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101.
In the night from 8/9 April 2009, shortly after midnight on Maundy Thursday before Easter, several people in Gross Flottbek, Hamburg, felt unusual strong ground shocks so that some of them left their houses in fear of earthquake shaking. Police and fire brigade received phone calls of worried residents. A few days later, Internet pages were published where people reported their observations. On 21 April 2009 at about 8 p.m. local time, a second ground-shaking event was felt. Damage to buildings or infrastructure did not occur to our knowledge. The Institute of Geophysics, University of Hamburg, installed from 22 April to 17 May 2009 three temporal seismic stations in the epicentral area. Seismological data from two nearby stations at the Deutsches Elektronen-Synchrotron at 1 km and the Geophysical Institute at 7 km distance were collected and integrated to the temporal network. The events occurred above the roof of the shallow Othmarschen Langenfelde salt diapir, in an area known for active sinkhole formation and previous historic ground-shaking events. The analysis of the seismological data shows that three shallow micro-earthquakes occurred from 8 to 21 April at a depth of about 100 m, the largest one with a moment magnitude of about M W 0.6. Depth location of such shallow events is difficult with standard methods and is here constrained by waveform modeling of surface waves. Earthquakes occurring in soft sediments within the uppermost 100 m are a rare phenomena and cannot be explained by standard models. Rupture process in soft sediments differs from those on faults in more competent rock. We discuss the rupture and source mechanism of the events in the context of previous historic shocks and existing sinkhole and deformation data. Although the event was weak, the rupture duration of 0.3 s was unusual long. Three possible models for the generation of repeated ground-shaking events in Gross Flottbek are developed and discussed, implying quit different hazards for subsidence, ground motion, and sinkhole formation. Our favored model postulates that roof failure occurs in an existing soil cavity beneath the epicenter at a depth of about 100 m. Other models bearing a smaller geo-hazard cannot be disproved with the data available, but future geophysical experiments may be planned to resolve this question.  相似文献   
102.
The compound NaFeGe2O6 was grown synthetically as polycrystalline powder and as large single crystals suitable for X-ray and neutron-diffraction experiments to clarify the low temperature evolution of secondary structural parameters and to determine the low temperature magnetic spins structure. NaFeGe2O6 is isotypic to the clinopyroxene-type compound aegirine and adopts the typical HT-C2/c clinopyroxene structure down to 2.5?K. The Na-bearing M2 polyhedra were identified to show the largest volume expansion between 2.5?K and room temperature, while the GeO4 tetrahedra behave as stiff units. Magnetic susceptibility measurements show a broad maximum around 33?K, which marks the onset of low-dimensional magnetic ordering. Below 12?K NaFeGe2O6 transforms to an incommensurately modulated magnetic spin state, with k?=?[0.323, 1.0, 0.080] and a helical order of spins within the M1-chains of FeO6 octahedra. This is determined by neutron-diffraction experiments on a single crystal. Comparison of NaFeGe2O6 with NaFeSi2O6 is given and it is shown that the magnetic ordering in the latter compound, aegirine, also is complex and is best described by two different spin states, a commensurate one with C2??/c?? symmetry and an incommensurate one, best being described by a spin density wave, oriented within the (1 0 1) plane.  相似文献   
103.
Urban areas are the focus of major ecological, social and economical activity. They are thus also prime locations of increasing conflict with regard to water use and water protection. As a direct and/or indirect consequence of urban land use and human activity, urban water systems are frequently polluted with organic contaminants including waste water-born xenobiotics such as pharmaceuticals, personal care products (collectively known as PPCPs) and endocrine-active substances. This study reviews new integrated methodologies including flux calculations as well as chemical investigations for determining the impact of human activities on urban water systems and on processes within the urban watershed. The use of indicator substances, representing different contaminant sources and pathways, integral pumping tests and mass balance approaches are suitable alternatives within these environments. The issues are explored using contaminant mass balance examples from Halle/Saale and Leipzig, Germany.  相似文献   
104.
