Structural and thermodynamic signatures of marine microlayer surfactant films     

Stanislaw J. Pogorzelski  Anna D. Kogut 《Journal of Sea Research》2003,49(4):347

Natural surface film experiments in inland waters and shallow offshore regions of the Baltic and Mediterranean Seas were carried out in the time period 1990–1999 under calm sea conditions using a novel device for sampling and force-area studies. The sampler-Langmuir trough-Wilhelmy filter paper plate system ‘cuts out’ an undisturbed film-covered sea area to perform π-A studies without any initial physico-chemical sample processing. The limiting specific area A_lim (2.68–31.57 nm²/molecule) and mean molecular mass M_w (0.65–9.7 kDa) of microlayer surfactants were determined from the 2D virial equation of state applied to the isotherms. Enthalpy ΔH and entropy ΔS_t of the 2D first-order phase transitions were evaluated using the Clausius-Clapeyron equation applied to the isotherms. Miscibility of film components and film structure evolution is expressed by the scaling exponent y adopting the 2D polymer film scaling theory. The stress-relaxation measurements revealed a two-step relaxation process at the interface with characteristic times τ₁=1.1–2.8 and τ₂=5.6–25.6 seconds suggesting the presence of diffusion-controlled and structural organisation relaxation phenomena. The obtained results suggest that natural films are a complex mixture of biomolecules covering a wide range of solubilities, surface activity and molecular masses with an apparent structural organisation exhibiting a spatial and temporal variability.  相似文献   

Mineral resources inventory in the northern part of haiti: A basic rationale for selecting areas of potential mining interest     

Gaston Georges Jr.  Claude Lepeltier  Pierre Nicolini  Stanislaw Przenioslo 《Mathematical Geology》1978,10(5):629-636

Agriculture has always been the major source of income of the Republic of Haiti. Only in the late sixties did the Haitian Government decide to move toward industrialization and explotation of natural resources, but no reliable inventory of mineral potential was available. In June 1970 the Resources and Transport Division of the U.N. (now CNRET) undertook a structural analysis of the Caribbean with reference to defining favorable loci for ore disposition. One of the conclusions of this survey was that from the metallogenetic point of view, the Northern part of Haiti was a favorable area for prospecting for habe metal deposits, especially for copper. Those conclusions were acknowleadged with great enthusiams by the Haitian authorities, and they welcomed in July 1971 a UN technical adviser who outlined a first phase of exploration. Following this mission, a “Mineral exploration Project” was created by the Haitian Government with the cooperation of UNDP, and an area of 9000 km² was selected, based on structural, lithological, and metallogenetic reasons, as an exploration target. The most important aspects of this project were:Mineral Exploration—First Phase (1973–1974). The following operations were carried out by a small team: (a) photo interpretation at 1:50,000 and 1:200,000 scale, (b) geological reconnaissance at 1:50,000 scale, (c) geochemical reconnaissance (stream sediment) at 1:50,000 scale. The photo interpretation helped outline zones of particular structural interest and was followed up by ground control studies. Stream sediment geochemical reconnaissance was carried out over half of the project area, following the indications given by the photo geological interpretation. finally, combining all the data, five areas were selected for detailed follow up survey: (1) Terrier Rouge—Perche, (2) Vallieres, (3) Mont-Organise, (4) Limonade, (5) Gros Morne—Le Borgne.Mineral Exploration—Second Phase (1975–1976). The main zones of interest were reduced to a few hundred km² and porphyry copper type deposits appeared to be the most promising target. Detailed geological mapping (1:25,000 to 1:2,000) and soil geochemistry were carried out on the above mentioned five areas, the most promising appearing quickly to be Terrier Rouge-Perges, with porphyry-type copper mineralization. A geophysical survey (IP and Mag) confirmed the geochemical results. At the end of the second phase of exploration (December 1976) two of the five prospects of the Terrier Rouge area have been diamond drilled and appeared to be of potential economic interest. Because of the number and importance of the prospects discovered a third phase of exploration was deemed necessary with the purpose of continuing the detailed prospection work and drilling the other prospects. This third phase started in January 1977 and was expected to last until December 1979. This paper was presented at the International Geological Correlation Program (IGCP) Project 98: “Standards for Computer Applications in Resource Studies” held at Taita Hills, Kenya, November 8–15, 1977.  相似文献   

