排序方式: 共有33条查询结果,搜索用时 15 毫秒
31.
The objective of this study was to quantify by experiments the initial seawater–suspended basaltic glass interactions following the 1996 outburst flood from the Vatnajökull glacier, Iceland. The altered basaltic glass dissolved in seawater as recorded by the Si release from the glass. The dissolved concentrations of Na, Ca, Si, Ba, Cd, Co, Cu, Hg, Mn, Ni and total dissolved inorganic N increased with time but the concentrations of Mg, K, S, Sr, Fe, Pb and Zn decreased. Calculated 1 to 10 day fluxes for Si range from 38,000 tons/day to 70,000 tons/10 days. The fluxes for other major elements are more uncertain, but the positive flux (release from suspended matter to seawater) of Ca and Na, and negative flux of Mg, K and S are greater than the Si flux. 相似文献
32.
Paul F. McMillan Sigurdur Jakobsson John R. Holloway Lynn A. Silver 《Geochimica et cosmochimica acta》1983,47(11):1937-1943
The Raman spectra of albite glasses with 4.5 and 6.6 weight percent water have been obtained, and are compared with that of a dry sample. The hydrous glasses show bands near 3600 cm?1 due to O-H stretching, and a previously unreported weak band near 1600 cm?1 due to bending of molecular H2O. Other weak spectral features are discussed, and the effect of dissolved water on the aluminosilicate framework vibrations is considered. 相似文献
33.
Sigurdur Jakobsson Jon Blundy Gordon Moore 《Contributions to Mineralogy and Petrology》2014,167(6):1-4
Jakobsson (Contrib Miner Petrol 164(3):397–407, 2012) investigated a double capsule assembly for use in piston-cylinder experiments that would allow hydrous, high-temperature, and high-pressure experiments to be conducted under controlled oxygen fugacity conditions. Using a platinum outer capsule containing a metal oxide oxygen buffer (Ni–NiO or Co–CoO) and H2O, with an inner gold–palladium capsule containing hydrous melt, this study was able to compare the oxygen fugacity imposed by the outer capsule oxygen buffer with an oxygen fugacity estimated by the AuPdFe ternary system calibrated by Barr and Grove (Contrib Miner Petrol 160(5):631–643, 2010). H2O loss or gain, as well as iron loss to the capsule walls and carbon contamination, is often observed in piston-cylinder experiments and often go unexplained. Only a few have attempted to actually quantify various aspects of these changes (Brooker et al. in Am Miner 83(9–10):985–994, 1998; Truckenbrodt and Johannes in Am Miner 84:1333–1335, 1999). It was one of the goals of Jakobsson (Contrib Miner Petrol 164(3):397–407, 2012) to address these issues by using and testing the AuPdFe solution model of Barr and Grove (Contrib Miner Petrol 160(5):631–643, 2010), as well as to constrain the oxygen fugacity of the inner capsule. The oxygen fugacities of the analyzed melts were assumed to be equal to those of the solid Ni–NiO and Co–CoO buffers, which is incorrect since the melts are all undersaturated in H2O and the oxygen fugacities should therefore be lower than that of the buffer by 2 log $a_{{{\text{H}}_{ 2} {\text{O}}}}$ . 相似文献