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81.
Calculations of the saturation of groundwaters with respect to minerals of the rocks hosting these waters indicate that most of the analyzed groundwaters were saturates with respect to calcite, dolomite, and quartz. Brines of chloride-calcic composition were determined to be saturated with respect to calcite, whereas brines of chloride-sodic composition are saturated with respect to dolomite and quartz. The solution was simultaneously saturated with respect to six minerals for the association ankerite-calcite-dolomite-pyrite-quartz-strontianite. An increase in the number of minerals with respect to which solution is saturated is correlated with an increase in the diversity of types of groundwaters and an increase in the runoff rate. The paper proposes possible avenues for searches for relations between hydrogeological and geochemical parameters that make it possible to adapt the thermodynamic models to real geological-hydrogeological conditions. The research was centered on the testing of groundwaters for their saturation with respect to minerals of the rocks hosting these waters. This parameter plays a significant part in forming the geochemical type of natural waters because it reflects the crystallization of a mineral from a solution and, consequently, the removal of an element from the aqueous solution. 相似文献
82.
N. E. Kozlov E. V. Martynov N. O. Sorokhtin A. A. Ivanov N. M. Kudryashov N. E. Kozlova 《Geochemistry International》2008,46(6):608-613
Rock associations characterized by heterogeneous sets of petrogeochemical parameters were compared by quantifying the degree of their similarity-dissimilarity and searching for discrimination trends between them. Using procedures specially developed for this purpose, it was demonstrated for the first time that the lithotectonic complexes of the Murmansk domain are fundamentally different from those of typical granulite-gneiss terrains and resemble the granite-greenstone terrains of the Baltic shield, Greenland, and Canada. Based on the whole data set, the Murmansk domain can be considered as a deeply eroded Archean granite-greenstone terrain retaining only the tonalite-trondhjemite-gneiss basement with abundant supracrustal enclaves. A trend of the compositional difference between the older and younger rock associations is similar to that between the tholeiitic and boninitic volcanic series. It was suggested that the petrogeochemical “age” trend reflects the initial stage of the compositional evolution of the metamagmatic rocks of the region from metamorphic rocks similar to tholeiites at the early stages to the Paleoproterozoic boninite-like rocks, which are believed to be linked to the unique PGE-bearing province of the northeastern Baltic shield. This implies that the specific metallogenic features of the region emerged already in the Archean, which supported the suggestion on the long duration of geological processes in the Early Precambrian. 相似文献
83.
N. M. Sushchevskaya A. N. Evdokimov B. V. Belyatsky V. A. Maslov D. V. Kuz’min 《Geochemistry International》2008,46(1):1-16
Petrological and geochemical data obtained on the Quaternary lavas of volcanoes at Spitsbergen Island indicate that the rocks were produced via the deep-seated crystallization of parental alkaline magmas at 8–10 kbar. The character of clinopyroxene enrichment in incompatible elements indicates that the mineral crystallized from more enriched melts than those inferred from the composition of the host lavas. These melts were close to the parental melts previously found as veinlets in mantle hyperbasite xenoliths in the lavas. According to the character of their enrichment in Pb and Sr radiogenic isotopes and depletion in Nd, the basalts from Spitsbergen Island define a single trend with the weakly enriched tholeiites of the Knipovich Ridge, a fact suggesting the closeness of the enriched sources beneath the continental margin of Spitsbergen and beneath the spreading zone. Magmatic activity at Spitsbergen was related to the evolution of the Norwegian-Greenland basin, which evolved in pulses according to the shift of the spreading axes. The most significant of the latter events took place in the Neogene, when the Knipovich Ridge obtained its modern position near the western boundary of Spitsbergen. Early in the course of the evolution, the emplacement of alkaline melts generated at Spitsbergen into the oceanic mantle could form the enriched mantle, which was later involved in the melting process beneath the spreading zone. 相似文献
84.
With recent changes in the ways that state agencies are implementing their environmental policies, the line between public and private is becoming increasingly blurred. This includes shifts from state-led implementation of environmental policies to conservation plans that are implemented and managed by multi-sectoral networks of governments, the private sector and environmental non-governmental organizations (ENGOs). This paper examines land trusts as private conservation initiatives that become part of neoliberal governance arrangements and partnerships that challenge our conceptions of environmental preservation and democratic participation. The paper starts with an examination of the concept of neoliberalized environmental governance. Next, it addresses the shifting social constructions of property and land in the context of protecting large scale ecosystems. Through a case study of the extension of new environmental governance arrangements on the Oak Ridges Moraine in Ontario, we examine the relationships that have formed between different levels of the state and environmental non-governmental organizations. Finally, we analyze the expansion of land trusts and private conservation initiatives that are predicated on private land ownership and the commodification of nature, the emerging discourses and practices of private conservation, and how these are implicated in the privatization and neoliberalization of nature. 相似文献
85.
