1980 volcanic eruption reported on Marion Island     

Wilhelm J. Verwoerd  Shaun Russell  Aldo Berruti 《Earth and Planetary Science Letters》1981,54(1):153-156

The first volcanic eruption in the recorded history of Marion Island (46°54′S, 37°45′E) occurred between February and October 1980 at a locality on the west coast. It was a minor event that passed unnoticed at the meteorological station 20 km distant. The discovery was made on November 4, by five expedition members who walked around the island. When examined in more detail on November 25, the lava was still warm in places and numerous fumaroles existed. Three blocky flows emanated from two adjacent cinder cones built-up on a pre-existing phreatomagmatic tuff cone known as Kaalkoppie. The largest flow covers an area of about seven hectares and a further two hectares have been inundated by ash. Another flow poured seawards to form a new beach front, blocking access to what was previously the largest elephant seal wallowing ground on the island. No earth tremors were felt and the activity seems to have ended for the time being.  相似文献   

X-ray absorption spectroscopy study of Cu and Zn adsorption complexes at the calcite surface: Implications for site-specific metal incorporation preferences during calcite crystal growth     

E.J Elzinga  R.J Reeder 《Geochimica et cosmochimica acta》2002,66(22):3943-3954

We report results from in situ extended X-ray absorption fine structure (EXAFS) spectroscopy studies of Cu(II) and Zn(II) complexes forming at the calcite surface following adsorption from preequilibrated calcite-saturated solutions. Both Cu(II) and Zn(II) coordinate at Ca sites on the calcite surface, forming mononuclear inner-sphere adsorption complexes. The Zn adsorption complexes are in tetrahedral coordination with first-shell O neighbors with R_Zn-O = 1.95 Å, and the Cu complexes are Jahn-Teller distorted, with equatorial R_Cu-O = 1.95 Å. Results from EXAFS data of dilute Cu- and Zn-calcite solid solutions confirm substitution of these metals in the Ca site of the calcite structure as octahedral complexes during coprecipitation. X-ray fluorescence microanalyses of calcite (101?4) hillocks grown in coprecipitation experiments show that divalent Cu and Zn, which have ionic radii smaller than Ca, are preferentially incorporated into the parallel arrays of <4?41>₊ steps that define one pair of symmetrically equivalent vicinal faces on polygonized growth spirals. In contrast, other divalent metals with sixfold ionic radii smaller than Ca (Co, Cd, Mn, Mg) have been shown to be preferentially incorporated into <4?41>₋ growth steps, which define the second pair of vicinal faces on the growth spirals, but which are symmetrically nonequivalent to the steps on the first pair. The distortion from octahedral symmetry observed for the Cu and Zn adsorption complexes likely plays a key role in the observed preference of Cu and Zn for incorporation into the <4?41>₊ steps.  相似文献   

Relating Radar Remote Sensing of Biomass to Modelling of Forest Carbon Budgets   总被引：1，自引：0，他引：1  

Thuy Le Toan  Shaun Quegan  Ian Woodward  Mark Lomas  Nicolas Delbart  Ghislain Picard 《Climatic change》2004,67(2):379-402

This paper addresses the use of radar remote sensing to map forest above-ground biomass, and discusses the use of biomass maps to test a dynamic vegetation model that identifies carbon sources and sinks and predicts their variation over time. For current radar satellite data, only the biomass of young/sparse forests or regrowth after disturbances can be recovered. An example from central Siberia illustrates that biomass can be measured by radar at a continental scale, and that a significant proportion of the Siberian forests have biomass values less than 50 tonnes/ha. Comparison between the radar map and calculations by the Sheffield Dynamic Global Vegetation Model (SDGVM) indicates that the model considerably overestimates biomass; under-representation of managed areas, disturbed areas and areas of low site quality in the model are suggested reasons for this effect. A case study carried out at the Büdingen plantation forest in Germany supports the argument that inadequate representations of site quality and forest management may cause model overestimates of biomass. Comparison of the calculated biomass of stands planted after 1990 with biomass estimates by radar allows identification of forest stands where the growth conditions assumed by the model are not valid. This allows a quality check on model calculations of carbon fluxes: only calculations for stands where there is good agreement between the data and the model predictions should be accepted. Although the paper only uses the SDGVM model, similar effects are likely in other dynamic vegetation models, and the results show that model calculations attempting to quantify the role of forests as carbon sources or sinks could be qualified and potentially improved by exploiting remotely sensed measurements of biomass.  相似文献   

Impact of a rock avalanche on a moraine‐dammed proglacial lake: Laguna Safuna Alta,Cordillera Blanca,Peru     

