High temperature X-ray study of single crystal stishovite synthesized with Li2WO4 as flux     

S. Endo  T. Akai  Y. Akahama  M. Wakatsuki  T. Nakamura  Y. Tomii  K. Koto  Y. Ito  M. Tokonami 《Physics and Chemistry of Minerals》1986,13(3):146-151

Single crystal stishovite with a square prismatic habit and maximum length 0.8 mm was grown from α-quartz at 120 kbar and ～1,300° C. Li₂WO₄, chosen as a result of a previous experiment in growing coesite, was also successful as flux for stishovite. Single crystal X-ray structure analysis of the crystals thus obtained has been carried out at high temperatures under ambient pressure. Lattice constant measurements give a larger thermal expansion coefficient along the a-axis than along the c-axis. The bond distances and bond angles show a decreasing distortion of the SiO₆ octahedron with increasing temperature. The increasing amplitude of thermal vibrations of oxygen atoms with increasing temperature results in increasing O-O repulsion in the basal plane, which explains the observed crystallographic changes.  相似文献   

Spatio-temporal stress states estimated from seismicity rate changes in the Tokai region, central Japan     

Shinji Toda  Shozo Matsumura   《Tectonophysics》2006,417(1-2):53

Since unprecedented large-scale silent slip was detected by GPS in 2001 in the Tokai region, evaluating whether such movement is uniquely connected to the expected Tokai earthquake or repeatedly occurs in this area becomes vitally important. Because of short history of GPS observations and the limited areal coverage surrounding the Suruga trough, we take advantage of continuously recorded seismicity that is presumed to be sensitive to the deformation at seismogenic depth. Together with the well-maintained NIED earthquake data, we employ the seismicity-to-stress inversion approach of rate/state friction to infer the spatio-temporal stress changes in and around the presumed hypocentral zone of the future Tokai earthquake. Mapping stress changes inverted from microseismicity year by year, we find that the stress under Lake Hamana, the western expected future Tokai source, has been decreasing since 1999, during which the GPS data showed a normal trend of plate coupling. In contrast, stresses in the surrounding regions are calculated to have increased by transfer from Lake Hamana region. We interpret that this continuous process is associated with the 2000–2004 Tokai slow slip event. The characteristic patterns related to aseismic stress-release are also identified in the early 1980s and during 1987–1989, when slow events are inferred to have occurred on the basis of conventional geodetic measurements. Revisiting the seismotectonics and taking into account the mechanical implications of the inversion results, we argue that the transition zone situated between a deep stable creeping zone and a locked zone undergoes episodic creep and plays an important role in the transfer of stress to the locked zone. Consequently, even though we speculate that the current (2000 to present-day) silent slip event might be one of the repeating events, the inferred enlargement of the stress releasing area is significant and possibly raises the likelihood of the next Tokai earthquake.  相似文献   

Progressive metamorphism of the Taitao ophiolite; evidence for axial and off-axis hydrothermal alterations     

Takazo Shibuya  Tsuyoshi Komiya  Ryo Anma  Tsutomu Ota  Soichi Omori  Yoshiaki Kon  Shinji Yamamoto  Shigenori Maruyama 《Lithos》2007,98(1-4):233-260

We estimated metamorphic conditions for the  6 Ma Taitao ophiolite, associated with the Chile triple junction. The metamorphic grade of the ophiolite, estimated from secondary matrix minerals, changes stratigraphically downwards from the zeolite facies, through the prehnite–actinolite facies, greenschist facies and the greenschist–amphibolite transition, to the amphibolite facies. The metamorphic facies series corresponds to the low-pressure type. The metamorphic zone boundaries are subparallel to the internal lithological boundaries of the ophiolite, indicating that the metamorphism was due to axial hydrothermal alteration at a mid-ocean ridge.

Mineral assemblages and the compositions of veins systematically change from quartz-dominated, through epidote-dominated, to prehnite-dominated with increasing depth. Temperatures estimated from the vein assemblages range from  230 °C in the volcanic unit to  380 °C at the bottom of the gabbro unit, systematically  200 °C lower than estimates from the adjoining matrix minerals. The late development of veins and the systematically lower temperatures suggest that the vein-forming alteration was due to off-axis hydrothermal alteration.

