铅在高岭石表面的解吸动力学   总被引：3，自引：0，他引：3  

魏俊峰  吴大清  彭金莲  刁桂仪 《矿物岩石》2002,22(2):5-8

经过酸性条件下（pH=3.1)Pb(Ⅱ）高岭石表面解吸动力学的研究，发现解吸反应与吸附反应动力学相似，也是一个二阶段的过程，即初始的快速解吸之后伴随着一个缓慢的释放过程。在快速解吸阶段，7min内解吸量即已达到41％。吸附铅没有完全解吸，有近38％残留在高岭石表面，即解吸和吸附过程不是完全可逆的。解吸过程可以用扩展Elovich方程、Elovich方程、双常数方程和一级扩散方程较好地似合。  相似文献   

柴北缘绿梁山地区辉长岩的锆石U-Pb年龄及意义   总被引：11，自引：0，他引：11  

袁桂邦  王惠初  李惠民  郝国杰  辛后田  张宝华  王青海  田琪 《华北地质》2002,25(1):36-40

柴达木盆地北缘绿梁山地区的辉长岩侵入到古生代滩间山群及超基性岩中 ,地球化学、微量元素、稀土元素显示出源幔特征。选自其中的锆石明显具岩浆型锆石特点 ,4个单颗粒锆石U -Pb同位素年龄均为谐和年龄 ,2 0 6 Pb 2 38U表面年龄统计权重平均值为 (496 .3± 6 .2 )Ma ,代表了该岩体的结晶年龄 ,从而间接地否定了本区滩间山群的时代为晚奥陶世 -志留纪的认识。辉长岩与滩间山群是柴北缘活动大陆边缘火山岛弧的组成部分。此类岩体同位素地质年龄的确定对柴北缘榴辉岩、滩间山群时代及大地构造性质的重新认识具有重要意义  相似文献   

Physical properties of ultrahigh-pressure metamorphic rocks from the Sulu terrain, eastern central China: implications for the seismic structure at the Donghai (CCSD) drilling site     

Hartmut Kern  Zhenmin Jin  Shan Gao  Till Popp  Zhiqin Xu 《Tectonophysics》2002,354(3-4)

About 30 samples representing major lithologies of Sulu ultrahigh-pressure (UHP) metamorphic rocks were collected from surface exposures and exploration wells, and compressional (Vp) and shear wave (Vs) velocities and their directional dependence (anisotropy) were determined over a range of constant confining pressures up to 600 MPa and temperatures ranging from 20 to 600 °C. Samples range in composition from acidic to ultramafic. P- and S-wave velocities measured at 600 MPa vary from 5.08 to 8.64 km/s and 2.34 to 4.93 km/s, respectively. Densities are in the range from 2.60 to 3.68 g/cm³. To make a direct tie between seismic measurements (refraction and reflection) and subsurface lithologies, the experimental velocity data (corresponding to shallow depths) were used to calculate velocity profiles for the different lithologies and profiles of reflection coefficients at possible lithologic interfaces across the projected 5000-m Chinese Continental Scientific Drilling Program (CCSD) crustal segment. Comparison of calculated in situ velocities with respective intrinsic velocities suggests that the in situ velocities at shallow depths are lowered by an increased abundance of open microcracks. The strongly reflective zone beneath the Donghai drill site can be explained by the impedance contrasts between the different lithologies. Contacts between eclogite/peridotite and felsic rocks (gt-gneiss, granitic gneiss), in particular, may give rise to strong seismic reflections. In addition, shear-induced (lattice preferred orientation (LPO)-related) seismic anisotropy can increase reflectivity. For the explanation of the high velocity bodies (>6.4 km/s) around 1000 m and below 3200-m depth, large proportions of eclogite/peridotite (about 40 and 30 vol.%, respectively) are needed.  相似文献   

厚层覆盖区综合物化探方法找金试验研究——以广西兴安金石金矿为例     

胡云沪  罗先熔  王桂琴  杜建波  张小路 《矿产与地质》2002,(5)

在兴安金石金矿外围 4号分散流异常区 ,通过地电化学提取金测量法 ,查明测区存在 5个走向规模小于 5 0 m的金异常区 ,W( Au) 最大值为 72 .4× 10 - 9,高出背景值十几倍 ,并藉综合土壤吸附汞测量 ,高精度磁测和激发极化法等多种物化探方法来确定这些异常区的地质、地球化学和地球物理特征 ,提出金矿成矿的有利部位在金的地电提取高异常区、高汞量异常区、高磁性异常区、低视电阻率异常区和中等视极化率异常区的“三高一低一中”的找矿模式。确定测区的北北东角 (右下角 )一带具备有利的金矿成矿条件  相似文献   

