Recent increase of DIC in the western North Pacific     

Tsuneo Ono  Yutaka W. Watanabe  Shuichi Watanabe   《Marine Chemistry》2000,72(2-4)

The temporal variation of the total dissolved inorganic carbon (DIC) content in the western North Pacific is investigated by comparing the DIC distribution obtained from the data sets of three different periods, the GEOSECS data observed in 1973, the CO₂ dynamics Cruise data observed in 1982, and recent Japanese data sets observed during the early 1990s. The overall feature of the signal of temporal DIC change during 1973 and early 1990s agreed with that of former studies, and did not significantly change with the calculation scheme (the grid-selection method vs. the multiple regression method). The observed increase in DIC among the different time scales showed a good inner consistency, which also indicates the stability of the method used in the DIC change calculation. The apparent rate of increase of the DIC inventory in the upper 1000 m water column, however, differed significantly by the data set used for the calculation: It was 5.6±2.4 g C/m²/year, based on the data comparison between 1982 and the early 1990s, while it became 7.6±2.4 g C/m²/year when based on the data between 1973 and the early 1990s. This result provides us an information about the data-dependency on the former estimation of temporal DIC change.  相似文献   

Age constraints on the Palaeoproterozoic Lomagundi–Jatuli Event in Zimbabwe: Zircon geochronology of the Magondi Supergroup     

Hikaru Sawada  Ernest Tafumanei Mugandani  Tomohiko Sato  Yusuke Sawaki  Shuhei Sakata  Yukio Isozaki  Shigenori Maruyama 《地学学报》2019,31(5):438-444

The ca. 2.2–2.1 Ga Magondi Supergroup on the Zimbabwe Craton in Southern Africa is mainly composed of sedimentary rocks deposited in a rift basin/passive continental margin, which record a unique episode in carbon isotope perturbation called the Lomagundi–Jatuli Event (LJE). This study reports new U–Pb ages of detrital zircons from the Deweras and Lomagundi groups of the Magondi Supergroup, and of igneous zircons from underlying granitoids, to constrain the timing of the LJE and to identify the provenance of the Magondi Supergroup. Most analysed detrital zircon grains range in ages between ca. 2.9 and 2.6 Ga. Three ca. 2.3–2.2 Ga detrital zircons from sandstone of the Deweras Group, with the youngest ²⁰⁷Pb‐²⁰⁶Pb age of 2,216 ± 22 Ma, indicate the onset of LJE in the Zimbabwe Craton was almost simultaneous to that in Fennoscandia and the Superior Craton, supporting the global synchronicity of the LJE.  相似文献   

Cross-Validation of Open-Path and Closed-Path Eddy-Covariance Techniques for Observing Methane Fluxes     

Hiroki Iwata  Yoshiko Kosugi  Keisuke Ono  Masayoshi Mano  Ayaka Sakabe  Akira Miyata  Kenshi Takahashi 《Boundary-Layer Meteorology》2014,151(1):95-118

Methane ( ${\mathrm {CH}}_{4}$ ) fluxes observed with the eddy-covariance technique using an open-path ${\mathrm {CH}}_{4}$ analyzer and a closed-path ${\mathrm {CH}}_{4}$ analyzer in a rice paddy field were evaluated with an emphasis on the flux correction methodology. A comparison of the fluxes obtained by the analyzers revealed that both the open-path and closed-path techniques were reliable, provided that appropriate corrections were applied. For the open-path approach, the influence of fluctuations in air density and the line shape variation in laser absorption spectroscopy (hereafter, spectroscopic effect) was significant, and the relative importance of these corrections would increase when observing small ${\mathrm {CH}}_{4}$ fluxes. A new procedure proposed by Li-Cor Inc. enabled us to accurately adjust for these effects. The high-frequency loss of the open-path ${\mathrm {CH}}_{4}$ analyzer was relatively large (11 % of the uncorrected covariance) at an observation height of 2.5 m above the canopy owing to its longer physical path length, and this correction should be carefully applied before correcting for the influence of fluctuations in air density and the spectroscopic effect. Uncorrected ${\mathrm {CH}}_{4}$ fluxes observed with the closed-path analyzer were substantially underestimated (37 %) due to high-frequency loss because an undersized pump was used in the observation. Both the bandpass and transfer function approaches successfully corrected this flux loss. Careful determination of the bandpass frequency range or the transfer function and the cospectral model is required for the accurate calculation of ${\mathrm {CH}}_{4}$ fluxes with the closed-path technique.  相似文献   

