Paleolimnology of McNearney lake: an acidic lake in northern Michigan     

Robert B. Cook  Russell G. Kreis Jr.  John C. Kingston  Keith E. Camburn  Stephen A. Norton  Myron J. Mitchell  Brian Fry  Linda C. K. Shane 《Journal of Paleolimnology》1990,3(1):13-34

McNearney Lake is an acidic (pH=4.4) lake in the Upper Peninsula of Michigan with low acid neutralizing capacity (ANC=-38 eq L^-1) and high SO _inf4 ^sup2- and aluminium concentrations. Oligotrophy is indicated by high Secchi transparency and by low chlorophyll a, total phosphorus, and total nitrogen concentrations. The lake water is currently acidic because base cations are supplied to the lake water at a low rate and because SO _inf4 ^sup2- from atmospheric deposition was not appreciably retained by the lake sediments or watershed and was present in the water column.This interdisciplinary paleolimnological study indicates that McNearney Lake is naturally acidic and has been so since at least 4000 years B.P., as determined from inferred-pH techniques based on contemporary diatom-pH relationships. Predicted pH values ranged from 4.7 to 5.0 over the 4000-year stratigraphy. Considerable shifts in species composition and abundance were observed in diatom stratigraphy, but present-day distributions indicate that all abundant taxa most frequently occur under acidic conditions, suggesting that factors other than pH are responsible for the shifts. The diatom-inferred pH technique as applied to McNearney Lake has too large an uncertainly and is not sensitive enough to determine the subtle recent changes in lakewater pH expected from changes in atmospheric deposition because: (1) McNearney Lake has the lowest pH in the contemporary diatom data set in the region and confidence intervals for pH predictions increase at the extremes of regressions; (2) other factors in addition to pH may be responsible for the diatom species distribution in the lake and in the entire northern Great Lakes region; (3) McNearney Lake has a well-buffered pH as a consequence of its low pH and high aluminium concentrations and is not expected to exhibit a large pH change as a result of changes in atmospheric deposition; and (4) atmospheric deposition in the region is modest and would not cause a pH shift large enough to be discernable in McNearney Lake.Elevated atmospheric deposition is indicated in recent sediments by Pb, V, and polycyclic aromatic hydrocarbon accumulation rates and to a lesser extent by those of Cu and Zn; however, these accumulation rates are substantially lower than those observed for acidified lakes in the northeastern United States. Although atmospheric loadings of materials associated with fossil fuel combustion have recently increased to McNearney Lake and apparently are continuing, the present study of the diatom subfossil record does not indicate a distinct, recent acidification (pH decrease).Order of the first two authors is alphabetical  相似文献   

An iron isotope signature related to electron transfer between aqueous ferrous iron and goethite     

Je-Hun Jang  Ryan Mathur  Laura J. Liermann  Shane Ruebush  Susan L. Brantley 《Chemical Geology》2008,250(1-4):40-48

We measured the Fe isotope fractionation during the reactions of Fe(II) with goethite in the presence and absence of a strong Fe(III) chelator (desferrioxamine mesylate, DFAM). All experiments were completed in an O₂-free glove box. The concentrations of aqueous Fe(II) ([Fe(II)_aq]) decreased below the initial total dissolved Fe concentrations ([Fe(II)_total], 2.15 mM) due to fast adsorption within 0.2 day. The concentration of adsorbed Fe(II) ([Fe(II)_ads]) was determined as the difference between [Fe(II)_aq] and the concentration of extracted Fe(II) in 0.5 M HCl ([Fe(II)_extr]) (i.e., [Fe(II)_ads] = [Fe(II)_extr] − [Fe(II)_aq]). [Fe(II)_ads] also decreased with time in experiments with and without DFAM, documenting that fast adsorption was accompanied by a second, slower reaction. Interestingly, [Fe(II)_extr] was always smaller than [Fe(II)_total], indicating that some Fe(II) was sequestered into a pool that is not HCl-extractable. The difference was attributed to Fe(II) incorporated into goethite structure (i.e., [Fe(II)_inc] = [Fe(II)_total] −[Fe(II)_extr]). More Fe(II) was incorporated in the presence of DFAM than in its absence at all time steps. Regardless of the presence of DFAM, both aqueous and extracted Fe(II) (δ^56/54Fe(II)_aq and δ^56/54Fe(II)_extr) became isotopically lighter than or similar to goethite (− 0.27‰) at day 7, implying that the isotope exchange occurred between bulk goethite and aqueous Fe. Consistently, the mass balance indicated that the incorporated Fe is isotopically heavier than extracted Fe. These observations suggested that (i) co-adsorption of Fe(II) with DFAM resulted in more pervasive electron transfer, (ii) the electron transfer from heavy Fe(II) in the adsorbed Fe(II) to light Fe(III) in goethite results in the fixation of heavy adsorbed Fe(III) on the surface and accumulation of Fe(II) within the goethite, and (iii) desorption of the reduced, light Fe from goethite does not necessarily occur at the same surface sites where adsorption occurred.  相似文献   

