Release of toxic elements from rocks and mine wastes at the Furtei gold mine (Sardinia, Italy)     

Stefania Da Pelo  Elodia Musu  Rosa Cidu  Franco Frau  Pierfranco Lattanzi 《Journal of Geochemical Exploration》2009,100(2-3):142-152

The Furtei gold mine in Sardinia (Italy) exploits a volcanic-hosted high-sulphidation epithermal deposit. Large amounts of materials derived from exploitation are present in open pits, waste rock dumps and cyanidation tailings impoundment. Mineralized rocks in outcrops and waste dumps contain significant amounts of sulphides (mainly pyrite and enargite). These materials have a high potential for acid drainage generation and release of toxic elements (notably Cu and As, but also Al, Ni, Co and Cd) as pointed out by laboratory leaching tests and in agreement with chemical composition of waters draining the mining area, that show pH as low as 2, up to 180 mg/L Cu, up to 5 mg/L As, and up to 788 mg/L Al. On the other hand, leaching solutions and waters interacting with mineral assemblages of the propylitic alteration zone (mainly composed of chlorite, quartz, and calcite, with relic magmatic plagioclase) show higher pH, and lower metal loads. Leachates from cyanidation tailings show variable pH (between 6.2 and 9.7, depending on sulphide content in tailings); cyanide concentration varies between 110 µg/L and about 3 mg/L, whereas contents of toxic elements in leachates are, with the exception of Hg, within the limits of Italian regulations for non-dangerous industrial wastes. Reclamation plans provide for confinement of tailings within specific repositories. This measure should effectively reduce the environmental impact of these materials. Reclamation plans should also include an adequate management of other high-sulphide wastes.  相似文献   

Distinctive Volcanic Material for the Production of Campana A Ware: The Workshop Area of Neapolis at the Duomo Metro Station in Naples,Italy     

Alberto De Bonis  Stefania Febbraro  Chiara Germinario  Daniela Giampaola  Celestino Grifa  Vincenza Guarino  Alessio Langella  Vincenzo Morra 《Geoarchaeology》2016,31(6):437-466

Recent transportation infrastructure works in Naples, Italy, provided important discoveries related to the production of pottery in the Hellenistic workshop area of Piazza Nicola Amore. A minero‐petrographic investigation was conducted on 35 samples belonging to the widespread Campana A ware and production indicators (clayey raw materials, unfired Graeco‐Italic amphorae, kiln wastes, workshop tools). Additional analysis was conducted on black‐glaze and common ware samples for comparison. The analyses reveal compositional and technological homogeneity of Campana A ware. Samples are characterized by low CaO content with evidence of both volcanic and sedimentary components, suggesting that different clay sources were properly mixed to prepare a standard recipe. Production indicators, black‐glaze and common wares, have a composition well consistent with the calcareous clays from the island of Ischia. Leucite‐ and garnet‐bearing temper from the Somma Volcano were used for the preparation of coarse‐grained pastes, unfired Graeco‐Italic amphorae, and clayey raw materials, thus suggesting that they represented the clay sources for amphorae production. Our results reveal new technological and socioeconomic aspects of Hellenistic pottery production in the Bay of Naples, in particular for the Campana A ware, now representing a new reference group: Neapolis.  相似文献   

Relative contribution of foliar and fine root pine litter to the molecular composition of soil organic matter after in situ degradation   总被引：1，自引：0，他引：1  

Stefania Mambelli  Jeffrey A. Bird  Gerd Gleixner  Todd E. Dawson  Margaret S. Torn 《Organic Geochemistry》2011,42(9):1099-1108

