XANES and Mg isotopic analyses of spinels in Ca‐Al‐rich inclusions: Evidence for formation under oxidizing conditions     

J. M. Paque  S. R. Sutton  S. B. Simon  J. R. Beckett  D. S. Burnett  L. Grossman  H. Yurimoto  S. Itoh  H. C. Connolly Jr. 《Meteoritics & planetary science》2013,48(10):2015-2043

Ti valence measurements in MgAl₂O₄ spinel from calcium‐aluminum‐rich inclusions (CAIs) by X‐ray absorption near‐edge structure (XANES) spectroscopy show that many spinels have predominantly tetravalent Ti, regardless of host phases. The average spinel in Allende type B1 inclusion TS34 has 87% Ti⁺⁴. Most spinels in fluffy type A (FTA) inclusions also have high Ti valence. In contrast, the rims of some spinels in TS34 and spinel grain cores in two Vigarano type B inclusions have larger amounts of trivalent titanium. Spinels from TS34 have approximately equal amounts of divalent and trivalent vanadium. Based on experiments conducted on CAI‐like compositions over a range of redox conditions, both clinopyroxene and spinel should be Ti⁺³‐rich if they equilibrated with CAI liquids under near‐solar oxygen fugacities. In igneous inclusions, the seeming paradox of high‐valence spinels coexisting with low‐valence clinopyroxene can be explained either by transient oxidizing conditions accompanying low‐pressure evaporation or by equilibration of spinel with relict Ti⁺⁴‐rich phases (e.g., perovskite) prior to or during melting. Ion probe analyses of large spinel grains in TS34 show that they are enriched in heavy Mg, with an average Δ²⁵Mg of 4.25 ± 0.028‰, consistent with formation of the spinel from an evaporating liquid. Δ²⁵Mg shows small, but significant, variation, both within individual spinels and between spinel and adjacent melilite hosts. The Δ²⁵Mg data are most simply explained by the low‐pressure evaporation model, but this model has difficulty explaining the high Ti⁺⁴ concentrations in spinel.  相似文献   

Partitioning and lateral transport of iron to the Canada Basin     

Ana M. Aguilar-Islas  Robert Rember  Shigeto Nishino  Takashi Kikuchi  Motoyo Itoh 《Polar Science》2013,7(2):82-99

The concentration of dissolved iron (DFe) and suspended leachable particulate iron (LPFe) in the water column of the western Beaufort Sea were investigated during the late summer of 2010. Elevated concentrations of surface DFe (0.49–1.42 nM) were similar to those reported in resent studies, likely reflecting input from melting sea ice and river discharge. The rapid decrease in DFe (5.20–0.48 nM) and LPFe (88.2–1.83 nM) values observed from inshore to offshore in Pacific influenced waters, suggest scavenging processes limit the input of DFe from the shelf to the deep basin. However, frequent eddies found in this region are likely important in promoting lateral advection, as suggested by higher surface DFe concentrations at an offshore station in the vicinity of a warm-core eddy. Within the Atlantic layer, relatively homogeneous DFe (0.69–0.80 nM) and LPFe (1.18–2.13 nM) concentrations were observed at all the stations, reflecting a balance in the interplay between input and removal processes within this watermass. An input of DFe east of the Lomonosov Ridge was inferred by comparing DFe values within the core of Atlantic water between the Eastern and Western Arctic.  相似文献   

Experimental studies on debris flow with logs focusing on specific weight difference of log species     

Haruki WATABE  Takahiro ITOH  Kazuhiko KAITSUKA  Shigeki NISHIMURA 《山地科学学报》2013,10(2):315-325

There are many experimental approaches,field investigations and numerical calculations for movements of woods in a clear water and debris flow.However,kinematic conditions for accumulated logs and the interactions between a main flow and logs have not been fully evaluated.Mitigations for woods need taking into account the characteristics of tree species such as conifer and broad-leaf trees and of shapes such as root swells and crown.In the present study,we focus on the differences in specific weight of conifer and broad-leaf trees with some moisture in a sediment-water mixture flow with narrow flow width,and consider that conifer and broad-leaf tree are floating and submerged solid phase,respectively.Flume tests are conducted in steady flow of clear and debris flow over a rigid bed in order to evaluate conifer and broad-leaf tree movement in clear water and debris flow.Experimental data indicates that dimensionless transverse diffusion coefficient can be 0.1 to 0.4 and 0.3 to 0.9 in flow direction.Those diffusive characteristics seem to be independent of Reynolds number and Froude number,but dependent of bed slope,i.e.,gravity,though detailed considerations are needed to discuss about flow characteristics such as spatial eddy structures,momentum transfer induced by interactions of logs and so on.  相似文献   

