CaPtO3 as a novel post-perovskite oxide     

Kenya Ohgushi  Yoshitaka Matsushita  Nobuyoshi Miyajima  Yoshio Katsuya  Masahiko Tanaka  Fujio Izumi  Hirotada Gotou  Yutaka Ueda  Takehiko Yagi 《Physics and Chemistry of Minerals》2008,35(4):189-195

Structural, morphological, magnetic, and thermal properties have been investigated for a novel post-perovskite oxide CaPtO₃ synthesized under high pressure. By comparing obtained structural parameters with those for known post-perovskite compounds, we argue that the chemical bond has a strong covalent character. Precise measurements of the Langevin susceptibility χ ₀ = −9.6 × 10⁻⁵ emu/mol and Debye temperature θ ∼ 470 K provide a good opportunity to confirm the reliability of first-principle calculations on predicting physical properties of the Earth’s D” layer.  相似文献   

A framework for economic loss estimation due to seismic transportation network disruption: a spatial computable general equilibrium approach   总被引：4，自引：4，他引：0  

Hirokazu Tatano  Satoshi Tsuchiya 《Natural Hazards》2008,44(2):253-265

This paper presents a framework for assessing the economic impact of disruption in transportation that can relate the physical damage to transportation networks to economic losses. A spatial computable general equilibrium (SCGE) model is formulated and then integrated with a transportation model that can estimate the traffic volumes of freight and passengers. Economic equilibrium under a disruption in the transportation network is computed subject to the condition that the adjustment of labor and capital inputs is restricted; the model reflects slow adjustment of these linked to the state of recovery. As a case study, the model reviews the large Niigata-Chuetsu earthquake of 2004. Considering the damage to the transportation infrastructure, the model indicates the extent of the economic losses arising from the earthquake distributed over regions as a consequence of the intra- and interregional trade in a regional economy. The results show that 20% of the indirect losses occur in the Niigata region directly affected by the earthquake, whereas 40% of the total losses are experienced in the Kanto region and non-negligible losses reach rather remote zones of the country such as Okinawa.  相似文献   

Selective detection of Fe and Mn species at mineral surfaces in weathered granite by conversion electron yield X-ray absorption fine structure     

Takaaki Itai  Yoshio Takahashi  Tomoya Uruga  Hajime Tanida  Atsuo Iida 《Applied Geochemistry》2008

A new method for the speciation of Fe and Mn at mineral surfaces is proposed using X-ray absorption fine structure in conversion electron yield mode (CEY-XAFS). This method generally reflects information on the species at the sub-μm scale from the particle surface due to the limited escape depth of the inelastic Auger electron. The surface sensitivity of this method was assessed by experiments on two samples of granite showing different degrees of weathering. The XANES spectra of the Fe-K and Mn-K edge clearly gave different information for CEY and fluorescence (FL) modes. These XANES spectra of Fe and Mn show a good fit upon application of least-squares fitting using ferrihydrite/MnO₂ and biotite as the end members. The XANES spectra collected by CEY mode provided more selective information on the secondary phases which are probably present at the mineral surfaces. In particular, CEY-XANES spectra of Mn indicated the presence of Mn oxide in unweathered granite despite a very small contribution of Mn oxide being indicated by FL-XANES and selective chemical-extraction analyses. Manganese oxide could not be detected by micro-beam XANES (beam size: 5 × 5 μm²) in unweathered granite, suggesting that Mn oxide thinly and ubiquitously coats mineral surface at a sub-μm scale. This information is important, since Mn oxide can be the host for various trace elements. CEY-XAFS can prove to be a powerful tool as a highly sensitive surface speciation method. Combination of CEY and FL-XAFS will help identify minor phases that form at mineral surfaces, but identification of Fe and Mn oxides at mineral surfaces is critical to understand the migration of trace elements in water-rock interaction.  相似文献   

Complex organic molecules in an early stage of protostellar evolution     

Nami Sakai  Takeshi Sakai  Satoshi Yamamoto 《Astrophysics and Space Science》2008,313(1-3):153-157

We have detected the rotational lines of HCOOCH₃ toward a Class 0 low-mass protostar, NGC1333 IRAS4B, which is reported to be extremely young according to the dynamical age of the molecular outflow (a few 100 yr). This suggests that the complex organic molecules appear from the very early stage of protostellar evolution. On the other hand, the complex organic molecules are not detected in a more evolved protostar, L1527. We have also found a similar trend in a massive star forming region, NGC2264. The HCOOCH₃ emission is almost absent toward IRS1, whereas it is concentrated near MMS3, which is younger than IRS1. In addition, the HCOOCH₃ intensity peak is slightly shifted from the dust emission peak, as is seen in the Orion KL Compact Ridge, giving an important clue to solve its origin.  相似文献   

