Constraining magma sources using primitive olivine-hosted melt inclusions from Puñalica and Sangay volcanoes (Ecuador)     

Diego?F.?NarvaezEmail authorView author&#;s OrcID profile  Estelle?F.?Rose-Koga  Pablo?Samaniego  Kenneth?T.?Koga  Silvana?Hidalgo 《Contributions to Mineralogy and Petrology》2018,173(10):80

Constraining arc magma sources at continental arc settings is a delicate task, because chemical signatures from crustal processes obscure the slab and mantle signatures. Here, we present major, trace, and volatile element compositions of olivine-hosted melt inclusions (Fo_82–89) selected from the most primitive lavas (Mg# >?60) from two Ecuadorian volcanoes (Puñalica and Sangay) situated at the southern termination of the Andean Northern Volcanic Zone. Melt inclusions (MI) from Puñalica are nepheline normative and have basaltic-to-basaltic-andesite compositions (45–56 wt% SiO₂) similar to peridotite-derived melts. Sangay MI is also nepheline normative, with high CaO (up to 16 wt% and CaO/Al₂O₃?<?1) and low silica contents (41.9–44.5 wt%) pointing out an amphibole-bearing clinopyroxenite source. Both volcanoes display volatile-rich compositions (up to 6100 ppm Cl, 2200 ppm F, and 6700 ppm S). These MI cannot be related to their host lavas by fractional crystallization, implying that they represent true primitive liquids. The source of Puñalica MI was metasomatized by slab-derived melts that imprints its low Ba/Th, Sr/Th, and high Th/La (average values of 66, 129, and 0.22, respectively). On the contrary, the slab component added to the source of Sangay MI has a higher Ba/Th, Sr/Th, and low Th/La (average values of 261, 517, and 0.11, respectively) which could suggest a relative contribution of aqueous fluids. This dichotomy is related to the presence of the Grijalva Fracture Zone that separates a younger and hotter oceanic crust to the north (below Puñalica) from a colder and older oceanic crust to the south (below Sangay).  相似文献   

Late Pleistocene and Holocene activity of the Atacazo–Ninahuilca Volcanic Complex (Ecuador)     

Silvana Hidalgo  Michel Monzier  Eduardo Almeida  Gilles Chazot  Jean-Philippe Eissen  Johannes van der Plicht  Minard L. Hall 《Journal of Volcanology and Geothermal Research》2008

The Atacazo–Ninahuilca Volcanic Complex (ANVC) is located in the Western Cordillera of Ecuador, 10 km southwest of Quito. At least six periods of Pleistocene to Holocene activity (N1 to N6) have been preserved in the geologic record as tephra fallouts and pyroclastic flow deposits. New field data, including petrographic and whole-rock geochemical analyses of over forty soil and tephra sections, 100 pumice and lithic samples, and 10 new ¹⁴C ages allow us to constrain: (1) the tephra fall isopachs and detailed characteristics of the last two events (N5–N6) including volume estimates of the tephra and pyroclastic flow deposits and the corresponding volcanic explosivity index (VEI); (2) the petrographical and geochemical correlations between domes, tephras, and pyroclastic flow deposits; and, (3) the timing of the last 4 eruptive events and a period of quiescence that endured a few thousand years (1000–4000).  相似文献   

Lake‐level changes in central Patagonia (Argentina): crossing environmental thresholds for Lateglacial and Holocene human occupation     

Daniel Ariztegui  Adrian Gilli  Flavio S. Anselmetti  Rafael A. Goñi  Juan B. Belardi  Silvana Espinosa 《第四纪科学杂志》2010,25(7):1092-1099

