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61.
A large-eddy simulation (LES) with the dynamic Smagorinsky-Germano subgrid-scale (SGS) model is used to study the dispersion of solid particles in a turbulent boundary layer. Solid particles are tracked in a Lagrangian way. The instantaneous velocity of the surrounding fluid is considered to have a large-scale part (directly computed by the LES) and a small-scale part. The SGS velocity of the surrounding fluid is given by a three-dimensional Langevin model written in terms of SGS statistics at a mesh level. An appropriate Lagrangian correlation time scale is considered in order to include the influences of gravity and inertia of the solid particle. Inter-particle collisions and the influence of particles on the mean flow are also taken into account. The results of the LES are compared with the wind-tunnel experiments of Nalpanis et al. (1993 J Fluid Mech 251: 661–685) and of Tanière et al. (1997 Exp in Fluids 23:463–471) on sand particles in saltation and in modified saltation, respectively.  相似文献   
62.
From April 1993 to March 1994, 135 samples were collected at two sites in the coastal Adriatic Sea, both near (14.5 km) and far (63 km) from the Po River delta. The nutrient(s) limiting algal growth potential (AGP) were estimated by bioassay usingNitzshia closterium (local isolate) andThalassiosira pseudonama (strain 3-H). Estimates were also made by comparing the nutrient molar ratios, ΣN:P and ΣN:Si (whereΣN=NO3 ?+NO2 ?+NH4 ++urea), to the Redfield Ratio (16∶1, 1∶1). According to the bioassay results, phosphorus was the sole nutrient limiting AGP in 2% of the samples and was the most limiting nutrient in 69% of the samples; nitrogen was sole limiting nutrient in 18% of the samples. In 11% of samples, nitrogen and phosphorus were equally co-limiting. Omission of phosphorus from spike enrichments allowed, on average, only a 1.6-fold increase in biomass over that in the unenriched controls. Similar omission of nitrogen allowed a 4-fold increase, while silicon, iron, and micronutrients resulted in 14-fold, 18-fold, and >20-fold increases, respectively. In most of the samples, ΣN:P was much greater than 16, indicating a marked phosphorus deficiency, while ΣN:Si values suggested that silicon was the third most limiting nutrient in 35% of samples. In water collected for from the Po delta, the yield ofN. closterium was not limited by any nutrients other than the three major ones: P, N and Si. In these same waters,T. pseudonana was also potentially limited by iron and, to a lesser extent, by vitamins. The role of iron varied. In samples collected near the Po delta, iron acted as the third most limiting nutrient forN. closterium in June and September; it appeared 29 times out of 78 on the list of potentially limiting nutrients forT. pseudonana, including 5 times as the most limiting. Altogether, comparison with published results suggests that the roles of iron and silicon in AGP limitation have increased during the past three decades, and could become even more important if eutrophication in the Adriatic Sea continues to increase.  相似文献   
63.
The Aleksod region is composed of metasedimentary rocks and large areas of biotite and hornblende-bearing migmatites. Anatexis associated with the main deformation stages, occurred under high pressure and temperature conditions estimated at 13±2 Kbar and 750±50° C. The bulk mineralogical composition of the Telohat migmatites shows that their protolith was granodioritic. Internal structures of zircons and U-Pb data suggest a polyphased evolution, with a 2131±12 Ma age for the protolith and a 609±17 Ma age for the Pan-African tectono-metamorphic evolution, thus precluding any Kibaran event in the Aleksod area. Leucosomes are richer in Sr and display lower Rb, Zr, Nb, Y, Th, U and REE contents than melanosomes wherein accessory phases are stored. Eu contents are also lower in the leucosomes but in lesser proportion than the other rare earth's, leading to a significant positive anomaly. Petrogenetic modelling accounting for accessory mineral phases clearly shows that the trace element contents of leucosomes and melanosomes follow a distribution law consistent neither with equilibrium nor fractional melting. Their trace element patterns are best explained by the model of disequilibrium melting, with mixing of a few residual phases. The present results and previous Sr isotopic data as well raise the question of disequilibrium melting in anatexis of crustal material CRPG Contribution no 782  相似文献   
64.
