Trace element behaviour during interaction between basalt and crustal rocks at 0.5–0.8 GPa: an experimental approach     

Silvio Mollo  Valeria Misiti  Piergiorgio Scarlato 《Central European Journal of Geosciences》2010,2(2):188-198

We experimentally investigate the major and trace elements behavior during the interaction between two partially molten crustal rocks (meta-anorthosite and metapelite) and a basaltic melt at 0.5–0.8 GPa. Results show that a hybrid melt is formed at the basalt-crust contact, where plagioclase crystallizes. This contact layer is enriched in trace elements which are incompatible with plagioclase crystals. Under these conditions, the trace element diffusion coefficients are one order of magnitude larger than those expected. Moreover, the HFSE diffusivity in the hybrid melt is surprisingly higher than the REE one. Such a feature is related to the plagioclase crystallization that changes the trace elements liquid-liquid partitioning (i.e. diffusivity) over a transient equilibrium that will persist as long as the crystal growth proceeds. These experiments suggests that the behaviour of the trace elements is strongly dependent on the crystallization at the magma-crust interface. Diffusive processes like those investigated can be invoked to explain some unusual chemical features of contaminated magmatic suites.  相似文献   

Seismic anisotropy in the wedge above the Philippine Sea slab beneath Kanto and southwest Japan derived from shear wave splitting     

Mohamed K. Salah  T. Seno  T. Iidaka 《Journal of Asian Earth Sciences》2009,34(1):61-75

We conduct shear wave splitting measurements on waveform data from the Hi-net and the broadband F-net seismic stations in Kanto and SW Japan generated by shallow and intermediate-depth earthquakes occurring in the subducting Philippine Sea and Pacific slabs. We obtain 1115 shear wave splitting parameter pairs. The results are divided into those from the shallow (depth < 50 km) and the deep (depth > 50 km) events. The deep events beneath Kanto are further divided into PHS1 and PHS2 (upper and lower planes of the double seismic zone in the Philippine Sea slab, respectively), PAC1 and PAC2 (western and eastern Pacific slab, respectively) events. The results from the shallow events represent the crustal anisotropy, and their fast directions are more or less aligned in the σ_Hmax directions, implying that the anisotropy is produced by the alignment of the vertical cracks in the crust induced by the compressive stresses. In Kanto, Kii Peninsula and Kyushu regions, the results from the deep events suggest a contribution from the mantle wedge anisotropy. Events from all groups beneath Kanto show NW, NE and EW fast directions. This complex pattern seems to be produced by the corner flows induced by both the WNW PAC plate subduction and the oblique NNW PHS slab subduction with the associated olivine lattice-preferred orientations (LPOs), and the anisotropy frozen in the PHS slab. The deep events beneath Kii Peninsula show NE and NW fast directions and may be produced by the corner flow produced by the NNW PHS slab subduction with the associated olivine LPOs. The NE directions might also be produced by the segregated melts in the thin layers parallel to the PHS slab subduction. The deep events beneath N Kyushu show NNW fast directions, which may result from the southeastward flow in the upper mantle inferred from the stresses in the upper plate. Results from the deep events beneath middle-south Kyushu show dominantly E–W fast directions, in both the fore- and back-arcs. They may be produced by the corner flow of the westward PHS slab subduction with the olivine LPOs. Because the source regions with multiple fast directions are not resolved in this study, further detailed analyses of shear wave splitting are necessary for a better understanding of the stress state, the induced mantle flow, and the melt-segregation processes.  相似文献   

Carbonate assimilation in magmas: A reappraisal based on experimental petrology     

Silvio Mollo  Mario Gaeta  Carmela Freda  Tommaso Di Rocco  Valeria Misiti  Piergiorgio Scarlato 《Lithos》2010,114(3-4):503-514

The main effect of magma–carbonate interaction on magma differentiation is the formation of a silica-undersaturated, alkali-rich residual melt. Such a desilication process was explained as the progressive dissolution of CaCO₃ in melt by consumption of SiO₂ and MgO to form diopside sensu stricto. Magma chambers emplaced in carbonate substrata, however, are generally associated with magmatic skarns containing clinopyroxene with a high Ca-Tschermak activity in their paragenesis. Data are presented from magma–carbonate interaction experiments, demonstrating that carbonate assimilation is a complex process involving more components than so far assumed. Experimental results show that, during carbonate assimilation, a diopside–hedenbergite–Ca-Tschermak clinopyroxene solid solution is formed and that Ca-Tschermak/diopside and hedenbergite/diopside ratios increase as a function of the progressive carbonate assimilation. Accordingly, carbonate assimilation reaction should be written as follows, taking into account all the involved magmatic components:CaCO₃^solid + SiO₂^melt + MgO^melt + FeO^melt + Al₂O₃^melt → (Di–Hd–CaTs)_ss^solid + CO₂^fluidThe texture of experimental products demonstrates that carbonate assimilation produces three-phases (solid, melt, and fluid) whose main products are: i) diopside–hedenbergite–Ca-Tschermak clinopyroxene solid solution; ii) silica-undersaturated CaO-rich melt; and iii) C–O–H fluid phase. The silica undersaturation of the melt and, more importantly, the occurrence of a CO₂-rich fluid phase, must be taken into account as they significantly affect partition coefficients and the redox state of carbonated systems, respectively.  相似文献   

