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31.
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CDB-P (phosphorus extractable by the citrate-dithionite-bicarbonate extraction procedure) was used as the indicator of bio-available inorganic P in the suspended and surface sediments in the inner part of Ariake Bay. The CDB-P pool of suspended and surface sediments in the tidal flat area was estimated to be 10 ton and 90 ton, respectively (total of 100 ton), which corresponds to 1.5 times the average dissolved inorganic phosphorus standing stock. During the summer periods of hypoxia, the CDB-P concentration in the surface sediments decreased with the decline of Eh, losing 43–47% of the CDB-P observed in April. These results suggest that the phosphorus dynamics have been affected by the decrease of resuspended sediment concentrations brought about by the reduction of the tidal currents and phosphate release from the surface sediments during frequently occurring summer hypoxia events.  相似文献   
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Micro‐X‐ray fluorescence scanning spectroscopy of marine and lake sedimentary sequences can provide detailed palaeoenvironmental records through element intensity proxy data. However, problems with the effects of interstitial pore water on the micro‐X‐ray fluorescence intensities have been pointed out. This is because the X‐ray fluorescence intensities are measured directly at the surfaces of split wet sediment core samples. This study developed a new method for correcting X‐ray fluorescence data to compensate for the effects of pore water using a scanning X‐ray analytical microscope. This involved simultaneous use of micro‐X‐ray fluorescence scanning spectroscopy and an X‐ray transmission detector. To evaluate the interstitial pore water content from the X‐ray transmission intensities, a fine‐grained sediment core retrieved from Lake Baikal (VER99‐G12) was used to prepare resin‐embedded samples with smooth surfaces and uniform thickness. Simple linear regression between the linear absorption coefficients of the samples and their porosity, based on the Lambert–Beer law, enabled calculation of the interstitial pore spaces and their resin content with high reproducibility. The X‐ray fluorescence intensities of resin‐embedded samples were reduced compared with those of dry sediment samples because of: (i) the X‐ray fluorescence absorption of resin within sediment; and (ii) the sediment dilution effects by resin. An improved micro‐X‐ray fluorescence correction equation based on X‐ray fluorescence emission theory considers the instrument's sensitivity to each element, which provides a reasonable explanation of these two effects. The resin‐corrected X‐ray fluorescence intensity was then successfully converted to elemental concentrations using simple linear regression between the data from micro‐X‐ray fluorescence scanning spectroscopy and from the conventional analyzer. In particular, the calculated concentration of SiO2 over the depth of the core, reflecting diatom/biogenic silica concentration, was significantly changed by the calibrations, from a progressively decreasing trend to an increasing trend towards the top of the core.  相似文献   
35.
The temporal evolution of a thin phytoplankton layer was observed by field measurements using a research vessel and mooring instruments in the Yatsushiro Sea, a semi-enclosed narrow embayment in Japan, in early August 2013. The subsurface chlorophyll maximum developed into a thin layer within 2 days just below the pycnocline at around 10-m depth, where turbulent mixing (the dissipation rate of turbulent kinetic energy) was weak (low). The layer persisted for 1.5 to 2 days and declined after irradiance drastically decreased at the sea surface. At the peak period, the layer thickness, which is defined as the full-width at half-maximum of the peak in chlorophyll a concentration, ranged from 0.6 to 1.4 m, and the maximum concentration reached 42.3 mg m?3. The horizontal extent of the layer was approximately 10 km along the longitudinal axis of the bay. The phytoplankton population characterized by the layer was dominated by a chain-forming centric diatom, Chaetoceros spp. The formation mechanisms of the thin diatom layer were investigated using the observed data and a vertical one-dimensional model that includes physical and biological processes. The results suggest that the development of the thin layer was caused by in situ growth and aggregation due to nutrient-dependent sinking of the species under weak turbulence. The study highlights that continuous multidisciplinary observations and understanding species-specific physiological responses to environmental variations are necessary to elucidate drastically fluctuating phytoplankton dynamics in a coastal water.  相似文献   
36.
An historical objective analysis of subsurface temperature and salinity was carried out on a monthly basis from 1945 to 2003 using the latest observational databases and a sea surface temperature analysis. In addition, steric sea level changes were mainly examined using outputs of the objective analyses. The objective analysis is a revised version of Ishii et al. and is available at 16 levels in the upper 700 m depth. Artificial errors in the previous analysis during the 1990s have been worked out in the present analysis. The steric sea level computed from the temperature analysis has been verified with tide gauge observations and TOPEX/Poseidon sea surface height data. A correction for crustal movement is applied for tide gauge data along the Japanese coast. The new analysis is suitable for the discussion of global warming. Validation against the tide gauge reveals that the amplitude of thermosteric sea level becomes larger and the agreement improves in comparison with the previous analysis. A substantial part of local sea level rise along the Japanese coast appears to be explained by the thermosteric effect. The thermal expansion averaged in all longitudes from 60°S to 60°N explains at most half of recent sea level rise detected by satellite observation during the last decade. Considerable uncertainties remain in steric sea level, particularly over the southern oceans. Temperature changes within MLD make no effective contribution to steric sea level changes along the Antarctic Circumpolar Current. According to statistics using only reliable profiles of the temperature and salinity analyses, salinity variations are intrinsically important to steric sea level changes in high latitudes and in the Atlantic Ocean. Although data sparseness is severe even in the latest decade, linear trends of global mean thermosteric and halosteric sea level for 1955 to 2003 are estimated to be 0.31 ± 0.07 mm/yr and 0.04 ± 0.01 mm/yr, respectively. These estimates are comparable to those of the former studies.  相似文献   
37.
