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741.
THE MONSOON IN THE ARABIAN SEA:IMPLICATIONS FROM RADIOLARIAN FLUXES TO THE DEEP SEA  相似文献   
742.
The weathering of granodiorite porphyry is examined in the extremely cold and dry environment of the inland part of Antarctica. Weathering features include granular disintegration, rock varnish, and sheeting. Sheeting has gradually proceeded since the exposing of the nunatak, but the other types of weathering have not actively advanced in recent times.
Granular disintegration primarily comprises the release of individual crystals. The mechanism of this release is that cracks are created along crystal boundaries and cleavages in phenocrysts mainly due to differential thermal expansion. Plagioclase and hypersthene are released more readily than quartz. Disintegration of plagioclase has produced many prism-shaped holes, 0.5 to 2.0 mm in length, while fine-grained quartz crystals, 0.05 to 0.1 mm in diameter, are incidentally released without cracking.
The reddish brown (10R4/4) rock varnishes result from oxidation and consist of limonite, which fills cracks and penetrates into crystals. Ferrous iron in hypersthene, biotite, ilmenite and magnetite is transformed into limonite by oxidation. Manganese is not found in the varnishes. Sulfur, which is important for oxidation and which may have originated from adhered snow, is concentrated on the surface of the rock.
Sheeting has precipitated rock falls, and has gradually formed a gray mosaic on the varnished wall. The sheeting was caused by gravitational body force, which is internal stress of the rock body due to the mass of the overburden.  相似文献   
743.
Geoelectric and hydrologic surveys during spring tides revealed the spatiotemporal distribution of groundwater quality produced by tidal forcing in Fongafale Islet, Funafuti Atoll, Tuvalu. The observed low resistivity showed that saline water largely immersed the surficial Holocene aquifer, indicating that there is no thick freshwater lens in Fongafale Islet, unlike in other atoll islands of comparable size. Half of the islet was constructed by reclaiming the original swamp with porous, highly permeable coral blocks; this reclaimed area should not be considered as part of the islet width for calculation of the expected thickness of the freshwater lens. The degree of aquifer salinization depends on the topographic characteristics and the hydrologic controls on the inland propagation of the tidal forcing. Large changes in bulk resistivity and the electrical conductivity of groundwater from wells indicate that periodic salinization in phase with the semidiurnal tides was occurring widely, especially in areas at lower elevation than the high-tide level and in reclaimed areas with high permeability. Thin sheets of nearly fresh and brackish water were observed in the surficial aquifer in areas above the high-tide level and in taro swamps, respectively. The thinness of the brackish and freshwater sheets suggests that the taro swamps and the fresh groundwater resources of the islet are highly vulnerable to salinization from anticipated sea-level rise. An understanding of the inherent geologic and topographic features of an atoll is necessary to evaluate the groundwater resources of the atoll and assess the vulnerability of its water resources to climate change.  相似文献   
744.
Concentrations of Cu, Pb, Sn and Zn have been determined in sediment (<500 μm) and macroscopic paint particles (>500 μm) retrieved from sections of two cores collected from a tidal inlet of the Plym estuary, southwest England. Paint particles contributed up to about 0.2% of the total mass retrieved from each section and were most abundant towards the base of the cores where, according to (210)Pb dating, deposition took place about a decade prior to sampling. Metal concentrations in the paint particles pooled from the sections were highly variable, typically spanning two orders of magnitude in each core, and were greatest for Cu and Zn (up to 460,000 and 170,000 μg g(-1), respectively) due to their use in contemporary antifouling formulations applied to boat hulls. Concentrations of metals in the sediment were, however, relatively invariant, an effect attributed to the abundance and dispersion of microscopic paint particles throughout the cores.  相似文献   
745.
We have detected the rotational lines of HCOOCH3 toward a Class 0 low-mass protostar, NGC1333 IRAS4B, which is reported to be extremely young according to the dynamical age of the molecular outflow (a few 100 yr). This suggests that the complex organic molecules appear from the very early stage of protostellar evolution. On the other hand, the complex organic molecules are not detected in a more evolved protostar, L1527. We have also found a similar trend in a massive star forming region, NGC2264. The HCOOCH3 emission is almost absent toward IRS1, whereas it is concentrated near MMS3, which is younger than IRS1. In addition, the HCOOCH3 intensity peak is slightly shifted from the dust emission peak, as is seen in the Orion KL Compact Ridge, giving an important clue to solve its origin.  相似文献   
746.
There is an urgent need to control nutrient release fluxes from organically-enriched sediments into overlying waters to alleviate the effects of eutrophication. This study aims to characterize blast furnace slag (BFS) and evaluate its remediation performance on organically-enriched sediments in terms of suppressing nutrient fluxes and reducing acid volatile sulfide. BFS was mainly composed of inorganic substances such as CaO, SiO2, Al2O3 and MgO in amorphous crystal phase. Container experiments showed that the phosphate concentration in the overlying water, its releasing flux from sediment and AVS of the sediment decreased by 17-23%, 39% and 16% compared to the control without BFS, respectively. The loss on ignition was significantly decreased by 3.6-11% compared to the control. Thus, the application of BFS to organically-enriched sediment has a suppressive role on organic matter, AVS concentration and phosphate releasing flux from sediments and therefore, is a good candidate as an effective environmental remediation agent.  相似文献   
747.