The role and extent of climate as a cause of the expansion and decline of human cultures is still debatable. It is clear, however, that human–environment interactions are enhanced and interplay more closely in climatically sensitive areas such as around hydrologically closed basins. Lago Cardiel is located at 49° S in the very arid rain shadow east of the Andes, providing an exceptionally receptive system to changes in hydrological balance. Results of a geophysical survey combined with sedimentological and geochemical studies provide a continuous Lateglacial–Holocene record of substantial water‐level changes. These variations, combined with archaeological results from the catchment area, offer a unique possibility to explore the pattern of peopling within this remote area of the globe and its possible relation to climate change. Human occupation in Patagonia is well documented towards the Andes throughout the entire Holocene. Archaeological data from the Lago Cardiel basin, however, show an apparent lack of human activity during the first part of this period, which coincides with well‐constrained high lake levels. Our results show an intriguing coincidence between low lake level and increasing human occupation, suggesting that the Lago Cardiel basin has focused human use during intervals with relatively lower effective moisture such as during the Late Pleistocene, but its evidence may have been submerged. This interpretation is confirmed by archaeological remains from Lago Strobel, another perennial lake with a comparable catchment located in the same climatic region and thus sharing the same climatic history as Lago Cardiel. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Petrological analysis of the pre-eruptive magmatic process prior to the 2006 explosive eruptions at Tungurahua volcano (Ecuador)     

Pablo Samaniego  Jean-Luc Le Pennec  Claude Robin  Silvana Hidalgo 《Journal of Volcanology and Geothermal Research》2011,199(1-2):69-84

Understanding the processes at the origin of explosive events is crucial for volcanic hazard mitigation, especially during long-lasting eruptions at andesitic volcanoes. This work exposes the case of Tungurahua volcano, whose unrest occurred in 1999. Since this date, the eruptive activity was characterized by low-to moderate explosiveness, including phases with stronger canon-like explosions and regional ash fallout. However, in 2006, a sudden increase of the explosiveness led to pyroclastic flow-forming eruptions on July 14th (VEI 2) and August 16–17th (VEI 3). All magmas emitted from 1999 to 2005, as well as the samples from the 2006 eruptions, have homogeneous bulk-rock andesitic compositions (58–59 wt.% SiO₂), and contain the same mineral assemblage consisting of pl + cpx + opx + mag ± ol. However, during the August 16–17th event, the erupted tephra comprise two types of magmas: a dominant, brown andesitic scoria; and scarce, light-grey pumice representing a subordinate, silica-rich juvenile component. For the andesitic magma, thermobarometric data point to magmatic temperatures ranging from 950 to 1015 °C and pressures in the range of 200 to 250 MPa, which corresponds to 7.5–9.5 km below the summit. Disequilibrium textures in plagioclase and pyroxene phenocrysts, particularly thin overgrowth rims, indicate the recharge of this magma body by mafic magma. Between 1999 and 2005, repeated injections from depth fed the intermittent eruptive activity observed while silica-rich melts were produced by in-situ crystallization in the peripheral parts of the reservoir. In April 2006, the recharge of a primitive magma produced strong convection and homogenisation in the reservoir, as well as pressure increase and higher magma ascent rate after seven years of only moderately explosive activity. This work emphasizes the importance of petrological studies in constraining the pre-eruptive magmatic conditions and processes, as a tool for understanding the fundamental causes of the changes in the eruptive dynamism, particularly the occurrence of paroxysmal phases in andesitic systems with open-vent behaviour.  相似文献   

Geochemical distribution of arsenic,cadmium, lead and zinc in river sediments affected by tailings in Zimapán,a historical polymetalic mining zone of México     

Erik Espinosa  María Aurora Armienta  Olivia Cruz  Alejandra Aguayo  Nora Ceniceros 《Environmental Geology》2009,58(7):1467-1477