川滇地区地震(Ms≥5.0)破裂类型与前兆异常分布的关系   总被引：1，自引：0，他引：1  

张永久  朱航  李桂芳  吴小平 《内陆地震》2002,16(2):136-142

对川滇地区 31次 (组 ) 5 .0级以上地震与余震次数的关系进行了统计 ,结合“强地震分为走滑型地震和断错型地震”的理论 ,确定了各次 (组 )地震的破裂类型。从物理机制上对地震破裂类型与震前前兆异常分布关系进行了讨论 ,由此进一步探讨了 5 .0级以上地震震后趋势预测  相似文献   

Extracting coseismic deformation of the 1997 Mani earthquake with differential interferometric SAR   总被引：2，自引：0，他引：2  

单新建  马瑾  王长林  柳稼航 《地震学报(英文版)》2002,15(4):431-438

Introduction The development and application of Interferometric Synthetic Aperture Radar (InSAR) have a close relationship with the sensors development of Synthetic Aperture Radar (SAR). The conception of SAR is proposed comparatively to the real aperture radar antenna. It is well known that the longer the antenna is, the higher the observation resolution will be. Just limited by the length of the antenna, the resolution of real aperture radar is generally very low and cannot meet the r…  相似文献   

多右端非对称位移方程组的GMRES种子投影方法     

朱文跃  顾桂定 《华东地质学院学报》2003,26(2):118-120

考虑用GMRES方法求解多右端非对称位移方程组(A-σjI)x^(j)=b^(j)，1≤j≤p。基于Smith的求解多右端方程组的种子投影思想，提出了求解上述位移方程组的GMRES种子投影方法，利用种子方程组产生的Krylov子空间来求近似解。本文给出了近似解的误差界，最后数值结果显示了该方法的有效性。  相似文献   

原子荧光光谱法测定地球化学样品中的砷、锑和汞的方法改进   总被引：1，自引：0，他引：1  

何贵  陈康林  王禄军 《四川地质学报》2003,23(1):62-64

在原子荧光光谱法中，通过改进地球化学样品的分解条件，预还原条件及测定条件，使砷、锑和汞能在同一介质中测定，而且实现了砷与汞的双道同时测定。方法的检测出限、准确度及精密度均能达到行业要求。  相似文献   

U–Pb zircon chronostratigraphy of early-Pliocene ignimbrites from La Pacana, north Chile: implications for the formation of stratified magma chambers     

Axel K Schmitt  Jan M Lindsay  Shan de Silva  Robert B Trumbull 《Journal of Volcanology and Geothermal Research》2003,120(1-2):43-53

High spatial resolution U–Pb dates of zircons from two consanguineous ignimbrites of contrasting composition, the high-silica rhyolitic Toconao and the overlying dacitic Atana ignimbrites, erupted from La Pacana caldera, north Chile, are presented in this study. Zircons from Atana and Toconao pumice clasts yield apparent ²³⁸U/²⁰⁶Pb ages of 4.11±0.20 Ma and 4.65±0.13 Ma (2σ), respectively. These data combined with previously published geochemical and stratigraphic data, reveal that the two ignimbrites were erupted from a stratified magma chamber. The Atana zircon U–Pb ages closely agree with the eruption age of Atana previously determined by K–Ar dating (4.0±0.1 Ma) and do not support long (>1 Ma) residence times. Xenocrystic zircons were found only in the Toconao bulk ignimbrite, which were probably entrained during eruption and transport. Apparent ²³⁸U/²⁰⁶Pb zircon ages of 13 Ma in these xenocrysts provide the first evidence that the onset of felsic magmatism within the Altiplano–Puna ignimbrite province occurred approximately 3 Myr earlier than previously documented.  相似文献   

潮滩沉积环境与岩相对比研究   总被引：12，自引：1，他引：12  

王颖  朱大奎  曹桂云 《沉积学报》2003,21(4):539-546

潮滩沉积是海陆交互作用的产物,形成于海岸坡度平缓、有丰富的细粒泥沙供应,以潮流动力为主的低能海岸环境,尤以河-海作用活跃的边缘海环境最为发育。潮滩沉积以粉砂为主,由于涨落潮流往复循环,潮滩具有动力、沉积、地貌与生物群体的分带现象。因海平面涨落与波浪参与的扰动筛选,导致潮滩沉积中的粗粒沉积物含量及微地貌形态的变化。这些因素反映于潮滩沉积相中具有下列特点:粉砂与粘土质交互叠置的页状层理;原始沉积层自下向上,粒径组成逐渐变细;下部的粉砂质层具有波痕、鱼刺状或丘状的交错层理、透镜体与扰动结构,或潮水沟堆积的镶嵌沙体;上部淤泥质层中具有草根、龟裂、虫管与钙质填充物、泥砾、泥块等。将现代潮滩沉积与南京钟山北麓下三叠统的黄马青组砂页岩,以及海口马村的下更新统湛江组粘土、粉砂岩进行对比,据泥沙粒径、矿物组合与含量,盐度,特别是薄互层理,虫管与钙质填充,泥裂块,波痕与交错层理等多项对比,均具有极好的相似性,表明该两组岩层为古潮滩沉积。  相似文献