Assessment of spatial distribution and possible sources of heavy metals in the soils of Sariseki-Dörtyol District in Hatay Province (Turkey)     

Necat Ağca  Engin Özdel 《Environmental Earth Sciences》2014,71(3):1033-1047

In this study, total heavy metal content of soil and their spatial distribution in Sar?seki-Dörtyol district were analyzed and mapped. Variable distance grids (0.5, 1.0 and 2.0 km) were established, with a total of 102 soil samples collected from two different soil depths (0–5 and 5–20 cm) at intersections of the grids (51 sampling point). Soil samples were analyzed for heavy metals (Cd, Co, Cr, Cu, Pb, Zn, Mn, Fe, and Ni). The most proper variogram models for the contents of all heavy metal were spherical and exponential ones. The ranges of semivariograms were between 1.9 and 31.1 km. According to the calculated geoaccumulation (I _geo) values, samples from both soil depths were classified as partly to highly polluted with Cd and Ni and partly polluted with Cr and as partly polluted-to-not polluted with Pb and not polluted with Cu, Fe and Mn. Similar results were also obtained when evaluated by the enrichment factor. The contamination levels of the heavy metals were Ni > Cd > Cr > Pb > Zn > Cu > Co > Fe > Mn in decreasing order. The soils in the study area are contaminated predominantly by Cd and Ni, which may give rise to various health hazards or diseases. Cadmium pollution results primarily from industrial activities and, to a lesser extent, from vehicular traffic, whereas Ni contents in the study area result from parent material, phosphorus fertilizer, industries, and vehicles.  相似文献   

Effect of the alkaline industrial residues fly ash,green liquor dregs,and lime mud on mine tailings oxidation when used as covering material     

Yu Jia  Christian Maurice  Björn Öhlander 《Environmental Earth Sciences》2014,72(2):319-334

The potential to use the alkaline residue products fly ash, green liquor dregs, and lime mud originating from paper mills as dry cover materials to seal tailings has been investigated. Metals concentration in lime mud and fly ash had the lowest and highest contents, respectively. The tailings (<1 % sulfur content, primarily pyrite) were disposed about 50 years ago and originated from the former Rönnskär mine site in Sweden. The results of chemical composition analysis show that the raw unoxidized tailings are active toward oxidation, while the components of the adjacent oxidized tailings are not. To quantify the release of metals from the tailings and to evaluate the effect of a sealing layer on oxidation and weathering of the tailings, batch leaching tests were conducted in which leachate from alkaline residue materials was fed to the tailings. The results show that a higher concentration of most trace elements is leached from the unoxidized tailings than from the oxidized tailings. Except As and Cr, the rest of analyzed metals (Cd, Cu, Ni, Pb) became immobilized in response to the increased pH as a consequence of the amendment. The three tested alkaline amendments show a similar potential for preventing the release of metals (with the exception of As and Cr) from the tailings. Under either aerobic or anaerobic conditions, microbial activity was found to be of minor importance. XRD analysis of the field samples revealed that it was feasible to use alkaline residue products in covering tailings, and that it was advantageous to use ash as a cover material more than dregs.  相似文献   

Geochemistry of uranium and thorium and natural radioactivity levels of the western Anatolian plutons,Turkey     

Papadopoulos  Argyrios  Altunkaynak  Şafak  Koroneos  Antonios  Ünal  Alp  Kamaci  Ömer 《Mineralogy and Petrology》2017,111(5):677-691

Mineralogy and Petrology - Seventy samples from major plutons (mainly granitic) of Western Anatolia (Turkey) have been analyzed by γ-ray spectrometry to determine the specific activities of...  相似文献   

Seasonal and spatial changes in water and sediment quality variables in Bafa Lake     

Ferah Koçak  Sinem Aydın-Önen  Şermin Açık  Filiz Küçüksezgin 《Environmental Earth Sciences》2017,76(17):617

