age is indicated. The KLzLla<aç formation is characterized by reddish-greyish pelagic marbles with marly-pelitic interlayers and coarsening up debris flow deposits. Pelagic marbles within the formation contain planktonic foraminifera and nanoplankton of late Campanian to late Maastrichtian age. The KazLklL formation is of flysch type and includes carbonate blocks. Planktonic foraminifera of Middle Palaeocene age are present in carbonate lenses within the formation. In the Serinhisar-Tavas area, Mesozoic platform-type marbles (YLlanlL formation) belonging to the cover series of the Menderes Massif exhibit an imbricated internal structure. Two rudist levels can be distinguished in the uppermost part of the formation: the first indicates a middle-late Cenomanian age and the upper one is Santonian to Campanian in age. These marbles are unconformably covered by the Palaeocene-Early Eocene Zeybekölentepe formation with polygenetic breccias. In the Çal-Denizli area, the Menderes massif succession consists of cherty marbles and clastic rocks with metavolcanic lenses. The Lower-Middle Eocene zalvan formation lies unconformably on this sequence and is interpreted as equivalent to the marble horizons at Serinhisar but with pelagic facies. The zalvan formation consists of shale, mafic volcanic rock, lenses of limestone and blocks of recrystallized limestone. The zalvan formation is dated here for the first time by Early-Middle Eocene foraminifera and nanoplankton from the matrix of the formation. An angular unconformity exists between the Upper Cretaceous and Lower Tertiary sequences, suggesting that a phase of deformation affected the southern and eastern part of the Menderes Massif at this time. This deformation may be caused by initial obduction of the Lycian ophiolite onto the passive margin to the north of the Menderes carbonate platform during the latest Cretaceous. Drowning of the platform led to termination of carbonate deposition and deposition of deep water flysch-like clastic sediments.  相似文献   

GPS constraints on Africa (Nubia) and Arabia plate motions   总被引：16，自引：0，他引：16  

S. McClusky  R. Reilinger  S. Mahmoud  D. Ben Sari  A. Tealeb 《Geophysical Journal International》2003,155(1):126-138

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Phenolic endocrine disrupting chemicals (EDCs) in Anzali Wetland, Iran: elevated concentrations of 4-nonylphenol, octhylphenol and bisphenol A   总被引：2，自引：0，他引：2  

Mortazavi S  Bakhtiari AR  Sari AE  Bahramifar N  Rahbarizade F 《Marine pollution bulletin》2012,64(5):1067-1073

We have studied the distribution and value of phenolic endocrine disrupting chemicals (EDCs) in surface sediment samples taken from Anzali Wetland, Iran. These samples were collected from 22 stations during the time span of June-May 2010. In each of the sampling stations, we detected 4-nonylphenol (4-NP), octylphenol (OP), and bisphenol A (BPA) with maximal concentrations of 29, 4.3, and 7 μg g(-1) dry weight (dw), respectively. High levels of alkylphenols (APs) and BPA were also found near urban areas. Furthermore there were no significant differences between those stations in terms of the detected levels. One of the important factors in controlling the fate of these compounds in the aquatic environment appeared to be Total Organic Carbon (TOC). Hierarchical cluster analysis showed differences in the biomarker characteristics of EDCs and TOC between the stations. Our findings indicate that EDCs are ubiquitous in sediments from northeast Wetlands of Iran, contaminating the aquatic habitats in this area.  相似文献   

Detection of Lineaments in Denizli Basin of Western Anatolia Region Using Bouguer Gravity Data     

Figen F. Altinoğlu  Murat Sari  Ali Aydin 《Pure and Applied Geophysics》2015,172(2):415-425

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Relating food and human hair to assess mercury exposure levels in Poboya,Central Sulawesi,Indonesia     

M. M. Sari  T. Inoue  Y. Matsumoto  K. Yokota 《International Journal of Environmental Science and Technology》2017,14(3):463-472

