Large-scale GIS-based hydrogeological modeling of Flanders: a tool for groundwater management     

Jan Cools  Yves Meyus  Solomon Tuccu Woldeamlak  Okke Batelaan  Florimond De Smedt 《Environmental Geology》2006,50(8):1201-1209

For the implementation of the European Union Water Framework Directive (WFD), technological and scientific support are required. This paper presents a methodology to support a first step of the implementation of WFD, which is the delineation of groundwater bodies. The methodology consists of (1) the development of a complete and generally-accepted hydrogeological classification system for Flanders, named the HCOV code, (2) the development of a geographic information systems (GIS)-managed borehole database, and (3) the development of aquifer and aquitard models by means of a solid modeling approach. For each unit of the hydrogeological classification code for Flanders unit, GIS maps are generated for the three basic characteristics of hydrogeological layers: extent, base level and thickness, such that combined, the volume and extent of a hydrogeological layer is unambiguously defined. This GIS-based hydrogeological database has become a useful tool for groundwater management purposes and to provide the input for groundwater modeling.  相似文献   

Multi-spectroscopic study of Fe(II) in silicate glasses: Implications for the coordination environment of Fe(II) in silicate melts   总被引：1，自引：0，他引：1  

William E. Jackson  Mark Yeager  Stéphanie Rossano  Edward I. Solomon 《Geochimica et cosmochimica acta》2005,69(17):4315-4332

The coordination environment of Fe(II) has been examined in seven anhydrous ferrosilicate glasses at 298 K and 1 bar using ⁵⁷Fe Mössbauer, Fe K-edge X-ray near edge structure (XANES), and extended X-ray absorption fine structure (EXAFS), UV-Vis-NIR, and magnetic circular dichroism (MCD) spectroscopies. Glasses of the following compositions were synthesized from oxide melts (abbreviation and nonbridging oxygen:tetrahedral cation ratio (NBO/T) in parentheses): Li₂FeSi₃O₈ (LI2: 1.33), Rb₂FeSi₃O₈ (RB2: 1.33), Na_l.08Fe_l.l7Si_3.l3O₈ (NAl: 1.09), Na_l.46Ca_0.24Fe_l.08Si_2.97O₈ (NC6: 1.38), Na_l.09Ca_0.51Fe_0.72Si_3.10O₈ (NC2: 1.15), Na_0.99Ca_0.92Fe_0.24 Si_3.17O₈ (NCl: 1.04), and Na_0.29Mg_0.53Ca_0.52Fe_0.56Al_0.91Si_2.44O₈ (BAS: 1.05). Mössbauer, XANES, and EXAFS information suggests that iron is dominantly ferrous in all glasses (<10 atom% Fe(III)) with an average first-neighbor Fe(II) coordination varying from ∼ 4 to 5.2 (±0.2) oxygens. The UV-Vis-NIR spectrum of each sample exhibits intense absorption centered near 8100-9200 cm⁻¹ and weak absorption near 5000 cm^−l, which cannot be assigned unambiguously. The MCD spectrum of NC6 glass, which is the first such measurement on a silicate glass, shows three transitions at ∼8500 cm⁻¹, ∼6700 cm⁻¹, and ∼4500 cm⁻¹. The behavior of these MCD bands as a function of temperature (1.6 K to 300 K) and magnetic field strength (1 T to 7 T) indicates that they most likely arise from three distinct Fe(II) sites with different ground states, two of which are 5-coordinated and one of which is 4-coordinated by oxygens.The combined results suggest that Fe(II) predominantly occupies 5- and 4-coordinated sites in each glass, with the ratios differing for the different compositions. Small amounts of 6-coordinated Fe(II) are possible as well, but primarily in the more basic glass compositions such as BAS. The substitution of Li(I) for Rb(I) in the M₂FeSi₃O₈ base glass composition causes a weakening of the average Fe(II)-O bond, as indicated by the longer Fe(II)-O distance in the latter. The basalt composition glass was found to have the largest Fe(II) sites relative to those in the other glasses in this study. A bond valence model that helps predict the coordination number of Fe(II) in silicate glasses is proposed. The structural information extrapolated to Fe(II)-bearing melts is parameterized using bond valence theory, which helps to rationalize the melt-crystal partitioning behavior of ferrous iron in natural and synthetic melt-crystal systems.  相似文献   