The brackish Bafa Lake located in the southwestern part of Turkey is under stress because of both natural and untreated wastewater effluents. The purpose of this research is to determine spatiotemporal distributions of some physicochemical variables in water column (temperature, salinity, pH, conductivity, dissolved oxygen, NH₄–N, NO₂–N, NO₃–N, oPO₄–P, TPO₄–P, chlorophyll-a, total suspended solids) and sediment (TN, TC, TOC, TP) and their relationships at coastal stations. In the water column, nitrate and phosphate concentrations showed seasonal variations with high values recorded in winter period. Ammonium was determined as a main source of TIN component. During summer period, a large amount of total phosphorus was found as dissolved organic form. However, in the winter period, inorganic phosphate levels increased at sampling stations. N limitation was a common feature throughout the lake where P-limitation was only observed in summer period. The total phosphorus levels which showed hypereutrophic condition at the western part of the lake changed between 1.55 and 4.99 μM and did not remain in the range for uncontaminated condition. In the lake sediment, a strong relationship was found between TOC and TC levels. Generally, the mean TOC concentrations constitute small amount of TC values in the sampling stations. The results also indicated that a strong correlation exists between TOC and TN values, and TN was greatly regulated by organic sources. In the lake, TOC:TN ratios changed between 5 and 13; the ratio greater than 10 could be an indicator of algal and land plant sources mixing as an organic matter.  相似文献   

Role of carbonates in mitigation of metal release from mining waste. Evidence from humidity cells tests   总被引：7，自引：0，他引：7  

H. Holmström  J. Ljungberg  B. Öhlander 《Environmental Geology》1999,37(4):267-280

 Leaching of two contrasting types of sulphidic tailings in humidity cells has been performed. The release of heavy metals and the oxidation rate have been studied. Tailings from the Laver mine contain a few percent sulphides and lack carbonates, whereas tailings from the Stekenjokk mine are both sulphide- and carbonate-rich. The results showed that in the leachates from the Laver samples, the metal concentrations increased and pH decreased with time, indicating an increased oxidation rate. In the Stekenjokk samples, pH remained high during the experiment, thereby keeping the metal concentrations low in the leachates. The oxidation rate also decreased with time, probably due to Fe-hydroxide coatings on sulphide surfaces. The results show that addition of carbonates and the maintenance of a high pH not only reduce the solubility of heavy metals, but also decrease the oxidation rate of sulphides. Received: 20 January 1998 · Accepted: 2 April 1998  相似文献   

Marine vibrators: the new phase of seismic exploration     

R.M. Laws  D. Halliday  J.-F. Hopperstad  D. Gerez  M. Supawala  A. Özbek  T. Murray  E. Kragh 《Geophysical Prospecting》2019,67(6):1443-1471

Marine seismic vibrators are generally considered to be less intrusive than airguns from an environmental perspective. This is because they emit their energy spread out in time, rather than in a single, high-intensity pulse. There are also significant geophysical benefits associated with marine vibrators, and they stem from the ability to specify in detail the output acoustic waveform. The phase can be specified independently at each frequency. Such detailed control cannot be achieved with conventional airgun sources, where the phase can only be modified using simple overall time delays. The vibrator phase can be employed in several different ways: it can be applied to the overall source phase in a sequence so that it varies from one source point to the next; it can be applied to the individual vibrators within the source array so the source directivity is changed; it can be applied to the overall source phase of each source in a simultaneous source acquisition. Carefully designed phase sequences can attenuate the residual source noise, and this in turn allows extra source points to be interleaved between the conventional ones. For these extra source points, the relative phase of the vibrators within the array can be chosen to create a transverse gradient source, which illuminates the earth predominantly in directions out of the plane of the sail line without left/right ambiguity. If seismic vibrator data are acquired using interleaved conventional and transverse gradient sweeps, more information is collected per kilometre of vessel travel than is the case in conventional acquisition. This richer data acquisition leads to the possibility of acquiring all the necessary seismic data in a shorter time. Three-dimensional reconstruction techniques are used to recover the same image quality that would have been obtained using the conventional, more time-consuming acquisition. For a marine vibrator to be suitable for these techniques it must, in general terms, have ‘high fidelity’. The precise device specifications are defined through realistic end-to-end simulations of the physical systems and the processing. The specifications are somewhat more onerous than for a conventional vibrator, but they are achievable. A prototype vibrator that satisfies these requirements has been built. In a simulated case study of a three-dimensional deep-water ocean bottom node survey, the seismic data could have been acquired using marine vibrators in one third of the time that it would have taken using airguns.  相似文献   

A comparative predictive analysis of weighted overlay,weighted sum and fuzzy logic for mineral prospectivity mapping of precious and base metal mineralizations at north-east of Gümüşhane city,NE Turkey     