Composition of widespread volcanic glass in deep-sea sediments of the Southern Pacific Ocean: an Antarctic source inferred     

Philip AR Shane  Paul C Froggatt 《Bulletin of Volcanology》1992,54(7):595-601

Widespread Plio-Pleistocene (2.43-0.06 Ma) tephra zones recognised in deep-sea cores from high latitudes (>60°) in the Southern Pacific Ocean were thought to have originated from calc-alkaline rhyolitic eruptions in New Zealand, some 5000 km distant. Electron microprobe analyses of the glasses reveal a wide diversity of alkalic felsic compositions, as well as minor components of basic and intermediate glasses, incompatible with a New Zealand Neogene source but similar to contemporaneous eruptives from the Antarctic region. Most tephra zones are trachytic; seven zones are peralkaline rhyolite. The rhyolitic zones represent a deep-sea record of widespread silicic eruptions from continental Antarctica, possibly Marie Byrd Land. The extent of these rhyolitic zones suggest a greater frequency of large explosive eruptions in Antarctica than previously documented. The coarse grain size of some of the shards (up to 3 mm), their great distance from the closest sources (>1600 km for some cores), and the presence of nonvolcanic ice-rafted debris indicate some of the glasses, especially the more basic compositions, may have been ice-rafted, contrary to previous suggestions of a fallout origin.  相似文献   

Electrical interferences observed in the Cassini CIRS spectrometer     

Cheong Chan  Shane Albright  Nicolas Gorius  John Brasunas  Don Jennings  F. Michael Flasar  Ronald Carlson  Ever Guandique  Conor Nixon 《Experimental Astronomy》2015,39(2):367-386

  相似文献   

Doppler Lidar Measurements of Vertical Velocity Spectra in the Convective Planetary Boundary Layer   总被引：1，自引：1，他引：0  

Marie Lothon  Donald H. Lenschow  Shane D. Mayor 《Boundary-Layer Meteorology》2009,132(2):205-226

We utilized a Doppler lidar to measure spectra of vertical velocity w from 390m above the surface to the top of the daytime convective boundary layer (CBL). The high resolution 2μm wavelength Doppler lidar developed by the NOAA Environmental Technology Laboratory was used to detect the mean radial velocity of aerosol particles. It operated continuously during the daytime in the zenith-pointing mode for several days in summer 1996 during the Lidars-in-Flat-Terrain experiment over level farmland in central Illinois, U.S.A. The temporal resolution of the lidar was about 1 s, and the range-gate resolution was about 30m. The vertical cross-sections were used to calculate spectra as a function of height with unprecedented vertical resolution throughout much of the CBL, and, in general, we find continuity of the spectral peaks throughout the depth of the CBL. We compare the observed spectra with previous formulations based on both measurements and numerical simulations, and discuss the considerable differences, both on an averaged and a case-by-case basis. We fit the observed spectra to a model that takes into account the wavelength of the spectral peak and the curvature of the spectra across the transition from low wavenumbers to the inertial subrange. The curvature generally is as large or larger than the von Kármán spectra. There is large case-to-case variability, some of which can be linked to the mean structure of the CBL, especially the mean wind and the convective instability. We also find a large case-to-case variability in our estimates of normalized turbulent kinetic energy dissipation deduced from the spectra, likely due for the most part to a varying ratio of entrainment flux to surface flux. Finally, we find a relatively larger contribution to the low wavenumber region of the spectra in cases with smaller shear across the capping inversion, and suggest that this may be due partly to gravity waves in the inversion and overlying free atmosphere.  相似文献   