3H/3He age data in assessing the susceptibility of wells to contamination   总被引：2，自引：0，他引：2  

Manning AH  Kip Solomon D  Thiros SA 《Ground water》2005,43(3):353-367

Regulatory agencies are becoming increasingly interested in using young-ground water dating techniques, such as the 3H/3He method, in assessing the susceptibility of public supply wells (PSWs) to contamination. However, recent studies emphasize that ground water samples of mixed age may be the norm, particularly from long-screened PSWs, and tracer-based "apparent" ages can differ substantially from actual mean ages for mixed-age samples. We present age and contaminant data from PSWs in Salt Lake Valley, Utah, that demonstrate the utility of 3H and 3He measurements in evaluating well susceptibility, despite potential age mixing. Initial 3H concentrations (measured 3H + measured tritiogenic 3He) are compared to those expected based on the apparent 3H/3He age and the local precipitation 3H record. This comparison is used to determine the amount of modern water (recharged after approximately 1950) vs. prebomb water (recharged before approximately 1950) samples might contain. Concentrations of common contaminants were also measured using detection limits generally lower than those used for regulatory purposes. A clear correlation exists between the potential magnitude of the modern water fraction and both the occurrence and concentration of contaminants. For samples containing dominantly modern water based on their initial 3H concentrations, potential discrepancies between apparent 3H/3He ages and mean ages are explored using synthetic samples that are random mixtures of different modern waters. Apparent ages can exceed mean ages by up to 13 years for these samples, with an exponential age distribution resulting in the greatest discrepancies.  相似文献   

On Q and Seismic Discrimination     

Sean C. Solomon 《Geophysical Journal International》1972,31(1-3):163-177

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Inversion Schemes for Surface Wave Attenuation and Q in the Crust and the Mantle     

Wook Bae Lee  Sean C. Solomon 《Geophysical Journal International》1975,43(1):47-71

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Thermal history and evolution of the moon     

M. Nafi Toksőz  Sean C. Solomon 《Earth, Moon, and Planets》1973,7(3-4):251-278

Possible models for the thermal evolution of the Moon are constrained by a wide assortment of lunar data. In this work, theoretical lunar temperature models are computed taking into account different initial conditions to represent possible accretion models and various abundances of heat sources to correspond to different compositions. Differentiation and convection are simulated in the numerical computational scheme.Models of the thermal evolution of the Moon that fit the chronology of igneous activity on the lunar surface, the stress history of the lunar lithosphere implied by the presence of mascons, and the surface concentrations of radioactive elements, involve extensive differentiation early in lunar history. This differentiation may be the result of rapid accretion and large-scale melting or of primary chemical layering during accretion. Differences in present-day temperatures for these two possibilities are significant only in the inner 1000 km of the Moon and are not resolvable with presently available data.If the Apollo 15 heat flow is a representative value, the average uranium concentration in the moon is 65±15 ppb. This is consistent with achondritic bulk composition (between howardites and eucrites) for the Moon.Paper dedicated to Professor Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.  相似文献   

International reductions of greenhouse-gas emissions: An equitable and efficient approach     

Barry D. Solomon  Dilip R. Ahuja   《Global Environmental Change》1991,1(5)

A strategy for a successful climate protection convention must highlight the role of equity in order to bring more nations to the bargaining table. The authors propose two commercial energy protocols for consideration by negotiators in this light. The first links international trading in greenhouse-gas emission ‘rights’ to a country's historical per capita carbon emissions. The charge for these rights should be based on the negotiated reduction in global emissions and the demand for them, via the marketplace. The second requires inefficient countries to make steady improvements in energy efficiency or fuel substitution away from carbon as their economies develop.  相似文献   

Interpretation of floodplain pollen in alluvial sediments from an Arid Region     

Allen M. Solomon  T.J. Blasing  J.A. Solomon 《Quaternary Research》1982,18(1):52-71

