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941.
The high-K calc-alkaline volcanic rocks along the Neogene Volcanic Province of SE Spain represent crustal anatectic melts mixed with mantle components during the opening of the Alborán Sea. Partially melted metapelitic enclaves, along with the geochemical signature, provide evidence of their crustal source. U–Pb SHRIMP geochronology on monazite and zircon from enclaves and their hosting lavas in the localities of El Hoyazo, Mazarrón and Mar Menor reveals variable delays between the melting at depth and the eruption of the volcanics. These data indicate that: (1) the most important event of anatexis in the Neogene spanned at least the 3 m.y. interval between 12 and 9 Ma; (2) there is no trend in age of crustal melting; and (3) the delay between magma generation and extrusion varies from more than 3 m.y. at El Hoyazo to ~0.5 m.y. and possibly 2.5 m.y. at Mar Menor, with no significant delay measurable at Mazarrón. The variable time delay between anatexis and lava extrusion indicates that radiometric ages of volcanics may provide misleading information on the timing of magma genesis occurring at depth. This highlights the pitfall of basing detailed geodynamic models on volcanic extrusion ages alone. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   
942.
The Mammoth Peak sheeted intrusive complex formed in the interior of a ~7–10 km deep magma chamber, specifically in the Half Dome granodiorite of the Tuolumne batholith, central Sierra Nevada, CA (USA). The sheets consist of fractionated melts with accumulated hornblende, biotite, magnetite, titanite, apatite, and zircon. The accumulation, especially of titanite, had a profound effect on minor and trace elements (Nb, Ta, Ti, REE, U, Th, P, Zr, Hf, etc.), increasing their contents up to five to six times. Our thermal–mechanical modeling using the finite element method shows that cooling-generated tensile stresses resulted in the inward propagation of two perpendicular sets of dilational cracks in the host granodiorite. We interpret the sheeted complex to have formed by a crack-seal mechanism in a high strength, crystal-rich mush, whereby outward younging pulses of fractionated magma were injected into these syn-magmatic cracks at the margin of an active magma chamber. Thermal–mechanical instabilities developed after the assembly of the sheeted complex, which was then overprinted by late ~NW–SE magmatic foliation. This case example provides a cautionary note regarding the interpretation that sheeted zones in large granitoid plutons imply a diking mechanism of growth because the sheeted/dike complexes in plutons (1) may display inverse growth directions from the growth of the overall intrusive sequence; (2) need not record initial chamber construction and instead may reflect late pulsing of magma within an already constructed magma chamber; (3) have an overprinting magmatic fabric indicating the continued presence of melt after construction of sheeted complexes and thus a prolonged thermal history as compared to dikes; and (4) because the scale of the observed sheeted complexes may be small (<1%) in comparison to large homogenous parts of plutons, in which there is no evidence for sheeting or diking. Thus, where extensive dike complexes in plutons are absent, such as in much of the Tuolumne batholith, the application of an incremental diking model to explain chamber construction is at best speculative.  相似文献   
943.
A detailed palaeomagnetic study of Cretaceous age volcanic and sedimentary arc rocks from central Cuba has been carried out. Samples from 32 sites (12 localities) were subjected to detailed demagnetisation experiments. Nineteen sites from the Los Paso, Mataguá, Provincial and Cabaiguán Formations yielded high unblocking temperature, dual polarity directions of magnetisation which pass the fold tests with confidence levels of 95% or more and are considered to be primary in origin. The palaeomagnetic inclinations are equivalent to palaeolatitudes of 9°N for the Aptian, 18°N for the Albian. A synfolding remanence identified in 5 sites from the younger Hilario Formation indicates a late Cretaceous remagnetisation at a palaeolatitude of 16°N. Our results are in good agreement with previous palaeogeographic models and provide the first high quality palaeomagnetic data demonstrating the gradual northward movement of the Cretaceous Volcanic Arc throughout the Cretaceous. The declination values obtained all indicate significant and similar amounts of anticlockwise rotation from the oldest sequences studied through to the late Cretaceous remagnetisation. This rotation is most likely related to collision of the arc with the North American plate and transpressional strike slip movement along the northern margin of the Caribbean plate as it progressed eastwards into the large Proto-Caribbean basin.  相似文献   
944.
Northeastern Mexico hosts numerous epigenetic stratabound carbonate-hosted low-temperature hydrothermal deposits of celestine, fluorite, barite and zinc-lead, which formed by replacement of Mesozoic evaporites or carbonate rocks. Such deposits can be permissively catalogued as Mississippi Valley-type (MVT) deposits. The deposits studied in the state of Coahuila are associated with granitic and metasedimentary basement highs (horsts) marginal or central to the Mesozoic Sabinas Basin. These horsts controlled the stratigraphy of the Mesozoic basins and subsequently influenced the Laramide structural pattern. The Sabinas Basin consists of ~6,000-m-thick Jurassic to Cretaceous siliciclastic, carbonate and evaporitic series. The MVT deposits are mostly in Barremian and in Aptian-Albian to Cenomanian formations and likely formed from basinal brines that were mobilized during the Laramide orogeny, although earlier diagenetic replacement of evaporite layers (barite and celestine deposits) and lining of paleokarstic cavities in reef carbonates (Zn–Pb deposits) is observed. Fluid inclusion microthermometry and isotopic studies suggest ore formation due to mixing of basinal brines and meteoric water. Homogenization temperatures of fluid inclusions range from 45°C to 210°C; salinities range from 0 to 26 wt.% NaCl equiv., and some inclusions contain hydrocarbons or bitumen. Sulfur isotope data suggest that most of the sulfur in barite and celestine is derived from Barremian to Cenomanian evaporites. Regional geology and a compilation of metallogenic features define the new MVT province of northeastern Mexico, which comprises most of the state of Coahuila and portions of the neighboring states of Nuevo León, Durango and, perhaps extends into Zacatecas and southern Texas. This province exhibits a regional metal zonation, with celestine deposits to the south, fluorite deposits to the north and barite and Zn–Pb deposits mostly in the central part.  相似文献   
945.
