Characterization of carbon monoxide,methane and nonmethane hydrocarbons in emerging cities of Saudi Arabia and Pakistan and in Singapore     

Barbara?BarlettaEmail authorView author&#;s OrcID profile  Isobel?J.?Simpson  Nicola?J.?Blake  Simone?Meinardi  Louisa?K.?Emmons  Omar?S.?Aburizaiza  Azhar?Siddique  Jahan?Zeb  Liya?E.?Yu  Haider?A.?Khwaja  Muhammad?A.?Farrukh  Donald?R.?Blake 《Journal of Atmospheric Chemistry》2017,74(1):87-113

We investigate the composition of 63 C₂-C₁₀ nonmethane hydrocarbons (NMHCs), methane (CH₄) and carbon monoxide (CO), in Jeddah, Mecca, and Madina (Saudi Arabia), in Lahore, (Pakistan), and in Singapore. We established a database with which to compare and contrast NMHCs in regions where ambient levels and emissions are poorly characterized, but where conditions are favorable to the formation of tropospheric ozone, and where measurements are essential for improving emission inventories and modeling. This dataset will also serve as a base for further analysis of air pollution in Western Saudi Arabia including, but not limited to, the estimation of urban emissions and long range pollution transport from these regions. The measured species showed enhanced levels in all Saudi Arabian cities compared to the local background but were generally much lower than in Lahore. In Madina, vehicle exhaust was the dominant NMHC source, as indicated by enhanced levels of combustion products and by the good correlation between NMHCs and CO, while in Jeddah and Mecca a combination of sources needs to be considered. Very high NMHC levels were measured in Lahore, and elevated levels of CH₄ in Lahore were attributed to natural gas. When we compared our results with 2010 emissions from the MACCity global inventory, we found discrepancies in the relative contribution of NMHCs between the measurements and the inventory. In all cities, alkenes (especially ethene and propene) dominated the hydroxyl radical (OH) reactivity (k _OH) because of their great abundance and their relatively fast reaction rates with OH.  相似文献   

Lake levels in the southern Bolivian Altiplano (19°–21°S.) during the Late Glacial based on diatom studies     

Florence Sylvestre  Simone Servant-Vildary  Marc Fournier  Michel Servant 《International Journal of Salt Lake Research》1995,4(4):281-300

This study is focused on the endorheic Uyni-Coipasa Basin located in the southern Bolivian Altiplano. Stratigraphical and fossil diatom studies based on a detailed radiocarbon chrnology revealed six phases in water-level changes and paleosalinity variations. At 15,430±80 yr B.P., lacustrine conditions settled in the southern Bolivian Altiplano. A saline lake, characterized by benthic meso-metasaline species, reached +4 m altitude above the present bottom of the basin. After 15,430±80 yr B.P., the level rapidly rose to +27 m, as suggested by a tychoplanktonic mesosaline flora. Between 14,500 years and 13,000 years, finely lanminated sediments at +32 m contained successively a dominance of epiphytic mesosaline to hypersaline species and tychoplanktonic oligosaline diatoms, indicating weak fluctuations in water-level and salinity. At 13,000 years, strong changes in the diatom flora occurred; epiphytic oligo-hypersaline diatoms were replaced by planktonic meso-polysaline species. They indicate a deep salt lake (the lake reached +100 m). After 12,000 years, the lake level abruptly dropped, as suggested by fluviatile sediments with a benthic mesopolysaline diatom flora. The main lake was replaced by shallow saline ponds. A wet pulse occurred at 11,400 years, characterized by low water level (+7 m) and high salinity. This lacustrine phase remained until 10,400 yr B.P. These data indicate changes in Precipitation minus Evaporation (P-E). Our regional interpretations are based on a comparison with teh available data on the northern (Lake Titicaca) and southern (Lipez are) Bolivian Altiplano and on the northern Chilean Altiplano (Atacama Desert).  相似文献   

FAOSTAT estimates of greenhouse gas emissions from biomass and peat fires     

Simone Rossi  Francesco N. Tubiello  Paolo Prosperi  Mirella Salvatore  Heather Jacobs  Riccardo Biancalani  Joanna I. House  Luigi Boschetti 《Climatic change》2016,135(3-4):699-711

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Erratum to: FAOSTAT estimates of greenhouse gas emissions from biomass and peat fires     

Simone Rossi  Francesco N. Tubiello  Paolo Prosperi  Mirella Salvatore  Heather Jacobs  Riccardo Biancalani  Joanna I. House  Luigi Boschetti 《Climatic change》2016,135(3-4):713-713