The lateral variability of structural elements in the collision zone of the Cretaceous-Paleocene Achaivayam-Valagin island arc with the northeastern Asian margin is considered. The similarity and difference of Eocene collision structural elements in the north and the south of Kamchatka are shown. In northern Kamchatka, the continent-arc boundary is traced along the Lesnaya-Vatyn Thrust Fault, which completed its evolution about 45 Ma ago. The thin, near-horizontal allochthon of this thrust, composed of island-arc rocks, overlies the deformed but unmetamorphosed terrigeneous sequences of the Asian margin. The general structure of this suture in the Kamchatka Isthmus and southern Koryakia is comparable with the uppermost subduction zone, where a thin lithospheric wedge overlaps intensely deformed sediments detached from the plunging plate. In southern Kamchatka (Malka Uplift of the Sredinny Range), the arc-continent collision started 55–53 Ma ago with thrusting of island-arc complexes over terrigenous rocks of continental margin. However, the thickness of the allochthon was much greater than in the north. Immediately after this event, both the autochthon and lower part of allochthon were deformed and subsided to a significant depth. This subsidence gave rise to metamorphism of both the autochthon (Kolpakov and Kamchatka groups, Kheivan Formation) and lower allochthon (Andrianovka and Khimka formations). The anomalously fast heating of the crust was most likely related to the ascent of asthenospheric masses due to slab breakoff, when the Eurasian Plate was plunging beneath the Achaivayam-Valagin arc. 相似文献
86.
3D models of apparent magnetization and density of rocks allow us to provide insights into the deep structure of the Volga-Ural, Pericaspian, and Fore-Caucasus petroliferous basins. In the Volga-Ural Basin, some Riphean rifts reveal close spatial relations to Paleoproterozoic linear zones, presumably of the rift nature as well. The structure of the Paleoproterozoic Toropets-Serdobsk Belt is interpreted in detail. Rocks with petrophysical properties inherent to basic volcanics are established in the pre-Paleozoic basement of the marginal zone of the Pericaspian Basin. These rocks locally spread beyond the boundary escarpment and may be regarded as a part of the Riphean plume-related basaltic province. It is shown that the Pericaspian Basin was formed on the place of a triple junction of Riphean rifts: the Sarpa and Central Pericaspian oceanic branches and the continental branch of the Pachelma Aulacogen. The drastically different petrophysical properties of the basement beneath Baltica and the Astrakhan Arch indicate that this arch is an element of the large terrane that was attached to Baltica in the Vendian. The suture along which the Astrachan Terrane is conjugated with the basement of the central and southern segments of the Karpinsky Ridge is traced beneath the Paleozoic complex. A system of northwest-verging thrust faults formed during the collision between Scythia and Eurasia is mapped in the basement of the junction zone between the Karpinsky Ridge and Scythian Platform (Terrane). According to geological data, this event took place in the Early Paleozoic. 相似文献
87.
Klauea historical summit lavas have a wide range in matrix 18OVSMOWvalues (4·9–5·6) with lower values in rockserupted following a major summit collapse or eruptive hiatus.In contrast, 18O values for olivines in most of these lavasare nearly constant (5·1 ± 0·1). The disequilibriumbetween matrix and olivine 18O values in many samples indicatesthat the lower matrix values were acquired by the magma afterolivine growth, probably just before or during eruption. BothMauna Loa and Klauea basement rocks are the likely sources ofthe contamination, based on O, Pb and Sr isotope data. However,the extent of crustal contamination of Klauea historical magmasis probably minor (< 12%, depending on the assumed contaminant)and it is superimposed on a longer-term, cyclic geochemicalvariation that reflects source heterogeneity. Klauea's heterogeneoussource, which is well represented by the historical summit lavas,probably has magma 18O values within the normal mid-ocean ridgebasalt mantle range (5·4–5·8) based on thenew olivine 18O values. KEY WORDS: Hawaii; Klauea; basalt; oxygen isotopes; crustal contamination 相似文献
88.