Modeling the sediment yield and the impact of vegetated filters using an event‐based soil erosion model—a case study of a small Canadian watershed          下载免费PDF全文

Gabriel Hould‐Gosselin  Alain N. Rousseau  Silvio J. Gumiere  Dennis W. Hallema  Claudie Ratté‐Fortin  Georges Thériault  Eric van Bochove 《水文研究》2016,30(16):2835-2850

This paper presents the first application of the event‐based MHYDAS‐Erosion model to a small agricultural watershed under temperate climate conditions (Quebec, Canada). Simulation results based on observed and synthetic rainfall events revealed a bimodal behaviour of sediment yield. During high‐intensity rainfall events, most of the sediments reaching the watershed outlet originate from cropland. Meanwhile, during low‐intensity events, most of the sediments come from the drainage network. Furthermore, simulation results show that implementation of 5‐m and 20‐m wide vegetated filters throughout the watershed or at the edge of the most problematic fields (4% of the total fields) could reduce soil loss by 52% and 31%, respectively. The modeling framework could be used for the design and location of beneficial management practices such as grass strips and riparian zones Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Kinematic evolution of thrusts wedge and erratic line length balancing: insights from deformed sandbox models     

Mohammad Irfan Ahmad  A. K. Dubey  Giovanni Toscani  Lorenzo Bonini  Silvio Seno 《International Journal of Earth Sciences》2014,103(1):329-347

Kinematic evolution of fold-thrust structures has been investigated by analogue models that include syntectonic sedimentation. Different decollement dips and basement thicknesses produced different wedge geometries and propagating characteristics. A model with one decollement level was characterized by a closely spaced thrust system during early stages of shortening as compared to the late stages. The frequency of fault nucleation was rapid during the early stages of deformation. Conversely, the frequency of fault nucleation was low and thrust spacing was significantly wider in a model with two decollement levels. Individual faults became locked at steep dips and deformation stepped forward as a new fault nucleated in-sequence in front of the older locked structure. Once the thrust system was established up to 27 % overall shortening, an overlying bed was introduced to simulate syntectonic deformation. Model sand wedge did not grow self similarly but rather its length and height increased episodically with deformation. Restoration of deformed models show that layer parallel shortening accommodated for approximately half of the total model shortening across the multilayers. Calculated error in apparent layer shortening from the restored layers revealed a direct relation with depth of the layers in the models. The experimental results are comparable to a natural example from the Northern Apennines fold-and-thrust belts.  相似文献   

Holocene sea-surface temperature variability in the Chilean fjord region     

Magaly Caniupán  Frank Lamy  Carina B. Lange  Jérôme Kaiser  Rolf Kilian  Helge W. Arz  Tania León  Gesine Mollenhauer  Susana Sandoval  Ricardo De Pol-Holz  Silvio Pantoja  Julia Wellner  Ralf Tiedemann 《Quaternary Research》2014

Here we provide three new Holocene (11–0 cal ka BP) alkenone-derived sea surface temperature (SST) records from the southernmost Chilean fjord region (50–53°S). SST estimates may be biased towards summer temperature in this region, as revealed by a large set of surface sediments. The Holocene records show consistently warmer than present-day SSTs except for the past ~ 0.6 cal ka BP. However, they do not exhibit an early Holocene temperature optimum as registered further north off Chile and in Antarctica. This may have resulted from a combination of factors including decreased inflow of warmer open marine waters due to lower sea-level stands, enhanced advection of colder and fresher inner fjord waters, and stronger westerly winds. During the mid-Holocene, pronounced short-term variations of up to 2.5°C and a cooling centered at ~ 5 cal ka BP, which coincides with the first Neoglacial glacier advance in the Southern Andes, are recorded. The latest Holocene is characterized by two pronounced cold events centered at ~ 0.6 and 0.25 cal ka BP, i.e., during the Little Ice Age. These cold events have lower amplitudes in the offshore records, suggesting an amplification of the SST signal in the inner fjords.  相似文献   