Flux of low salinity water from Aniva Bay (Sakhalin Island) to the southern Okhotsk Sea     

Sachiko Oguma  Tsuneo Ono  Yutaka W. Watanabe  Hiromi Kasai  Shuichi Watanabe  Daiki Nomura  Humio Mitsudera 《Estuarine, Coastal and Shelf Science》2011

In this study, we examined the relationship between the low salinity water in the shelf region of the southern Okhotsk Sea which was seasonally sampled (0–200 m), and fluxes of low salinity water from Aniva Bay. To express the source of freshwater mixing in the surface layer, we applied normalized total alkalinity (NTA) and stable isotopes of seawater as chemical tracers. NTA-S diagrams indicate that NTA of low salinity water in the upper 30 m layer just off the Soya Warm Current is clearly higher than in the far offshore region in summer and autumn. Using NTA-S regression lines, we could deduce that the low salinity and high NTA water in the upper layer originates from Aniva Bay. For convenience, we defined this water as the Aniva Surface Water (ASW) with values S < 32, NTA > 2450 μmol kg⁻¹. Formation and transport processes of ASW are discussed using historical data. The interaction between the maximum core of high NTA water on the bottom slope of eastern Aniva Bay and an anticyclonic eddy at the mouth of Aniva Bay are concluded to control ASW formation. Upwelling of the Cold Water Belt water at the tip of Cape Krillion is considered to cause ASW outflow from Aniva Bay.  相似文献   

New high-pressure phases in BaCO<Subscript>3</Subscript>     

Shigeaki Ono 《Physics and Chemistry of Minerals》2007,34(4):215-221

Barium carbonate (BaCO₃) was examined in a diamond anvil cell up to a pressure of 73 GPa using an in situ angle-dispersive X-ray diffraction technique. Three new phases of BaCO₃ were observed at pressures >10 GPa. From 10 to 24 GPa, BaCO₃-IV had a post-aragonite structure with space group Pmmn. There are two molecules in a single unit cell (Z = 2) of the orthorhombic phase, which is same as the high-pressure phases of CaCO₃ and SrCO₃. The isothermal bulk modulus of BaCO₃-IV is K ₀ = 84(4) GPa, with V ₀ = 129.0(7) Å³ when K ₀′ = 4. The c axis of the unit cell parameter is less compressible than the a and b axes. The relative change in volume that accompanies the transformation between BaCO₃-III and BaCO₃-IV is ～6%. BaCO₃-V, which has an orthorhombic symmetry, was synthesized at 50 GPa. As the pressure increases, BaCO₃-V is transformed into tetragonal BaCO₃-VI. This transformation is likely to be second order, because the diffraction pattern of BaCO₃-V is similar to that of BaCO₃-VI, and some single peaks in BaCO₃-VI become doublets in BaCO₃-V. After decompression, the new high-pressure phases transform into BaCO₃-II. Our findings resolve a dispute regarding the stable high-pressure phases of BaCO₃.  相似文献   

Secular change in lifetime of granitic crust and the continental growth: A new view from detrital zircon ages of sandstones     

Hikaru Sawada  Yukio Isozaki  Shuhei Sakata  Takafumi Hirata  Shigenori Maruyama 《地学前缘(英文版)》2018,9(4):1099-1115

