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41.
S. Türk Çulha M. Çulha İ. Karayücel M. Y. Çelik Y. Işler 《International Journal of Environmental Science and Technology》2017,14(2):385-396
The study was performed between March 2009 and March 2010 at the Sinop Inner Harbor on cultured mussels at the offshore submerged longline system. The samples of mussels, sediment and suspended particulate matter were seasonally taken for the purpose of monitoring differences of metal contents. In addition, burnable organic matter, contamination factors (CF), pollution load index (PLI) in sediment samples, meat yield of mussels were seasonally determined. All metals in suspended particulate matter were found to be above the national limit. Cd concentration in sediment was above the limit according to sediment quality guidelines, and Cd concentration in mussel was above both national and international limit values. According to CF and PLI identified in sediment, it was found that Inner Harbor was under the effect of anthropogenic pollution in terms of Cd accumulation. Provisional tolerable weekly intake calculated in mussel did not exceed the tolerable consumption values. In conclusion, it can be said that this region considered for commercial mussel cultivation is not a suitable area. 相似文献
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Sorption behavior of Lanaset Red (LR) G on lentil straw (LS) was studied as a function of particle size, adsorbent dose, initial pH value, initial dye concentration, and contact time. Sorption kinetics data was well described by logistic model. Modified logistic equation can be used to explain effects of initial dye concentrations and contact time on the sorption of LR G with high R2 value. Freundlich model was found to be excellent in representing the equilibrium data. Thermodynamic parameters like free energy (ΔG0), enthalpy (ΔH0), and entropy (ΔS0) were calculated by the use of Langmuir constant. Thermodynamic data showed that the sorption processes were spontaneous and endothermic in nature. Desorption process suggested that strong binding and weak interactions could be formed between adsorbent surface and dye molecules. Results revealed that LS has a remarkable potential for the sorption of LR G. 相似文献
44.
In this study, the adsorption of reactive red 120 (RR 120) on pistachio husk, and the modeling of the adsorption was investigated. Characterization of the pistachio husk was confirmed by Fourier transform infrared spectroscopy. The pHzpc of pistachio husk was found to be pH 8.5. Increasing the initial pH value decreased (p < 0.01) the amount of dye adsorbed. However, increasing the initial dye concentration from 50 to 900 mg/L at pH 1 increased (p < 0.01) the equilibrium dye uptake from 20.83 to 182.10 mg/g. Results indicated that this adsorbent had great potential for the removal of RR 120 dye. The logistic model was found to be the most suitable of the kinetic and equilibrium models tested to describe the adsorption of the dye. The parameters determined from the logistic model were well correlated with the initial dye concentration, and were seen to increase with the increasing initial dye concentration, but this was not observed from pseudo‐second order kinetics. 相似文献
45.
The 03 February 2002 Çay Earthquake (Mw ~6.7) occurred on the fault segment between Eber and Ak?ehir Lakes followed by a large aftershock (Mw ~5.6) near the western end of the fault and two sequential aftershocks. We computed the coseismic surface displacements from static GPS measurements to determine the fault geometry parameters and uniform slip components. The coseismic displacements were obtained through combining the regional pre-earthquake and post-earthquake GPS data. Fault geometry and slips were acquired through the inversion of GPS data modeling the events as elastic dislocations in a half-space and assuming all four events took place on the same fault plane. Results suggest that one-segment fault of ~33 km length and dipping ~43° northward suffices to model the dislocation, assuming uniform slip distribution with 0.51 m dip slip, 0.26 m left-lateral slip extending to a depth down to ~11.5 km which is consistent with seismological evidence. The results also verify the normal faulting in the eastern flank of Isparta Angle which has long been assumed as a thrusting structure. While the available data cannot identify the four individual events on the same day, an attempted distributed slip model differentiates dip slip and left-lateral slips near the hypocenter with maximum values of ~1 and 0.6 m, respectively. 相似文献
46.
47.