On the basis of radiocarbon ages obtained on wood burned by base surges and tephrochronological observations, it has been possible to assess that the Puy Chopine, aged ca 9700 yr is older by a few centuries than both the Vasset and Kilian volcanoes. The last two have nearly the same age, ca 9300–9400 yr. Layers of trachytic tephra, most probably originated from Kilian or Vasset, can be observed overlapping those from the Pariou. This last volcano had been previously thought to be the younger of the area on the basis of the observation of trachytic tephra beneath its own tephra. However, new observations allow us to assume that those trachytes originated from the acid phase of the Pariou itself. Therefore, it can be assessed that the four volcanoes erupted according to the following sequence: Chopine/Pariou/?Vasset?/Kilian; the chronological situation of Vasset lies on poor arguments and it should be confirmed. To cite this article: D. Miallier et al., C. R. Geoscience 336 (2004).  相似文献   
65.
During the Neogene, a magmatic change from calc-alkaline to alkaline types occurred in all the regions surrounding the western Mediterranean. This change has been studied in Oranie (western Algeria). In this area, potassic to shoshonitic calc-alkaline andesites (with La/Nb ratios in the range 4–6) were mainly erupted between 12 and 9 Ma. They were followed (between 10 and 7 Ma) by basalts displaying geochemical features which are transitional between calc-alkaline and alkaline lavas (La/Nb=1–1.7). After a ca. 3-Ma quiescence period, volcanic activity resumed, with the eruption of OIB-type alkaline basalts (La/Nb=0.5–0.6), from 4 to 0.8 Ma. A combined geochemical approach, using incompatible elements and Sr, Nd and O isotopes, allows us to conclude that the transitional basalts derived from the melting of a heterogeneous mantle source, at the boundary between lithosphere and asthenosphere. We propose that melting of a previously subduction-modified lithospheric mantle occurred between 12 and 10 Ma, in response to the upwelling of hot asthenosphere flowing up into an opening gap above a detached sinking slab. As a result, calc-alkaline magmas were formed. From 10 to 7 Ma, the transitional basalts were generated through melting of the boundary mantle zone between the lithosphere and the upwelling asthenosphere. During that stage, the contribution of the lithospheric source was still predominant. Then, as sinking of the oceanic slab progressed, the increasing uprise of the asthenosphere led to the formation and emplacement (from 4 to 0.8 Ma) of typical within-plate alkaline basalts derived from a plume-modified asthenospheric mantle.  相似文献   
66.
Two climate simulations of 150 years, performed with a coupled ocean/sea-ice/atmosphere model including stratospheric ozone, respectively with and without heterogeneous chemistry, simulate the tropospheric warming associated with an increase of the greenhouse effect of carbon dioxide and other trace gases since 1950 and their impact on sea–ice extent, as well as the stratospheric cooling and its impact on ozone concentration. The scenario with heterogeneous chemistry reproduces the formation of the ozone hole over the South Pole from the 1970s and its deepening until the present time, and shows that the ozone hole should progressively fill during the coming decades. To cite this article: J.-F. Royer et al., C. R. Geoscience 334 (2002) 147–154.  相似文献   
67.
The modelling of elastic waves in fractured media with an explicit finite‐difference scheme causes instability problems on a staggered grid when the medium possesses high‐contrast discontinuities (strong heterogeneities). For the present study we apply the rotated staggered grid. Using this modified grid it is possible to simulate the propagation of elastic waves in a 2D or 3D medium containing cracks, pores or free surfaces without hard‐coded boundary conditions. Therefore it allows an efficient and precise numerical study of effective velocities in fractured structures. We model the propagation of plane waves through a set of different, randomly cracked media. In these numerical experiments we vary the wavelength of the plane waves, the crack porosity and the crack density. The synthetic results are compared with several static theories that predict the effective P‐ and S‐wave velocities in fractured materials in the long wavelength limit. For randomly distributed and randomly orientated, rectilinear, non‐intersecting, thin, dry cracks, the numerical simulations of velocities of P‐, SV‐ and SH‐waves are in excellent agreement with the results of the modified (or differential) self‐consistent theory. On the other hand for intersecting cracks, the critical crack‐density (porosity) concept must be taken into account. To describe the wave velocities in media with intersecting cracks, we propose introducing the critical crack‐density concept into the modified self‐consistent theory. Numerical simulations show that this new formulation predicts effective elastic properties accurately for such a case.  相似文献   
68.