Pin‐supported walls for enhancing the seismic performance of building structures     

Zhe Qu  Akira Wada  Shojiro Motoyui  Hiroyasu Sakata  Shoichi Kishiki 《地震工程与结构动力学》2012,41(14):2075-2091

An application of a pin‐supported wall‐frame system in retrofitting an eleven‐story steel reinforced concrete frame is introduced. The retrofit aims at enhancing integrity and avoiding weak story failure in an existing moment‐resisting frame. Seismic performance of the building before and after the retrofit is assessed through nonlinear dynamic analysis. The results show that the pin‐supported walls are effective in controlling the deformation pattern of the ductile frame and hence in avoiding weak story failure. With the well‐controlled deformation pattern, carefully arranged energy dissipating devices are able to concentrate energy dissipations so that damage to the rest of the structure can be significantly reduced. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Influence of the Oyashio Current and Tsugaru Warm Current on the circulation and water properties of Otsuchi Bay,Japan     

Miho Ishizu  Sachihiko Itoh  Kiyoshi Tanaka  Kosei Komatsu 《Journal of Oceanography》2017,73(1):115-131

Mooring and hydrographic observations were conducted from September 2012 to May 2014 at the mouth of Otsuchi Bay, a ria along the Pacific coast of Japan. Our observations quantitatively demonstrated that the circulation and the water properties of Otsuchi Bay are strongly influenced by the Tsugaru Warm Current (TWC) and Oyashio Current (OY) at seasonal and subseasonal time scales. Two bottom-mounted velocity profilers and temperature and salinity measurements beneath the near-surface halocline showed a counterclockwise lateral circulation pattern related to the TWC, which was enhanced from summer to autumn. From winter to early spring, the lateral circulation patterns related to the TWC weakened and the influence of the OY occasionally increased. When the OY was weak, surface flows became an overturning structure, with outflows in the upper layer and inflows in the lower layer. When the OY was strong and passed close to the Sanriku coast, the circulation became highly variable and intermittent. Intrusions of the markedly low-salinity OY water were observed on two occasions and persisted for periods of several weeks to several months. Salinity was sometimes less than 33.7, the lower limit of the typical TWC from late summer to autumn even when the TWC dominates. We suggested that this is the seasonal fluctuations of the TWC itself, as the upstream current of the Tsushima Warm Current is freshened in summer as a result of the influence of the Changjiang River. The surface water was generally fresher in the south of the bay than in the north, suggesting the Coriolis deflection of the river plume.  相似文献   

Geochemical modeling of sedimentary rocks in the central Hokkaido,Japan: Episodic deformation and subsequent confined basin-formation along the eastern Eurasian margin since the Cretaceous     

Machiko Tamaki  Kunihiro Tsuchida  Yasuto Itoh 《Journal of Asian Earth Sciences》2009,34(2):198-208