Bryn Hubbard  Andrew Heald  John M. Reynolds  Duncan Quincey  Shaun D. Richardson  Marco Zapata Luyo  Nelson Santillan Portilla  Michael J. Hambrey 《地球表面变化过程与地形》2005,30(10):1251-1264

Moraines that dam proglacial lakes pose an increasing hazard to communities in the Andes and other mountain ranges. The moraines are prone to failure through collapse, overtopping by lake waters or the effect of displacement waves resulting from ice and rock avalanches. Resulting floods have led to the loss of thousands of lives in the Cordillera Blanca mountains of Peru alone in the last 100 years. On 22 April 2002 a rock avalanche occurred immediately to the south‐west of Laguna Safuna Alta, in the Cordillera Blanca. The geomorphic evidence for the nature, magnitude and consequences of this event was investigated in August 2002. Field mapping indicated that the avalanche deposited 8–20 × 10⁶ m³ of rock into the lake and onto the surface of the frontal region of Glaciar Pucajirca, which flows into the lake. Repeated bathymetric surveying indicated that ～5 × 10⁶ m³ of this material was deposited directly into the lake. The immediate effect of this event was to create a displacement wave that gained in height as it travelled along the lake basin, overtopping the impounding moraine at the lake's northern end. To achieve overtopping, the maximum wave height must have been greater than 100 m. This, and subsequent seiche waves, caused extensive erosion of both the proximal and distal faces of the impounding terminal moraine. Further deep gullying of the distal face of this moraine resulted from the supply of pressurized water to the face via a relief overflow tunnel constructed in 1978. Two‐dimensional, steady‐state analysis of the stability of the post‐avalanche moraine rampart indicates that its proximal face remains susceptible to major large‐scale rotational failure. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Spontaneous strain at the structural phase transition in NaNO3     

Richard J. Reeder  Simon A. T. Redfern  Ekhard Salje 《Physics and Chemistry of Minerals》1988,15(6):605-611

The temperature dependence of the hexagonal c unit cell parameter of high-purity NaNO₃ shows an anomaly at 553 K corresponding to the orientational ordering transition. The a unit cell parameter is barely influenced by the transition. The single component spontaneous strain for this zone boundary instability is large (55×10^–3 at 295 K), and couples quadratically with the order parameter. The critical exponent is found to have the value 0.22 ± 0.01, which differs from that expected in the classical case. Below ca 450 K, crossover to tricritical behaviour is observed (=1/4). The temperature evolution of the macroscopic order parameter as revealed by the temperature dependence of the spontaneous strain follows a tricritical behaviour between 70 K and 450 K. At temperatures below 70 K order parameter saturation is observed. Combined with recent data from specific heat measurements, the critical exponents suggest that the three-dimensional, three-states Potts model may describe the transition.Precursor spontaneous strain above T _c is consistent with local ordering and may result from fluctuations associated with an antiordered NO₃ group pair configuration.  相似文献   

The role of citrate and phthalate during Co(II) coprecipitation with calcite     

Young J. Lee  Richard J. Reeder 《Geochimica et cosmochimica acta》2006,70(9):2253-2263

The influence of citrate and phthalate on Co coprecipitation with calcite was investigated using a combination of batch experiments, Fourier-transform infra-red (FT-IR) spectroscopy, and thermogravimetric analysis (TGA) over a wide range of precipitation rates. Steady-state growth conditions (at constant [Ca], [Co], DIC, and pH) were generally achieved within 3-5 h, after which Co(II) partitioning into calcite was evaluated. Only minor differences are observed in the partition coefficient (K_d) trends with and without citrate and phthalate as a function of calcite precipitation rate except at very low rates. Slight inhibition of calcite growth is observed in the presence of citrate or phthalate, which can be attributed to adsorption at surface sites. TGA curves for samples coprecipitated with citrate show a significant mass loss between 375 and 550 °C, whereas the weight-loss curves for the Co-phthalate coprecipitates are indistinguishable from those of the organic-free Co coprecipitates. This indicates that citrate is incorporated into calcite during calcite crystallization, whereas phthalate is excluded. FT-IR spectra for the sample with citrate show a broad absorption in the range 3700-3100 cm⁻¹, which is attributable to water molecules coordinated to citrate coprecipitated with calcite. The preferential incorporation of citrate over phthalate likely reflects differences in both aqueous speciation and conformation of the carboxylate groups. This new finding may provide new insight to the factors that control the behavior of macromolecules and their incorporation into the structure of calcium carbonate during biomineralization.  相似文献   

Chlorine stable isotope studies of old groundwater,southwestern Great Artesian Basin,Australia     

Min Zhang  Shaun K. Frape  Andrew J. Love  Andrew L. Herczeg  B.E. Lehmann  U. Beyerle  R. Purtschert 《Applied Geochemistry》2007