Pollen was collected from modern alluvium and from the atmosphere to document the nature and amount of paleoenvironmental information reflected by alluvial pollen chronologies. Results indicate that pollen in alluvium is a homogeneous mixture derived almost entirely from the floodplain itself. The few pollen grains derived from nonfloodplain plant communities and preserved in alluvial sediments are so well mixed that their frequencies no longer reflect the geographic distribution of the specific plant communities in which they originated. In contrast, the abundance of alluvial pollen grains, derived from the major floodplain taxa (Chenopodiineae, Ambrosia type), varies with summer and winter climate. This annual variation is preserved in alluvial pollen assemblages through a combination of processes within sedimentation basins involving discontinuous deposition events and mechanical pollen degradation. The high-frequency, wide-amplitude pollen variance in alluvial pollen assemblages contrasts with the low-frequency, narrow-amplitude pollen variance in sediments of lakes and ponds. The slight geographic variance in alluvial pollen assemblages, in contrast to the large variance in soil pollen, allows use of alluvial pollen to infer climate throughout the watershed in which pollen is sampled.  相似文献   

Differentiation of crusts and cores of the terrestrial planets: Lessons for the early Earth?     

Sean C Solomon 《Precambrian Research》1980,10(3-4)

It now appears probable that all of the terrestrial planets underwent some form of global chemical differentiation to produce crusts, mantles, and cores of variable relative mass fractions. There is direct seismic evidence for a crust on the Moon, and indirect evidence for distinct crusts on Mars and Venus. Substantial portions of these crusts have been in place since the time that heavy bombardment of the inner solar system ceased 4 Ga ago. There is direct evidence for a sizeable core on Mars, indirect evidence for one on Mercury, and bounds on a possible small core for the Moon. Core formation is an important heat source confined to times prior to 4 Ga ago for Mercury and the Earth, but was not closely linked to crustal formation on the Moon nor, apparently, on Mars. The tectonic and volcanic histories of the surfaces of the terrestrial planets Moon, Mars, and Mercury can be used, with simple thermal history models, to restrict the earliest chemical differentiation to be shallow (outer 200–400 km) for the first two bodies and much more extensive for Mercury. Extension of these models to an Earth-size planet leads to the prediction of a hot and vigorously convecting mantle with an easily deformable crust immediately following core formation, and of the gradual development of a lithosphere and of plates with some lateral rigidity in Late Archean—Proterozoic times.  相似文献   

Localization of gravity and topography: constraints on the tectonics and mantle dynamics of Venus   总被引：3，自引：0，他引：3  

Mark Simons  Sean C. Solomon  Bradford H. Hager 《Geophysical Journal International》1997,131(1):24-44

We develop a method for spatio-spectral localization of harmonic data on a sphere and use it to interpret recent high-resolution global estimates of the gravity and topography of Venus in the context of geodynamical models. Our approach applies equally to the simple spatial windowing of harmonic data and to variable-length-scale analyses, which are analogous to a wavelet transform in the Cartesian domain. Using the variable-length-scale approach, we calculate the localized RMS amplitudes of gravity and topography, as well as the spectral admittance between the two fields, as functions of position and wavelength. The observed admittances over 10 per cent of the surface of Venus (highland plateaus and tessera regions) are consistent with isostatic compensation of topography by variations in crustal thickness, while admittances over the remaining 90 per cent of the surface (rises, plains and lowlands) indicate that long-wavelength topography is dominantly the result of vertical convective tractions at the base of the lithosphere. The global average crustal thickness is less than 30 km, but can reach values as large as 40 km beneath tesserae and highland plateaus. We also note that an Earth-like radial viscosity structure cannot be rejected by the gravity and topography data and that, without a mechanical model of the lithosphere, admittance values cannot constrain the thickness of the thermal boundary layer of Venus. Modelling the lithosphere as a thin elastic plate indicates that at the time of formation of relief in highland plateaus and tesserae, the effective elastic plate thickness, T_e , was less than 20 km. Estimates of T_e at highland rises are consistently less than 30 km. Our inability to find regions with T_e > 30 km is inconsistent with predictions made by a class of catastrophic resurfacing models.  相似文献