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31.
32.
Distance correlations of Late Tortonian–Messinian littoral carbonate complexes are proposed from the study of eight platforms in the western and central Mediterranean. Correlations are based on the identification of two major biological sedimentary cycles and of two index surfaces. Surface A is a maximum flooding surface during cycle 1 at around 6.7 Ma. Surface B is a regional marine planation surface at around 5.95 Ma, at the base of cycle 2 (Terminal Carbonate Complex). A general sedimentary model is proposed for the 7–5.6-Ma time-span. The boundary between cycles 1 and 2 is coincident with the onset of the Messinian Salinity Crisis, and appears to be related to major environmental–paleo-oceanographic changes in the Mediterranean, rather than to a major sea-level drop or to climatic change.  相似文献   
33.
Biotites from mafic rocks occurring at different stratigraphic levels of the Ivrea-Verbano Mafic Complex are studied. The rocks are gabbros and diorites. All the biotites are intermediate between phlogopite and annite [0.282 (up to 7.14 and 9.32 wt%, respectively) with respect to those of the diorites (up to 1.26 and 6.26 wt%, respectively). Systematic compositional variations support the substitution model 2 IV Si+( IV R2+)2 IV Al+ VI Ti (R2+=Fe+Mg+Mn) in gabbros and IV Si+ VI Al IV Al+ VI Ti in diorites. A predominance of disordered stacking sequences, coexisting with 1M, 2M 1 and 3T polytypes was observed in all biotites. It was possible to carry out structural refinements only on three biotites-2M 1 from diorites (R-values between 2.68 and 3.77) and one biotite-1M from gabbros (R-value=3.09). It was shown that: (1) the reduced thickness of the tetrahedral sheet in Ba-rich biotites supports the coupled substitution IV Si+ XII K IV Al+ XII Ba; (2) the interlayer site geometry is affected by the whole layer chemistry and does not reflect only local chemical variations; (3) in two samples of the 2M 1 polytype, the M(1) octahedral site is larger and more distorted than the M(2) sites because of the preferential ordering of Fe2+ in the M(1) site, whereas one sample shows complete cation disorder in the octahedral sites. Biotite-1M shows that Fe2+ can also be located in the M(2) site. Some of the differences between the biotites of gabbros and diorites (e.g. Ba concentration and exchange vectors) may be linked to the host rock composition and to its crystallization process. Biotite occurs in trace amounts in gabbros and its crystallization is related to the interstitial melt which contributed to the adcumulus growth of the main rock forming phases and became highly enriched in K, Ba and Ti. Diorites are the result of equilibrium crystallization of a residual melt rich in incompatible elements, where biotite is a major constituent.  相似文献   
34.
Holocene cooling events have been reconstructed for the southern Adriatic Sea (central Mediterranean) by means of analyses of organic walled dinoflagellate cysts, planktonic foraminifera, oxygen isotopes, calcareous nanoplankton, alkenones and pollen from a sediment core. Two cooling events have been detected, during which sea‐surface temperatures (SSTs) were ca. 2°C lower. Unravelling the SST signal into dominant seasonal components suggests maximum winter cooling of 2°C at around 6.0 ka, whereas the cooling at ca. 3.0 ka might be the result of a spring temperature cooling of 2–3°C. The events, lasting several hundred years, are apparently synchronous with those in the Aegean Sea, where they have been related to known cooling events from the Greenland ice‐core record. A distinct interruption in Adriatic Sea sapropel S1 is not clearly accompanied by a local drop in winter temperatures, but seems to be forced by ventilation, which probably occurred earlier in the Aegean Sea and was subsequently transmitted to the Adriatic Sea. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
35.