Non-parametric Seismic Hazard in Mines     

A. Kijko  S. Lasocki  G. Graham 《Pure and Applied Geophysics》2001,158(9-10):1655-1675

— Seismic hazard analysis methods in mines are reviewed for the purpose of selecting the best technique. To achieve this goal, the most often-used hazard analysis procedure, which is based on the classical frequency-magnitude Gutenberg-Richter relation, as well as alternative procedures are investigated.¶Since the maximum regional seismic event magnitude m _max is of paramount importance in seismic hazard analysis, this work provides a generic formula for the evaluation of this important parameter. The formula is capable of generating solutions in different forms, depending on the assumptions of the model of the magnitude distribution and/or the available information regarding past seismicity. It includes the cases (i) in which seismic event magnitudes are distributed according to the truncated frequency-magnitude Gutenberg-Richter relation, and (ii) in which no specific model of the magnitude distribution is assumed.¶Both synthetic, Monte-Carlo simulated seismic event catalogues, and actual data from the copper mine in Poland and gold mine in South Africa, are used to demonstrate the discussed hazard analysis techniques.¶Our studies show that the non-parametric technique, which is independent of the assumed model of the distribution of magnitude, provides an appropriate tool for seismic hazard assessment in mines where the magnitude distribution can be very complex.  相似文献   

Evaluation of rock-mass state in Polish copper mines through monitoring the borehole deformations     

Stanislaw Orzepowski  Jan Butra   《Tectonophysics》2008,456(1-2):52

Sensors for borehole deformation measurements in mining panel roofs, as well as a method of high-energy tremors risk evaluation, based on borehole deformation monitoring are described. There are differences in manners in which borehole deformation takes place prior to a high-energy tremor. A method for rock-mass instability detection in copper mining panels is developed and described, as well as a practical procedure for forecasting the rock-mass state. On the basis of 1351 “real time” forecasts made in the 10 copper mine panels during 5451 days and on the basis of the 55 high-energy tremors occurred, the evaluation of forecast effectiveness is presented. The mean chance value of occurrence of the high-energy tremor after a rock-mass stability forecast was evaluated as 1% and after a rock-mass instability forecast, as 20%.  相似文献   

Russian cross-border shopping tourists in the Finnish and Polish borderlands     

Dominika Studzińska  Alena Sivkoz  Stanislaw Domaniewski 《Norsk geografisk tidsskrift. Norwegian journal of geography》2018,72(2):115-126

Cross-border shopping and tourism are worldwide phenomena, appearing at any border with at least some degree of permeability. The authors investigate the range of cross-border shopping and tourism activities practised by Russians at two of the EU’s external borders, one between Finland and the Leningrad Oblast, and the other between Poland and the Russian exclave of Kaliningrad Oblast. The study is based on research conducted in the Polish–Russian and Finnish–Russian border regions between 2013 and 2015, when the authors held interviews, administered survey questionnaires, and engaged in participant observation. The information was supplemented with data from the Finnish and Polish Border Guard services. Based on the results of the fieldwork, the authors argue that cross-border shopping and tourism are often combined during the same trip, and thus constitute a specific form of cross-border activity. Their study sheds light on how cross-border shopping tourism depends on and is interconnected with more than just the factor of the non-availability of goods and services. They conclude that cross-border shopping at the Polish–Russian border and the Finnish–Russian border has become more like a Western European practice, namely shopping for pleasure.  相似文献   

The use of deep-water agglutinated Foraminifera in correlating Lower Cretaceous pelagic and flysch sequences: current status and prospects for the future     

Michael A. Kaminski  Stanislaw Geroch 《Cretaceous Research》1992,13(5-6)

Deep-water agglutinated Foraminifera (DWAF) display potential for correlating pelagic (calcareous and non-calcareous) and flysch environments. This is illustrated by an example from Sites 765 and 261 on the Argo Abyssal Plain. A working zonation based on DWAF has been developed for Lower Cretaceous flysch sequences of the Polish Carpathians, but this zonal scheme has not been tested in other areas of the Tethys. No zonation has yet been developed for abyssal oceanic DWAF. The challenge for the future, under the auspices of Project 262, is to test the existing zonation in other regions and develop a widely applicable biochronology for integration into a general Tethyan biochronological correlation scheme.  相似文献   

Refinements in BaSO₄ to CO₂ Preparation and δ¹⁸ O Calibration of the Sulfate Reference Materials NBS-127, IAEA SO-5 and IAEA SO-6     

Stanislaw Halas  Janina Szaran  Maciej Czarnacki  Ahmad Tanweer 《Geostandards and Geoanalytical Research》2007,31(1):61-68