Fuzzy parameters analysis of time‐dependent fracture of concrete dam models     

Fabrizio Barpi  Silvio Valente 《国际地质力学数值与分析法杂志》2002,26(10):1005-1027

In order to apply the mechanical properties (measured on material specimens or laboratory‐sized models) to large structures (such as concrete dams), a non‐linear theory able to predict the size‐scale effect has to be used. One of these theories was first proposed by Hillerborg and co‐workers (fictitious crack model) and is based on the earlier works by Barenblatt and Dugdale for metals (cohesive crack model). It is based on the existence of a fracture process zone (FPZ), where the material undergoes strain softening. The behaviour of the material outside the FPZ is linear elastic. A large number of short‐time laboratory tests were executed, by varying the load, under crack mouth opening displacement control. Since concrete exhibits a time‐dependent behaviour, an interaction between creep and micro‐crack growth occurs in the FPZ. Therefore, different testing conditions can be applied: rupture can be achieved by keeping the load constant before peak value (pre‐peak tests), or after peak value and after an unloading and reloading procedure (post‐peak tests). The crack propagation rate is shown to be small enough to neglect inertial forces and large enough to keep the time‐dependent behaviour of the process zone as dominant compared to the behaviour of the undamaged and viscoelastic zone. Due to the variability in material microstructure from one specimen to another, experimental data show large ranges of scatter. Well established methods in probability theory require sufficient experimental data in order to assume a probability density distribution. The objective of this study is to investigate the ranges of variation of the time response under constant load in simple structural elements associated with pre‐selected variation (fuzziness) in the main material parameters. For situations where the values of the material parameters are of a non‐stochastic nature, the fuzzy set approach to modelling variability has been proposed as a better and more natural approach. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

The role of the export of tropical moisture into midlatitudes for extreme precipitation events in the Mediterranean region     

Simon O. Krichak  Joseph Barkan  Joseph S. Breitgand  Silvio Gualdi  Steven B. Feldstein 《Theoretical and Applied Climatology》2015,121(3-4):499-515

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Late Quaternary colluvial deposits in the Bocaina Plateau,southeastern Brazil highlands: age and palaeoenvironmental consequences     

Silvio Takashi Hiruma  May Christine Modenesi‐Gauttieri  Claudio Riccomini 《Boreas: An International Journal of Quaternary Research》2013,42(2):306-316

Despite the generalized occurrence of colluvial deposits in the humid tropical areas of southeastern Brazil, regional correlation is difficult because the deposits are discontinuous, and chronological data are very scarce and scattered. For the first time, colluvial deposits in the Bocaina Plateau are described, including 18 radiocarbon ages from 12 profiles. The plateau is located on the eastern flank of the Continental Rift of Southeastern Brazil and is the highest part of the Serra do Mar, with elevations up to 2000 m above sea level. Because the Bocaina Plateau is part of the summit surfaces of southeastern Brazil, it was subjected to specific climatic conditions during the Quaternary. Colluvial deposits on the lower hillslopes and edges of amphitheatres can show complex sequences with up to three intercalated dark humic horizons, corresponding to Late Pleistocene and Holocene phases of morphodynamic activity and pedogenesis. Ages of palaeosols vary from 650±50 a BP to 36 880±980 a BP. Landforms and colluvia on the Bocaina Plateau are very similar to those found on the opposite flank of the continental rift, on the Campos do Jordão Plateau. Ages of buried soils point to similar soil formation and colluviation episodes in the two plateaus. As in Campos do Jordão, the succession of erosive, depositional and pedogenetic processes on the altos campos hillslopes is probably related to late Quaternary climate changes.  相似文献   

Comparison of cosmic‐ray exposure ages and trapped noble gases in chondrule and matrix samples of ordinary,enstatite, and carbonaceous chondrites     

Otto Eugster  Silvio Lorenzetti  Urs Krhenbühl  Kurt Marti 《Meteoritics & planetary science》2007,42(7-8):1351-1371

Abstract— We performed a comprehensive study of the He, Ne, and Ar isotopic abundances and of the chemical composition of bulk material and components of the H chondrites Dhajala, Bath, Cullison, Grove Mountains 98004, Nadiabondi, Ogi, and Zag, of the L chondrites Grassland, Northwest Africa 055, Pavlograd, and Ladder Creek, of the E chondrite Indarch, and of the C chondrites Hammadah al Hamra 288, Acfer 059, and Allende. We discuss a procedure and necessary assumptions for the partitioning of measured data into cosmogenic, radiogenic, implanted, and indigenous noble gas components. For stone meteorites, we derive a cosmogenic ratio ²⁰Ne/²²Ne of 0.80 ± 0.03 and a trapped solar ⁴He/³He ratio of 3310 ± 130 using our own and literature data. Chondrules and matrix from nine meteorites were analyzed. Data from Dhajala chondrules suggest that some of these may have experienced precompaction irradiation by cosmic rays. The other chondrules and matrix samples yield consistent cosmic‐ray exposure (CRE) ages within experimental errors. Some CRE ages of some of the investigated meteorites fall into clusters typically observed for the respective meteorite groups. Only Bath's CRE age falls on the 7 Ma double‐peak of H chondrites, while Ogi's fits the 22 Ma peak. The studied chondrules contain trapped ²⁰Ne and ³⁶Ar concentrations in the range of 10^?6–10^?9 cm³ STP/g. In most chondrules, trapped Ar is of type Q (ordinary chondritic Ar), which suggests that this component is indigenous to the chondrule precursor material. The history of the Cullison chondrite is special in several respects: large fractions of both CR‐produced ³He and of radiogenic ⁴He were lost during or after parent body breakup, in the latter case possibly by solar heating at small perihelion distances. Furthermore, one of the matrix samples contains constituents with a regolith history on the parent body before compaction. It also contains trapped Ne with a ²⁰Ne/²²Ne ratio of 15.5 ± 0.5, apparently fractionated solar Ne.  相似文献