Finding work in 2001: urban–rural contrasts across England in employment rates and local job availability     

Mike Coombes  Simon Raybould 《Area》2004,36(2):202-222

Early results from the 2001 census of England allow a preliminary analysis of joblessness. People in the prime working ages (25–49) are more likely to be in work than those in their 50s, but the differences are quite subtle: in particular, men without qualifications are not much more likely to be in work when they are younger, despite the suggestions that too many men cease working in their 50s. The evidence supports the view that there is a national shortfall of demand for labour, that the low-skilled are the least able to compete for scarce jobs, and older people are the most likely to be unqualified. Moreover there is a strong spatial clustering of areas where job availability has declined or grown least, undermining the government's claim that there were often available jobs near to concentrations of people without work.  相似文献   

Aliens like us?   总被引：1，自引：0，他引：1  

Simon Conway Morris 《Astronomy& Geophysics》2005,46(4):4.24-4.26

Simon Conway Morris explains that as and when (and indeed if) we meet the extraterrestrials, they will look eerily like us.  相似文献   

Postglacial topographic evolution of glaciated valleys: a stochastic landscape evolution model   总被引：1，自引：0，他引：1  

Simon J. Dadson  Michael Church 《地球表面变化过程与地形》2005,30(11):1387-1403

The retreat of valley glaciers has a dramatic effect on the stability of glaciated valleys and exerts a prolonged influence on the subsequent fluvial sediment transport regime. We have studied the evolution of an idealized glaciated valley during the period following retreat of ice using a numerical model. The model incorporates a stochastic process to represent deep‐seated landsliding, non‐linear diffusion to represent shallow landsliding and an approximation of the Bagnold relation to represent fluvial sediment transport. It was calibrated using field data from several recent surveys within British Columbia, Canada. We present ensemble model results and compare them with results from a deterministic linear‐diffusion model to show that explicit representation of large landslides is necessary to reproduce the morphology and channel network structure of a typical postglacial valley. Our model predicts a rapid rate of fluvial sediment transport following deglaciation with a subsequent gradual decline, similar to that inferred for Holocene time. We also describe how changes in the model parameters affect the estimated magnitude and duration of the paraglacial sediment pulse. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Riparian perspectives of international cooperation in the Eastern Nile Basin     

Simon A. Mason 《Aquatic Sciences - Research Across Boundaries》2005,67(1):1-2

No Abstract.  .  相似文献   

Sediment concentration changes in runoff pathways from a forest road network and the resultant spatial pattern of catchment connectivity   总被引：6，自引：0，他引：6  

Jacky Croke  Simon Mockler  Peter Fogarty  Ingrid Takken 《Geomorphology》2005,68(3-4):257-268

Hydrological connectivity is a term often used to describe the internal linkages between runoff and sediment generation in upper parts of catchments and the receiving waters. In this paper, we identify two types of connectivity: direct connectivity via new channels or gullies, and diffuse connectivity as surface runoff reaches the stream network via overland flow pathways. Using a forest road network as an example of a landscape element with a high runoff source strength, we demonstrate the spatial distribution of these two types of linkages in a 57 km² catchment in southeastern Australia. Field surveys and empirical modelling indicate that direct connectivity occurs primarily due to gully development at road culverts, where the average sediment transport distance is 89 m below the road outlet. The majority of road outlets were characterised by dispersive flow pathways where the maximum potential sediment transport distance is measured as the available hillslope length below the road outlet. This length has a mean value of 120 m for this catchment. Reductions in sediment concentration in runoff plumes from both pathways are modelled using an exponential decay function and data derived from large rainfall simulator experiments in the catchment. The concept of the volume to breakthrough is used to model the potential delivery of runoff from dispersive pathways. Of the surveyed road drains (n=218), only 11 are predicted to deliver runoff to a stream and the greatest contributor of runoff occurs at a stream crossing where a road segment discharges directly into the stream. The methodology described here can be used to assess the spatial distribution and likely impact of dispersive and gullied pathways on in-stream water quality.  相似文献   

Relief-rejuvenation and topographic length scales in a fluvial drainage basin, Napf area, Central Switzerland   总被引：2，自引：2，他引：2  

