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71.
The reproducibility of the interannual variability of the summertime East Asian circulation is examined using an atmospheric
general circulation model (AGCM). An ensemble experiment is conducted using observed sea surface temperature (SST) of recent
20 years as a lower boundary condition. The spatial pattern associated with the first principal mode of observation of geopotential
height at 500 hPa is characterized by a meridional wavy pattern extending over eastern Siberia, the vicinity of Japan and
the subtropical western Pacific. The principal component (PC) time series of the leading mode is represented well by a high-resolution
version of the AGCM with horizontal resolution T106 and with 56 vertical levels (T106L56), while with a lower resolution version,
T42 and 20 vertical levels, the reproducibility is considerably degraded. The reproducibility by the AGCM suggests the importance
of SST as a boundary condition. However, the simulated interannual variations show the alternating appearance of two distinct
circulation regimes, a cold summer regime and a hot summer regime, exhibiting interesting bimodality in probability density distribution in PC phase space. This implies that the system’s
response to the continuously varying boundary condition includes nonlinearity. The nature of this nonlinearity is suggested
to be wave breaking in the westerly region of the high latitudes that requires high resolution for the reproduction. Using
the T106L56 model, another ensemble experiment was carried out with doubled CO2. The climate change appears as an increase in residence frequency of the cold summer regime of the principal patterns of the present-day climate.
This paper is a contribution to the AMIP-CMIP Diagnostic Sub-project on General Circulation Model Simulation of the East Asian
Climate, coordinated by W.-C. Wang. 相似文献
72.
We present a Monte Carlo (MC) model of [OI] 6300 Å and [SII] 6716 Å emission from Io entering eclipse. The simulation accounts for the 3-D distribution of SO2, O, SO, S, and O2 in Io’s atmosphere, several volcanic plumes, and the magnetic field around Io. Thermal electrons from the jovian plasma torus are input along the simulation domain boundaries and move along the magnetic field lines distorted by Io, occasionally participating in collisions with neutrals. We find that the atmospheric asymmetry resulting from varying degrees of atmospheric collapse across Io (due to eclipse ingress) and the presence of volcanoes contributes significantly to the unique morphology of the [OI] 6300 Å emission. The [OI] radiation lifetime of ∼134 s limits the emission to regions that have a sufficiently low neutral density so that intermolecular collisions are rare. We find that at low altitudes (typically <40 km) and in volcanic plumes (Pele, Prometheus, etc.) the number density is large enough (>4 × 109 cm−3) to collisionally quench nearly all (>95%) of the excited oxygen for reasonable quenching efficiencies. Upstream (relative to the plasma flow), Io’s perturbation of the jovian magnetic field mirrors electrons with high pitch angles, while downstream collisions can trap the electrons. This magnetic field perturbation is one of the main physical mechanisms that results in the upstream/downstream brightness asymmetry in [OI] emission seen in the observation by Trauger et al. (Trauger, J.T., Stapelfeldt, K.R., Ballester, G.E., Clarke, J.I., 1997. HST observations of [OI] emissions from Io in eclipse. AAS-DPS Abstract (1997DPS29.1802T)). There are two other main causes for the observed brightness asymmetry. First, the observation’s viewing geometry of the wake spot crosses the dayside atmosphere and therefore the wake’s observational field of view includes higher oxygen column density than the upstream side. Second, the phased entry into eclipse results in less atmospheric collapse and thus higher collisional quenching on the upstream side relative to the wake. We compute a location (both in altitude and latitude) for the intense wake emission feature that agrees reasonably well with this observation. Furthermore, the peak intensity of the simulated wake feature is less than that observed by a factor of ∼3, most likely because our model does not include direct dissociation-excitation of SO2 and SO. We find that the latitudinal location of the emission feature depends not so much on the tilt of the magnetic field as on the relative north/south flux tube depletion that occurs due to Io’s changing magnetic latitude in the plasma torus. From 1-D simulations, we also find that the intensity of [SII] 6716 and 6731 Å emission is much weaker than that of [OI] even if the [SII] excitation cross section is 103 times larger than excitation to [OI]. This is because the density of S+ is much less than that of O and because the Einstein-A coefficient of the [SII] emission is a factor of ∼10 smaller than that of [OI]. 相似文献
73.