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Looking beyond the neighbourhood: income inequality and residential segregation in Swedish metropolitan areas, 1991–2010     

Simone Scarpa 《Urban geography》2016,37(7):963-984

In recent years, residential segregation has become a major issue in the Swedish policy debate. The prevailing view is that residential segregation is a crucial contributing factor to the development of income inequality, since individual income prospects are thought to be influenced by the population characteristics of their neighbourhoods. This study takes the opposite approach and analyses the extent to which, in the period 1991–2010, rising income inequality contributed to the development of residential segregation by income in Swedish metropolitan areas. The period was characterized by unprecedented growth in income inequality, which was associated with a decline in the redistributive power of the welfare state. Residential segregation by income mirrored locally the general trend in income inequality. Another factor was the change in income dispersion in neighbourhoods, relative to the metropolitan areas as a whole, which indicates a tendency towards increased population homogeneity in neighbourhoods with respect to income.  相似文献   

Assessment of toxicological status of a SW Mediterranean segment population of striped dolphin (Stenella coeruleoalba) using skin biopsy     

M. Cristina Fossi  Letizia Marsili  Giancarlo Lauriano  Caterina Fortuna  Simone Canese  Stefania Ancora  Claudio Leonzio  Teresa Romeo  Ruben Merino  Esteban Abad  Begoa Jimnez 《Marine environmental research》2004,58(2-5):269

Various studies have revealed high concentrations of contaminants such as organochlorines (OCs) and heavy metals in Mediterranean cetaceans. A geographical trend of contamination (PCBs and DDTs) has been found for striped dolphin (Stenella coeruleoalba). In this study we used a non-lethal approach (skin biopsy) to investigate bioaccumulation of OCs, including polychlorobiphenyls (PCBs), DDTs, polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), trace elements (Hg, Cd, Pb) and CYP1A activity (BPMO) in nine striped dolphins sampled in the Aeolian area (Sicily – Italy) in summer 2002. The arithmetic mean value of BPMO activity in this group was 43.46 AUF/g tissue/h. This value is approximately 3 times and 5 times lower, respectively, than the value found in the Ionian and in the Ligurian groups. Skin biopsies of striped dolphins emerged as a suitable material for assessing the toxicological status of the various Mediterranean groups.  相似文献   

Subsidence due to crack closure and depressurization of hydrothermal systems: a case study from Mt Epomeo (Ischia Island,Italy)     

Vincenzo Sepe  Simone Atzori  Guido Ventura 《地学学报》2007,19(2):127-132

Levelling surveys carried out between 1990 and 2003 on the Mt Epomeo resurgent block (Ischia Island) record negative dislocations on its northern and southern flanks with a maximum subsidence rate of 1.27 cm yr⁻¹. This deformation is not associated with the cooling, crystallization or lateral drainage of magma and cannot be explained by a pressure point or prolate ellipsoid source. Results from dislocation models and the available structural and geochemical information indicate that the subsidence is due to crack closure processes along two main ENE–WSW and E–W preexisting faults, which represent the preferred pathway of CO₂ degassing from the hydrothermal system located beneath Mt Epomeo. The monitoring of the dislocations and CO₂ flux along these faults could give useful information on the dynamics of the hydrothermal system.  相似文献   

Diagenesis of the Khuff Formation (Permian–Triassic), northern United Arab Emirates     

Simone Fontana  Fadi H. Nader  Sadoon Morad  Andrea Ceriani  Ihsan S. Al-Aasm 《Arabian Journal of Geosciences》2010,3(4):351-368