Poboya is a major small-scale gold-mining area in Central Sulawesi, Indonesia, that has been operating since 2009. About 200–500 kg of mercury is released each day as a result of gold-mining activities over a total area of 7000 ha. We examined mercury contamination by using two types of sample, namely food and human hair. Samples were obtained in Poboya and in the city of Palu, 11 km away. Samples of 22 foods were obtained from traditional markets in Poboya and Palu. Total mercury concentrations ranged from 0.003 to 0.31 µg/g in foods from Poboya and from 0.001 to 0.13 µg/g in those from Palu. The highest total mercury concentration in Poboya was found in unripe banana, which is frequently consumed by the local people. In Poboya, the weekly mercury intakes from foods were calculated at 180.3 µg/person from vegetables, 1.7 µg/person from processed foods, 51.4 µg/person from seafood, and 17.2 µg/person from meat and eggs. In Palu, the weekly mercury intakes were 2.9 µg/person from vegetables, 3.1 µg/person from processed foods, 60.8 µg/person from seafood, and 19 µg/person from meat and eggs. These findings delineated Poboya as an area polluted by mercury contamination. Intake of mercury-contaminated food influenced the results obtained in human hair. Hair concentrations of total mercury in Poboya ranged from 0.3 to 19.6 µg/g.  相似文献   

Investigation of dynamic behavior of geosynthetic reinforced soil retaining structures under earthquake loads     

Erol Guler  Ali K. Enunlu 《Bulletin of Earthquake Engineering》2009,7(3):737-777

The results of an experimental study conducted on two 1:2 reduced-scale geotextile-reinforced soil retaining walls are presented and discussed. El Centro earthquake and sinusoidal harmonic motion excitations were applied to the 1.9 m tall models. The design parameter investigated was the reinforcement length (L/H = 0.9 in the 1st model and L/H = 0.6 in the 2nd model). The results were analyzed to evaluate the acceleration amplification, strains in the reinforcement layers and facing wall deformation. The test results showed that in both experiments the walls were in fact designed to behave rigidly and almost no residual displacements were observed on the front of the wall. The most important conclusion drawn from the experimental work was that Geosynthetic Reinforced Retaining Structures designed according to the current specifications behave very successfully under earthquake loading conditions.  相似文献   

Influence of large dam on seismic hazard in low seismic region of Ulu Padas Area,Northern Borneo     

Ade Faisal  Taksiah A. Majid  Fauziah Ahmad  Felix Tongkul  Syafrina Mayang Sari 《Natural Hazards》2011,59(1):237-269

The seismic hazard assessment of a site that lies in the low seismic region affected by the future existence of a large dam has been given less attention in many studies. Moreover, this condition is not addressed directly in the current seismic codes. This paper explains the importance of such information in mitigating the seismic hazard properly. Ulu Padas Area in Northern Borneo is used as an example for a case study of a site classified as a low seismic region. It is located close to the border of Malaysia, Brunei Darussalam, and Indonesia and may have a large dam in the future as the region lies in hilly geography with river flow. This study conducts probabilistic and deterministic seismic hazard analyses, and reservoir-triggered seismicity of a site affected by the future existence of a large dam. The result shows that the spectrum acceleration of the maximum design earthquake for the investigated site in the Ulu Padas Area in Northern Borneo is taken from the reservoir-triggered seismicity earthquake at short periods and from the current condition at longer periods.  相似文献   

Batch and Continuous Design of a Full‐Scale Treatment Facility for Removing Dissolved Natural Organic Matter     

Bulent Sari  Ali Erdem Oztas  Olcayto Keskinkan  Cagatayhan Bekir Ersu 《洁净——土壤、空气、水》2021,49(1)

Batch and continuous flow adsorption experiments are carried out and the design of a full‐scale facility for removing dissolved natural organic matter (DNOM) from Catalan Lakewater is demonstrated. The adsorption efficiency is proportional to the temperature and the amount of adsorbent unlike pH increase. The highest DNOM removal rate is obtained at 35 °C, pH 4, and an adsorbent amount of 0.8 g L^?1. Optimum contact time for batch studies is 60 min at equilibrium. Correlation constants (r) of Langmuir and Freundlich isotherms are 0.8905 and 0.9739, respectively. Based on the Freundlich isotherm, the highest adsorption capacity (q_max) obtained is 2.44 and 6.01 mg DNOM/g granulated activated carbon (GAC) for raw and enriched water, respectively. Consequently, the effects of adsorbent amount, bed depth, empty bed contact time, and organic loading on removal performance are investigated in the rapid small‐scale column test (RSSCT) columns. The targeted effluent concentration of 1 mg DNOM/L can easily be achieved in the columns. At the design capacity of the facility, 15 adsorption columns with dimensions of 7 m height, 4.33 m diameter, and 22 days of operation cycle are required to remove DNOM from raw water.  相似文献