High arsenic (As) groundwater is widely distributed in northwestern Hetao Plain, an arid region with sluggish groundwater flow. Observed As concentration in groundwater from wells ranges from 76 to 1,093 μg/l. Most water samples have high total dissolved solids, with Cl and HCO₃ as the dominant anions and Na as the dominant cation. The major hydrochemical types of most saline groundwaters are Na–Mg–Cl–HCO₃ and Na–Mg–Cl. By contrast, fresh groundwaters generally belong to the Na–Mg–HCO₃ type. High concentrations of arsenic in shallow aquifers are associated with strongly reducing conditions, as evidenced by high concentrations of dissolved organic carbon, ammonium, as well as dissolved sulfide and Fe, dominance of arsenite, relatively low concentrations of nitrate and sulfate, and occasionally high content of dissolved methane (CH₄). High As groundwaters from different places at Hetao Plain experienced different redox processes. Fluoride is also present in high As groundwater, ranging between 0.40 and 3.36 mg/l. Although fluorosis poses an additional health problem in the region, it does not correlate well with As in spatial distribution. Geochemical analysis indicates that evapotranspiration is an important process controlling the enrichment of Na and Cl, as well as trace elements such as As, B, and Br in groundwater. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Druse clinopyroxene in D'Orbigny angritic meteorite studied by single‐crystal X‐ray diffraction,electron microprobe analysis,and Mössbauer spectroscopy     

Yassir A. ABDU  Rosa B. SCORZELLI  Maria E. VARELA  Gero KURAT  Izabel de Souza AZEVEDO  Silvana J. STEWART  Frank C. HAWTHORNE 《Meteoritics & planetary science》2009,44(4):581-587

Abstract— The crystal structure of druse clinopyroxene from the D'Orbigny angrite, (Ca_0.944 Fe²⁺_0.042 Mg_0.010Mn_0.004) (Mg_0.469Fe²⁺_0.317Fe³⁺_0.035Al_0.125Cr_0.010Ti_0.044) (Si_1.742Al_0.258) O₆, a = 9.7684(2), b = 8.9124(2), c = 5.2859(1) Å, β = 105.903(1)°, V = 442.58 ų, space group C2/c, Z = 2, has been refined to an R₁ index of 1.92% using single‐crystal X‐ray diffraction data. The unit formula, calculated from electron microprobe analysis, and the refined site scattering values were used to assign site populations. The distribution of Fe²⁺and Mg over the M1 and M2 sites suggests a closure temperature of 1000 °C. Mössbauer spectroscopy measurements were done at room temperature on a single crystal and a powdered sample. The spectra are adequately fit by a Voigt‐based quadrupole‐splitting distribution model having two generalized sites, one for Fe²⁺with two Gaussian components and one for Fe³⁺with one Gaussian component. The two ferrous components are assigned to Fe²⁺at the M1 site, and arise from two different next‐nearest‐neighbor configurations of Ca and Fe cations at the M2 site: (3Ca,0Fe) and (2Ca,1Fe). The Fe³⁺/Fe_tot ratio determined by Mössbauer spectroscopy is in agreement with that calculated from the electron microprobe analysis. The results are discussed in connection with the redox and thermal history of D'Orbigny.  相似文献   

Characterization of the Eva Verda basin aquifer (Saint Marcel, Aosta Valley, Italy) through geochemical and geostructural methods and analysis     

Silvia Terrana  Roberto Gambillara  Laura Scesi  Silvana Martin  Elena Ciceri 《Hydrogeology Journal》2010,18(2):487-499

The groundwater system of the Eva Verda basin (Saint Marcel Valley, southern side of the middle Aosta Valley, Italy) has many springs that can be used as sources for drinking water. This area is near the disused Servette mine, which can be a pollutant source (metals and sulfides) for the springs located downhill. Aquifer characterization was done using a multidisciplinary approach: geostructural, lithological, hydrogeological and geochemical. In particular, the geostructural analysis showed that the preferential water-flow direction is controlled by tectonics and that it has a trend along the slope toward the downhill springs. The mine drainage flow direction is in agreement with this trend and can pollute the springs. Chemical analysis revealed three water groups: (1) SO ₄ ^2- –Ca²⁺–Mg²⁺ rich water (mine drainage), (2) HCO ₃ ^- –SO ₄ ^2- –Ca²⁺ rich water and (3) HCO ₃ ^- –Ca²⁺ rich water (freshwater). The second group of water results from the different percentage mix between the first and the third waters. The low percentage of mine polluted water demonstrates that there is a high dilution and low pollution of waters that can be exploited for drinking.  相似文献   

Petrogenesis of A-type Granitoids from the Alto Moxoto and Alto Pajeu Terranes of the Borborema Province, ne Brazil: Constraints from Geochemistry and Isotopic Composition     