U-Pb ages of detrital zircons were newly dated for 4 Archean sandstones from the Pilbara craton in Australia, Wyoming craton in North America, and Kaapvaal craton in Africa. By using the present results with previously published data, we compiled the age spectra of detrital zircons for 2.9, 2.6, 2.3,1.0, and0.6 Ga sandstones and modern river sands in order to document the secular change in age structure of continental crusts through time. The results demonstrated the following episodes in the history of continental crust:(1) low growth rate of the continents due to the short cycle in production/destruction of granitic crust during the Neoarchean to Paleoproterozoic(2.9-23 Ga),(2) net increase in volume of the continents during Paleo-to Mesoproterozoic(2.3-1.0 Ga), and(3) net decrease in volume of the continents during the Neoproterozoic and Phanerozoic(after 1.0 Ga). In the Archean and Paleoproterozoic, the embryonic continents were smaller than the modern continents, probably owing to the relatively rapid production and destruction of continental crust. This is indeed reflected in the heterogeneous crustal age structure of modern continents that usually have relatively small amount of Archean crusts with respect to the post-Archean ones. During the Mesoproterozoic, plural continents amalgamated into larger ones comparable to modern continental blocks in size. Relatively older crusts were preserved in continental interiors, whereas younger crusts were accreted along continental peripheries.In addition to continental arc magmatism, the direct accretion of intra-oceanic island arc around continental peripheries also became important for net continental growth. Since 1.0 Ga, total volume of continents has decreased, and this appears consistent with on-going phenomena along modern active arc-trench system with dominant tectonic erosion and/or arc subduction. Subduction of a huge amount of granitic crusts into the mantle through time is suggested, and this requires re-consideration of the mantle composition and heterogeneity.  相似文献   

Au–Ag–Te Mineralization of the Low‐Sulfidation Epithermal Aginskoe Deposit,Central Kamchatka,Russia     

Elena D. Andreeva  Hiroharu Matsueda  Victor M. Okrugin  Ryohei Takahashi  Shuji Ono 《Resource Geology》2013,63(4):337-349

Mineralogic studies of major ore minerals and fluid inclusion analysis in gangue quartz were carried out for the for the two largest veins, the Aginskoe and Surprise, in the Late Miocene Aginskoe Au–Ag–Te deposit in central Kamchatka, Russia. The veins consist of quartz–adularia–calcite gangue, which are hosted by Late Miocene andesitic and basaltic rocks of the Alnei Formation. The major ore minerals in these veins are native gold, altaite, petzite, hessite, calaverite, sphalerite, and chalcopyrite. Minor and trace minerals are pyrite, galena, and acanthine. Primary gold occurs as free grains, inclusions in sulfides, and constituent in tellurides. Secondary gold is present in form of native mustard gold that usually occur in Fe‐hydroxides and accumulates on the decomposed primary Au‐bearing tellurides such as calaverite, krennerite, and sylvanite. K–Ar dating on vein adularia yielded age of mineralization 7.1–6.9 Ma. Mineralization of the deposit is divided into barren massive quartz (stage I), Au–Ag–Te mineralization occurring in quartz‐adularia‐clays banded ore (Stage II), intensive brecciation (Stage III), post‐ore coarse amethyst (Stage IV), carbonate (Stage V), and supergene stages (Stage VI). In the supergene stage various secondary minerals, including rare bilibinskite, bogdanovite, bessmertnovite metallic alloys, secondary gold, and various oxides, formed under intensely oxidized conditions. Despite heavy oxidation of the ores in the deposit, Te and S fugacities are estimated as Stage II tellurides precipitated at the log f Te₂ values ?9 and at log fS₂ ?13 based on the chemical compositions of hypogene tellurides and sphalerite. Homogenization temperature of fluid inclusions in quartz broadly ranges from 200 to 300°C. Ore texture, fluid inclusions, gangue, and vein mineral assemblages indicate that the Aginskoe deposit is a low‐sulfidation (quartz–adularia–sericite) vein system.  相似文献   

Ore‐forming Ages and Sulfur Isotope Study of Hydrothermal Deposits in Kamchatka,Russia     

Ryohei Takahashi  Hiroharu Matsueda  Victor M. Okrugin  Naotatsu Shikazono  Shuji Ono  Akira Imai  Elena D. Andreeva  Koichiro Watanabe 《Resource Geology》2013,63(2):210-223

