Structural relaxation in silicate melts and non-Newtonian melt rheology in geologic processes   总被引：4，自引：0，他引：4  

Donald B. Dingwell  Sharon L. Webb 《Physics and Chemistry of Minerals》1989,16(5):508-516

The timescale of structural relaxation in a silicate melt defines the transition from liquid (relaxed) to glassy (unrelaxed) behavior. Structural relaxation in silicate melts can be described by a relaxation time, , consistent with the observation that the timescales of both volume and shear relaxation are of the same order of magnitude. The onset of significantly unrelaxed behavior occurs 2 log₁₀ units of time above . In the case of shear relaxation, the relaxation time can be quantified using the Maxwell relationship for a viscoelastic material; _S = _S/G (where _S is the shear relaxation time, G is the shear modulus at infinite frequency and _S is the zero frequency shear viscosity). The value of G known for SiO₂ and several other silicate glasses. The shear modulus, G , and the bulk modulus, K , are similar in magnitude for every glass, with both moduli being relatively insensitive to changes in temperature and composition. In contrast, the shear viscosity of silicate melts ranges over at least ten orders of magnitude, with composition at fixed temperature, and with temperature at fixed composition. Therefore, relative to _S, G may be considered a constant (independent of composition and temperature) and the value of _S, the relaxation time, may be estimated directly for the large number of silicate melts for which the shear viscosity is known.For silicate melts, the relaxation times calculated from the Maxwell relationship agree well with available data for the onset of the frequency-dependence (dispersion) of acoustic velocities, the onset of non-Newtonian viscosities, the scan-rate dependence of the calorimetric glass transition, with the timescale of an oxygen diffusive jump and with the Si-O bond exchange frequency obtained from ²⁹Si NMR studies.  相似文献   

Assessment of temporal changes in coastal sand dune environments using the log-hyperbolic grain-size method     

Jasper Knight  Julian D. Orford†  Peter Wilson  Sharon M. Braley 《Sedimentology》2002,49(6):1229-1252

Abstract Three cores (<9 m long) recovered from late Holocene coastal sand dunes in Northumberland, north‐eastern England, were examined stratigraphically and dated by the infrared stimulated luminescence (IRSL) method to the time period between the Medieval Warm Period (MWP; ≈ 900–1200 AD) and Little Ice Age (LIA; ≈ 1550–1800 AD). Grain‐size variability and CaCO₃ content were determined at 10‐mm intervals throughout parts of the cores. The sahara computer program was used to plot the log‐hyperbolic distribution (LHD) of grain‐size spectra from different stratigraphic levels and estimate the LHD's statistical components. Core samples plot variously in the depositional and erosional domains of the hyperbolic chi (χ) vs. xi (ξ) shape triangle, which describes components of sediment sorting. Depositional and erosional phases, discriminated within the LHD's shape triangle, cannot readily be resolved from core stratigraphies or correlated between cores. IRSL dates from single cores show a clustering about the period 1430–1540. Between the dated horizons, dunes accreted at ≈ 0·02–0·05 m year^?1, enabling the timing of excursions in χ and ξ to be estimated. These excursions, which can be resolved to the subannual level between the dated horizons, may be related to deposition by episodic storms or storm surges in the North Sea region, which is supported by historical documentary evidence. This innovative use of the LHD method and its derived statistics can be used successfully to describe temporal trends in coastal depositional environments and identify likely storm events in dune sediment records.  相似文献   

Locally modified surface winds on linear dunes as derived from directional raingauges     

David Sharon  Adina Margalit  Simon M. Berkowicz 《地球表面变化过程与地形》2002,27(8):867-889

The study deals with local airflow patterns induced by 12–16 m high, partly vegetated dunes, under various prevailing wind conditions. Detailed empirical data were derived by means of an unconventional use of directional raingauges. The utility and accuracy of the method have been previously tested in a combined empirical and numerical study over ridges on a similar scale. Results are presented on the nature, extent and intensity of locally modified patterns of surface flow and on their dependence on wind conditions and slope inclination. Results may serve to verify or refine existing perceptions or models of the flow affecting sand movement over dunes. For example, deflected surface wind flow and even stationary vortices were found to form under winds with resultant angles of incidence of only 5–10° relative to the axes of the dunes, and on slopes inclined only 12–15°, i.e. lower angles than often assumed in previous studies of dune morphology. Various effects of the resulting surface flow on the dune ecosystem are also referred to, e.g. the distribution of settling dust and seed dispersal. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Post‐wildfire changes in suspended sediment rating curves: Sabino Canyon,Arizona     

Sharon L. E. Desilets  Bart Nijssen  Brenda Ekwurzel  Ty P. A. Ferré 《水文研究》2007,21(11):1413-1423