Under future scenarios of business-as-usual emissions, the ocean storage of anthropogenic carbon is anticipated to decrease because of ocean chemistry constraints and positive feedbacks in the carbon-climate dynamics, whereas it is still unknown how the oceanic carbon cycle will respond to more substantial mitigation scenarios. To evaluate the natural system response to prescribed atmospheric ??target?? concentrations and assess the response of the ocean carbon pool to these values, 2 centennial projection simulations have been performed with an Earth System Model that includes a fully coupled carbon cycle, forced in one case with a mitigation scenario and the other with the SRES A1B scenario. End of century ocean uptake with the mitigation scenario is projected to return to the same magnitude of carbon fluxes as simulated in 1960 in the Pacific Ocean and to lower values in the Atlantic. With A1B, the major ocean basins are instead projected to decrease the capacity for carbon uptake globally as found with simpler carbon cycle models, while at the regional level the response is contrasting. The model indicates that the equatorial Pacific may increase the carbon uptake rates in both scenarios, owing to enhancement of the biological carbon pump evidenced by an increase in Net Community Production (NCP) following changes in the subsurface equatorial circulation and enhanced iron availability from extratropical regions. NCP is a proxy of the bulk organic carbon made available to the higher trophic levels and potentially exportable from the surface layers. The model results indicate that, besides the localized increase in the equatorial Pacific, the NCP of lower trophic levels in the northern Pacific and Atlantic oceans is projected to be halved with respect to the current climate under a substantial mitigation scenario at the end of the twenty-first century. It is thus suggested that changes due to cumulative carbon emissions up to present and the projected concentration pathways of aerosol in the next decades control the evolution of surface ocean biogeochemistry in the second half of this century more than the specific pathways of atmospheric CO2 concentrations.  相似文献   
36.
Source location of long period seismicity at Volcàn de Colima,México   总被引:1,自引:0,他引:1  
This paper presents an analysis of seismicity associated with the volcanic activity of Volcàn de Colima (México) and recorded in the period November 2005–April 2006 during a field survey by the Istituto Nazionale di Geofisica e Vulcanologia (INGV)–Osservatorio Vesuviano, the Observatorio Vulcanologico de Colima of Colima University and the Instituto Andaluz de Geofisica, University of Granada. Three different types of volcanic earthquakes have been identified on the basis of their spectral properties: Type A (0.3–1 Hz), Type B (1–5 Hz) and Type C (3–4 Hz). Results of polarization analysis applied to Type A events show a predominance of radial motion, indicating that the wavefield comprises compressional waves (P) and shear waves polarized in the vertical plane (SV), while the signal always begins with a negative polarity. Type A, B and C earthquakes have been located using both a flat layered model and a 3D model including topography. Hypocentre distributions indicate that the source of Type A signals is very shallow and confined to a small volume lying about 1 km below the crater. In contrast, the source of Type B and C events is significantly deeper, with most hypocentres located in a volume of about 1 km3 centred at 2.5–3 km depth. A cluster analysis based on the cross-correlation among the waveforms of different events recorded at the same station was applied to Type A earthquakes. Only two clusters, which include only a small percentage of events were found, indicating that earthquake families were uncommon during the period of our survey.  相似文献   
37.
Short and medium range order of silica and sodium silicate glasses have been investigated from a quantitative analysis of 29Si MAS NMR and 23Na, 17O MQMAS NMR spectra. The method described enables the extraction of the underlying 17O NMR parameter distributions of bridging oxygens (BOs) and non-bridging oxygens (NBOs), and yields site populations which are confirmed by 29Si NMR data. The extracted NMR parameter distributions and their variations with respect to the glass chemical composition can then be analyzed in terms of local structural features (bond angles and bond lengths, coordination numbers) with the help of molecular dynamics simulations combined with first-principles calculations of NMR parameters. Correlations of relevant structural parameters with 23Na, 29Si and 17O NMR interactions (isotropic chemical shift δiso, quadrupolar coupling constant CQ and quadrupolar asymmetry parameter ηQ) are re-examined and their applicability is discussed. These data offer better insights into the structural organization of the glass network, including both chemical and topological disorder. Adding sodium to pure silica significantly diminishes the Si-O-Si bond angles and leads to a longer mean Si-O bond length with a slight decrease of the mean Na-O bond length. Moreover, the present data are in favor of a homogeneous distribution of Na around both oxygen species in the silicate network. Finally, our approach was found to be sensitive enough to investigate the effect of addition of a small quantity of molybdenum oxide (about 1 mol%) on the 17O MAS spectrum, opening new possibilities for investigating the Mo environment in silicate glasses.  相似文献   
38.