Fritz Schlunegger  Heinz Schneider 《Geomorphology》2005,69(1-4):102-117

This paper explores how, and to what extent, a phase of relief-rejuvenation modifies the mode of surface erosion in an approximately 63 km² drainage basin located at the northern border of the Swiss Alps (Luzern area). In the study area, the retreat of the Alpine glaciers at the end of the Last Glacial Maximum (LGM) caused base level to lower by approximately 80 m. The fluvial system adapted to the lowered base level by headward erosion. This is indicated by knickzones in the longitudinal stream profiles and by the continuous upstream narrowing of the width of the valley floor towards these knickzones. In the headwaters above these knickzones, processes are still to a significant extent controlled by the higher base level of the LGM. There, frequent exposure of bedrock in channels and especially on hillslopes implies that sediment flux is to a large extent limited by weathering rates. In the knickzones, however, exposure of bedrock in channels implies that sediment flux is supply-limited, and that erosion rates are controlled by stream power.The morphometric analysis reveals the existence of length scales in the topography that result from distinct geomorphic processes. Along the tributaries where the upstream sizes of the drainage basins exceed 100,000–200,000 m², the mode of sediment transport and erosion changes from predominantly hillslope processes (i.e., landsliding, creep of regolith, rock avalanches and to some extent debris flows) to processes in channels (fluvial processes and debris flows). This length scale reflects the minimum size of the contributing area for channelized processes to take over in the geomorphic development (i.e., threshold size of drainage basin). This threshold size depends on the ratio between production rates of sediment on hillslopes, and export rates of sediment by processes in channels. Consequently, in the headwaters, erosion rates and sediment flux, and hence landscape evolution rates, are to a large extent limited by weathering processes. In contrast, in the lower portion of the drainage basin that adjusts to the lowered base-level, rates of channelized erosion and relief formation are controlled mainly by stream power. Hence, this paper shows that base-level lowering, headward erosion and establishment of knickzones separate drainage basins in two segments with different controls on rates of surface erosion, sediment flux and relief formation.  相似文献   

The dynamics of chironomid assemblages and vegetation during the Late Quaternary at Laguna Facil, Chonos Archipelago, southern Chile     

Julieta Massaferro  Stephen J. Brooks  Simon G. Haberle 《Quaternary Science Reviews》2005,24(23-24):2510-2522

We compare high-resolution pollen and chironomid records from the last 15,000 yr in Laguna Facil, southern Chile. Major vegetation and chironomid changes are recorded between ca 14,900 and 14,700 cal. yr BP. During the Lateglacial, changes in the chironomid stratigraphy lag behind changes in the pollen stratigraphy suggesting that the chironomids are responding to changes in the tree canopy or in soil chemistry brought about by vegetational development. At about 7200 cal. yr BP there is a change in the chironomid stratigraphy in advance of changes in the vegetation. This suggests that the response is to regional climatic change. The relatively close correlation of the chironomid and pollen stratigraphies with changes in charcoal concentrations also implicates the importance of fire and/or vulcanism in influencing the dynamics of forest and limnological systems. There is no clear evidence of cooling during the Younger Dryas chronozone in Laguna Facil.  相似文献   

Étude expérimentale de la réactivité du CO2 supercritique vis-à-vis de phases minérales pures. Implications pour la séquestration géologique de CO2     

Olivier Regnault  Vincent Lagneau  Hubert Catalette  Hélène Schneider 《Comptes Rendus Geoscience》2005,337(15):1331-1339

Carbon dioxide sequestration in deep aquifers and depleted oilfields is a potential technical solution for reducing green-house gas release to the atmosphere: the gas containment relies on several trapping mechanisms (supercritical CO₂, CO_2(sc), dissolution together with slow water flows, mineral trapping) and on a low permeability cap-rock to prevent CO_2(sc), which is less dense than the formation water, from leaking upwards. A leakproof cap-rock is thus essential to ensure the sequestration efficiency. It is also crucial for safety assessment to identify and assess potential alteration processes that may damage the cap-rock properties: chemical alteration, fracture reactivation, degradation of injection borehole seals, etc. The reactivity of the host-rock minerals with the supercritical CO₂ fluid is one of the potential mechanisms, but it is altogether unknown. Reactivity tests have been carried out under such conditions, consisting of batch reactions between pure minerals and anhydrous supercritical CO₂, or a two-phase CO₂/H₂O fluid at 200?°C and 105/160 bar. After 45 to 60 days, evidence of appreciable mineral-fluid reactivity was identified, including in the water-free experiments. For the mixed H₂O/CO₂ experiments, portlandite was totally transformed into calcite; anorthite displayed many dissolution patterns associated with calcite, aragonite, tridymite and smectite precipitations. For the anhydrous CO₂ experiments, portlandite was totally carbonated to form calcite and aragonite; anorthite also displayed surface alteration patterns with secondary precipitation of fibrous calcite. To cite this article: O. Regnault et al., C. R. Geoscience 337 (2005).  相似文献   