Wildfire has been shown to increase erosion by several orders of magnitude, but knowledge regarding short‐term variations in post‐fire sediment transport processes has been lacking. We present a detailed analysis of the immediate post‐fire sediment dynamics in a semi‐arid basin in the southwestern USA based on suspended sediment rating curves. During June and July 2003, the Aspen Fire in the Coronado National Forest of southern Arizona burned an area of 343 km². Surface water samples were collected in an affected watershed using an event‐based sampling strategy. Sediment rating parameters were determined for individual storm events during the first 18 months after the fire. The highest sediment concentrations were observed immediately after the fire. Through the two subsequent monsoon seasons there was a progressive change in rating parameters related to the preferential removal of fine to coarse sediment. During the corresponding winter seasons, there was a lower supply of sediment from the hillslopes, resulting in a time‐invariant set of sediment rating parameters. A sediment mass‐balance model corroborated the physical interpretations. The temporal variability in the sediment rating parameters demonstrates the importance of storm‐based sampling in areas with intense monsoon activity to characterize post‐fire sediment transport accurately. In particular, recovery of rating parameters depends on the number of high‐intensity rainstorms. These findings can be used to constrain rapid assessment fire‐response models for planning mitigation activities. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

DISCUSSION OF "'Where's the Benzene?'—Examining California Ground-Water Quality Surveys," by Paul W. Hadley and Richard Armstrong, January-February 1991 issue, v. 29, no. 1, pp. 35-40     

Sharon P. McLelland 《Ground water》1991,29(3):434-435

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Spatio-temporal pattern of viral meningitis in Michigan, 1993-2001     

Sharon K. Greene  Mark A. Schmidt  Mary Grace Stobierski  Mark L. Wilson 《Journal of Geographical Systems》2005,7(1):85-99

To characterize Michigans high viral meningitis incidence rates, 8,803 cases from 1993–2001 were analyzed for standard epidemiological indices, geographic distribution, and spatio-temporal clusters. Blacks and infants were found to be high-risk groups. Annual seasonality and interannual variability in epidemic magnitude were apparent. Cases were concentrated in southern Michigan, and cumulative incidence was correlated with population density at the county level (r=0.45, p<0.001). Kulldorffs Scan test identified the occurrence of spatio-temporal clusters in Lower Michigan during July–October 1998 and 2001 (p=0.01). More extensive data on cases, laboratory isolates, sociodemographics, and environmental exposures should improve detection and enhance the effectiveness of a Space-Time Information System aimed at prevention.The authors gratefully acknowledge Dr. Duane Newton, former manager of the Virology Section, Michigan Department of Community Health Bureau of Laboratories, for his provision of data on viral isolates. We also appreciate the contributions of Drs. Leah Estberg and Dunrie Greiling for ClusterSeer support, Scott Swan for his assistance with ArcView GIS, and Dr. Edward L. Ionides for his advice on time series analysis. We are grateful to Dr. Pierre Goovaerts and two anonymous reviewers for their insightful comments on an earlier draft of this paper. This project was supported in part by a grant from the National Oceanic and Atmospheric Administrations Joint Program on Climate Variability and Human Health, a consortium including the EPA, NASA, NSF, and EPRI (NA16GP2361) to MLW.  相似文献   

Agent-based model simulations of future changes in migration flows for Burkina Faso     

Dominic Kniveton  Christopher Smith  Sharon Wood 《Global Environmental Change》2011

Attempts to quantify the numbers of migrants generated by changes in climate have commonly been calculated by projecting physical climate changes on an exposed population. These studies generally make simplistic assumptions about the response of an individual to variations in climate. However, empirical evidence of environmentally induced migration does not support such a structural approach and recognises that migration decisions are usually both multi-causal and shaped through individual agency. As such, agent-based modelling offers a robust method to simulate the autonomous decision making process relating to environmental migration. The Theory of Planned Behaviour provides a basis that can be used to effectively break down the reasoning process relating to the development of a behavioural intention. By developing an agent-based model of environmental migration for Burkina Faso from the basis of a combination of such theoretical developments and data analysis we further investigate the role of the environment in the decision to migrate using scenarios of future demographic, economic, social, political, and climate change in a dryland context. We find that in terms of climate change, it can be seen that that change to a drier environment produces the largest total and international migration fluxes when combined with changes to inclusive and connected social and political governance. While the lowest international migration flows are produced under a wetter climate with exclusive and diverse governance scenarios. In summary this paper illustrates how agent-based models incorporating the Theory of Planned Behaviour can be used to project evidence based future changes in migration in response to future demographic, economic social and climate change.  相似文献   