Despite the seismic vulnerability of gas systems and the significance of the direct and indirect consequences that loss functionality might have on large communities, the analysis of the earthquake performance and of post-earthquake management for this kind of distribution networks appears under-represented in the international literature, with respect to other lifeline systems. To contribute on this matter, the study presented comprises an investigation of the impact of L’Aquila 2009 earthquake ( $\text{ M }_\mathrm{w}$ 6.3) on the performance of the local medium- and low-pressure gas distribution networks. The assessment of the physical impact of the earthquake to the buried components of network, namely pipes, valves, and demand nodes, was carried out when processing post-earthquake repair activity reports. Repair data, along with geometrical and constructive features, were collected in a geographic information system linked to the digitized maps of the network, and compared with the interpolated map of recorded transient ground motion, measured in terms of peak ground velocity (i.e., a $Shakemap^\mathrm{TM}$ ). The impact of permanent ground deformation was also investigated and found to be limited in the study area. The resulting observed repair rates (number of repairs per km), presented for different pipeline materials, were compared with repair ratio fragility functions available in literature, showing relatively agreement especially to those for steel pipes, likely also because of the uncertainties in the estimations. Finally, the management of the L’Aquila gas system in the emergency phase and the resilience (functionality recover versus time) of the system was discussed.  相似文献   
39.
This work investigated the combined effects of nutrient availability and temperature on phytoplankton in large and deep lakes south of the Alps (lakes Garda, Iseo, Como, Lugano and Maggiore). The more eutrophic basins (Lugano and Iseo) showed a higher presence of cyanobacteria, green algae (Chlorophyta and Charophyta) and dinoflagellates (Dinophyta). Besides these two water bodies, high biomasses of cyanobacteria were recorded also in the oligo-mesotrophic Lake Garda. The development of these algal groups during the growing season showed a strong dependence on the surface spring availability of SRP, which, in turn, was related to winter climatic oscillations, deep mixing dynamics, and trophic status. A specific analysis carried out by applying additive mixed modelling, generalized least squares and mixed modelling, allowed investigation of the direct, seasonal effects of water temperature variations and trophic status on different algal groups. The dominant cyanobacteria (Oscillatoriales) showed only a partial relationship with temperature, while Nostocales and Chroococcales, which did not appear to have a close relationship with the trophic status of the lakes, were characterised by abrupt increases during the warmer months. High positive relationships with temperature were found for a few other algal groups (e.g., Chlorophyta, Charophyta and Dinophyta). Overall, the results indicated a positive relationship between the seasonal development of the more abundant and eutrophic-sensitive algal groups and the concurrent effect of trophic status and water temperature. Nevertheless, it was stressed that specific differences could be interpreted taking into account the different autoecological characteristics and susceptibilities of different species and functional groups to other stressing factors favouring losses, including, e.g., vertical sinking and grazing.  相似文献   
40.
We present an accurate characterization of the particle background behaviour on XMM-Newton based on the entire EPIC archive. This corresponds to the largest EPIC data set ever examined. Our results have been obtained thanks to the collaboration between the FP7 European program EXTraS and the ESA R&D ATHENA activity AREMBES. We used as a diagnostic an improved version of the diagnostic which compares the data collected in unexposed region of the detector with the region of the field of view in the EPIC-MOS. We will show that the in Field-of-View excess background is made up of two different components, one associated to flares produced by soft protons and the other one to a low-intensity background. Its origin needs to be further investigated.  相似文献   
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