Önder Kayadibi  Doğan Aydal 《国际地球制图》2019,34(5):539-559

The study area located south of the Eastern Pontide metallogenic belt (NE Turkey) has an important potential for valuable and base metallic minerals. Geological, tectonic, geochemical, hydrothermal alteration, mineralogical and fluid inclusion characteristics of ore formations in the region have been studied in detail. The purpose of this study is to combine and analyse the acquired spatial data layers in a geographic information system (GIS) environment using knowledge-driven approaches and to identify prospective areas in terms of mineralization. Moreover, evaluating the performance of different knowledge-driven mineral probability modelling results comparatively and quantitatively constitutes the other goal of the study. As a result, in addition to the known mineralization locations, a number of new prospective and favourable areas have been identified for future detailed studies. In addition, it has been found that the mineral predictive map generated using fuzzy logic-OR method produces the best and successful results compared to others.  相似文献   

Long-Term 3D Hydrodynamic Modeling and Water Surface Statistics in Marmara Sea     

Tarkan Erdik  Olgay Şen  Jasna Duricic Erdik  İzzet Öztürk 《Marine Geodesy》2018,41(2):126-143

Marmara Sea (MS) lies in the strategic crossroad, accommodating one of the busiest shipping routes in the world. In general, there is a two-layer current system in the MS and Turkish Straits system; the brackish waters originating in the Black Sea (BS) (18 PSU) moving southward to the Aegean Sea (AS), and a lower layer return flow of saltier Aegean waters (38.5 PSU) back to the BS. This variability poses a challenging task within the modeling perspective. In this research, 3D hydrodynamic modeling of MS is performed in order to investigate the spatial and temporal behavior of elevations between years 2000 and 2015. During the calibration process, the grid configuration, time step, and model coefficients (Manning bed roughness coefficient, a wind drag coefficient and horizontal viscosity are coefficients) are adjusted until the computed solution produced the best match to the observed data such as water surface elevations, velocities, and net discharges. To this end, a series of simulations are made. As a result, the observed and the predicted water surface elevations follow each other very closely. The developed model could accurately estimate the net discharge as well. In order to understand the behavior of MS, elevation pattern is calculated and depicted both on annual and seasonal scales. It is demonstrated that the influence of seasonally varying strong fresh water river discharges of Danube in BS have strong influence on the water mass characteristics of the MS.  相似文献   

Factors controlling the morphological evolution of the Çanakkale Strait (Dardanelles, Turkey)     

Erkan Gökaşan  Mustafa Ergin  Mustafa Özyalvaç  Halil İbrahim Sur  Hüseyin Tur  Tolga Görüm  Timur Ustaömer  Fatma Gül Batuk  Hakan Alp  Halim Birkan  Ahmet Türker  Erhan Gezgin  Murat Özturan 《Geo-Marine Letters》2008,28(2):107-129

Seismic profiling, bathymetric and physical oceanographic data collected from the Çanakkale Strait revealed that the morphological evolution of the strait has been controlled by tectonic activity, and sediment erosion and deposition. Sediments in the strait have been sourced mostly by rivers draining the Biga Peninsula during lowstand periods. In highstand periods, by contrast, deposits in the strait were reworked by currents. The seafloor morphology of the Çanakkale Strait is also controlled by a sequence of factors ranging from tectonics to current erosion and deposition. Channel deposits overlying the basement are being eroded at the narrower, meandering central section of the strait (the Nara Passage) due to high current velocities. The eroded sediments are deposited in the relatively linear and wider, northern and southern sectors of the strait exposed to low current velocities. As a result, the high-energy areas are more deeply incised due to the erosion, whereas deposition elevates the seafloor in the areas exposed to lower current energy. Three strike-slip faults, which possibly relate to the activity of the North Anatolian Fault Zone, are responsible for the irregular shape of the strait and this, in turn, controls the current velocity along the strait. The high-energy conditions probably commenced with the latest invasion of Mediterranean waters some 12 ka b.p., and have continued as a two-layered current system to the present day.  相似文献   

Formation of glauconie in foraminiferal shells on the continental shelf off Norway     

Kristian Bjerkli  Johan Sverre Östmo-Saeter 《Marine Geology》1973,14(3):169-178

Glauconie inside shells of foraminifers, assumed to be formed during the timespan from the Last Glaciation to the present, is reported. The process is thought to take place at water temperatures of 6–7°C. The nature of the infilling process is suggested to be neoformation of clay minerals rather than transformation of pre-infilled clay.  相似文献