105.
Polyfluorinated compounds (PFCs) were investigated in waste water treatment plant (WWTP) effluents and surface waters of the River Elbe from samples collected in 2007. Concentrations of various PFCs, including C4–C8 perfluorinated sulfonates (PFSAs), C6 and C8 perfluorinated sulfinates, 6:2 fluorotelomer sulfonate, C5–C13 perfluorinated carboxylic acids (PFCAs), C4 and C8 perfluoroalkyl sulfonamides and 6:2, 8:2 and 10:2 unsaturated fluorotelomercarboxylic acids were quantified. ∑PFC concentrations of the river water ranged from 7.6 to 26.4 ng L−1, whereas ∑PFC concentrations of WWTP effluents were approximately 5–10 times higher (30.5–266.3 ng L−1), indicating that WWTPs are potential sources of PFCs in the marine environment. PFC patterns of different WWTP effluents varied depending on the origin of the waste water, whereas the profile of PFC composition in the river water was relatively constant. In both kinds of water samples, perfluorooctanoic acid (PFOA) was the major PFC, whereas perfluorobutane sulfonate (PFBS) was the predominant PFSA.  相似文献   
106.
Dissociative recombination (DR) of ionospheric O2+ ions is an important source of suprathermal atomic oxygen in the exosphere as previous studies about the Martian upper atmosphere have shown. Because of the weaker gravitational attraction a hot oxygen corona on Mars should be denser than that observed on Venus. Since the most important mechanism for the production of the hot oxygen atoms in the Martian exosphere is DR, we investigated the variability of this production mechanism depending of solar activity. The Japanese Nozomi spacecraft will have the possibility to detect with the neutral mass spectrometer (NMS) for the first time in-situ the theoretically predicted hot oxygen corona on Mars, if the corona number density above the cold background atmosphere is of the order of 10,000 cm−3. Due to a problem in the propulsion system Nozomi failed its planned arrival rendevouzs with Mars in October 1999 and will, therefore, arrive at the red planet not before January 2004. Solar activity will reach its maximum in 2001, so the related production rate of hot oxygen atoms will be in the medium range during the new arrival date of Nozomi. We used the ionospheric profiles from the Viking mission for low solar activity conditions (F10.7≈70) and the Mariner 9 mission with a solar activity of about 120 for medium solar wind activity. The latter is comparable to the level we expect for the Mars arrival of Nozomi. The resulting influence of the hot oxygen corona number density distribution was calculated with a Monte Carlo technique. This technique is used to compute a hot particle density distribution function. We studied the atomic diffusion process in the Martian atmosphere by simulating the collision probability, particle direction and energy loss after collisions by generating random numbers. Compared to previous studies we have improved the Monte Carlo model by using more and smaller altitude steps and more detailed treatment of particles with a temporary downward motion. This has resulted in an increased amount of collisions and a shift to lower energies in the energy spectrum. Our results show that the hot oxygen component should begin to dominate above the cold background atmosphere at an altitude of about 500 km above the Martian surface. The NMS instrument on board of Nozomi should detect the hot oxygen component after its arrival at Mars in January 2004, at an altitude of about 600 km above the Martian surface. Since the solar activity will decrease during the mission the measurements during the first orbits will be the most significant ones. The first in-situ measurements of the hot oxygen number density would be very important for adjusting atmospheric escape models by separating ballistic, satellite and escape trajectories of the hot oxygen atoms, which are significant for studies of the evolution and solar wind interaction of the Martian atmosphere.  相似文献   
107.
A method is presented to include irradiation effects in the modeling of over-contact binaries. The Roche potential is numerically modified in a way to account for mechanical effects of the mutual irradiation of the two binary components. The efficiency of radiative interaction is parametrized by means of the fraction of radiative over gravitational forces for each component of the binary. The modified Roche geometry is implemented as binary model in an eclipse light curve solution code, which is based on the general Wilson–Devinney scheme. As an example the method is applied to the early-type over-contact system V606 Cen.  相似文献   
108.
