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11.
Serkan Sayin Fatih Ozcan Mustafa Yilmaz Ali Tor Shahabuddin Memon Yunus Cengeloglu 《洁净——土壤、空气、水》2010,38(7):639-648
In this study, 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy‐calix[4]arene ( 3 ) has been prepared by the treatment of calix[4]arene with a secondary amine (4‐benzylpiperidine) and formaldehyde by means of Mannich reaction. The prepared Mannich base ( 3 ) has been grafted onto [3‐(2,3‐epoxypropoxy)‐propyl]‐trimethoxysilane‐modified Fe3O4 magnetite nanoparticles (EPPTMS‐MN) in order to obtain 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy calix[4]arene‐grafted EPPTMS‐MN (BP‐calix[4]arene‐grafted Fe3O4). All new compounds were characterized by a combination of FTIR and 1H‐NMR analyses. The morphology of the magnetic nanoparticles was examined by transmission electron microscopy. Moreover, the studies regarding the removal of arsenate and dichromate ions from the aqueous solutions were also carried out by using 5,17‐bis‐[(4‐benzylpiperidine)methyl]‐25,26,27,28‐tetrahydroxy‐calix[4]arene in liquid–liquid extraction and BP‐calix[4]arene‐grafted Fe3O4 ( 4 ) in solid–liquid extraction experiments. The extraction results indicated that 3 is protonated at proton‐switchable binding sites in acidic conditions. Hence, facilitating binding of arsenate and dichromate is resulted from both electrostatic interactions and hydrogen bonding. To understand the selectivity of 3 , the retention of dichromate anions in the presence of Cl−, NO, and SO anions at pH 1.5 was also examined. 相似文献
12.
In this study, carboxymethylcellulose (CMC) based thermoresponsive nanocomposite hydrogel was synthesized for the removal of Cu2+ and Pb2+ ions from aqueous solutions. To prepare nanocomposite hydrogel, graft copolymerization of N‐isopropyl acrylamide (NIPAm) and acrylic acid (AA) onto CMC was carried out in Na‐montmorillonite (MMT)/water suspension media and ammonium persulfate (APS) used as initiator. The chemical structures of hydrogels were characterized by Fourier transform infrared (FT‐IR) and X‐ray diffraction spectroscopy (XRD). Lower critical solution temperature (LCST), pH responsivity, swelling, and deswelling properties of the hydrogels were also examined. In addition competitive and non‐competitive removal of Cu2+ and Pb2+ studies were carried out. According to heavy metal sorption studies results, removal capacities of nanocomposite hydrogel for both metal ions were found to be higher than those of pure hydrogel. The analyzed adsorption data showed that the adsorption process of Cu2+ and Pb2+ could be explained by pseudo‐second order kinetic model. Moreover, according to competitive sorption studies, it is found to be that both hydrogels are more selective to Cu2+ ion rather than Pb2+. 相似文献
13.
In this study, the oxidative decolorization of C.I. reactive yellow 145 (RY 145) from synthetic textile wastewater including RY 145 and polyvinyl alcohol by Fenton and sono‐Fenton processes which are the combination of Fenton process with ultrasound has been carried out. The effects of some operating parameters which are the initial pH of the solution, the initial concentration of Fe2+, H2O2, and the dye, temperature, and agitation speed on the color and chemical oxygen demand (COD) removals have been investigated. The optimum conditions have been found as [Fe2+] = 20 mg/L, [H2O2] = 20 mg/L, pH 3 for Fenton process and [Fe2+] = 20 mg/L, [H2O2] = 15 mg/L, pH 3 for sono‐Fenton process by indirectly sonication at 35 kHz ultrasonic frequency and 80 W ultrasonic power. The color and COD removal efficiencies have been obtained as 91 and 47% by Fenton process, and 95 and 51% by sono‐Fenton processes, respectively. Kinetic studies have been performed for the decolorization of RY 145 under optimum conditions at room temperature. It has been determined that the decolorization has occurred rapidly by sono‐Fenton process, compared to Fenton process. 相似文献
14.
Mahdi Zoorabadi Serkan Saydam Bruce Hebblewhite 《Geotechnical and Geological Engineering》2013,31(2):783-791
Penetration rate prediction of Tunnel Boring Machine (TBM) is the first step to advance prediction process of mechanized tunnelling. In this research, influence of effective parameters on TBM penetration rate is investigated by sensitivity analysis of three main TBM performance prediction methods; Norwegian University of Science and Technology (NTNU), rock mass index (RMi) and QTBM. Based on these analyses, it is shown that applied thrust per disc and joint spacing in NTNU and RMi models have more influence on penetration rate. In QTBM model, Q value, applied thrust per disc and induced biaxial stress are more effective. 相似文献
15.
