δ³⁰Si and δ²⁹Si Determinations on USGS BHVO-1 and BHVO-2 Reference Materials with a New Configuration on a Nu Plasma Multi-Collector ICP-MS     

Kathrin Abraham  Sophie Opfergelt  François Fripiat  Anne-Julie Cavagna  Jeroen T.M. de Jong  Stephen F. Foley  Luc André  Damien Cardinal 《Geostandards and Geoanalytical Research》2008,32(2):193-202

We report silicon isotopic determinations for USGS rock reference materials BHVO-1 and BHVO-2 using a Nu Plasma multi-collector (MC)-ICP-MS, upgraded with a new adjustable entrance slit, to obtain medium resolution, as well as a stronger primary pump and newly designed sampler and skimmer cones ("B" cones). These settings, combined with the use of collector slits, allowed a resolution to be reached that was sufficient to overcome the ¹⁴N¹⁶O and ¹⁴N₂ interferences overlying the ³⁰Si and the ²⁸Si peaks, respectively, in an earlier set-up. This enabled accurate measurement of both δ³⁰Si and δ²⁹Si. The δ value is expressed in per mil variation relative to the NBS 28 quartz reference material. Based on data acquired from numerous sessions spread over a period of six months, we propose a recommended average δ³⁰Si of −0.33 ± 0.05‰ and −0.29 ± 0.11‰ (2se) for BHVO-1 and BHVO-2, respectively. Our BHVO grand mean silicon isotope composition (δ³⁰Si =−0.31 ± 0.06‰) is significantly more negative than the only published value for BHVO-2, but is in very good agreement with the recently established average value of ocean island basalts (OIB), confirming the conclusion that the OIB reservoir has a distinct isotopic composition from the solar reservoir as sampled by chondrites.  相似文献   

Households’ Resilience to Hurricanes in Coastal Communities of Oaxaca,Mexico     

V. Sophie Avila-Foucat  A. F. Martínez 《社会与自然资源》2018,31(7):807-821

Hurricanes represent a common threat to coastal communities, affecting livelihood strategies and assets. Households are resilient if they can recover from a stress or shock while maintaining and arranging assets to secure a sustainable livelihood. The objective of this research is to measure the degree of resilience in the coastal households of Oaxaca, Mexico, following a hurricane using the asset approach and describing diversity, connectivity, and slow variables. The results show different degrees of resilience among the households and that social, natural, and financial capital are relevant to resilience. The diversification of income, savings, community help, natural resource use, and government transfers is among the most important assets. In particular, social capital and natural capital determine the structure and dynamics of the system.  相似文献   

Geomorphic,sedimentary and hydraulic reconstruction of a glacial lake outburst flood in northern Alberta,Canada     

Sophie L. Norris  Martin Margold  Daniel J. Utting  Duane G. Froese 《Boreas: An International Journal of Quaternary Research》2019,48(4):1006-1018

Glacial lake outburst floods occurred frequently during the last deglaciation of the Laurentide Ice Sheet. Within the Interior Plains, these floods carved large spillway systems; however, due to a lack of abundant sediment, deposits within prairie spillways are rarely preserved. Here, we present geomorphic and sedimentary evidence and hydraulic modelling of the eastern Beaver River Spillway, formed by the catastrophic drainage of the ice‐dammed glacial Lake Algar, in north central Alberta. During this flood, coarse‐grained sediment eroded from local till formed large pendant bars. Within the first ~50 km of the spillway (Reach 1), pendant bars contain downstream orientated foresets overlain by horizontally bedded coarser gravels. The remaining pendant bars (Reach 2), present downflow of a moraine barrier, differ, comprising massive, matrix‐supported, inversely graded gravels capped by a boulder layer. We use a HEC‐GeoRAS/HEC‐RAS system in conjunction with palaeostage indicators to estimate the steady‐state water surface elevation. Modelling results show that peak discharge within Reach 1 of the eastern Beaver River Spillway was approximately 14 000–21 000 m³ s^?1. For Reach 2, 30 km downstream, the peak discharge was estimated at 23 000–40 000 m³ s^?1 (n_bulked 18 000–26 000 m³ s^?1). The downstream discharge increase, consistent with the sedimentary change in pendant bar deposits, is attributed to sediment bulking of the flood flow. This provides the opportunity to observe a range of flow conditions, and associated sedimentology, from a single flood event. The reconstructed flow conditions, coupled with lake volume estimates from the ponding above the moraine barrier suggest a minimum flow duration of 3–5 days.  相似文献   