Refinements have been made to achieve over 99% yield in the conversion of CO to CO₂ in order to improve the reproducibility and accuracy of δ¹⁸ O measurements in sulfates. BaSO₄ (10-15 mg) was mixed with an identical amount of spectrographic-grade graphite and loaded into a Pt boat. The mixture was gradually heated to 1100 °C to reduce sulfate to CO and CO₂; the former gas was simultaneously converted to CO₂ by a glow discharge between Pt electrodes immersed in a magnetic field (produced by a pair of external neodymium magnets). A small memory effect was noticed during the analysis (less than 0.3‰ per 10‰ difference in δ¹⁸ O between two subsequently analysed samples). The memory effect, however, was suppressed by repetitive preparation of the same specimen. CO₂ produced in this way from sulfate reference samples was analysed on a dual inlet and triple collector mass spectrometer along with CO₂ equilibrated with VSMOW, GISP and SLAP water reference samples. To avoid large departures of measured isotope ratios from ¹⁸O/¹⁶O of the working calibrator we used CO₂ gas prepared from ocean water sulfate for this purpose. The calibrated δ¹⁸ O values (in ‰) obtained in this way for NBS-127, IAEA SO-5 and IAEA SO-6 reference materials were 8.73 ± 0.05, 12.20 ± 0.07 and -10.43 ± 0.12, respectively.  相似文献   

The Effect of Particulate Matter Components on the Acidity of Rain in Upper Silesia (Poland)     

Stanislaw Hlawiczka  Katarzyna Korszun 《洁净——土壤、空气、水》2012,40(7):673-680

Analysis of data characterizing the chemical composition of atmospheric precipitation was presented, with an emphasis on components responsible for neutralization of rain acidity. For this purpose, chemometric methods were applied. Based on a principal component analysis (PCA) a strong correlation between precipitation pH and potassium and ammonium ions in the heating period (October–March) and potassium and sodium ions in the non‐heating period (April–September) was observed. Additionally, a classification of eight variables, i.e., Na⁺, K⁺, Mg²⁺, Ca²⁺, , , Cl^?, and according to their similarities was made using a cluster analysis. Based on this study, two ions, potassium and ammonium, together with the pH value were classified into one group (cluster) in the heating period while in the non‐heating period ions of potassium and sodium were clustered together with the pH. The results of the cluster analysis indicated that the selected ions contributed the most to the neutralization of the atmospheric precipitation acidity. This relationship was confirmed by a discriminant analysis in which potassium and ammonium ions were selected as components of the highest potential for precipitation classification according to its acidity degree. The relationship between the precipitation pH and the number of non‐precipitation days preceding the precipitation was also analyzed. It was found that although the observed an increase of the pH value was not very high, nevertheless, the effect of the duration of the period preceding the precipitation on the pH value recorded on the day of the precipitation occurrence was quite evident.  相似文献   

Studies of short and long memory in mining-induced seismic processes     

Stanisław Węglarczyk  Stanisław Lasocki 《Acta Geophysica》2009,57(3):696-715

Memory of a stochastic process implies its predictability, understood as a possibility to gain information on the future above the random guess level. Here we search for memory in the mining-induced seismic process (MIS), that is, a process induced or triggered by mining operations. Long memory is investigated by means of the Hurst rescaled range analysis, and the autocorrelation function estimate is used to test for short memory. Both methods are complemented with result uncertainty analyses based on different resampling techniques. The analyzed data comprise event series from Rudna copper mine in Poland. The studies show that the interevent time and interevent distance processes have both long and short memory. MIS occurrences and locations are internally interrelated. Internal relations among the sizes of MIS events are apparently weaker than those of other two studied parameterizations and are limited to long term interactions.  相似文献   

New terrestrial heat flow map of Europe after regional paleoclimatic correction application     

Jacek Majorowicz  Stanislaw Wybraniec 《International Journal of Earth Sciences》2011,100(4):881-887

Heat flow variations with depth in Europe can be explained by a model of surface temperature changes >10°C. New heat flow map of Europe is based on updated database of uncorrected heat flow values to which paleoclimatic correction is applied across the continent. Correction is depth dependent due to a diffusive thermal transfer of the surface temperature forcing of which glacial–interglacial history has the largest impact. It is obvious that large part of the uncorrected heat flow values in the existing heat flow databases from wells as shallow as few hundreds of meters is underestimated. This explains some very low uncorrected heat flow values 20–30 mW/m² in the shields and shallow basin areas of the craton. Also, heat flow values in other areas including orogenic belts are likely underestimated. Based on the uncorrected and corrected heat flow maps using 5 km × 5 km grid, we have calculated average heat flow values (uncorrected heat flow: 56.0 mW/m²; SD 20.3 mW/m² vs. corrected heat flow: 63.2 mW/m²; SD 19.6 m/Wm²) and heat loss for the continental part. Total heat loss is 928 E09 W for the uncorrected values versus corrected 1050 E09 W.  相似文献