In Kamchatka, Central Koryak, Central Kamchatka and East Kamchatka metallogenic belts are distributed from northwest to southeast. K–Ar age, sulfur isotopic composition of sulfide minerals, and bulk chemical compositions of ores were analyzed for 13 ore deposits including hydrothermal gold‐silver and base metal, in order to elucidate the geological time periods of ore formation, relationship to regional volcanic belts, type of mineralization, and origin of sulfur in sulfides. The dating yielded ore‐forming ages of 41 Ma for the Ametistovoe deposit in the Central Koryak, 17.1 Ma for the Zolotoe deposit and 6.9 Ma for the Aginskoe deposit in the Central Kamchatka, and 7.4 Ma for the Porozhistoe deposit and 5.1 Ma for the Vilyuchinskoe deposit in the East Kamchatka metallogenic belt. The data combined with previous data of ore‐forming ages indicate that the time periods of ore formation in these metallogenic belts become young towards the southeast. The averaged δ³⁴S_CDT of sulfides are ?2.8‰ for the Ametistovoe deposit in Central Koryak, ?1.8‰ to +2.0‰ (av. ?0.1‰) for the Zolotoe, Aginskoe, Baranievskoe and Ozernovskoe deposits in Central Kamchatka, and ?0.7 to +3.8‰ (av. +1.7‰) for Bolshe‐Bannoe, Kumroch, Vilyuchinskoe, Bystrinskoe, Asachinskoe, Rodnikovoe, and Mutnovskoe deposits in East Kamchatka. The negative δ³⁴S_CDT value from the Ametistovoe deposit in Central Koryak is ascribed to the contamination of ³²S‐enriched sedimentary sulfur in the Ukelayat‐Lesnaya River trough of basement rock. Comparison of the sulfur isotope compositions of the mineral deposits shows similarity between the Central Koryak and Magadan metallogenic belts, and East Kamchatka and Kuril Islands belts. The Central Kamchatka belt is intermediate between these two groups in term of sulfur isotopic composition.  相似文献   

The layered structure of lunar maria: Identification of the HF-radar reflector in Mare Serenitatis using multiband optical images     

Shoko Oshigami  Shinya Okuno  Yasushi Yamaguchi  Makiko Ohtake  Junichi Haruyama  Takao Kobayashi  Atsushi Kumamoto  Takayuki Ono 《Icarus》2012,218(1):506-512

Comparison of the Lunar Radar Sounder (LRS) data to the Multiband Imager (MI) data is performed to identify the subsurface reflectors in Mare Serenitatis. The LRS is FM-CW radar (4–6 MHz) and the 2 MHz bandwidth leads to the range resolution of 75 m in a vacuum, whereas the sampling interval in the flight direction is about 75 m when an altitude of the spacecraft with polar orbit is nominal (100 km). Horizontally continuous reflectors were clearly detected by LRS in limited areas that consist of about 9% of the whole maria. The typical depth of the reflectors is estimated to be a few hundred meters. Layered structures of mare basalts are also discernible on some crater walls in the MI data of the visible bands (VIS). The VIS range has nine wavelengths of 415, 750, 900, 950, and 1000 nm, and their spatial resolution is 20 m/pixel at a nominal altitude. The stratigraphies around Bessel and Bessel-H craters in Mare Serenitatis are examined in this paper. It was revealed that the subsurface reflectors lie on the boundaries between basalt units with different chemical compositions. In addition, model calculations using the simplified radar equation indicate that the subsurface reflectors are not compositional interfaces but layer boundaries with a high-porosity contrast. These results suggest that the detected reflectors in Mare Serenitatis are regolith accumulated during so long hiatus of mare volcanisms enough for chemical composition of magma to change, not instantaneously. Therefore combination of the LRS and MI data has a potential to reveal characteristics of a series of magmatism forming each lithostratigraphic unit in Mare Serenitatis and other maria.  相似文献   

In situ observation of a phase transition in Fe2SiO4 at high pressure and high temperature     

Shigeaki Ono  Takumi Kikegawa  Yuji Higo 《Physics and Chemistry of Minerals》2013,40(10):811-816

We used an in situ measurement method to investigate the phase transition of Fe₂SiO₄ polymorphs under high pressures and temperatures. A multi-anvil high-pressure apparatus combined with synchrotron X-ray radiation was used. The stability of each polymorph was identified by observing the X-ray diffraction data from the sample. In most experiments, the diffraction patterns were collected 10–30 min after reaching the desired pressure and temperature conditions. The transition boundary between the olivine and spinel phase at T = 1,000–1,500 K and P = 2–8 GPa was determined to occur at P (GPa) = 0.5 + 0.0034 × T (K). The transition pressure determined in this study was in general agreement with that observed in previous high-pressure experiments. However, the slope of the transition, dP/dT, determined in our study was significantly higher than that estimated by the previous study combined with the in situ X-ray method.  相似文献