Interactions and connectivity between runoff generation processes of different spatial scales          下载免费PDF全文

Sophie Bachmair  Markus Weiler 《水文研究》2014,28(4):1916-1930

Monitoring runoff generation processes in the field is a prerequisite for developing conceptual hydrological models and theories. At the same time, our perception of hydrological processes strongly depends on the spatial and temporal scale of observation. Therefore, the aim of this study is to investigate interactions between runoff generation processes of different spatial scales (plot scale, hillslope scale, and headwater scale). Different runoff generation processes of three hillslopes with similar topography, geology and soil properties, but differences in vegetation cover (grassland, coniferous forest, and mixed forest) within a small v‐shaped headwater were measured: water table dynamics in wells with high spatial and temporal resolution, subsurface flow (SSF) of three 10 m wide trenches at the bottom of the hillslopes subdivided into two trench sections each, overland flow at the plot scale, and catchment runoff. Bachmair et al. ( 2012 ) found a high spatial variability of water table dynamics at the plot scale. In this study, we investigate the representativity of SSF observations at the plot scale versus the hillslope scale and vice versa, and the linkage between hillslope dynamics (SSF and overland flow) and streamflow. Distinct differences in total SSF within each 10 m wide trench confirm the high spatial variability of the water table dynamics. The representativity of plot scale observations for hillslope scale SSF strongly depends on whether or not wells capture spatially variable flowpaths. At the grassland hillslope, subsurface flowpaths are not captured by our relatively densely spaced wells (3 m), despite a similar trench flow response to the coniferous forest hillslope. Regarding the linkage between hillslope dynamics and catchment runoff, we found an intermediate to high correlation between streamflow and hillslope hydrological dynamics (trench flow and overland flow), which highlights the importance of hillslope processes in this small watershed. Although the total contribution of SSF to total event catchment runoff is rather small, the contribution during peak flow is moderate to substantial. Additionally, there is process synchronicity between spatially discontiguous measurement points across scales, potentially indicating subsurface flowpath connectivity. Our findings stress the need for (i) a combination of observations at different spatial scales, and (ii) a consideration of the high spatial variability of SSF at the plot and hillslope scale when designing monitoring networks and assessing hydrological connectivity. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Negotiating neoliberalism: Conservationists’ role in the development of payments for ecosystem services     

Sophie Wynne-Jones 《Geoforum》2012,43(6):1035-1044

This paper critically engages with the role of conservation practitioners as ‘expert intermediaries’ in the development of payments for ecosystem services (PES) schemes in the UK. Centring on the case study of the Wildlife Trust’s Pumlumon Project in Mid Wales, the paper connects the advance of neoliberal governance strategies to the experiences and attitudes of conservationists, charting a more personalised geography of how PES has gained traction here, beyond its dissemination as an anonymous discourse or top-down imposition. In methodological terms, the paper combines ethnography with the insights of governmentality in order to demonstrate how conservationists have made sense of, and subsequently engaged with processes of neoliberalisation. This is set out as a means to attain a grounded perspective on the advancement of PES, but equally to appreciate how the hegemony of market-style governance is accepted and advanced by the conservationists involved.  相似文献   

Density,Shell Use and Species Composition of Juvenile Fiddler Crabs (Uca spp.) at Low and High Anthropogenic Impact Salt Marsh Sites     

Michelle D. Carlson  Laura B. Regassa  Sophie B. George 《Estuaries and Coasts》2014,37(3):602-609

Coastal wetlands worldwide have been negatively impacted by humans, causing decreases in the vegetation used as a refuge from predation by juveniles of many species. This study examined juvenile fiddler crab densities and species composition (Uca pugnax, Uca pugilator, and Uca minax), and their use of gastropod shells (Littorina littoraria), at three low and three high impact sites on barrier islands in southeast Georgia. On six dates in June–August 2010, samples were taken from 10 quadrats (1 m²) at each site to determine juvenile fiddler crab densities and species composition, as well as gastropod shell densities and percent shell use. Multiplex PCR was used to identify juvenile fiddler crabs to species. Juvenile fiddler crab densities were lower at high impact sites, while gastropod shell densities and shell use were similar at both low and high impact sites. Species compositions differed between low and high impact sites on the substrate and in shells, with more U. pugilator and U. minax at high impact sites. A change in fiddler crab densities and species composition could cause a substantial change in southeastern salt marshes.  相似文献   

How light affect the magnetotactic behavior and reproduction of ellipsoidal multicellular magnetoglobules?     