The influence of litter quality on soil organic matter (SOM) stabilization rate and pathways remains unclear. We used ¹³C/¹⁵N labeled litter addition and Curie-point pyrolysis gas chromatography–mass spectrometry combustion-isotope ratio mass spectrometry (Py–GC–MS–C–IRMS) to explore the transformation of litter with different composition and decay rate (ponderosa pine needle vs. fine root) to SOM during 18 months in a temperate conifer forest mineral (A horizon) soil. Based on ¹³C Py–GC–MS–C–IRMS the initial litter and bulk soil had ∼1/3 of the total pyrolysis products identified in common. The majority was related either to carbohydrates or was non-specific in origin. In bulk soil, carbohydrates had similar levels of enrichment after needle input and fine root input, while the non-specific products were more enriched after needle input. In the humin SOM fraction (260 yr C turnover time) we found only carbohydrate and alkyl C-derived compounds and greater ¹³C enrichment in the “carbohydrate” pool after fine root decomposition. ¹⁵N Py–GC–MS–C–IRMS of humic substances showed that root litter contributed more than needle litter to the enrichment of specific protein markers during initial decomposition.We found little evidence for the selective preservation of plant compounds considered to be recalcitrant. Our findings suggest an indirect role for decomposing plant material composition, where microbial alteration of fine root litter seems to favor greater initial stabilization of microbially derived C and N in SOM fractions with long mean turnover times, such as humin, compared to needles with a faster decay rate.  相似文献   

On the reliability of the equivalent frame models: the case study of the permanently monitored Pizzoli’s town hall     

Degli Abbati  Stefania  Morandi  Paolo  Cattari  Serena  Spacone  Enrico 《Bulletin of Earthquake Engineering》2022,20(4):2187-2217

Bulletin of Earthquake Engineering - This paper presents the comparison of the results of modal and nonlinear analyses carried out on a 2-story masonry building with rigid diaphragms, inspired by...  相似文献   

HTLP metamorphism and fluid-fluxed melting during multistage anatexis of continental crust (N Sardinia,Italy)     

Leonardo Casini  Matteo Maino  Antonio Langone  Giacomo Oggiano  Stefania Corvò  Joan Reche Estrada  Montserrat Liesa 《Journal of Metamorphic Geology》2023,41(1):25-57

The Variscan high-grade metamorphic basement of northern Sardinia and southern Corsica record lower Carboniferous anatexis related to post-collisional decompression of the orogen. Migmatites exposed in the Punta Bianca locality (Italy) consist of quartz + biotite + plagioclase + K-feldspar orthogneisses, garnet and cordierite-bearing diatexite and metatexites, derived from metasediments. Field evidence, petrographic observations, ELA-ICP-MS zircon and monazite dating and pseudosection modelling suggest that anatexis was apparently episodic involving two main stages of partial melting. Using pseudosection modelling, we infer that the first stage of partial melting is in the upper amphibolite facies (~0.45 GPa at ~740°C). Cordierite overgrowths replacing sillimanite, combined with the composition of plagioclase and K-feldspar, suggest decompression followed cooling below the solidus at low pressures of ~0.3 GPa. The age of the first anatectic event is not precisely constrained because of extensive resetting of the isotopic systems during the second melting stage, yet few zircons preserve a lower Carboniferous age which is consistent with the regional dataset. This lower Carboniferous migmatitic fabric is offset by a network of pseudotachylyte-bearing faults suggestive of cooling to greenschist facies conditions. Garnet/cordierite-bearing diatexites incorporate fragments of pseudotachylite-bearing orthogneiss and metatexites. Pseudosection modelling indicates nearly isobaric re-heating up to ~750°C, followed by further cooling below the solidus. The inferred P–T path is consistent with decompression and cooling of the Variscan crust through post-collisional extension and collapse of the thickened orogenic crust, followed by nearly isobaric re-heating at low pressures (~0.3 GPa) yielding to a second melting stage under LP-HT conditions. U/Th-Pb monazite ages for diatexite migmatites indicate an upper bound of 310–316 Ma for the second melting stage, suggesting that the second melting stage is coincident with the regional phase of crustal shearing. The cause of the high geothermal gradient required for re-heating during the second melting stage is unknown but likely requires some heat source that was probably related to dissipation of mechanical work within crustal-scale shear zones. According to this interpretation, some upper Carboniferous peraluminous granite precursors of the Corsica–Sardinia Batholith could be the outcome rather than the cause of the late-Variscan high-T metamorphism.  相似文献   