The isotopic effects of electron transfer: An explanation for Fe isotope fractionation in nature     

Abby Kavner  François Bonet  Justin Simon 《Geochimica et cosmochimica acta》2005,69(12):2971-2979

Isotope fractionation of electroplated Fe was measured as a function of applied electrochemical potential. As plating voltage was varied from −0.9 V to 2.0 V, the isotopic signature of the electroplated iron became depleted in heavy Fe, with δ⁵⁶Fe values (relative to IRMM-14) ranging from −0.18(±0.02) to −2.290(±0.006) ‰, and corresponding δ⁵⁷Fe values of −0.247(±0.014) and −3.354(±0.019) ‰. This study demonstrates that there is a voltage-dependent isotope fractionation associated with the reduction of iron. We show that Marcus’s theory for the kinetics of electron transfer can be extended to include the isotope effects of electron transfer, and that the extended theory accounts for the voltage dependence of Fe isotope fractionation. The magnitude of the electrochemically-induced fractionation is similar to that of Fe reduction by certain bacteria, suggesting that similar electrochemical processes may be responsible for biogeochemical Fe isotope effects. Charge transfer is a fundamental physicochemical process involving Fe as well as other transition metals with multiple isotopes. Partitioning of isotopes among elements with varying redox states holds promise as a tool in a wide range of the Earth and environmental sciences, biology, and industry.  相似文献   

Gold partitioning in melt-vapor-brine systems   总被引：5，自引：0，他引：5  

Adam C. Simon  Mark R. Frank  Philip A. Candela  Christoph A. Heinrich 《Geochimica et cosmochimica acta》2005,69(13):3321-3335

We used laser-ablation inductively coupled plasma mass spectrometry to measure the solubility of gold in synthetic sulfur-free vapor and brine fluid inclusions in a vapor + brine + haplogranite + magnetite + gold metal assemblage. Experiments were conducted at 800°C, oxygen fugacity buffered at Ni-NiO (NNO), and pressures ranging from 110 to 145 MPa. The wt% NaCl eq. of vapor increases from 2.3 to 19 and that of brine decreases from 57 to 35 with increasing pressure. The composition of the vapors and brines are dominated by NaCl + KCl + FeCl₂ + H₂O. Gold concentrations in vapor and brine decrease from 36 to 5 and 50 to 28 μg/g, respectively, and the calculated vapor:brine partition coefficients for gold decrease from 0.72 to 0.17 as pressure decreases from 145 to 110 MPa. These data are consistent with the thermodynamic boundary condition that the concentration of gold in the vapor and brine must approach a common value as the critical pressure is approached along the 800°C isotherm in the NaCl-KCl-FeCl₂-HCl-H₂O system.We use the equilibrium constant for gold dissolution as AuOH⁰, extrapolated from lower temperature and overlapping pressure range, to calculate expected concentrations of AuOH⁰ in our experimental vapors. These calculations suggest that a significant quantity of gold in our experimental vapors is present as a non-hydroxide species. Possible chloridogold(I) species are hypothesized based on the positively correlated gold and chloride concentrations in our experimental vapors. The absolute concentration of gold in our synthetic vapor, brine, and melt and calculated mass partition coefficients for gold between these physicochemically distinct magmatic phases suggests that gold solubility in aqueous fluids is a function of aqueous phase salinity, specifically total chloride concentration, at magmatic conditions. However, though we highlight here the effect of salinity, the combination of our data with data sets from lower temperatures evinces a significant decrease in gold solubility as temperature drops from 800°C to 600°C. This decrease in solubility has implications for gold deposition from ascending magmatic fluids.  相似文献