Qian  Xinxin  Zhao  Yicong  Santini  Claire-Lise  Pan  Hongmiao  Xiao  Tian  Chen  Haitao  Song  Tao  Li  Jinhua  Alberto  Francois  Brustlein  Sophie  Wu  Long-Fei 《中国海洋湖沼学报》2021,39(6):2005-2014

Journal of Oceanology and Limnology - Magnetotactic bacteria (MTB) synthesize intracellular magnetic organelles, magnetosomes, which consist of magnetic crystals that are enveloped in a membrane....  相似文献   

Formation of pristane from α-tocopherol under simulated anoxic sedimentary conditions: A combination of biotic and abiotic degradative processes     

Jean-François Rontani  Mina Nassiry  Valérie Michotey  Sophie Guasco  Patricia Bonin 《Geochimica et cosmochimica acta》2010,74(1):252-14

Incubation of intact and oxidized α-tocopherol (vitamin E) in anaerobic sediment slurries allowed us to demonstrate that, as previously suggested by Goossens et al. (1984), the degradation of α-tocopherol in anoxic sediments results in the formation of pristane. The conversion of α-tocopherol to this isoprenoid alkane involves a combination of biotic and abiotic degradative processes, i.e. the anaerobic biodegradation (which seems to be mainly induced by denitrifying bacteria) of trimeric structures resulting from the abiotic oxidation of α-tocopherol. On the basis of the results obtained, it is proposed that in the marine environment most of the α-tocopherol present in phytoplanktonic cells should be quickly degraded within the water column and the oxic zone of sediments by way of aerobic biodegradation, photo- and autoxidation processes. Abiotic transformation of this compound mainly results in the production of trimeric oxidation products, sufficiently stable to be incorporated into anoxic sediments and whose subsequent anaerobic bacterial degradation affords pristane. These results confirm that the ratio pristane to phytane cannot be used as an indicator of the oxicity of the environment of deposition; in contrast, they support the use of PFI (Pristane Formation Index) as a proxy for the state of diagenesis of sedimentary organic matter.  相似文献   

Identifying sources of groundwater in the lower Colorado River valley, USA, with δ18O, δD, and 3H: implications for river water accounting     

Bradley E. Guay  Christopher J. Eastoe  R. Bassett  Austin Long 《Hydrogeology Journal》2006,14(1-2):146-158

Isotope measurements (¹⁸O, D, ³H) indicate groundwater origin in the Lower Colorado River Valley (LCRV) and provide an alternative, or supplement, to the US Bureau of Reclamations proposed accounting surface method. The accounting surface method uses a hydraulic criterion to identify certain wells away from the flood plain that will eventually yield mainstream Colorado River water. New isotope data for 5 surface-water and 18 groundwater sites around Topock Marsh, Arizona, are compared with river-water data (1974–2002) from 11 sites between Utah and Mexico and with groundwater data from previous LCRV studies. Three groundwater sources are repeatedly identified in the LCRV: (1) local recharge derived from precipitation, usually winter rain, plots slightly below the global meteoric water line (GMWL) and has D values that are 20 greater than those of recent river water; (2) older (pre-1950) upper basin river-water plots on or near the GMWL, distinct from local rainfall and recent river water; and (3) recent (post-1950) Colorado River water, including Topock Marsh samples, plots below the GMWL along an evaporation trend. Large floods, as in 1983, complicate interpretation by routing less evaporated upper basin water into the LCRV; however, tritium content can indicate the age of a water. River-water tritium has declined steadily from its peak of 716 TU in 1967 to about 11 TU in 2002. Mixtures of all three groundwater sources are common.