Engineering characterisation of Norwegian glaciomarine silt     

Michael Long  Gisli Gudjonsson  Shane Donohue  Knut Hagberg 《Engineering Geology》2010,110(3-4):51-65

Guidance is provided for geotechnical engineers designing civil engineering works in silty soils based on a detailed characterisation of a glaciomarine silt from Os in western Norway. It was found that these soils are susceptible to disturbance by good quality fixed piston tube sampling and care needs to be taken when using laboratory derived design parameters, particularly for consolidation and shear strength properties. A technique for assessing sample disturbance using shear wave velocity and suction measurements proved promising. Conventional techniques for determining soil strength from triaxial tests in silt are inappropriate due to the dilational nature of the material and more reliable and logical strength estimates can be made from a limiting strain criterion. Field vane data should be used with caution as measured strength, particularly remoulded values, may be high and it seems more reliable parameters can be derived from CPTU tests. One dimensional consolidation and creep of these silts can be modelled successfully by the well-known Janbu formulation. The behaviour of the Os silts does not fit easily into classical soil mechanics and published frameworks for soft soils. It seems the material is of “transitional” type and this work adds to the database of such soils which includes other natural silts and gap graded soils. For future work it is recommended that larger sample tubes (say 75 mm) with a very sharp cutting edge should be used in parallel with in situ CPTU testing.  相似文献   

Insights into silicic melt generation using plagioclase, quartz and melt inclusions from the caldera-forming Rotoiti eruption, Taupo volcanic zone, New Zealand     

Victoria Smith  Phil Shane  Ian Nairn 《Contributions to Mineralogy and Petrology》2010,160(6):951-971

The Rotoiti (~120 km³) and Earthquake Flat (~10 km³) eruptions occurred in close succession from the Okataina Volcanic Centre at ~50 ka. While accessory mineral geochronology points to long periods of crystallization prior to eruption (10⁴–10⁵ years) and separate thermal histories for the magmas, little was known about the rates and processes of the final melt production and eruption. Crystal zoning patterns in plagioclase and quartz reveal the thermal and compositional history of the magmatic system leading up to the eruption. The dominant modal phase, plagioclase, displays considerable within-crystal zonation: An_37–74, ~40–227 ppm MgO, 45–227 ppm TiO₂, 416–910 ppm Sr and 168–1164 ppm Ba. Resorption horizons in the crystals are marked by sharp increases (10–30%) in Sr, MgO and X_An that reflect changes in melt composition and are consistent with open system processes. Melt inclusions display further evidence for open system behaviour, some are depleted in Sr and Ba relative to accompanying matrix glass not consistent with crystallization of modal assemblage. MI also display a wide range in XH₂O that is consistent with volatile fluxing. Quartz CL images reveal zoning that is truncated by resorption, and accompanied by abrupt increases in Ti concentration (30–80 ppm) that reflect temperature increases ~50–110°C. Diffusion across these resorption horizons is restricted to zones of <20 μm, suggesting most crystallization within the magma occurred in <2000 years. These episodes are brief compared to the longevity (10⁴–10⁵ year) of the crystal mush zones. All textural and compositional features observed within the quartz and plagioclase crystals are best explained by periodic mafic intrusions repeatedly melting parts of a crystal-rich zone and recharging the system with silicic melt. These periodic influxes of silicic melt would have accumulated to form the large volume of magma that fed the caldera-forming Rotoiti eruption.  相似文献   

The exceptional Herbig Ae star HD 101412: The first detection of resolved magnetically split lines and the presence of chemical spots in a Herbig star     

S. Hubrig  M. Schller  I. Savanov  J.F. Gonzlez  C.R. Cowley  O. Schütz  R. Arlt  G. Rüdiger 《Astronomische Nachrichten》2010,331(4):361-367