This diagenetic study (including fieldwork, petrographic, fluid inclusion, and stable isotope investigations) deals with the outcrop of Upper Permian–Lower Triassic carbonate rocks, which are equivalent to the Khuff Formation. The studied succession, which outcrops in the Ras Al Khaimah region, northern United Arab Emirates, comprises three formations, including the Bih, the Hagil, and the Ghail formations. The study focuses on unraveling the conditions and fluid compositions encountered during diagenesis of the succession. Emphasize is also made on linking diagenesis to major stratigraphic surfaces and to highlight reservoir property evolution and heterogeneity of the studied rocks. The evolution of fluids and related diagenetic products can be summarized as follows: (1) formation of near-surface to shallow burial, fine-crystalline dolomite (dolomite matrix) through pervasive dolomitization of carbonate sediments by modified marine pore waters; (2) formation of coarse-crystalline dolomite cement by highly evolved marine pore waters (13–23 wt.% NaCl eq.) at elevated temperatures (120–208°C), and (3) calcite cementation by highly saline fluid (20–23 wt.% NaCl eq.) at high temperature (170–212°C). A final calcite cement generation has been formed by the percolation of meteoric fluids during uplift. Fracture- and vug-filling diagenetic minerals are mainly restricted to the mid-Bih breccia marker level, suggesting preferential focused fluid flow through specific stratigraphic surfaces as well as along tectonic-related structures. Reservoir properties have been evolved as result of the interplay of the original sedimentary texture and the diagenetic evolution. Porosity is higher in the Bih Formation, which is dominated by dolomitized packstones and grainstones, than in the Hagil and Ghail formations, consisting mainly of dolomitized mudstones and wackestones. Image analyses were used to quantify the visual porosity in thin sections. The highest porosity values were measured in the Bih Formation, which is characterized by significant amounts of vug- and fracture-filling cements. This feature is attributed to the increase of porosity owing to substantial dissolution of abundant intergranular and vug-filling cements. In contrast, the Hagil and Ghail formations, which consist of finer-grained rock than the Bih Formation, were less cemented, and thus, the porosity enhancement by cement dissolution was insignificant.  相似文献   

An integrated evaluation of thirteen modelling solutions for the generation of hourly values of air relative humidity     

Simone Bregaglio  Marcello Donatelli  Roberto Confalonieri  Marco Acutis  Simone Orlandini 《Theoretical and Applied Climatology》2010,102(3-4):429-438

The availability of hourly air relative humidity (HARH) data is a key requirement for the estimation of epidemic dynamics of plant fungal pathogens, in particular for the simulation of both the germination of the spores and the infection process. Most of the existing epidemic forecasting models require these data as input directly or indirectly, in the latter case for the estimation of leaf wetness duration. In many cases, HARH must be generated because it is not available in historical series and when there is the need to simulate epidemics either on a wide scale or with different climate scenarios. Thirteen modelling solutions (MS) for the generation of this variable were evaluated, with different input requirements and alternative approaches, on a large dataset including several sites and years. A composite indicator was developed using fuzzy logic to compare and to evaluate the performances of the models. The indicator consists of four modules: Accuracy, Correlation, Pattern and Robustness. Results showed that when available, daily maximum and minimum air relative humidity data substantially improved the estimation of HARH. When such data are not available, the choice of the MS is crucial, given the difference in predicting skills obtained during the analysis, which allowed a clear detection of the best performing MS. This study represents the first step of the creation of a robust modelling chain coupling the MS for the generation of HARH and disease forecasting models, including the systematic validation of each step of the simulation.  相似文献   

Boron and Oxygen Isotope Composition of Certified Reference Materials NIST SRM 610/612 and Reference Materials JB-2 and JR-2   总被引：1，自引：0，他引：1  

Simone Kasemann  Anette Meixner  Alexander Rocholl  Torsten Vennemann  Martin Rosner  Axel K. Schmitt  Michael Wiedenbeck 《Geostandards and Geoanalytical Research》2001,25(2-3):405-416

We present data on the concentration, the isotope composition and the homogeneity of boron in NIST silicate glass reference materials SRM 610 and SRM 612, and in powders and glasses of geological reference materials JB-2 (basalt) and JR-2 (rhyolite). Our data are intended to serve as references for both microanalytical and wet-chemical techniques. The δ¹¹ B compositions determined by N-TIMS and P-TIMS agree within 0.5% and compare with SIMS data within 2.5%. SIMS profiles demonstrate boron isotope homogeneity to better than δ¹¹ B = 2% for both NIST glasses, however a slight boron depletion was detected towards the outermost 200 μm of the rim of each sample wafer. The boron isotope compositions of SRM 610 and SRM 612 were indistinguishable. Glasses produced in this study by fusing JB-2 and JR-2 powder also showed good boron isotope homogeneity, both within and between different glass fragments. Their major element abundance as well as boron isotope compositions and concentrations were identical to those of the starting composition. Hence, reference materials (glasses) for the in situ measurement of boron isotopes can be produced from already well-studied volcanic samples without significant isotope fractionation. Oxygen isotope ratios, both within and between wafers, of NIST reference glasses SRM 610 and SRM 612 are uniform. In contrast to boron, significant differences in oxygen isotope compositions were found between the two glasses, which may be due to the different amounts of trace element oxides added at ten-fold different concentration levels to the silicate matrix.  相似文献