Groundwater dynamics of Fongafale Islet, Funafuti Atoll, Tuvalu     

Nakada S  Umezawa Y  Taniguchi M  Yamano H 《Ground water》2012,50(4):639-644

Geoelectric and hydrologic surveys during spring tides revealed the spatiotemporal distribution of groundwater quality produced by tidal forcing in Fongafale Islet, Funafuti Atoll, Tuvalu. The observed low resistivity showed that saline water largely immersed the surficial Holocene aquifer, indicating that there is no thick freshwater lens in Fongafale Islet, unlike in other atoll islands of comparable size. Half of the islet was constructed by reclaiming the original swamp with porous, highly permeable coral blocks; this reclaimed area should not be considered as part of the islet width for calculation of the expected thickness of the freshwater lens. The degree of aquifer salinization depends on the topographic characteristics and the hydrologic controls on the inland propagation of the tidal forcing. Large changes in bulk resistivity and the electrical conductivity of groundwater from wells indicate that periodic salinization in phase with the semidiurnal tides was occurring widely, especially in areas at lower elevation than the high-tide level and in reclaimed areas with high permeability. Thin sheets of nearly fresh and brackish water were observed in the surficial aquifer in areas above the high-tide level and in taro swamps, respectively. The thinness of the brackish and freshwater sheets suggests that the taro swamps and the fresh groundwater resources of the islet are highly vulnerable to salinization from anticipated sea-level rise. An understanding of the inherent geologic and topographic features of an atoll is necessary to evaluate the groundwater resources of the atoll and assess the vulnerability of its water resources to climate change.  相似文献   

Persistence and metallic composition of paint particles in sediments from a tidal inlet     

Takahashi CK  Turner A  Millward GE  Glegg GA 《Marine pollution bulletin》2012,64(1):133-137

Concentrations of Cu, Pb, Sn and Zn have been determined in sediment (<500 μm) and macroscopic paint particles (>500 μm) retrieved from sections of two cores collected from a tidal inlet of the Plym estuary, southwest England. Paint particles contributed up to about 0.2% of the total mass retrieved from each section and were most abundant towards the base of the cores where, according to (210)Pb dating, deposition took place about a decade prior to sampling. Metal concentrations in the paint particles pooled from the sections were highly variable, typically spanning two orders of magnitude in each core, and were greatest for Cu and Zn (up to 460,000 and 170,000 μg g(-1), respectively) due to their use in contemporary antifouling formulations applied to boat hulls. Concentrations of metals in the sediment were, however, relatively invariant, an effect attributed to the abundance and dispersion of microscopic paint particles throughout the cores.  相似文献   

AMS analysis of I in Japanese soil samples collected from background areas far from nuclear facilities     

Yasuyuki Muramatsu  Yukari Takada  Hiroyuki Matsuzaki  Satoshi Yoshida 《Quaternary Geochronology》2008,3(3):291-297

Analytical procedures in the determination of iodine-129 (half-life: 1.6×10⁷ y) have been studied using accelerator mass spectrometry (AMS), with special references to the separation procedures of iodine from soil samples for the AMS measurement. Iodine was successfully volatilized from soil samples by pyrohydrolysis at 1000 °C and collected in a trap solution. Iodine was purified from the matrix by solvent extraction. Finally, it was precipitated as silver iodide to make a target for AMS. In order to obtain information on the ¹²⁹I/¹²⁷I ratio in a chemical blank (or iodine carrier), we have determined the ratios in several iodine reagents and found that the ratios fell in a narrow range around 1.7×10⁻¹³. The detection limit for soil sample (1 g material) by the present method was about 0.01 mBq/kg or 4×10⁻¹¹ as the ratio of stable iodine (¹²⁹I/¹²⁷I ratio), i.e. these values were much better than that by neutron activation analysis (NAA) used in our previous studies. We have applied this method in the analysis of soil samples collected from different places in Japan. We could successfully determine ¹²⁹I in soil samples with low ¹²⁹I concentrations, which could not be detected by NAA. Sample size necessary for the soil analysis by AMS was only about 0.5 g or less, whereas about 100 g of the sample were required for NAA [Muramatsu, Y., Ohmomo, Y., 1986. Iodine-129 and iodine-127 in environmental samples collected from Tokaimura/ Ibaraki, Japan. Sci. Total Environ. 48, 33-43]. Using this method, new data were obtained for the ¹²⁹I levels in 20 soil samples collected from background areas far from nuclear facilities, and the ranges were 1.4×10⁻⁵−4.5×10⁻³ Bq/kg as ¹²⁹I concentrations and 3.9×10⁻¹¹−2.2×10⁻⁸ as ¹²⁹I/¹²⁷I ratios. These values are useful in understanding the ¹²⁹I levels in Japanese environments. Higher ¹²⁹I concentrations were observed in forest soils than those in field and rice paddy soils should be related to the interception effect of atmospheric ¹²⁹I due to tree canopies. Relatively high ¹²⁹I/¹²⁷I ratios found in rice paddy soils could be explained by their low stable iodine concentrations which were caused by the desorption of stable iodine from the rice paddies during the cultivation.  相似文献   

Benthic ecosystem development in an artificial tidal flat constructed from dredged spoil     

Ishii R  Nakano Y  Nakai S  Nishijima W  Okada M 《Marine pollution bulletin》2008,56(12):2059-2066