V. A. Lebedev S. N. Bubnov O. Z. Dudauri G. T. Vashakidze 《Stratigraphy and Geological Correlation》2008,16(2):204-224
Isotopic-geochronological study of the Pliocene magmatic activity in western part of the Dzhavakheti Highland (northwestern region of the Lesser Caucasus) is carried out. The results obtained imply that the Pliocene magmatic activity lasted in this part of the highland approximately 2 million years from 3.75 to 1.75–1.55 Ma. As is established, the studied volcanic rocks correspond in composition mostly to K-Na subalkaline and more abundant normal basalts. Time constraints of main phases in development of basic volcanism within the study region are figured out. We assume that individual pulses of silicic to moderately silicic volcanism presumably took place in the Dzhavakheti Highland about 3.2 and 2.5 Ma ago. 相似文献
89.
G. V. Ovchinnikova A. B. Kuznetsov I. M. Vasil’eva I. M. Gorokhov M. T. Krupenin A. V. Maslov T. L. Turchenko 《Stratigraphy and Geological Correlation》2008,16(2):138-142
The mineral composition and U-Pb and Rb-Sr systematics of phosphorites from the Satka Formation of Lower Riphean carbonates, the Burzyan Group of Southern Urals, are studied. Phosphorites occurring as small lenses between stromatolite layers are composed largely of fluorapatite with admixture of detrital quartz, feldspars, illite, and chlorite. Phosphorite samples have been subjected to stepwise dissolution in 1 N (fraction L-1) and 2 N (fraction L-2) HCl. As is established, the maximum apatite content is characteristic of fraction L-1, while fraction L-2 is enriched in products of dolomite and sulfide dissolution and in elements leached from siliciclastic components. The Sr content in the Satka apatites (280–560 ppm) is substantially lower as compared with that in unaltered marine apatite. The 87Sr/86Sr “initial ratio in the phosphorites studied (0.71705–0.72484) and host dolomites from the lower part of the Satka Formation is significantly higher than in the Early Riphean seawater that indicates a reset of the Rb-Sr original systems in sediments. The Pb-Pb age of 1340 ± 30 Ma (MSWD = 6.4) estimated based on 7 data points characterizing fractions L-1 and L-2 is younger than the formation time of overlying Burzyan sediments, being consistent, within the error range, with date of the Mashak rifting event recorded at the Early-Middle Riphean boundary. The comparative U-Pb characteristics of two soluble fractions (L-1 and L-2) and silicate residue of phosphorites show that epigenetic redistribution of Pb and U was characteristic of the phosphorite horizon only. The initial Pb isotope composition and μ (238U/204Pb) estimated according to model by Stacey and Kramers for the early diagenetic fluids in carbonate and phosphate sediments of the Satka Formation suggest that they were in isotopic equilibrium with erosion products of the Taratash crystalline complex. 相似文献
90.
V. S. Kulikov Ya. V. Bychkova V. V. Kulikova Yu. A. Kostitsyn O. S. Pokrovsky M. V. Vasil’ev 《Petrology》2008,16(6):531-551
The Ruiga differentiated mafic-ultramafic intrusion in the northwestern part of the Vetreny Belt paleorift was described for the first time based on geological, petrological, geochronological, and geochemical data. The massif (20 km2 in exposed area) is a typical example of shallow-facies peridotite-gabbro-komatiite-basalt associations and consists of three zones up to 810 m in total thickness (from bottom to top): melanogab-bronorite, peridotite, and gabbro. In spite of pervasive greenschist metamorphism, the rocks contain locally preserved primary minerals: olivine (Fo 75–86), bronzite, augite of variable composition, labradorite, and Cr-spinels. A mineral Sm-Nd isochron on olivine melanogabbronorite from the Ruiga Massif defines an age of 2.39 ± 0.05 Ga, while komatiitic basalts of the Vetreny Belt Formation were dated at 2.40–2.41 Ga (Puchtel et al., 1997). The rocks of the Ruiga intrusion and lava flows of Mt. Golets have similar major, rare-earth, and trace element composition, which suggests their derivation from a single deep-seated source. Their parent magma was presumably a high-Mg komatiitic basalt. In transitional crustal chambers, its composition was modified by olivine-controlled fractionation and crustal contamination, with the most contaminated first portions of the ejected melt. In terms of geology and geochemistry, the considered magmatic rocks of the Vetreny Belt are comparable with the Raglan Ni-PGE komatiite gabbro-peridotite complex in Canada (Naldrett, 2003). 相似文献