The Khushaym Matruk site in central Jordan may represent a natural analogue depicting the interaction of alkaline solutions with a clayey sedimentary formation or with clay-rich confining barriers at the interface with concrete structures in waste disposal sites. In this locality, past spontaneous combustion of organic matter in a clayey biomicritic formation produced a ca. 60 m-thick layer of cement-marble containing some of the high-temperature phases usually found in industrial cements (e.g., spurrite, brucite, and Ca-aluminate). A vertical cross-section of the underlying sediments was used in order to study the interaction between cement-marbles and neighbouring clayey limestones under weathering conditions. A thermodynamic approach of the alteration parageneses (calcite–jennite–afwillite–brucite and CSH phases) in the cement-marbles constrains the interacting solutions to have had pH-values between 10.5 and 12. Over 3 m, the sediments located beneath the metamorphic unit were compacted and underwent carbonation. They display large C and O isotopic variations with respect to “pristine” sediments from the bottom of the section. Low δ13C-values down to −31.4‰/PDB show the contribution of CO2 derived from the oxidization of organic matter and from the atmosphere to the intense carbonation process affecting that particular sedimentary level. The size of the C isotopic anomalies, their geometrical extent and their coincidence with the variations of other markers like the Zn content, the structure of organic matter, the mineralogical composition, all argue that the carbonation process was induced by the percolation of high pH solutions which derived from the alteration of cement-marbles. The temperature of the carbonation process remains conjectural and some post-formation O isotopic reequilibration likely affected the newly-formed carbonate. Carbonation induced a considerable porosity reduction, both in fractures and matrixes. The Khushaym Matruk site may have some bearing to the early life of a repository site, when water saturation of the geological formations hosting the concrete structures is incomplete, enabling simultaneous diffusion of alkaline waters and gaseous CO2 in the near field.  相似文献   
69.
Spontaneous combustion, less than 1 Ma ago, affected a 60-m thick sediment pile of biomicrite at the Khushaym Matruck site (Jordan). The present study shows that three retrograde alteration stages occurred: weathering, thermal stress and oxidative alkaline perturbation. μ-FT-i.r. spectra of isolated kerogens and oxygen index of whole rocks indicate that oxidation of organic matter occurred down to ∼10 m beneath the metamorphosed zone at Khushaym Matruck. The occurrence of the oxidative weathering bacterially mediated, as suggested by the mass chromatograms of saturated hydrocarbons, can explain high Rock-Eval Tmax values and low petroliferous potential measured along the sedimentary pile. On the other hand, the thermal extent of combustion events was limited to the first 2 m from the contact. The mean reflectance of 0.20–0.24% and porosity of ca. 50% of the grey clayey biomicrites indicate that organic matter was very immature and sediments were unconsolidated at the time of the combustion event. Using mineralogy, microscopic analyses of vegetable debris and magnetic susceptibility, a suite of characteristic points corresponding to the thermal imprint can be assessed: (i) x = 0m, T ∼ 1000 °C, (ii) x = 1 m, T ∼ 350 °C, (iii) x = 2 m, T ∼ 150 °C and (iv) x > ∼ 8 m, T ∼ 30 °C. Paleocirculation of meteoric groundwater in the ‘cement-marbles’ generated high-pH fluids that have circulated via fractures and through the matrix porosity of the underlying biomicrites but have also induced alkaline hydrolysis and oxidative attack of the organic matter. The polysaccharide/lignin ratio derived from μ-FT-i.r. analyses shows that the delignification of vegetable debris and degradation of polysaccharides progressively decline in the indurated zone, which indicates a decrease in the pH of migrating solutions. The latter also severely oxidized organic matter at 2.10 and 3.05 m as revealed by the oxygen index and induced the generation of bitumen. The spatial correlation between the oxidation levels of organic matter and the metal contents (Fe, Ti and Cr) suggests that redox reactions were responsible for the immobilization of metals in the indurated biomicrites. The intensity of these reactions is attributed to changes in the fluid flow regime within the sedimentary column.  相似文献   
70.
The general variational principle obtained by Unno for the study of stellar stability is extended to include the effects of magnetic fields in the general case where the perturbations are nonadiabatic. The unperturbed configuration is non-rotating, but internal motions are possible.A general stability equation is derived, using the modified variational principle. In the simplest case, this equation is identical to the one derived by Unno except for the appearance of magnetic terms in one of the coefficients (through the Lorentz force). If dissipation is neglected, the characteristic equation reduces to the one derived by Frieman and Rotenberg in the stationary case and by Kovetz in the static case.The stability of magnetic stars against homologous oscillations is examined and the usual result for the dynamical mode is obtained.  相似文献   
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