The growth of critical clusters is discussed in the paper according to the classical and molecular dynamics (MD) approaches. A new formula for molecule numbers in critical clusters has been derived within the framework of the classical approach. A set of equations controlling the early stage of growth in a neighborhood of a critical size is presented. As far as molecular dynamics simulation is concerned, a computational technique based on the DL_POLY code is described in brief. Computation results are presented concerning cluster formation of H2O vapor, distribution of clusters versus time, cluster growth and radial density distribution of isolated clusters. A comparison with the classical results is made for a case of dense vapor, where the mechanism of strong condensation is predominant. The Hertz–Knudsen formula seems to be verified by the molecular dynamics results. 相似文献
Summary Energy fluxes have been measured over an area near the centre of the city of Łódź, Poland, since November 2000. The site was
selected because the building style (surface cover and morphology) is typical of European cities, yet distinct from the majority
of cities where energy balance observations have been studied thus far. The multi-year dataset permits consideration of temporal
changes in energy balance partitioning over a wide range of seasonal and synoptic conditions and of the role of heat storage
and anthropogenic fluxes in the energy balance. Partitioning of net radiation into the turbulent fluxes is consistent in the
two years, with the largest differences occurring due to differing precipitation. The monthly ensemble diurnal cycles of the
turbulent fluxes over the two years are similar. The largest differences occur during the July–September period, and are attributable
to greater net radiation and lower rainfall in 2002. The latent heat flux accounts for approximately 40% of the turbulent
heat transfer on an annual basis. The average daily daytime Bowen ratio and its variability are slightly reduced during the
summer (growing) season. Anthropogenic heat is a significant input to the urban energy balance in the winter. The fluxes observed
in this study are consistent with results from other urban sites. 相似文献
Summary Data from two automatic stations in Łódź (one urban and one rural) for the period 1997–2002 are analyzed to reveal urban–rural
contrasts of such parameters as air temperature, relative humidity, water vapour pressure and wind speed. Under favourable
weather conditions the highest temperature differences between the urban and rural station exceeds 8 °C. Relative humidity
is lower in the town, sometimes by more than 40%. Water vapour pressure differences can be either positive (up to 5 hPa) or
negative (up to −4 hPa). Wind speed at the urban station is on average lower by about 34% in night and 39% during daytime.
Regression analysis shows that for rural winds lower than 1.13 m s−1 urban winds can be stronger than rural speeds. Attention has also been paid to singularities in the course of the analyzed
parameters over 24 hour periods. It is shown that the typical course of the urban heat island intensity under favourable conditions
is similar in all season. Four stages of this course have been distinguished. Wind speed differences also seem to change in
a typical way. Case studies show that humidity contrasts, unlike temperature, can evolve in different ways under fine weather
conditions. Types of relative humidity evolution are proposed. 相似文献
The comprehensive biomarker characteristics from previously undescribed Middle Jurassic clays of Poland are presented. The molecular composition of the organic matter (OM) derived from clays of Aalenian to Callovian age has not changed significantly through time. High relative concentrations of many biomarkers typical for terrestrial material suggest a distinct dominance of OM derived from land plants. Increasing concentrations of C29-diaster-13(17)-enes towards the northern part of the basin indicate an increase in terrestrial input. This terrestrial material would have originated from the enhanced transport of organic matter from land situated at the northern bank of the basin, i.e., the Fennoscandian Shield. The organic matter was deposited in an oxic to suboxic environment, as indicated by relatively low concentrations of C33–C35 homohopanes, moderate to high Pr/Ph ratio values, an absence of compounds characteristic for anoxia and water column stratification, such as isorenieratane, aryl isoprenoids and gammacerane, as well as common benthic fauna and burrows. δ18O measurements from calcitic rostra of belemnites suggest that the mean value of the Middle Jurassic sea-water temperature of the Polish Basin was 13.1 °C. It is suggested that this mirrored the temperature of the lower water column because belemnites are considered here to be necto-benthic. The organic matter from the Middle Jurassic basin of Poland is immature. This is clearly indicated by a large concentration of biomarkers with the biogenic configurations, such as ββ-hopanes, hop-13(18)-enes, hop-17(21)-enes, diasterenes and sterenes. The identification of preserved, unaltered biomolecules like ferruginol, 6,7-dehydroferruginol and sugiol in Protopodocarpoxylon wood samples from these sediments present particularly strong evidence for the presence of immature OM in the Middle Jurassic sediments. Moreover, the occurrence of these polar diterpenoids is important due to the fact that they are definitely the oldest known natural products detected in geological samples. 相似文献
Combining Lu–Hf garnet geochronology with in situ trace element analyses in garnet allowed us to gain new insight into the metamorphic evolution of UHP–UHT rocks in the Stary Gierałtów region, in the Polish Sudetes. Prograde garnet growth recorded by Rayleigh-type heavy REE (HREE) zoning in the felsic granulites indicates that the obtained 386.6 ± 4.9 Ma Lu–Hf age represents the time of garnet crystallization on a prograde UHP metamorphic path. The surrounding rocks were metamorphosed at the same time as indicated by 381.2 ± 6.7 Ma Sm–Nd garnet age obtained for the mid-crustal metapelites. The second metamorphic episode, which affected most of the lower crust in the Orlica–Śnieżnik Massif (OSM) occurred at ca. 340 Ma as determined by U–Pb zircon and Sm–Nd garnet dating of granulites in this and previous studies is interpreted as a high temperature event, which took place on a retrograde path.