It has been reported that sand production, which is a simultaneous production of soil particles along with gas and water into a production well, forced to terminate the operation during the world's first offshore methane production test from hydrate-bearing sediments in the Eastern Nankai Tough. The sand production is induced by internal erosion, which is the detachment and migration of soil particles from soil skeleton due to seepage flow. The inflow of the eroded soil particles into the production well leads to damage of the production devices. In the present study, a numerical model to predict the chemo-thermo-mechanically coupled behavior including internal erosion during hydrate dissociation has been formulated based on the multiphase mixture theory. In the proposed model, the internal erosion is expressed as mass transition of soil particles from soil skeleton to the fluidized soil particles. Since the internal erosion is considered to depend on the soil particle size, mass of soil particles are divided into several groups that have different representative particle diameters, and the constitutive equations for the onset condition and the mass transition rate of the internal erosion are formulated for each group. Also, transportation of soil particles in the liquid phase is formulated for each particle size group in the proposed model. Finally, a simulation of the methane gas production from the hydrate-bearing sediment by depressurization method is presented, and the internal erosion and the dissociation behavior are discussed.  相似文献   
38.
In the present study, we have developed a numerical method which can simulate the dynamic behaviour of a seabed ground during gas production from methane hydrate‐bearing sediments. The proposed method can describe the chemo‐thermo‐mechanical‐seismic coupled behaviours, such as phase changes from hydrates to water and gas, temperature changes and ground deformation related to the flow of pore fluids during earthquakes. In the first part of the present study, the governing equations for the proposed method and its discretization are presented. Then, numerical analyses are performed for hydrate‐bearing sediments in order to investigate the dynamic behaviour during gas production. The geological conditions and the material parameters are determined using the data of the seabed ground at Daini‐Atsumi knoll, Eastern Nankai Trough, Japan, where the first offshore production test of methane hydrates was conducted. A predicted earthquake at the site is used in the analyses. Regarding the seismic response to the earthquake which occur during gas production process, the wave profiles of horizontal acceleration and horizontal velocity were not extensively affected by the gas production. Hydrate dissociation behaviour is sensitive to changes in the pore pressure during earthquakes. Methane hydrate dissociation temporarily became active in some areas because of the main motion of the earthquake, then methane hydrate dissociation brought about an increase in the average pressure of the fluids during the earthquake. And, it was this increase in average pore pressure that finally caused the methane hydrate dissociation to cease during the earthquake. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
39.
To understand the effects of temperature, pH and mechanical stress on the pressure dissolution of quartz, two experiments using monocrystalline quartz samples were conducted. The first was a closed-fluid experiment to investigate the effect of pH, and the second was a flow-through experiment to investigate stress and temperature effects. To initiate the pressure dissolution, a pair of samples was immersed in a solution with a prescribed pH. The samples were stressed mechanically by pressing one sample against the other. In the closed-fluid experiments, the pH of the solution was fixed to 7, 9, 11 and 13, the applied stress was approximately 200 MPa and temperature 25°C. The flow-through experiments were conducted at three different temperatures (35, 50 and 75°C) at the same pH 11.7. The value of the applied stress was 7.32, 13.72, 21.42 or 25.27 MPa. During each of these dissolution tests, the solution was regularly sampled and analyzed by an Inductively Coupled Plasma-Atomic Emission Spectrometry technique to measure Si-concentration. With the measured Si-concentration, a dissolution rate constant was computed the different pH, stress and temperature conditions. The rate constant is proportional to pH, stress and temperature, as indicated in the literature. It should be noted that the rate constant for the highest stress (200 MPa) was considerably greater than for the other cases. In addition, island-channel patterns characterized by micro-cracks a few nanometers in length were seen on the dissolved parts of the samples. The findings and the measured data in this paper may be useful for the future development of theoretical models for pressure dissolution and its validation.  相似文献   
40.
A long-term warming pattern of global subsurface ocean was detected separately from other natural variations. Three dominant modes were extracted: a long-term warming mode, a mode related to the El Niño/Southern Oscillation, and a mode related to the Atlantic Multidecadal Oscillation. The long-term warming mode explained 78 % of the global mean temperature variance from the surface to a depth of 300 m, and the other two modes could explain most of the residual variance. Subsurface warming associated with the long-term warming mode was strong in the subtropics. In contrast, there was a local minimum of warming in the northern hemisphere subarctic ocean, and warming was suppressed in subsurface waters south of the equator. Atmospheric changes associated with the long-term warming mode showed negative (positive) sea level pressure anomalies at high (middle) latitudes in both hemispheres, and an intensification and/or a poleward expansion of mid-latitude westerlies. Wind stress curl changes were negative in the subtropics and positive in the subarctic of the northern hemisphere; changes that were consistent with the strong warming in the subtropics and the local minimum of warming in the subarctic. Warming of Southern Ocean subsurface waters coincided with southward migration and intensification of westerly winds, whereas surface warming to the south of 50°S was suppressed, probably by strengthened northward Ekman transport. Positive wind stress curl off the equator with weakening of the tropical easterly winds in the Pacific and Indian Oceans was consistent with the subsurface negative temperature anomaly there.  相似文献   
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