Phthalates are considered priority pollutants because of their potential adverse effects on ecosystems and human health. The objectives of this study were to determine the occurrence of five phthalates (DMP, DEP, DBP, BBP, and DEHP) in sewage sludge and to determine the seasonal variability of these contaminants at three (Bahçe?ehir, Pa?aköy, and Tuzla) full‐scale municipal and domestic wastewater treatment plants (WWTP) in Istanbul, Turkey. Mass balance was also calculated for DEHP at Tuzla WWTP sludge treatment units. DMP, DEP, DBP, BBP, and DEHP concentrations in sewage sludge ranged from 1.4 to 2.7 mg/kg dry weight (dw), 1.1 to 2.8, 0.6 to 4.6, 2.8 to 6.2, 18 to 490 mg/kg dw, respectively. Phthalate concentrations from the Bahçe?ehir and Pa?aköy WWTPs met the limit (100 mg/kg dw) of Turkey national sludge regulation and the Europe Union draft of sludge directive for land application, whereas phthalate concentrations from Tuzla WWTP exceeded the maximum permissible concentration. Phthalate concentrations did not show seasonal variations for Bahçe?ehir and Pa?aköy WWTPs, which receive mainly household wastewater while some fluctuations were observed DEP, DBP, and DEHP at Tuzla WWTP which has a lot of industrial wastewater contribution. The mass balance showed that approximately 17% of DEHP in the primary and secondary sludge was removed by anaerobic digestion, while 43% returned back to the beginning of the WWTP and 40% remained in the dewatered sludge. This study suggests that phthalates in sludge from WWTPs with industrial wastewater contribution may limit the use of sludge for land application. 相似文献
48.
In this study, it was aimed to characterize temporal variations of air pollutants for determining contribution to pollution episodes and to obtain correlations between these pollutants. With this aim we used data analysis for measured sulfur dioxide (SO2), particulate matter (PM, black fume and PM10), nitrogen oxides (NOx), ozone (O3), carbon monoxide (CO), methane (CH4), and non‐methane hydrocarbons (NMHC) recorded in Kocaeli, one of the most industrilizated cities of Turkey. Pollutant concentrations were the results of continuous and semi‐automatic measurements. Semi‐automatic measurements of SO2 and PM (black fume) were enclosing period from 1987 to 2008 whereas continuous monitoring of all pollutants included years of 2007–2009. In the first stage of the study daily, monthly, annual, and seasonal variations of pollution were researched. Annual average concentrations were compared with limits set by Air Quality Protection Regulation (AQPR), Air Quality Evaluation and Management Regulation (AQEMR), World Health Organization (WHO), European Union (EU), and National Ambient Air Quality Standards (USEPA). In the following stage relationships between pollutants such as NO2–O3, NOx–CO, NOx–NMHC, and NOx–SO2 were investigated and correlation coefficients were determined as 0.87, 0.56, 0.51, and 0.69, respectively. R2 values of regression models developed from these correlations were 0.78, 0.56, 0.34, and 0.72, respectively. Vehicle density of the traffic was evaluated with NOx–O3 emissions and decrease was seen in NOx emissions due to decreasing vehicle density at weekends whereas O3 concentrations increased. These correlations enable prediction of the parameters that cannot be measured which is important for providing improvement in early warning systems. 相似文献
49.