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Resumen Mediciones isotópicas (¹⁸O, D, ³H) indican cual es el origen del agua subterránea en el Valle Bajo del Río Colorado (LCRV) y aportan una alternativa, o complemento, para el método superficie de conteo propuesto por el Buró de Reclamación de Estados Unidos. El método superficie de conteo utiliza un criterio hidráulico para identificar ciertos pozos alejados de la planicie de inundación que eventualmente producirán agua a partir de la corriente principal del Río Colorado. Los nuevos datos isotópicos para 18 sitios de agua subterránea y 5 sitios de agua superficial cerca de los Pantanos Topock, Arizona, se comparan con datos de agua de río (1974–2002) provenientes de 11 sitios localizados entre Utah y México, y con datos de aguas subterráneas de estudios previos realizados en el LCRV. Se identifican reiteradamente tres fuentes de aguas subterráneas en el LCRV: (1) recarga local derivada de precipitación, generalmente lluvia de invierno, cuya composición cae ligeramente por debajo de la línea de agua meteórica global (GMWL) y tiene valores D que son 20 mayores que los reportados para agua de río reciente; (2) el agua de río más vieja (pre-1950) de la cuenca alta cuya composición cae sobre o cerca de la GMWL, diferente de la lluvia local y del agua de río reciente; (3) agua reciente (post-1950) del Río Colorado, incluyendo muestras de los Pantanos Topock, con composición por debajo de la GMWL a lo largo de una tendencia a la evaporación. Inundaciones grandes, como en 1983, complican la interpretación al transmitir menos agua evaporada de la cuenca alta hacia el LCRV; sin embargo, el contenido de tritio puede indicar la edad del agua. El contenido de tritio en agua de río ha disminuido constantemente desde la concentración pico de 716 TU en 1967 a cerca de 11 TU en 2002. Es común que exista mezclas de las tres fuentes de agua subterránea.

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Résumé Les mesures isotopiques (d18O, dD, 3H) indiquent les origine de leaux souterraines dans la Vallée de la Rivière du Bas Colorado (LCRV) et sont une alternative, ou un supplément, à la méthode des bilans hydrologiques proposée par du «US Bureau of Reclamation». Cette méthode de bilan hydrologique utilise un critère hydraulique permettant didentifier certains puits hors de la plaine dinondation qui pomperaient une part non négligeable de leur eau dans la rivière Colorado. De nouvelles données isotopiques provenant de 5 sites deau de surface et 18 deaux souterraines autour de Topock Marsh en Arizona, sont comparées avec les données (1974–2000) de 11 sites localisés entre Utah et Mexico, ainsi que des données dautres études sur la LCRV. Ces sources deaux souterraines sont identifiées à plusieurs reprises dans la LCRV: (1) la recharge locale dérivant des précipitations, généralement les pluies hivernales, se retrouvent légèrement sous la ligne deau météoritique globale (GMWL) et possède des valeurs de dD 20% supérieures aux valeurs des eaux récentes de la rivière; (2) les eaux vieilles (pre-1950) du bassin supérieur de la rivière possèdent une valeurs très proches de la GMWL, distinctes des valeurs de la pluie locale et des eaux récentes de la rivière; et (3) les eaux récentes (post-1950) de la Rivière Colorado, incluant les échantillons de Topock Marsh, se positionnent à côté de la GMWL sur une droite dévaporation. Les grandes inondations, par exemple celle de 1983, compliquent linterprétation en reprenant dans la LCRV moins deaux marquées comme évaporées et provenant du bassin supérieur; par ailleurs le pic de tritium est descendu de 716 TU en 1967 à 11 TU en 2002. Les mélanges de ces trois sources sont assez fréquentes.

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Spatial observation of the ozone layer     

Sophie Godin-Beekmann 《Comptes Rendus Geoscience》2010,342(4-5):339-348

This article provides an overview of the various satellite instruments, which have been used to observe stratospheric ozone and other chemical compounds playing a key role in stratospheric chemistry. It describes the various instruments that have been launched since the late 1970s for the measurement of total ozone column and ozone vertical profile, as well as the major satellite missions designed for the study of stratospheric chemistry. Since the discovery of the ozone hole in the early 1980s, spatial ozone measurements have been widely used to evaluate and quantify the spatial extension of polar ozone depletion and global ozone decreasing trends as a function of latitude and height. Validation and evaluation of satellite ozone data have been the subject of intense scientific activity, which was reported in the various ozone assessments of the state of the ozone layer published after the signature of the Montreal protocol. Major results, based on satellite observations for the study of ozone depletion at the global scale and chemical polar ozone loss, are provided. The use of satellite observations for the validation of chemistry climate models that simulate the recovery of the ozone layer and in data assimilation is also described.  相似文献