Late Cretaceous to Paleogene tectonic episodes around the eastern Eurasian margin are described utilizing one-dimensional (1D) basin modeling technique on the basis of organic maturation; vitrinite reflectance and T_max parameter values of the Rock-Eval pyrolysis. Fine-grained marine sediment of the Yezo Supergroup in central Hokkaido is one of the most extensive Cretaceous constituents along the plate margin. To evaluate organic maturation within the Yezo Supergroup, a surface section (Hakkin-zawa) and a deep borehole (MITI Yubari) were selected, from which quite different maturation trends were obtained. Notably low and constant maturation was suggested throughout the thick Hakkin-zawa section, and it was confirmed on the basis of various biomarker analyses. It requires anomalously rapid burial, probably related to thrust-stacking or large-scale slumping, followed by prompt tilting/exhumation event. In sharp contrast, Late Cretaceous strata in the MITI Yubari do not indicate coeval tectonic disturbances in a short period. A wider view of the ancient convergent margin suggests that deformation of the forearc propagated westward during the Cretaceous. High maturation levels in the uppermost thrust sheet around the MITI Yubari are optimized in 1D geochemical modeling on the assumption that a thick missing Paleogene unit has been eroded out as a result of thrust-forming contraction scheme emerged during the Neogene. A similar Cenozoic burial pattern is adopted for the once tilted and exhumed Hakkin-zawa section in order to match the present maturation levels. Although such an active subsidence of a ‘forearc’ is generally interpreted as an effect of the subduction erosion, heavy mineral composition of the shallow marine to fluvial Paleogene implies uplift and exhumation of ultramafic rocks to the east (trench-side). Thus the confined basin-formation in central Hokkaido is to be understood in a different tectonic framework that may reflect transcurrent motions on the plate margin.  相似文献   

Probability Distribution of Surface Wave Slope Derived Using Sun Glitter Images from Geostationary Meteorological Satellite and Surface Vector Winds from Scatterometers     

Naoto Ebuchi  Shoichi Kizu 《Journal of Oceanography》2002,58(3):477-486

The probability distribution of the sea surface slope has been estimated using sun glitter images derived from the visible wavelength radiometer on the Geostationary Meteorological Satellite (GMS) and surface vector winds observed by spaceborne scatterometers. The brightness of the visible images is converted to the probability of wave surfaces which reflect the sunlight toward GMS in grids of 0.25° × 0.25° (latitude × longitude). The slope and azimuth angle required for the reflection of the sun's rays toward GMS are calculated for each grid from the geometry of GMS observation and location of the sun. The GMS images are then collocated with surface wind data observed by three scatterometers. Using the collocated data set of about 30 million points obtained in a period of 4 years from 1995 to 1999, the probability distribution function of the surface slope is estimated as a function of wind speed and azimuth angle relative to the wind direction. The results are compared with those of Cox and Munk (1954a). The surface slope estimated by the present method shows a narrower distribution and much less directivity relative to the wind direction than that reported by Cox and Munk. It is expected that their data were obtained under conditions of growing wind waves. In general, wind waves are not always developing, and the slope distribution might differ from the results of Cox and Munk. Most of our data are obtained in the subtropical seas under clear-sky conditions. This difference in the conditions may be the reason for the difference of slope distribution. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Behavior of Warm-Core Rings in a Double-Gyre Wind-Driven Ocean Circulation Model     

Sachihiko Itoh  Takashige Sugimoto 《Journal of Oceanography》2002,58(5):651-660

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Mesoscale eddy effects on temporal variability of surface chlorophyll a in the Kuroshio Extension     

Shinya Kouketsu  Hitoshi Kaneko  Takeshi Okunishi  Kosei Sasaoka  Sachihiko Itoh  Ryuichiro Inoue  Hiromichi Ueno 《Journal of Oceanography》2016,72(3):439-451

We investigated the relationship between chlorophyll a (Chl-a) concentrations estimated from satellite observations and the activity of eddies in the Kuroshio Extension region. High (low) area-averaged Chl-a concentrations were frequently observed in the core of cyclonic (anticyclonic) eddies. Such relationships between Chl-a concentrations and eddy cores were not frequently observed in the southern part of the recirculation gyre, and advection of background meridional gradient of Chl-a by eddy-edge currents accounted for Chl-a spatial variability. Decadal-scale changes of Chl-a concentrations around the Kuroshio Extension were strongly affected by eddy activity and transport but not by large-scale near-surface isopycnal heaving. We also found that decadal changes of nutrient concentrations near the main stream could affect Chl-a concentrations in the southern part of the recirculation gyre via southward transport of eddies and mean flow.  相似文献   

Fine-scale structure and mixing across the front between the Tsugaru Warm and Oyashio Currents in summer along the Sanriku Coast,east of Japan     

Sachihiko Itoh  Hitoshi Kaneko  Miho Ishizu  Daigo Yanagimoto  Takeshi Okunishi  Hajime Nishigaki  Kiyoshi Tanaka 《Journal of Oceanography》2016,72(1):23-37

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