Trace-element study and age dating of zircon from chromitites of the Bushveld Complex (South Africa)     

Marina Yudovskaya  Judith Kinnaird  Anthony J. Naldrett  Nickolay Rodionov  Anton Antonov  Sergey Simakin  Dmitry Kuzmin 《Mineralogy and Petrology》2013,107(6):915-942

The layered Bushveld Complex hosts a number of chromitite layers, which were found to contain significant amounts of zircon grains compared with adjacent silicate rocks. Cathodoluminescent-dark, partially metamict cores and transparent rims of composite zircon grains were analyzed for trace elements with SIMS and LA-ICPMS techniques. The cores are enriched in REE, Y, Th and U and are characterized by distinctly flatter REE patterns in contrast to those of the rims and transparent homogenous crystals. Zircon from the different stratigraphic units has specific Th/U ratios, the highest of which (1.5–4) occurs in a Merensky Reef zircon core. The Ti content of Bushveld zircon ranges from 12 to 52 ppm correlating to a crystallization temperature range of 760–930 °C. The geochemical characteristics of the first zircon generation are consistent with its high-temperature crystallization as the first major U, Th and REE acceptor from a highly-evolved residue of the high-Mg basalt magma, whereas the rims and coreless crystals have crystallized from percolating intercumulus liquid of new influx of the same magma. U-Pb SHRIMP dating of zircon cores and rims does not reveal a distinguishable difference between their ages indicating the absence of inherited zircon. Concordia ages of 2,051?±?9 Ma (2σ, MSWD?=?0.1) and 2,056?±?5 Ma (2σ, MSWD?=?0.05) for zircons from the Merensky Reef and the Upper Platreef located equally near the top of the Critical Zone are in agreement with published ages for the Merensky Reef. Zircon from the deeper-seated Lower Group, Middle Group and Lower Platreef chromitites yields younger concordia ages that may reflect prolonged late-stage volatile activity.  相似文献   

The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds     

Sergey V. Krivovichev  Stanislav K. Filatov  Lidiya P. Vergasova 《Mineralogy and Petrology》2013,107(2):235-242

The crystal structure of ilinskite, NaCu₅O₂(SeO₃)₂Cl₃, a rare copper selenite chloride from volcanic fumaroles of the Great fissure Tolbachik eruption (Kamchatka peninsula, Russia), has been solved by direct methods and refined to R ₁?=?0.044 on the basis of 2720 unique observed reflections. The mineral is orthorhombic, Pnma, a?=?17.769(7), b?=?6.448(3), c?=?10.522(4) Å, V?=?1205.6(8) ų, Z?=?4. The The CuO_mCl_n coordination polyhedra share edges to form tetramers that have 'additional' O1 and O2 atoms as centers. The O1Cu₄ and O2Cu₄ tetrahedra share common Cu atoms to form [O₂Cu₅]⁶⁺ sheets. The SeO₃ groups and Cl atoms are adjacent to the [O₂Cu₅]⁶⁺ sheets to form complex layers parallel to (100). The Na⁺ cations are located in between the layers. A review of mixed-ligand CuO_mCl_n coordination polyhedra in minerals and inorganic compounds is given. There are in total 26 stereochemically different mixed-ligand Cu-O-Cl coordinations.  相似文献   

A series expansion of the solid Earth tide effect on geopotential     

Sergey M. Kudryavtsev 《Celestial Mechanics and Dynamical Astronomy》2013,115(4):353-364

We develop analytical series representing the main part of corrections to the geopotential coefficients caused by the solid Earth tides, where Love numbers are assumed to be frequency-independent. The series are compact, precise and valid over 1800 A.D.–2200 A.D. The maximum difference between the corrections given by the analytical series and their numerical values, obtained with use of the DE/LE-423 planetary/lunar ephemerides, does not exceed $0.7\times 10^{-12}$ . A new algorithm is proposed for calculating amplitudes of the additional variations of the geopotential coefficients for frequency dependence of Love numbers. It uses the representation of the Earth tide-generating potential in the standard HW95 format and takes into account the phase of tidal waves. Corrections of up to $2\times 10^{-12}$ to the published by the IERS Conventions (2010) amplitudes of the additional variations of the geopotential coefficients are suggested. Examples of use of the obtained series in analytical theories of motion of low-altitude STARLETTE and high-altitude ETALON-1 satellites are given.  相似文献   

High-order kernels for Riemannian wavefield extrapolation     

Paul Sava  Sergey Fomel 《Geophysical Prospecting》2008,56(1):49-60

Riemannian wavefield extrapolation is a technique for one‐way extrapolation of acoustic waves. Riemannian wavefield extrapolation generalizes wavefield extrapolation by downward continuation by considering coordinate systems different from conventional Cartesian ones. Coordinate systems can conform with the extrapolated wavefield, with the velocity model or with the acquisition geometry. When coordinate systems conform with the propagated wavefield, extrapolation can be done accurately using low‐order kernels. However, in complex media or in cases where the coordinate systems do not conform with the propagating wavefields, low order kernels are not accurate enough and need to be replaced by more accurate, higher‐order kernels. Since Riemannian wavefield extrapolation is based on factorization of an acoustic wave‐equation, higher‐order kernels can be constructed using methods analogous to the one employed for factorization of the acoustic wave‐equation in Cartesian coordinates. Thus, we can construct space‐domain finite‐differences as well as mixed‐domain techniques for extrapolation. High‐order Riemannian wavefield extrapolation kernels improve the accuracy of extrapolation, particularly when the Riemannian coordinate systems does not closely match the general direction of wave propagation.  相似文献   