Yusuf Bayrak Serkan Öztürk Hakan Çınar G. Ch. Koravos T. M. Tsapanos 《Pure and Applied Geophysics》2008,165(7):1367-1390
Complete data set of earthquakes in Turkey and the adjacent areas has been used in order to compute the ω values in 24 seismic
regions of Turkey. The parameter is obtained through Gumbel’s third asymptotic distribution of extreme values and is well
known as upper bound magnitude. This is an interpretation that no earthquake magnitude greater than ω can occur in a region. The results also estimate the
most probable magnitude for a time period of 100 years. The estimates of ω exceed the value of 7.00 in 20 of the 24 seismic
regions. An effort is also made to find a relation between the magnitude and the length of a fault in the complicated tectonics
of Turkey and the surrounding area. Earthquake hazard revealed as tables and maps are also considered for Turkey and the surrounding
area. 相似文献
16.
Serkan Öztürk 《Acta Geophysica》2011,59(2):209-238
Characteristics of seismic activity along the North Anatolian Fault Zone are analyzed between 1970 and 2010. Magnitude completeness
changes between 2.7 and 2.9 in the North Anatolian Fault Zone. The frequency-magnitude distribution of earthquakes is well
represented with a b-value typically close to 1. A clear decrease in temporal distribution of b-value is observed before the strong main shocks. Correlation dimension values are relatively large and the seismic activity
is more clustered at larger scales in the North Anatolian Fault Zone. 相似文献
17.
The Harsit Stream flowing into the Black Sea is an important watershed in the northeastern part of Turkey. The monthly averages of dissolved oxygen, carbonaceous biochemical oxygen demand, temperature, pH, total suspended solids, total phosphorus and total nitrogen were obtained for the water samples taken from the Tekke, Akcakale and Haciemin sites of the Harsit Stream. Water quality parameters were analyzed and evaluated according to the WHO standards and the Turkish Water Pollution Control Regulation. Initially, the variations in the dissolved oxygen profile were determined from dissolved oxygen, temperature and carbonaceous biochemical oxygen demand measurements by using the point source Streeter‐Phelps equation. Critical dissolved oxygen deficit values were calculated for the monthly average from January–December 2005, which are below the limit value (4 mg L–1) excluding April (7.26 mg L–1) and May (5.98 mg L–1) in the Harsit Stream, resulting in it having second class water quality in terms of dissolved oxygen concentration, temperature, pH and biochemical oxygen demand. It is also seen that the minimum dissolved oxygen limit value (8 mg L–1), which is a desired quantity for drinking water, is under the limit value for all months in the case of the water mixture. In particular, during the summer months, the consumption speed of oxygen is greater than the production speed of oxygen with increasing temperature and decreasing discharge, and negative values (anoxia) of dissolved oxygen sag are seen. These situations call for significant precautions and treatment criteria. 相似文献
18.
Azad Sağlam Selçuk M. Korhan Erturaç Serkan Üner Erman Özsayın Edwige Pons-Branchu 《Geodinamica Acta》2017,29(1):1-19
Fissure-ridge travertines (FRTs) are of great importance for the determination and comparison of tectonic deformation in a region. The coeval development of these travertines with active fault zones supplies significant information about regional dynamics in terms of deformation pattern and evolution. In this paper, the characteristics of FRTs of the Ba?kale basin (eastern Turkey) and responsible regional tectonism are discussed for the first time. The Ba?kale basin is located between the Ba?kale Fault Zone (BFZ) characterised by Çaml?k fault and I??kl?–Zirani? fault. It is located between dextral Yüksekova Fault Zone and southern end of dextral Guilato–Siahcheshmeh–Khoy Fault system (Iran). Various morphological features indicating recent activity are exposed along the BFZ, including offsetting rivers, fissure-ridge travertine and fault scarps. The Çaml?k fissure-ridge travertine composing of three different depositions is observed along the eastern edge of the BFZ with approximately parallel orientations. The Çaml?k fissure-ridge travertine has been formed and developed on fault zone related to strike-slip or oblique movements. We explain how kinematic changes of faults can influence the fissure-ridge development. 相似文献
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20.
Zoorabadi Mahdi Saydam Serkan Timms Wendy Hebblewhite Bruce 《Hydrogeology Journal》2022,30(1):111-119
Hydrogeology Journal - The hydraulic conductivity of jointed rocks is one of the main input parameters to predict water inflow to engineering structures that are located in the jointed rocks.... 相似文献