Comparison between the Taitao ophiolite with its mid-ocean ridge (MOR) affinity, and other ophiolites and MOR crusts, suggests that the Taitao ophiolite has many hydrothermal alteration features similar to those of MOR crusts. This is consistent with the tectonic history that the Taitao ophiolite was formed at the South Chile ridge system near the South American continent (Anma, R., Armstrong, R., Danhara, T., Orihashi, Y. and Iwano, H., 2006. Zircon sensitive high mass-resolution ion microprobe U–Pb and fission-track ages for gabbros and sheeted dykes of the Taitao ophiolite, Southern Chile, and their tectonic implications. The Island Arc, 15(1): 130–142).  相似文献   

Suction dynamics-induced bubbly sand under groundwater table fluctuations     

Shinji Sassa  Soonbo Yang 《Sedimentology》2023,70(1):280-288

Bubbly sand is found in intertidal zones and has been considered to be closely related to swash and tides. Unlike bubble structures that arise from in situ methane gas production and bubble growth in river and marine sediments due to organic matter decomposition, the formation mechanism and conditions of bubbly sand remain unresolved. The present study aims to resolve them on the basis of a conceptual model and controlled laboratory experiments. The study demonstrates that bubbly sand is a consequence of the cyclic expansion of sand under groundwater table fluctuations. The varying intensity of dynamics of suction, which is sand moisture tension defined by negative pore water pressure relative to atmospheric pressure, controls the manifestation of a full spectrum of sand behaviour relevant to the formation of bubbly sand. Namely, with increasing intensity of suction dynamics under larger groundwater table fluctuations, the sand behaviour varies from enhanced cyclic contraction, to weak contraction, loosening and expansion resulting in bubbly sand. The suction dynamics-induced cyclic expansion of sand occurs under conditions where the maximum suction developed exceeds the air-entry suction of sand such that the degree of saturation becomes lower than 60%, while the groundwater tables cyclically rise to and fall from the sediment surface. Accordingly, the sand porosity changes remarkably from dense to super-loose states of bubbly sand. These findings account for previously unanswered questions with respect to bubbly sand, both qualitatively and quantitatively, and will lead to a renewed understanding of the geological record and morphological features at waterfronts that are subject to groundwater table fluctuations.  相似文献   

Effects of raised CO2 concentration on the egg production rate and early development of two marine copepods (Acartia steueri and Acartia erythraea)     

Kurihara H  Shimode S  Shirayama Y 《Marine pollution bulletin》2004,49(9-10):721-727

Direct injection of CO(2) into the deep ocean is receiving increasing attention as a way to mitigate increasing atmospheric CO(2) concentration. To assess the potential impact of the environmental change associated with CO(2) sequestration in the ocean, we studied the lethal and sub-lethal effects of raised CO(2) concentration in seawater on adult and early stage embryos of marine planktonic copepods. We found that the reproduction rate and larval development of copepods are very sensitive to increased CO(2) concentration. The hatching rate tended to decrease, and nauplius mortality rate to increase, with increased CO(2) concentration. These results suggest that the marine copepod community will be negatively affected by the disposal of CO(2). This could decrease on the carbon export flux to the deep ocean and change the biological pump. Clearly, further studies are needed to determine whether ocean CO(2) injection is an acceptable strategy to reduce anthropogenic CO(2).  相似文献   

Ecological aspects of hydrothermal vent animals in captivity at atmospheric pressure     

Hiroshi Miyake  Mitsugu Kitada  Shinji Tsuchida  Yoko Okuyama  & Ko-ichi Nakamura 《Marine Ecology》2007,28(1):86-92

Hydrothermal vent animals were kept and displayed at atmospheric pressure with an artificial hydrothermal vent system in Enoshima Aquarium, Fujisawa, Kanagawa, Japan. The artificial hydrothermal vent system was composed of a main rearing tank, a heating tank, a hot water outlet with added Na₂S as the source of H₂S, and added CO₂ for chemosynthetic bacteria and pH regulation. When the need arises, a dissolved oxygen control unit and submersible heaters can be attached. We are now rearing hydrothermal vent crabs (Austinograea yunohana), hydrothermal vent galatheid crabs (Shinkaia crosnieri), vestimentiferan tubeworms (Lamellibrachia satsuma), hydrothermal vent shrimp (Opaepele spp.), hydrothermal vent barnacles (Ashinkailepas seepiophilia and Neoverruca sp.), and tonguefish (Symphurus sp.). In the artificial hydrothermal vent tank, shrimp and crabs have been observed to cluster close to the artificial hydrothermal vent. In particular, large (adult) crabs needed a heat source to live in the aquarium over a long term. Additionally, some species (A. yunohana, S. crosnieri, Opaepele sp. and Symphurus sp.) have spawned and hatched in captivity. It is likely higher water temperatures are needed for egg and larval development compared with temperatures for adult requirements.  相似文献   

Sub-Lethal Effects of Elevated Concentration of CO<Subscript>2</Subscript> on Planktonic Copepods and Sea Urchins   总被引：2，自引：0，他引：2  

Haruko Kurihara  Shinji Shimode  Yoshihisa Shirayama 《Journal of Oceanography》2004,60(4):743-750

