Study on the fate of petroleum-derived polycyclic aromatic hydrocarbons (PAHs) and the effect of chemical dispersant using an enclosed ecosystem,mesocosm     

Yamada M  Takada H  Toyoda K  Yoshida A  Shibata A  Nomura H  Wada M  Nishimura M  Okamoto K  Ohwada K 《Marine pollution bulletin》2003,47(1-6):105-113

Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant.  相似文献   

Systematic errors in future weak-lensing surveys: requirements and prospects for self-calibration     

Dragan Huterer  Masahiro Takada  Gary Bernstein  Bhuvnesh Jain 《Monthly notices of the Royal Astronomical Society》2006,366(1):101-114

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Peroxy Radical Concentrations Measured at a Forest Canopy in Nikko,Japan, in Summer 2002     

Bin?Qi  Akinori?Takami  Shiro?HatakeyamaEmail author 《Journal of Atmospheric Chemistry》2005,52(1):63-79

Concentrations of peroxy radicals were measured by a chemical amplification technique at a remote forested site as part of the Program for Research on Oxidants in a Forested Region in Nikko (PROFRN). During the measurement period of 22–27 July 2002, the mixing ratios of peroxy radicals averaged for 3 min at midday ranged from 109 to 134 pptv at a height approximately 5 m above the forest canopy. Significant diurnal variation in concentrations of peroxy radicals was observed, with the maximum usually occurring around noon. Most of the variation was driven by changes in the intensity of solar radiation. However, it was found that the peroxy radical concentration reached its peak about 3-h later than that of solar radiation on 24 and 26 July. The origins of this delay are discussed based on an analysis of the total radical budget in that period. A transport of polluted air masses to the site was one of possible causes for the inconsistency. In addition, the measured peroxy radical concentrations were compared with those derived from the deviations of NO-NO₂-O₃ photo-stationary state (PSSD) for clear days. The estimated half-hour-average concentrations of peroxy radical were in agreement with the PERCA measured in the morning and late afternoon. However the two techniques differed by as much as a factor of two during the time of near midday.  相似文献   

The effect of the stellar wind velocity on the eccentric-orbit binary model     

Toru Okuda  Shiro Sakashita 《Astrophysics and Space Science》1982,83(1-2):441-444

The previous eccentric-orbit binary model for the recurrent X-ray sources is modified by taking account of the velocity field of the stellar wind. The resultant formula of the light curves for the X-ray sources may have an useful application to the observed X-ray sources.  相似文献   

Polycyclic aromatic hydrocarbon (PAHs) and hopanes in stranded tar-balls on the coasts of Peninsular Malaysia: applications of biomarkers for identifying sources of oil pollution   总被引：1，自引：0，他引：1  

Zakaria MP  Okuda T  Takada H 《Marine pollution bulletin》2001,42(12):1357-1366

Malaysian coasts are subjected to various threats of petroleum pollution including routine and accidental oil spill from tankers, spillage of crude oils from inland and offshore oil fields, and run-off from land-based human activities. Due to its strategic location, the Straits of Malacca serves as a major shipping lane. This paper expands the utility of biomarker compounds, hopanes, in identifying the source of tar-balls stranded on Malaysian coasts. 20 tar-ball samples collected from the east and west coast were analyzed for hopanes and polycyclic aromatic hydrocarbons (PAHs). Four of the 13 tar-ball samples collected from the west coast of Peninsular Malaysia were identified as the Middle East crude oil (MECO) based on their biomarker signatures, suggesting tanker-derived sources significantly contributing the petroleum pollution in the Straits of Malacca. The tar-balls found on the east coast seem to originate from the offshore oil platforms in the South China Sea. The presence of South East Asian crude oil (SEACO) tar-balls on the west coast carry several plausible explanations. Some of the tar-balls could have been transported via sea currents from the east coast. The tankers carrying SEACO to other countries could have accidentally spilt the oil as well. Furthermore, discharge of tank washings and ballast water from the tankers were suggested based on the abundance in higher molecular weight n-alkanes and the absence of unresolved complex mixture (UCM) in the tar-ball samples. The other possibilities are that the tar-balls may have been originated from the Sumatran oil fields and spillage of domestic oil from oil refineries in Port Dickson and Malacca. The results of PAHs analysis suggest that all the tar-ball samples have undergone various extent of weathering through evaporation, dissolution and photo-oxidation.  相似文献   

1998 Compilation of Analytical Data for Five GSJ Geochemical Reference Samples: The "Instrumental Analysis Series"   总被引：1，自引：0，他引：1  

Noboru Imai  Shigeru Terashima  Shiro Itoh  Atsushi Ando 《Geostandards and Geoanalytical Research》1999,23(2):223-250

Analytical data for five GSJ (Geological Survey of Japan) reference samples, the "Instrumental analysis series" received by October 1998, are compiled. The data reported in publications and personal communications were evaluated statistically, taking into account the analytical method and sample preparation. Based on the selected available data, recommended and preferred values for fourteen major and fifty one minor and trace elements are proposed.  相似文献   

The optical/near-infrared broad-line emission and hard X-ray continuum of active galactic nuclei and ultraluminous infrared galaxies     

Masatoshi Imanishi †  Shiro Ueno 《Monthly notices of the Royal Astronomical Society》1999,305(4):829-833

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Comparison of Kuroshio surface velocities derived from satellite altimeter and drifting buoy data   总被引：2，自引：0，他引：2  

Hiroshi Uchida  Shiro Imawaki  Jian-Hwa Hu 《Journal of Oceanography》1998,54(1):115-122

Sea-surface geostrophic velocities for the Kuroshio region calculated from TOPEX/POSEIDON altimetry data together within situ oceanographic data are compared with surface velocities derived from drifting buoy trajectories. The geostrophic velocities agree well with the observed velocities, suggesting that the Kuroshio surface layer is essentially in geostrophic balance, within measurement error. The comparison is improved a little when the centrifugal acceleration is taken into account. The observed velocities are divided into the temporal mean and fluctuation components, and the partitioning of velocities between these two components is examined. For the Kuroshio region, most of the fluctuation components of the velocities derived from drifting buoys are found to be positive. This result suggests that Eulerian mean velocities for the Kuroshio region estimated from drifting buoy data tend to be larger than actual means, due to the buoy’s tendency to sample preferentially in the high-velocity Kuroshio.  相似文献