Trace element distribution in garnets from the layered granulites showed significant differences in distribution of medium and HREE in garnets from mafic and felsic protoliths over the course of the metamorphic evolution. This had strong impact on the isotopic dating results and led to “decoupling” of the Sm–Nd and Lu–Hf clocks, which recorded timing of the two different metamorphic episodes separated by as much as 40 Ma. Moreover, the preservation of the HREE growth zonation profile in garnets from the felsic granulites whose minimum metamorphic temperature was established at 900 °C implies that the Lu–Hf system under relatively dry conditions does not undergo significant diffusional re-equilibration even at such extreme temperatures and therefore it sill provides the age of prograde garnet growth. Under hydrous conditions, at least some resetting will take place, as documented by the partially relaxed HREE zonation profile in the amphibolitised mafic granulite, which yielded a 10 Ma younger age. The HREE distribution study appeared to be a particularly valuable and essential tool, which allowed us to distinguish garnet growth from post-growth complexities and hence, provide improved age interpretation. Medium REE, on the other hand, did not show any obvious correlation with the isotopic signature of garnet.
Two distinct metamorphic episodes recorded in the Stary Gierałtów region show that buoyancy-driven uplift of UHP rocks can be arrested at the base of a continental crust if not supported by any additional force. In our case study, the UHP rocks would have never reached the surface if their uplift had not been resumed after a long pause under a different tectonic regime. The multistage, discontinuous uplift revealed by the UHP rocks of the OSM provides a new scenario for the exhumation of continental crust from mantle depths distinct from the fast-track exhumation histories recognized in UHP terranes elsewhere. 相似文献
In order to assess how the Bonin high affects interannual variability of the East Asian summer monsoon (EASM) around the Korean Peninsula, the pulsation of the Bonin high and its association with teleconnection patterns was examined. The major factor for the interannual intensity of the EASM is the center position of the Bonin high rather than its center pressure. Up to 12 harmonics over time can be used to reconstruct the Bonin high, demonstrating its intraseasonal variation. The interannual variability of the Bonin high correlates with the Tibet high. This correlation is dominant for the EASM onset time, though not its retreat. The primary teleconnection pattern, reliant up on the interannual variability of the Bonin high, is the Western Pacific oscillation (WPO) in April. In relation to long-term variability, the correlation between the WPO and the Bonin high appears to contribute to the retreat stage of the EASM, which has itself increased since the mid-1970s. Furthermore, the WPO in May and the Tibet correlation has marked the onset rather than the retreat of the EASM since the 1970s. This highly correlated pattern since the mid-1970s may be the result of El Niño. 相似文献
In view of the small size of most Polish farms, attempts have been made to encourage diversification into rural tourism. The
paper examines the progress made in Lower Silesia which has good resources for domestic and international tourism. Thanks
to the promotional work of the Agricultural Consultative Centres over a hundred farms are now providing services. They do
not generate a large share of the farm income but business is expanding and some areas are becoming very popular. Thus a base
has been established for future expansion. Further development depends on easier access to credit and government support for
ecological agriculture. Better promotion is also needed to increase interest in rural tourism in Poland and attract more visitors
from abroad.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献