Ridge belts on Venus: Morphology and origin     

Frank  Sharon L.  Head  James W. 《Earth, Moon, and Planets》1990,(1):421-470

Ridge belts, composed of closely spaced individual ridges 5–20 km wide, form sinuous patterns 30–400 km wide and 200–2000 km long in the plains of northern Venus. They are not homogeneously distributed, but occur primarily in two regions: between 0 ° E and 90 ° E ridge belts are associated with large blocks of tessera, and have a cumulative length of about 13,200 km; and between 150 ° E and 250 ° E, the ridge belts form a fan-shaped pattern and have a total cumulative length of about 25,800 km. Most ridge belts trend within 10 ° of N-S. Five morphologic components exist within the ridge belts: (1) broad ridges, which have no sharp crest and usually occur individually in the plains: (2) discontinuous ridges, with short ridge segments less than 20 km long; (3) paired ridges, with closely spaced ridges (less than 10 km apart) that never merge; (4) parallel ridges, with widely spaced (10–50 km), less prominent ridges; and (5) anastomosing ridges, in which ridges splay at angles up to 30 °. Subtle cross-strike lineaments cut the ridge belts at angles of 30–90 ° to the ridge belt, and augen-shaped plains are often present in anastomosing ridges. We examine the relationships between the components, plains, cross-strike lineaments, and augen-shaped plains in five ridge belts. Broad arches similar to the arches associated with wrinkle ridges on the Moon, Mars and Mercury appear in all of the ridge belts examined. Through studying each of these components individually and in the context of five specific ridge belts, we conclude that these ridge belts formed by compressional forces. The ridge belts form a continuum of deformation, from the simple broad arches (Nephele Dorsa), representing small amounts of shortening, through asymmetric ridge belts in the plains (Pandrosa Dorsa) and adjacent to tessera (Kamari Dorsa), to ridge belts in troughs representing underthrusting (Ausra and Lukelong Dorsa). Underthrusting is also observed along the borders of Lakshmi Planum, associated with Freyja and Danu Montes.The interpreted compressional origins for the ridge belt components suggests that many of the other ridge belts are of compressional origin, although complex origins (involving a combination of extension, shear, and/or compression) for some ridge belts cannot be ruled out. Global high resolution data from the Magellan mission will permit global mapping of the characteristics and distribution of ridge belts and allow further tests for their origin and evolution.'Geology and Tectonics of Venus', special issue edited by Alexander T. Basilevsky (USSR Acad. of Sci., Moscow), James W. Head (Brown University, Providence). Gordon H. Pettengill (MIT. Cambridge, Massachusetts) and R. S. Saunders (J.P.L., Pasadena).  相似文献   

The hydrocarbons in the Isla Vista marine seep environment     

Daniel H. Stuermer  Robert B. Spies  Paul H. Davis  Douglas J. Ng  Clarence J. Morris  Sharon Neal 《Marine Chemistry》1982,11(5):413-426

Hydrocarbon analyses on samples of sediment, interstitial water, and dissolved and particulate fractions of the water column from the vicinity of the Isla Vista seep near Santa Barbara, California, are presented. The results demonstrate that a very heterogeneous distribution of hydrocarbon composition and concentration exists in the seep environment and that the life-style and feeding habits of the organisms in this environment will have a dramatic effect on their hydrocarbon exposure.  相似文献   

Seasonal controls on sediment transport and deposition in Lake Ohau,South Island,New Zealand: Implications for a high‐resolution Holocene palaeoclimate reconstruction          下载免费PDF全文

Heidi A. Roop  Gavin B. Dunbar  Richard Levy  Marcus J. Vandergoes  Alexander L. Forrest  Sharon L. Walker  Jennifer Purdie  Phaedra Upton  James Whinney 《Sedimentology》2015,62(3):826-844

Laminated sediments in Lake Ohau, Mackenzie Basin, New Zealand, offer a potential high‐resolution climate record for the past 17 kyr. Such records are particularly important due to the relative paucity of detailed palaeoclimate data from the Southern Hemisphere mid‐latitudes. This paper presents outcomes of a study of the sedimentation processes of this temperate lake setting. Hydrometeorological, limnological and sedimentological data were collected over a 14 month period between 2011 and 2013. These data indicate that seasonality in the hydrometeorological system in combination with internal lake dynamics drives a distinct seasonal pattern of sediment dispersal and deposition on a basin‐wide scale. Sedimentary layers that accumulate proximal to the lake inflow at the northern end of the lake form in response to discrete inflow events throughout the year and display an event stratigraphy. In contrast, seasonal change in the lake system controls accumulation of light (winter) and dark (summer) laminations at the distal end of the lake, resulting in the preservation of varves. This study documents the key processes influencing sediment deposition throughout Lake Ohau and provides fundamental data for generating a high‐resolution palaeoclimate record from this temperate lake.  相似文献