Dredged spoil (DS) was used as a silt and clay additive in the construction of artificial tidal flats from mountain sand (MS). As the ratio of DS in the sediment media increased, the number of emerging macrobenthos increased. The composition of the macrobenthic community was also affected by the addition of DS, and the changes might be dependent on the ratio of DS to MS. In addition, the macrobenthos in the artificial tidal flats was more abundant than that in the control tidal flat, which was constructed with natural tidal flat sediment. With a silt and clay content of 25%, polychaetes Ceratonereis erythraeensis and Capitella sp. and the gastropod Batillaria cumingii were dominant, whereas no bivalves were present. With less silt and clay (5% and 10%), the bivalves Ruditapes philippinarum and Musculista senhousia were observed in the artificial flats, while their numbers in the control tidal flat were lower.  相似文献   

Geological relationship between Anyui Metamorphic Complex and Samarka terrane,Far East Russia     

Satoru Kojima  Kazuhiro Tsukada  Shigeru Otoh  Satoshi Yamakita  Masayuki Ehiro  Cheikhna Dia  Galina Leontievna Kirillova  Vladimir Akimovich Dymovich  Lyudmila Petrovna Eichwald 《Island Arc》2008,17(4):502-516

The Anyui Metamorphic Complex (AMC) of Cretaceous age is composed of metachert, schist, gneiss, migmatite and ultramafic rocks, and forms a dome structure within the northernmost part of the Jurassic accretionary complex of the Samarka terrane. The two adjacent geological units are bounded by a fault, but the gradual changes of grain size and crystallinity index of quartz in chert and metachert of the Samarka terrane and the AMC, together with the gradual lithological change, indicate that at least parts of the AMC are metamorphic equivalents of the Samarka rocks. Radiolarian fossils from siliceous mudstone of the Samarka terrane indicates Tithonian age (uppermost Jurassic), and hence, form a slightly later accretion. This signifies that the accretionary complex in the study area is one of the youngest tectonostratigraphic units of the Samarka terrane. The relationship between the Samarka terrane and AMC, as well as their ages and lithologies, are similar to those of the Tamba–Mino–Ashio terrane and Ryoke Metamorphic Complex in southwest Japan. In both areas the lower (younger) part of the Jurassic accretionary complexes were intruded and metamorphosed by Late Cretaceous granitic magma. Crustal development of the Pacific‐type orogen has been achieved by the cycle of: (i) accretion of oceanic materials and turbidites derived from the continent; and (ii) granitic intrusion by the next subduction and accretion events, accompanied by formation of high T/P metamorphic complexes.  相似文献   

Geological and Geochemical Characteristics of Gold Mineralization in the Salu Bulo Prospect,Sulawesi, Indonesia     

Muhammad Zain Tuakia  Ryohei Takahashi  Akira Imai 《Resource Geology》2019,69(2):176-192

The Salu Bulo prospect is one of the gold prospects in the Awak Mas project in the central part of the western province, Sulawesi, Indonesia. The gold mineralization is hosted by the meta‐sedimentary rocks intercalated with the meta‐volcanic and volcaniclastic rocks of the Latimojong Metamorphic Complex. The ores are approximately three meters thick, consisting of veins, stockwork, and breccias. The veins can be classified into three stages, namely, early, main, and late stages, and gold mineralization is related to the main stage. The mineral assemblage of the matrix of breccia and the veins are both composed of quartz, carbonate (mainly ankerite), and albite. High‐grade gold ores in the Salu Bulo prospect are accompanied by intense alteration, such as carbonatization, albitization, silicification, and sulfidation along the main stage veins and breccia. Alteration mineral assemblage includes ankerite ± calcite, quartz, albite, and pyrite along with minor sericite. Pyrite is the most abundant sulfide mineral that is spatially related to native gold and electrum (<2–42 μm in size). It is more abundant as dissemination in the altered host rocks than those in veins. This suggests that water–rock interaction played a role to precipitate pyrite and Au in the Salu Bulo prospect. The Au contents of intensely altered host rocks and ores have positive correlations with Ag, Ni, Mo, and Na. Fluid inclusions in the veins of the main stage and the matrix of breccia are mainly two‐phase liquid‐rich inclusions with minor two‐phase, vapor‐rich, and single‐phase liquid or vapor inclusions. CO₂ and N₂ gases are detected in the fluid inclusions by Laser Raman microspectrometry. Fluid boiling probably occurred when the fluid was trapped at approximately 120–190 m below the paleo water table. δ¹⁸O_SMOW values of fluid, +5.8 and +7.6‰, calculated from δ¹⁸O_SMOW of quartz from the main stage vein indicate oxygen isotopic exchange with wall rocks during deep circulation. δ³⁴S_CDT of pyrite narrowly ranges from ?2.0 to +3.4‰, suggesting a single source of sulfur. Gold mineralization in the Salu Bulo prospect occurred in an epithermal condition, after the metamorphism of the host rocks. It formed at a relatively shallow depth from fluids with low to moderate salinity (3.0–8.5 wt% NaCl equiv.). The temperature and pressure of ore formation range from 190 to 210°C and 1.2 to 1.9 MPa, respectively.  相似文献