A solid‐phase extraction (SPE)‐gas chromatography (GC)‐mass spectrometry (MS) analytical method was developed for the simultaneous analysis of natural free estrogens and their conjugates in wastewater samples. Natural free estrogens and their conjugates in wastewater were successfully separated by the oasis hydrophilic‐lipophilic balance solid phase extraction (Oasis HLB SPE) method, and the conjugates were initially enzyme hydrolyzed by β‐glucuronidase or arylsulfatase from Helix pomatia prior to derivatization. N‐methyl‐N‐(tert‐butyldimethylsilyl)trifluoroacetamide (MTBSTFA) plus 1% tert‐butyldimetheylchlorosilane (TBDMCS) was chosen as the derivatization reagent, and the most appropriate conditions of derivatization were determined to be at 95°C for 90 min. The recovery ratios of nine target chemicals were determined by spiking them in 1 L of ultra‐purified water or the influent of a wastewater treatment plant (WWTP). The recovery ratios of six out of nine for the analytes ranged from 73.3–114.9% with relative standard deviations (RSD) from 1.6–19.9%. The established method was successfully applied to environmental wastewater samples which were collected from one municipal wastewater treatment plant (WWTP) in Osaka, Japan, for the determination of natural free estrogens and their conjugates. In the influent sample, E1, E2, E1‐3S, E3‐3S, and E1‐3G were detected at concentrations of 16.6, 9.6, 8.2, 21.9, and 3.2 ng L–1, respectively. However, only E1 was detected at a high concentration of 44 ng L–1 in the effluent sample, suggesting that it is the dominant natural free estrogen in the effluent.  相似文献   
748.
Natural estrogens from humans increasingly attract attention because of their strong endocrine disrupting potency. The discharge of sewage water is considered as the most important source of these endocrine disrupting chemicals (EDCs) in the environment. Therefore, a GC‐MS method was developed for the simultaneous analysis of six natural free estrogens and their sulfate conjugates in municipal wastewater, in which natural free estrogens and sulfate conjugates were successfully separated from an Oasis HLB solid phase extraction (SPE) cartridge with two different eluents, and the sulfate conjugates were then transformed to their corresponding free estrogens by acid solvolysis. Before the analysis with GC‐MS, samples were derivatized by N,O‐bis (trimethylsilyl) trifluoroacetamide (BSTFA) plus 1% trimethylchlorosilane (TMCS) at 80°C for 40 min. Satisfactory recoveries ranging from 64 to 112.3% were obtained by spiking ultra‐purified water, raw, and treated municipal wastewater with the six estrogens at 50, 100, and 50 ng/L, respectively. The method was successfully applied to wastewater samples from one WWTP, which suggested that E1 was the dominant natural estrogens in effluent and E3‐3S was one of the conjugates possibly occurring in the effluent.  相似文献   
749.
Large earthquake-induced displacements of a bridge abutment can occur, when the bridge is built on a floodplain or reclaimed area, i.e., liquefiable ground, and crosses a water channel. Seismic responses of a bridge abutment on liquefiable ground are the consequence of complex interactions between the abutment and surrounding soils. Therefore identification of the factors dominating the abutment response is important for the development of simplified seismic design methods. This paper presents the results of dynamic three-dimensional finite element analyses of bridge abutments adjacent to a river dike, including the effect of liquefaction of the underlying ground using earthquake motions widely used in Japan. The analysis shows that conventional design methods may underestimate the permanent abutment displacements unless the following two items are considered: (1) softening of the soil beneath the liquefiable layer, due to cyclic shearing of the soil surrounding the piles, and (2) the forces acting on the side faces of the abutment.  相似文献   
750.
Flow fluctuations inside an anticyclonic eddy in summertime Funka Bay were examined using three moorings and hydrographic data. The flow pattern above a sharp pycnocline with a concave isopycnal structure during the mooring period was characterized by high mean kinetic energy and relatively low eddy kinetic energy. The ratios of eddy to mean kinetic energy were equal to or less than one, and the mean flow field and isopycnal structure indicated the existence of a stable anticyclonic eddy above the sharp pycnocline under approximate geostrophic balance. Larger flow fluctuations with periods longer than 7 days were dominant inside the eddy. The low-frequency flow fluctuations are accompanied by north to northeastward movement of the eddy with deepening of the pycnocline and spin-up of the anticyclonic circulation. The wind field over Funka Bay is characterized by bay-scale wind fluctuations. The bay-scale winds are greatly influenced by the land topography around Funka Bay, resulting in non-uniform structure with significant wind stress curl. The bay-scale wind fluctuations are termed “locally modified wind” in the present study. The locally modified wind has a negative (positive) wind stress curl in the central–northeastern (southwestern) region of Funka Bay. The north to northeastward movement of the eddy is caused by horizontal non-uniform supply of vorticity from the locally modified wind forcing by the Ekman pumping process. Through this process, the anticyclonic circulation is enhanced (weakened) in the central–northeastern (southwestern) part of the eddy, resulting in the eddy moving north to northeastward with the pycnocline deepening and spin-up of the anticyclonic circulation. The locally modified wind forcing induces low-frequency flow fluctuations through the movement of the eddy in summertime Funka Bay.  相似文献   
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