Silicate regeneration was determined in a shallow-water coastal ecosystem (Shido Bay, the Seto Inland Sea, Japan) during 1999-2000. The present study was carried out directly by core incubation and by determining gradients of dissolved silicate (DSi) in the pore water. Incubated fluxes ranged from 25.5 to 132.6 mgSim(-2)d(-1), and were 1.6-21.6 times greater than diffusive fluxes (5.4-43.3 mgSim(-2)d(-1)). The disparity between fluxes measured by core incubation and modeling pore water indicated that other physical, chemical or biological processes, in addition to diffusion of DSi from below, contribute to DSi fluxes measured during the incubation of undisturbed cores. A regression analysis revealed that water temperature and salinity explained 24% and 23%, respectively, of season to season variability in incubated fluxes. Microphytobenthos was responsible for 37% of the variability in measured rate of DSi fluxes, with greatly reducing DSi release rates due to their own DSi demand. Moreover, the inverse relationship between the DSi fluxes and biogenic silica (Bio-Si) concentrations in the surface sediment, suggested that about 41% of the variability in the DSi fluxes were explained by Bio-Si concentrations in the surface sediment. As a result, Shido Bay showed silicate regeneration of incubated cores to be a consequence of Bio-Si dissolution depending on microphytobenthos, temperature and salinity, while diffusive fluxes appeared to be limited by DSi in the pore water. An annual average of DSi flux (68.7+/-32.9 mgSim(-2)d(-1)) from the sediments to the water column corresponds to 38% of DSi, required for primary production by phytoplankton in Shido Bay. 相似文献
74.
Noboru IMAI Hiroshi SAKURAMACHI Shigeru TERASHIMA Shiro ITOH Atsushi ANDO 《Geostandards and Geoanalytical Research》1996,20(2):161-164
A database on thirty-one Geological Survey of Japan (GSJ) geochemical reference samples has been set up on Internet which allows the retrieval of recommended or preferable values, compiled data, location, sample preparation and other relevant information. The URL location on WWW server is: http://www.aist.go.jp./RIODB/geostand/welcome.html 相似文献
75.
Shigeru Terashima 《Geostandards and Geoanalytical Research》2001,25(1):127-132
The indium (In) and tellurium (Te) contents of fifty nine geological reference materials, issued by several reference material producers (USGS, CRPG, ANRT, GIT-IWG and GSJ) have been determined by graphite furnace atomic absorption spectrometry, after aqua regia and HF digestion, and extraction of iodide complexes with trioctylmethylammonium (TOMA) - metyl isobutyl ketone (MIBK). Although the interferences from most elements can be minimised by the addition of palladium solution as the matrix modifier, large concentrations of Bi, Cu, Pb or Sn suppress the absorbance of In and/or Te. Samples for analysis were therefore restricted to those in which the concentrations of these interfering elements did not cause a significant interference. The limit of detection was 0.2 ng g−1 In and Te for 1 g test portions. The agreement between the reported results and published data is satisfactory. 相似文献
76.
Gold has been determined in 26 geochemical reference samples with graphite furnace AAS after digesting the samples with aqua regia and hydrofluoric acid and extracting gold by methyl isobutyl ketone (MIBK). This method yields clearly higher values than those by the partial attack using aqua regia digestion. 相似文献
77.