Branched glycerol dialkyl glycerol tetraethers (GDGTs) are membrane lipids of unknown bacteria that are ubiquitous in soil and peat. Two indices based on the distribution of these lipids in soils, the Cyclization of Branched Tetraethers (CBT) and the Methylation of Branched Tetraethers (MBT) indices have been shown to correlate with soil pH, and mean annual air temperature (MAT) and soil pH, respectively, and can be used to reconstruct MAT in palaeoenvironments. To verify the extent to which branched GDGTs in marine sediments reflect the distribution pattern on land and whether these proxies are applicable for palaeoclimate reconstruction in high latitude environments with a MAT of <0 °C, we compared the branched GDGT distribution in Svalbard soils and nearby fjord sediments. Although branched GDGT concentrations in the soil are relatively low (0.02–0.95 μg/g dry weight (dw)) because of the cold climate and the short growing season, reconstructed MATs based on the MBT/CBT proxy are ca. ?4 °C, close to the measured MAT (ca. ?6 °C). Concentrations of branched GDGTs (0.01–0.20 μg/g dw) in fjord sediments increased towards the open ocean and the distribution was strikingly different from that in soil, i.e. dominated by GDGTs with one cyclopentane moiety. This resulted in MBT/CBT-reconstructed MAT values of 11–19 °C, well above measured MAT. The results suggest that at least part of the branched GDGTs in marine sediments in settings with a low soil organic matter (OM) input may be produced in situ. In these cases, the application of the MBT/CBT palaeothermometer will generate unrealistic MAT reconstructions. The MBT/CBT proxy should therefore only be used at sites with a substantial input of soil OM relative to the amount of marine OM, i.e. at sites close to the mouth of rivers with a catchment area where sufficient soil formation takes place and the soil thus contains substantial amounts of branched GDGTs.  相似文献   
946.
The main objectives of fisheries management are generally similar throughout the world. These are often stated in policy documents such as the Common Fisheries Policy and the Magnuson–Stevens Fishery Conservation and Management Act. However, at the local level often the key objectives of management are more detailed, characterised by both the overriding management structure and the status and type of fishery concerned. In this paper, we consider case study fisheries from the UK, France, Spain and Denmark to compare some of the various types of fisheries and fisheries management systems that exist in the European Union. From this, we define the key objectives for each management system.  相似文献   
947.
An array of bow-tie slot antennas coupled through an extended hemispherical lens is proposed to operate in the 30?GHz frequency band. The design includes a combination of three microstrip Wilkinson power dividers (WPD) and transitions to coplanar wave guides (CPW) to form the feeding antenna network. This configuration is suitable for the integration with heterodyne imaging detectors commonly used in radioastronomy. Measurements and simulation results exhibit a frequency range of operation from 20 to 40?GHz with a bandwidth of 24% achieved for ?10?dB return loss at the central frequency. The measured radiation patterns show a maximum peak gain of around 13?dB with HPBW of 10° for the E-plane, and whose first side lobes are lower than 13?dB below the main lobe in both angular shift sides. The presented results will be considered as preliminary feasibility studies in the 30?GHz QUIJOTE-CMB Instrument, which is designed to study the anisotropies of the Cosmic Microwave Background (CMB).  相似文献   
948.
949.
The reaction of CN? with cyanoacetylene (HC3N), has been studied as a function of the HC3N pressure in a quadrupole tandem mass spectrometer. The mass spectra revealed the fast depletion of the CN? parent ion and formation of larger anions of rapidly growing size. Most of the ions observed were found to belong to two series of products: (HC3N)x·C2p+1N? and (HC3N)x·C2pN? resulting from the sequential additions of HC3N molecules and loss of HCN or HCCN molecules. The mechanism and energetics of the first two reaction steps are briefly discussed. The laboratory data are compared with those from the Cassini CAPS-ELS spectrometer. It is believed that the reactions observed could account for the growth of anions in Titan’s ionosphere.  相似文献   
950.
High surface water-groundwater connectivity characterizes watersheds underlain by karsts, increasing contaminant transport risks. However, karsts are highly complex, making research necessary to understand the transport of contaminants from the surface, through the aquifer, to discharge areas. In Yucatan, the lack of waste water treatment raises the risk of groundwater contamination. We monitored stable isotopes (δ18O-NO3 and δ15N-NO3), cadmium, and lead to document waste water contamination and transport during the rainy and dry seasons, using water samples collected along the Ring of Cenotes during each season. Specific conductance and pH showed no consistent seasonality, with conductance ranging from 0.5 to 55 mS/cm and pH ranging from 6.6 to 8.6 for most samples. Nitrate concentrations in the cenotes averaged 205 ± 260 μM and no seasonal pattern was observed. Cd and Pb concentrations were 0.1 to 37.9 μg/L and 0.2 to 243.2 μg/L, respectively. Nitrate stable isotope values were 2.6 to 27.2‰ for δ18O and 1.2 to 20.7‰ for δ15N. The statistical relationship between δ15N and δ18O, in dry season samples, indicated that denitrification was occurring. A scale measure for waste water recognition showed: (1) high variability among sites probably related with dry/rainy seasons and/or diverse anthropogenic activities; and (2) specific water quality variables that contribute to contamination at each site during each season. Importantly, our analyses indicate that in the area surrounding the Ring of Cenotes, waste water exhibits spatial and temporal patterns related to complex transport and dilution processes, as is the case in karsts in general.  相似文献   
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