Ignez P. Guimares  Adejardo F. Da Silva Filho  Silvana C. Melo  Moacir B. Macambira 《Gondwana Research》2005,8(3):347

A-type granitoids (512 Ma) either intruded into Paleoproterozoic gneiss of the Alto Moxoto Terrane (Prata Complex and Serra da Engabelada Pluton) or into Early Neoproterozoic metavolcanic metasedimentary sequence of the Alto Pajeu Terrane (Serrote Santo Antonio Pluton), constitute a small proportion of Brasiliano (= Pan-African) granitoids in the Central Tectonic Domain of the Borborema Province, northeastern Brazil. The Prata Complex consists of syenogranites, monzogranites, mafic enclaves of diorites and norites. The felsic and mafic members are not genetically related through fractionation. Mingling and mixing were extensive processes within the Prata Complex. The granites evolution appears to have involved fractionation of alkali feldspar, biotite, apatite and sphene without significant wall-rock assimilation. The Serra da Engabelada and Serrote Santo Antonio plutons consist of biotite syenogranites, with rare mafic enclaves. The studied granitoids are dominantly metaluminous, characterized by Fe-rich biotite and Fe-hornblende. High total alkalis, Y, Nb and REE and low CaO, MgO and Sr abundances and high FeO/(FeO+MgO) ratios characterize these granitoids. Chondrite-normalized REE patterns show enriched LREE, moderate to strong negative Eu anomalies and more or less flat heavy REE.The studied granitoids and diabase from dykes and enclaves show negative eNd _(512Ma) values (-14 to -10), high incompatible elements such as LILE, HFSE and REE, suggesting important contribution of Paleoproterozoic crust. The origin of the granites is thought to have involved partial melting of granodioritic or tonalitic lower crust. Such isotopic signature of the diabase from the dykes also reflects a Paleoproterozoic enriched lithospheric mantle in the area. The intrusion of the studied granitoids contemporary with sub-volcanic bimodal magmatism and deposition of many Cambrian "pull-apart" basins in the north and central tectonic Domain of the Borborema Province, suggest intrusion during post-tectonic relaxation of the Brasiliano orogeny following the assembly of West Gondwana.  相似文献   

Extended ionized emission from Seyfert galaxies     

J. M. Rodríguez Espinosa  R. M. Stanga 《Astrophysics and Space Science》1989,157(1-2):173-177

Preliminary results of a programme aimed at investigating the presence of Hii regions around Seyfert nuclei are presented. We have detected extended zones of ionized gas around some classical Seyfert galaxies. We think that the ionizing mechanism in these extended regions is UV radiation from young stars formed in a recent burst of star formation. In many instances the objects studied show morphological disturbances arising from the interaction with nearby companion galaxies.  相似文献   

Crystallization of sodium sulfate salts in limestone   总被引：1，自引：0，他引：1  

Rosa M. Espinosa Marzal  George W. Scherer 《Environmental Geology》2008,56(3-4):605-621

Crystallization pressure of salt crystals growing in confined pores is found to be the main cause for damage to stone and masonry. In this work, the crystallization of sodium sulfate salts in Cordova Cream and Indiana limestones is investigated using differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). The DSC experiments indicate that sodium heptahydrate always precipitates prior to the decahydrate (mirabilite), at a temperature between 15 and 7°C in the selected stones. The threshold supersaturation for the nucleation of heptahydrate is less than 2. In constrast, mirabilite precipitates close to or below 0°C and its crystallization pattern is completely different: precipitation takes place abruptly when the threshold supersaturation is reached, which is greater than 7. Indeed, the DSC and the DMA experiments reveal the rare nature of the nucleation of mirabilite for the investigated stones. The crystallization pressure exerted by heptahydrate does not cause damage under the conditions of the cooling experiments. In contrast, mirabilite exerts a very high crystallization pressure on the pore wall causing damage of the stone; moreover, the transient stress can remain for a long period of time since the relaxation process is slow.  相似文献