This study describes the stratigraphic and palaeoenvironmental significance of the Lower-“middle” Oligocene sediments based on the fauna from the Delikarkas? Formation and the microflora from the ?ncesu Formation of the ?ncesu area (northern part of the western Taurides, Isparta province, Turkey). In the area, the Oligocene sediments show a regressive succession, which begins with the limestones of the Delikarkas? Formation indicating marine conditions followed by conglomerates, sandstones and coaly mudstones of alluvial and fluvial (shallow marine-continental) origin. A well preserved foraminiferal assemblage including Nummulites intermedius, Nummulites vascus and Halkyardia maxima proves an Early Oligocene age for the Delikarkas? Formation. Due to palynological markers such as Boehlensipollis hohli, Slowakipollis hippophaëoides, Dicolpopollis kockelii, Magnolipollis neogenicus ssp. minor, Plicapollis pseudoexcelsus, Caryapollenites simplex and Intratriporopollenites instructus the ?ncesu Formation, which concordantly rests on the Delikarkas? Formation, may be assigned to the Early-“middle” Oligocene. From the palynomorph assemblage, three zones have been recognised according to abundance of species. Zone 1 is characterized by predominance of C. simplex and Momipites punctatus and rarely presence of tricolpate and tricolporate pollen. Zone 2 consists mainly of Inaperturopollenites dubius, Leiotriletes maxoides ssp. maximus, Verrucatosporites favus, Verrucatosporites alienus and infrequently marine dinoflagellate cysts. Zone 3 is characterized by a high percentage of ferns such as Echinatisporis?chattensis and Polypodiaceoisporites saxonicus. The presence of marine dinoflagellate cysts like Apectodinium sp. and Cleistosphaeridium sp., back-mangrove elements such as Acrostichum aureum and lepidocaryoid palms (e.g. Longapertites discordis, Longapertites punctatus and Longapertites psilatus) in the sediments of the ?ncesu Formation imply coastal or near-coastal conditions. Terrestrial palynomorphs in more inland settings were transported by running water towards the sea. Conifers are represented by poorly preserved and rare pollen grains of Pityosporites, Cathayapollis and Piceapollis which may have been transported by wind. In this study, the terrestrial climate of the ?ncesu Formation is also discussed on the basis of the Coexistence Approach method. The climate was warm at the coast (over 20 °C), as evidenced by A. aureum and lepidocaryoid palms, whereas there was a mean annual temperature of 17.2–17.4 °C must be assumed for the upland environment(s). 相似文献
50.
The effect of welding degree on geotechnical properties of an ignimbrite flow unit: the Bitlis castle case (eastern Turkey) 总被引:1,自引:0,他引:1
Tamer Koralay Mehmet ?zkul Halil Kumsar Sefer Beran ?elik Kadir Pekta? 《Environmental Earth Sciences》2011,64(3):869-881
Ignimbrites are associated with nearly most of the world’s volcanoes and are defined as a deposit from pyroclastic density
currents. They consist predominantly of pumiceous lapilli and blocks, and glass shards, which shows evidence of having been
emplaced as a concentrated hot and dry particulate flow. These rocks are widely used as building stone especially in ancient
buildings. Bitlis valley is covered by ignimbritic products, derived from Nemrut stratovolcano, one of the significant volcanic
centers in Eastern Anatolia. The Bitlis ignimbrite is separated into lower level (LL), middle level (ML) and upper level (UL)
according to color, welding degree and structural features. All three levels were used extensively in many parts of the Bitlis
castle as masonry materials. Studies were carried out on mineralogical and geochemical composition and on physical and mechanical
properties of the ignimbrites. In addition, a freeze–thaw cycle test was executed. There are no considerable differences in
mineralogical composition among the levels of ignimbrite. All levels contain plagioclase, sanidine, pyroxene, and opaque mineral.
In addition, anorthoclase and quartz are seen. In general, the LL of ignimbrite shows relic perlitic and eutaxitic texture,
whereas eutaxitic and vesicular texture are commonly developed in the ML and UL, respectively. Lower, middle, and upper level
ignimbrite samples display similar and limited compositional spread in terms of major oxide elements. They have trachyte composition.
Building stones can be classified according to mineralogy, mechanical and physical properties and processing types. Mechanical
and physical properties are very important with respect to stone quality/durability. The mechanical and physical properties
of the ignimbrites are controlled by the welding degree. It was found that increasing welding degree from UL to LL correlates
with increasing density, compressive strength and slake durability index and with decreasing porosity. The Bitlis ignimbrites
have turned out as susceptible to freeze–thaw cycles. 相似文献