Optimizing fixed observational assets in a coastal observatory     

Sergey Frolov  António Baptista  Michael Wilkin 《Continental Shelf Research》2008

Proliferation of coastal observatories necessitates an objective approach to managing of observational assets. In this article, we used our experience in the coastal observatory for the Columbia River estuary and plume to identify and address common problems in managing of fixed observational assets, such as salinity, temperature, and water level sensors attached to pilings and moorings. Specifically, we addressed the following problems: assessing the quality of an existing array, adding stations to an existing array, removing stations from an existing array, validating an array design, and targeting of an array toward data assimilation or monitoring.  相似文献   

Modeling ocean circulation on unstructured meshes: comparison of two horizontal discretizations     

Sergey Danilov  Qiang Wang  Martin Losch  Dmitry Sidorenko  Jens Schröter 《Ocean Dynamics》2008,58(5-6):365-374

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Risk Assessment and Disaster Management for Natural and Anthropogenically Induced Geologic Hazards: Application to the Preolkhon Region,Western Lake Baikal,Siberia, Russia   总被引：1，自引：0，他引：1  

Danko  Lidia V.  Kuzmin  Sergey B.  Snytko  Valerian A. 《Natural Resources Research》2000,9(4):315-319

In the Western Lake Baikal, recent Baikal Rift's tectonics control the topography, seismicity, climate, geomorphology, and economy. Scarps, facets, structural terraces, horsts and grabens, and trapezoid valleys can be clearly observed. They have been generated by the recent tectonic movements along the faults and represent a serious geologic hazard. The specific geological conditions predetermine a unique variety of landscapes. Thus, the main type of the economy is tourism. However, unorganized tourism leads to the degradation of the unique landscapes. It increases risk and requires disaster management. Three criteria has been used for risk assessment: (1) degree of geologic hazard; (2) degree of landscape degradation; and (3) degree of the economy's vitality. The high ecological significance and low stability to antropogeneous pressure are typical for landscapes of the Western Lake Baikal. Thus, some special activities of disaster management should be implemented based on our investigation.  相似文献   

Methane in the Sevastopol coastal area, Black Sea     

Lyudmila V. Malakhova  Viktor N. Egorov  Tatiana V. Malakhova  Sergey B. Gulin  Yury G. Artemov 《Geo-Marine Letters》2010,30(3-4):391-398

Concentrations of dissolved methane in seawater and bottom sediments, as well as of methane emanating from gas seeps were measured at 18 stations including several small bays in the Sevastopol coastal area (Black Sea) during 2007–2008. Methane concentrations in surface waters ranged from 10 to 2,970 nmol l^?1, and correlated well with values recorded for sediments. Methane concentrations in the water column were influenced by water depth, as well as by air and water temperatures. In the spring and summer of 2008, in situ CH₄ saturation relative to air was in the range of 970–71,900%. Maximum saturation was in summer. CH₄ fluxes to the atmosphere from the Sevastopol coastal area were estimated to vary from 190 to 1,550 μmol m^?2 day^?1. Gas bubbles escaping from the seepages contained about 57 vol% methane. Radiocarbon dating of the methane revealed an age not exceeding 150 years, implying a biogenic origin.  相似文献   

Second Species Periodic Orbits of the Elliptic 3 Body Problem     

Sergey Bolotin 《Celestial Mechanics and Dynamical Astronomy》2005,93(1-4):343-371

We consider the plane restricted elliptic 3 body problem with small mass ratio and small eccentricity and prove the existence of many periodic orbits shadowing chains of collision orbits of the Kepler problem. Such periodic orbits were first studied by Poincaré for the non-restricted 3 body problem. Poincaré called them second species solutions.  相似文献   

基于GIS模拟的Votkinsk水库流域积雪和融化过程（英文）     

Sergey V.PYANKOV  Andrey N.SHIKHOV  Nikolay A.KALININ  Eugene M.SVIYAZOV 《地理学报(英文版)》2018,(2)

Coupled hydrological and atmospheric modeling is an efficient method for snowmelt runoff forecast in large basins. We use short-range precipitation forecasts of mesoscale atmospheric Weather Research and Forecasting(WRF) model combining them with ground-based and satellite observations for modeling snow accumulation and snowmelt processes in the Votkinsk reservoir basin(184,319 km2). The method is tested during three winter seasons(2012–2015). The MODIS-based vegetation map and leaf area index data are used to calculate the snowmelt intensity and snow evaporation in the studied basin. The GIS-based snow accumulation and snowmelt modeling provides a reliable and highly detailed spatial distribution for snow water equivalent(SWE) and snow-covered areas(SCA). The modelling results are validated by comparing actual and estimated SWE and SCA data. The actual SCA results are derived from MODIS satellite data. The algorithm for assessing the SCA by MODIS data(ATBD-MOD 10) has been adapted to a forest zone. In general, the proposed method provides satisfactory results for maximum SWE calculations. The calculation accuracy is slightly degraded during snowmelt periods. The SCA data is simulated with a higher reliability than the SWE data. The differences between the simulated and actual SWE may be explained by the overestimation of the WRF-simulated total precipitation and the unrepresentativeness of the SWE measurements(snow survey).  相似文献