A modified version of the bore hole sheat device (BHSD) was used to obtain field consolidation curves in a soft sensitive clay. The Porewater pressure dissipation was monitored at the centre of one of the shear plates. This paper describes briefly the in situ device employed and demonstrates the basic features of the linearelastic F. E. program ‘SOL’. A detailed study is made to simulate the field behaviour with the finite element approach. Comparisons are made between the field and analytical consolidation behaviour. Difficulties in predicting the value of the coefficient of consolidation of a sensitive clay using the BHSD consolidation curves are discussed.  相似文献   
109.
Wetlands are significant sources and sinks for arsenic (As), yet the geochemical conditions and processes causing a release of dissolved arsenic and its association with the solid phase of wetland soils are poorly known. Here we present experiments in which arsenic speciation was determined in peatland mesocosms in high spatiotemporal resolution over 10 months. The experiment included a drought/rewetting treatment, a permanently wet, and a defoliated treatment. Soil water content was determined by the TDR technique, and arsenic, iron and sulfate turnover from mass balancing stocks and fluxes in the peat, and solid phase contents by sequential extractions. Arsenic content ranged from 5 to 25 mg kg−1 and dissolved concentrations from 10 to 300 μg L−1, mainly in form of As(III), and secondarily of As(V) and dimethylated arsenic (DMA). Total arsenic was mainly associated with amorphous iron hydroxides (R2 > 0.95, α < 0.01) and deeper into the peat with an unidentified residual fraction. Arsenic release was linked to ferrous iron release and primarily occurred in the intensely rooted uppermost soil. Volumetric air contents of 2-13 % during drought eliminated DMA from the porewater and suppressed its release after rewetting for >30 d. Dissolved As(III) was oxidized and immobilized as As(V) at rates of up to 0.015 mmol m−3 d−1. Rewetting mobilized As(III) at rates of up to 0.018 mmol m−3 d−1 within days. Concurrently, Fe(II) was released at depth integrated rates of up 20 mmol m−3 d−1. The redox half systems of arsenic, iron, and sulfur were in persistent disequilibrium, with H2S being a thermodynamically viable reductant for As(V) to As(III). The study suggests that rewetting can lead to a rapid release of arsenic in iron-rich peatlands and that methylation is of lesser importance than co-release with iron reduction, which was largely driven by root activity.  相似文献   
110.
Precise and efficient numerical simulation of transport processes in subsurface systems is a prerequisite for many site investigation or remediation studies. Random walk particle tracking (RWPT) methods have been introduced in the past to overcome numerical difficulties when simulating propagation processes in porous media such as advection-dominated mass transport. Crucial for the precision of RWPT methods is the accuracy of the numerically calculated ground water velocity field. In this paper, a global node-based method for velocity calculation is used, which was originally proposed by Yeh (Water Resour Res 7:1216–1225, 1981). This method is improved in three ways: (1) extension to unstructured grids, (2) significant enhancement of computational efficiency, and (3) extension to saturated (groundwater) as well as unsaturated systems (soil water). The novel RWPT method is tested with numerical benchmark examples from the literature and used in two field scale applications of contaminant transport in saturated and unsaturated ground water. To evaluate advective transport of the model, the accuracy of the velocity field is demonstrated by comparing several published results of particle pathlines or streamlines. Given the chosen test problem, the global node-based velocity estimation is found to be as accurate as the CK method (Cordes and Kinzelbach in Water Resour Res 28(11):2903–2911, 1992) but less accurate than the mixed or mixed-hybrid finite element methods for flow in highly heterogeneous media. To evaluate advective–diffusive transport, a transport problem studied by Hassan and Mohamed (J Hydrol 275(3–4):242–260, 2003) is investigated here and evaluated using different numbers of particles. The results indicate that the number of particles required for the given problem is decreased using the proposed method by about two orders of magnitude without losing accuracy of the concentration contours as compared to the published numbers.  相似文献   
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