In our previous search for magnetic fields in Herbig Ae stars, we pointed out that HD 101412 possesses the strongest magnetic field among the Herbig Ae stars and hence is of special interest for follow‐up studies of magnetism among young pre‐main‐sequence stars. We obtained high‐resolution, high signal‐to‐noise UVES and a few lower quality HARPS spectra revealing the presence of resolved magnetically split lines. HD 101412 is the first Herbig Ae star for which the rotational Doppler effect was found to be small in comparison to the magnetic splitting and several spectral lines observed in unpolarized light at high dispersion are resolved into magnetically split components. The measured mean magnetic field modulus varies from 2.5 to 3.5kG, while the mean quadratic field was found to vary in the range of 3.5 to 4.8 kG. To determine the period of variations, we used radial velocity, equivalent width, line width, and line asymmetry measurements of variable spectral lines of several elements, as well as magnetic field measurements. The period determination was done using the Lomb‐Scargle method. The most pronounced variability was detected for spectral lines of He I and the iron peak elements, whereas the spectral lines of CNO elements are only slightly variable. From spectral variations and magnetic field measurements we derived a potential rotation period P_rot = 13.86 d, which has to be proven in future studies with a larger number of observations. It is the first time that the presence of element spots is detected on the surface of a Herbig Ae/Be star. Our previous study of Herbig Ae stars revealed a trend towards stronger magnetic fields for younger Herbig Ae stars, confirmed by statistical tests. This is in contrast to a few other (non‐statistical) studies claiming that magnetic Herbig Ae stars are progenitors of the magnetic Ap stars. New developments in MHD theory show that the measured magnetic field strengths are compatible with a current‐driven instability of toroidal fields generated by differential rotation in the stellar interior. This explanation for magnetic intermediate‐mass stars could be an alternative to a frozen‐in fossil field (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

Constraints on Titan’s topography through fractal analysis of shorelines     

Priyanka Sharma  Shane Byrne 《Icarus》2010,209(2):723-737

Titan’s north polar hydrocarbon lakes offer a unique opportunity to indirectly characterize the statistical properties of Titan’s landscape. The complexity of a shoreline can be related to the complexity of the landscape it is embedded in through fractal theory. We mapped the shorelines of 290 of the north polar titanian lakes in the Cassini synthetic aperture radar dataset. Out of these, we used a subset of 190 lake shorelines for our analysis. The fractal dimensions of the shorelines were calculated via two methods: the divider/ruler method and the box-counting method, at length scales of (1-10) km and found to average 1.27 and 1.32, respectively. The inferred power-spectral exponent of Titan’s topography (β) from theoretical and empirical relations is found to be ?2, which is lower than the values obtained from the global topography of the Earth or Venus. Some of the shorelines exhibit multi-fractal behavior (different fractal dimensions at different scales), which we interpret to signify a transition from one set of dominant surface processes to another. We did not observe any spatial variation in the fractal dimension with latitude; however we do report significant spatial variation of the fractal dimension with longitude. A systematic difference between the dimensions of orthogonal sections of lake shorelines is also noted, which signifies possible anisotropy in Titan’s topography. The topographic information thus gleaned can be used to constrain landscape evolution modeling to infer the dominant surface processes that sculpt the landscape of Titan.  相似文献   

A probabilistic assessment of eruption recurrence on Taveuni volcano, Fiji     

Shane J. Cronin  Mark Bebbington  Chin Lai 《Bulletin of Volcanology》2001,63(4):274-288

Taveuni, a 437-km² oceanic intraplate volcano in the northeastern Fiji Group, has been active throughout the Holocene and currently has a rapidly growing population. Alkali basalt magmas were erupted through monogenetic vents at constantly shifting locations along a SW-striking rift zone. Hence, quantification of volcanic hazard, in both spatial and temporal terms, is of great importance for disaster management and development agencies. Unlike previous probabilistic assessments of hazards in volcanic fields, the activity on Taveuni is both more recent and on a lesser spatial scale. This enables us to focus our attention on different aspects of the analysis. In particular, we propose a first attempt at dealing with the imprecision and inaccuracy inherent in volcanic eruption age data obtained via radiocarbon dating. Our results indicate that volcanic activity on Taveuni has a tendency to occur in episodes. If this tendency is strong, the present hazard may be considerably greater than otherwise supposed. We also confirm an apparent tendency for the volcanic activity to migrate southwards along the Taveuni rift axis towards the most densely settled area, and also the widest axial vent zone. This indicates that the risk from volcanic activity is again higher than might otherwise be supposed. We estimate a Taveuni-wide probability of0.56 for renewed activity within the next 50 years. Such quantitative results can be utilised within loss estimations during the planning stages of new infrastructure and business developments at various locations on the island.  相似文献