Fluorite Deposits at Voznesenka in the Khanka Massif, Russia: Geology and Age of Mineralization 总被引:1,自引:0,他引:1
Kohei Sato Kazuhiro Suzuki Munetomo Nedachi Shigeru Terashima Margarita D. Ryazantseva Anatoly A. Vrublevsky + Alexander I. Khanchuk ++ 《Resource Geology》2003,53(3):193-211
Abstract. A huge fluorite deposit at Voznesenka in the Khanka massif, Far East Russia is concluded to have formed at ca. 450 Ma in Late Ordovician time based on the K‐Ar ages for Li‐micas in the fluorite ore and greisenized leucogranite within the deposit. This conclusion is inconsistent with the current view of Devonian mineralization that stemmed from widely scattered whole‐rock Rb‐Sr isotope data for the heterogeneous leucogranite stocks influenced by strong alteration. The Voznesenka and neighboring fluorite deposits may have formed in Cambrian limestone in relation to the intrusion of the Li‐F‐rich felsic magma which has a similar chemistry to representative Li‐F‐rich felsic rocks including topaz granite and ongonite or topaz rhyolite; these rocks may be classified as a specific group of highly fractionated felsic magmas. Biotite granite plutons exposed in the Voznesenka district are divided in age into two groups based on the CHIME age data for zircon, monazite and xenotime: Ordovician and Permian. The Ordovician plutons seem to be coeval to the fluorite deposits and are characterized by F‐rich chemistry, reduced nature and association of tin mineralization with the deposition of fluorite and tourmaline. The biotite granite magmas of initially enhanced F contents could have been highly fractionated to form Li‐F‐rich leucogranite cupolas that provided fluorite deposits within the host limestone. Future prospecting for similar fluorite deposits is to be focused on areas of intersection between Ordovician Li‐F‐rich granite and Cambrian carbonate sequences. The Permian granite of southeastern margin of the Grodekovo batholith is characterized by lesser F content, oxidized nature and the lack of tin and fluorite mineralization in contrast to the Ordovician granite. The result of Permian age does not support the current view of Silurian age for the batholith and requires overall chronological reinvestigation in connection with the tectonic history of the Khanka massif because the Grodekovo is a representative of Paleozoic batholiths in Primorie. 相似文献
78.
79.
Tomoaki Morishita Yoshito Ishida Shoji Arai Miki Shirasaka 《Geostandards and Geoanalytical Research》2005,29(1):107-122
To understand and/or avoid small-scale chemical heterogeneities within geological materials prepared as normal thin sections, in situ multiple trace element determination coupled with the simultaneous microscopic observation of the sample during analysis is preferable. We have examined fifty trace elements in thin (< 30 μm) layers of the NIST SRM 614 and 616 glass reference materials by LA-ICP-MS using different pit diameters and internal standard elements (Ca and Si). Compositional heterogeneities of Tl, Bi, As and Cd were found in NIST SRM 614 and 616 at the spatial resolution of ca. 10 0 μm. Except for these elements, the RSDs of six determinations for most elements were better than 10% in NIST SRM 614 when ablation diameters were < 50 μm. The measured concentrations for most elements in NIST SRM 614 and 616 agree with previous values in the literature at the 95% confidence level with the exception of W and Bi. New LA-ICP-MS data for K, As and Cd are also reported. The results support the view that the latest LA-ICP-MS is a powerful and flexible analytical technique for the determination of multiple ultra-trace element compositions in geological materials prepared as normal thin sections of the type that has been used for polarising optical microscopic observations since the end of the 19th century. 相似文献
80.
Shigeru Terashima 《Geostandards and Geoanalytical Research》1997,21(1):93-96
The molybdenum (Mo) contents of fifty three geochemical reference materials issued by ANRT, GIT-IWG, NIST and GSJ, have been determined by atomic absorption spectrometry, using a graphite furnace atomiser, after extraction of Mo dithiol with isoamyl acetate. Detection limits for this method (0.01 μg g−1 ) are ten times smaller than for most classical methods. The agreement between the present results and published data is satisfactory. 相似文献