Stable Cl isotope ratios (³⁷Cl/³⁵Cl) were measured in groundwater samples from the southwestern flow system of the Great Artesian Basin, Australia to gain a better understanding of the Cl⁻ sources and transport mechanisms. δ³⁷Cl values range from 0‰ to −2.5‰ (SMOC), and are inversely correlated with Cl⁻ concentration along the inferred flow direction. The Cl isotopic compositions, in conjunction with other geochemical parameters, suggest that Cl⁻ in groundwaters is not derived from salt dissolution. Mixing of the recharge water with saline groundwater cannot explain the relationship between δ³⁷Cl and Cl⁻ concentration measured. Marine aerosols deposited via rainfall and subsequent evapotranspiration appear to be responsible for the Cl⁻ concentrations observed in wells that are close to the recharge area, and in groundwaters sampled along the southern transect. δ³⁷Cl values measured in the leachate of the Bulldog shale suggest that the aquitard is the subsurface source of Cl⁻ for the majority of groundwater samples studied. Diffusion is likely the mechanism through which Cl⁻ is transported from the pore water of the Bulldog shale to the aquifer. However, a more detailed study of the aquitard rocks is required to verify this hypothesis.  相似文献   

Automatic Detection of Magnetic δ in Sunspot Groups     

Sreejith Padinhatteeri  Paul A. Higgins  D. Shaun Bloomfield  Peter T. Gallagher 《Solar physics》2016,291(1):41-53

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Infrared observations and numerical modelling of grassland fires in the Northern Territory, Australia     

T. L. Clark  M. J. Reeder  M. Griffiths  D. Packham  N. Krusel 《Meteorology and Atmospheric Physics》2005,88(3-4):193-201

Summary This paper reports on a small-scale pilot experiment held early in the dry season near Darwin, Australia, in which fine-scale observations of several prescribed fires were made using infrared digital video. Infrared imaging is used routinely to locate fires as infrared radiation suffers little attenuation as it propagates through the smoke that normally obscures visible imagery. However, until now, little use has been made of digital video imagery in analyzing the convective-scale structure of prescribed (or wild) fires. The advantage of digital video imagery is that the individual frames can be objectively analyzed to determine the convective motion in the plane viewed by the camera. The infrared imagery shows mostly rising plumes, much like convective clouds. The flow is highly convective, and the vertical transport of heat is confined to relatively narrow thermals. The updrafts range from a few ms^–1 to around 15ms^–1. A numerical model is used to simulate one of the prescribed fires at very high-resolution. For the most part, the model predictions compare well to the observations. The model produces plumes that are around 7m high, and spaced around 5m apart, which is similar to that observed. The model correctly predicts the mean rate of spread of the fire to be 1.3ms^–1. Perhaps the most serious limitations to using infrared observations of the type presented here are the difficulties in interpreting precisely the relationship between the observed infrared temperature field and the air temperature calculated by the model, and the exact connection between the infrared camera derived flow field and that calculated by the model.  相似文献   

Relating Radar Remote Sensing of Biomass to Modelling of Forest Carbon Budgets     

Thuy?Le?ToanEmail author  Shaun?Quegan  Ian?Woodward  Mark?Lomas  Nicolas?Delbart  Ghislain?Picard 《Climatic change》2004,67(2-3):379-402

This paper addresses the use of radar remote sensing to map forest above-ground biomass, and discusses the use of biomass maps to test a dynamic vegetation model that identifies carbon sources and sinks and predicts their variation over time. For current radar satellite data, only the biomass of young/sparse forests or regrowth after disturbances can be recovered. An example from central Siberia illustrates that biomass can be measured by radar at a continental scale, and that a significant proportion of the Siberian forests have biomass values less than 50 tonnes/ha. Comparison between the radar map and calculations by the Sheffield Dynamic Global Vegetation Model (SDGVM) indicates that the model considerably overestimates biomass; under-representation of managed areas, disturbed areas and areas of low site quality in the model are suggested reasons for this effect. A case study carried out at the Büdingen plantation forest in Germany supports the argument that inadequate representations of site quality and forest management may cause model overestimates of biomass. Comparison of the calculated biomass of stands planted after 1990 with biomass estimates by radar allows identification of forest stands where the growth conditions assumed by the model are not valid. This allows a quality check on model calculations of carbon fluxes: only calculations for stands where there is good agreement between the data and the model predictions should be accepted. Although the paper only uses the SDGVM model, similar effects are likely in other dynamic vegetation models, and the results show that model calculations attempting to quantify the role of forests as carbon sources or sinks could be qualified and potentially improved by exploiting remotely sensed measurements of biomass.  相似文献