Data concerning the effects of high CO₂ concentrations on marine organisms are essential for both predicting future impacts of the increasing atmospheric CO₂ concentration and assessing the effects of deep-sea CO₂sequestration. Here we review our recent studies evaluating the effects of elevated CO₂ concentrations in seawater on the mortality and egg production of the marine planktonic copepod, Acartia steueri, and on the fertilization rate and larval morphology of sea urchin embryos, Hemicentrotus pulcherrimus and Echinometra mathaei. Under conditions of +10,000 ppm CO₂ in seawater (pH 6.8), the egg production rates of copepods decreased significantly. The survival rates of adult copepods were not affected when reared under increased CO₂ for 8 days, however longer exposure times could have revealed toxic effects of elevated CO₂ concentrations. The fertilization rate of sea urchin eggs of both species decreased with increasing CO₂ concentration. Furthermore, the size of pluteus larvae decreased with increasing CO₂ concentration and malformed skeletogenesis was observed in both larvae. This suggests that calcification is affected by elevated CO₂ in the seawater. From these results, we conclude that increased CO₂ concentration in seawater will chronically affect several marine organisms and we discuss the effects of increased CO₂ on the marine carbon cycle and marine ecosystem. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Geographical Variations in Prosome Length and Body Weight of Neocalanus Copepods in the North Pacific     

Toru Kobari  Kazuaki Tadokoro  Akihiro Shiomoto  Shinji Hashimoto 《Journal of Oceanography》2003,59(1):3-10

Geographical variations in prosome length and body weight of Neocalanus copepods (N. cristatus, N. plumchrus and N. flemingeri) were investigated on samples from North-South and East-West transects in the North Pacific during spring to early summer in 1998 and 1999. Southward and eastward increasing patterns were pronounced for water temperature, although no significant pattern was observed for chlorophyll a concentrations. All Neocalanus species showed large geographical variations in prosome length and body weight, being smaller in the southern and eastern waters. Comparing the relationship between prosome length and body weight, large deviations (lower body weight at a given prosome length) were evident for the eastern specimens of N. cristatus and N. plumchrus. In stepwise regression analysis, the geographical variations of prosome length and body weight revealed a significantly negative correlation with temperature variations. These results suggest that temperature is a more important environmental factor than chlorophyll a concentration in its effect on geographical variations in prosome length and body weight of Neocalanus copepods in the North Pacific. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Evolution of the composition of seawater through geologic time, and its influence on the evolution of life   总被引：2，自引：2，他引：0  

Tsuyoshi Komiya  Takafumi Hirata  Kouki Kitajima  Shinji Yamamoto  Takazo Shibuya  Yusuke Sawaki  Tomoko Ishikawa  Degan Shu  Yong Li  Jian Han 《Gondwana Research》2008,14(1-2):159

The redox state of the surface environment of the early Earth is still controversial, and a detailed and quantitative estimate is still lacking. We carried out in-situ analyses of major, trace, and rare-earth elements of carbonate minerals in rocks with primary sedimentary structures in shallow and deep sea-deposits, in order to eliminate secondary carbonate and contamination of detrital materials, and to estimate the redox condition of seawater through time. Based on the Ce content and anomalies of the carbonate minerals at given parameters of atmospheric CO₂ content (pCO₂) and Ca content of seawater, we calculated the oxygen contents of shallow and deep seawater, respectively. The results show that the oxygen content of the deep sea was low and constant until at least 1.9 Ga. The oxygen content of shallow seawater increased after 2.7 Ga, but fluctuated. It became quite high at 2.5 and 2.3 Ga, but eventually increased after the Phanerozoic. In addition, the calculation of a high pCO₂ condition shows that seawater was more oxic even in the Archean than at present, suggesting a relatively low pCO₂ through geologic time.Our detailed calculations from compositions of carbonate minerals in Three Gorge area, south China show a low oxygen content of seawater after the Snowball Earth until the late Ediacaran, an increase in the late Ediacaran, and a significant decrease around the Precambrian–Cambrian and Nemakit/Daldynian–Tommotian boundaries. These variations were possibly caused by global regression and dissolution of methane hydrates.  相似文献   

Classification of magnetic reconnection during two current-loop coalescence     

Jun-ichi Sakai  Shinji Koide 《Solar physics》1992,142(2):399-402

We present a classification of magnetic reconnection during two current loop coalescence, which may be quite important for the physical process of both solar flares and coronal loop heating in the solar active region. It is suggested that different kinds of the current loop coalescence processes could be identified from the soft X-ray telescope(SXT) of the Yohkoh satellite and the magnetic field data in the active region.  相似文献