Groundwater vulnerability maps derived from a time-dependent method using satellite scatterometer data     

Stefania Stevenazzi  Marco Masetti  Son V. Nghiem  Alessandro Sorichetta 《Hydrogeology Journal》2015,23(4):631-647

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One Year of Surface-Based Temperature Inversions at Dome C, Antarctica     

Ilaria Pietroni  Stefania Argentini  Igor Petenko 《Boundary-Layer Meteorology》2014,150(1):131-151

In 2005 the Study of Stable Boundary Layer Environment at Dome C (STABLEDC) experimental campaign was conducted at the plateau station of Concordia at Dome C, Antarctica. Temperature profiles measured with a microwave radiometer were used to study the characteristics of surface-based temperature inversions over the course of a year. Statistics of temperature profiles for every month are discussed; the difference between daytime and nocturnal cases observed during the summer months disappears during winter. Surface-based temperature inversions occurred in 70 % of the time during summer, and almost all of the time during winter. During winter the occurrence of warming events leads to a decrease in the temperature difference between the top and the base of the inversion (i.e. the inversion strength). The inversion strength maxima ranged between $3\,^{\circ }\mathrm{C}$ (December) and $35\,^{\circ }\mathrm{C}$ (August) corresponding to gradients of 0.1 and $0.3\,^{\circ }\mathrm{C}\, \mathrm{m}^{-1}$ , respectively. The average surface-based inversion height presents a daily cycle during the summer months with values up to 200 m in the morning hours, while it affects a layer always deeper than 100 m during the winter months. The relationships between inversion strength and the downward longwave radiative flux, absolute temperature, and wind speed are examined. The inversion strength decreases as the longwave radiation increases. A clear anti-correlation between inversion strength and near-surface temperature is evident throughout the year. During the winter, the largest inversion strength values were observed under low wind-speed conditions; in contrast, a clear dependence was not found during the summer.  相似文献   

Erratum to: Observed and Modelled Convective Mixing-Layer Height at Dome C,Antarctica     

Giampietro Casasanta  Ilaria Pietroni  Igor Petenko  Stefania Argentini 《Boundary-Layer Meteorology》2014,153(1):163-164

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Conditional versus unconditional industrial agglomeration: disentangling spatial dependence and spatial heterogeneity in the analysis of ICT firms’ distribution in Milan     

Giuseppe Espa  Giuseppe Arbia  Diego Giuliani 《Journal of Geographical Systems》2013,15(1):31-50

A series of recent papers have introduced some explorative methods based on Ripley’s K-function (Ripley in J R Stat Soc B 39(2):172–212, 1977) analyzing the micro-geographical patterns of firms. Often the spatial heterogeneity of an area is handled by referring to a case–control design, in which spatial clusters occur as over-concentrations of firms belonging to a specific industry as opposed to the distribution of firms in the whole economy. Therefore, positive, or negative, spatial dependence between firms occurs when a specific sector of industry is seen to present a more aggregated pattern (or more dispersed) than is common in the economy as a whole. This approach has led to the development of relative measures of spatial concentration which, as a consequence, are not straightforwardly comparable across different economies. In this article, we explore a parametric approach based on the inhomogeneous K-function (Baddeley et al. in Statistica Nederlandica 54(3):329–350, 2000) that makes it possible to obtain an absolute measure of the industrial agglomeration that is also able to capture spatial heterogeneity. We provide an empirical application of the approach taken with regard to the spatial distribution of high-tech industries in Milan (Italy) in 2001.  相似文献   

Zonal jets and cyclone–anticyclone asymmetry in decaying rotating turbulence: laboratory experiments and numerical simulations     

Stefania Espa  Isabella Bordi  Thomas Frisius  Klaus Fraedrich  Antonio Cenedese  Alfonso Sutera 《地球物理与天体物理流体动力学》2013,107(6):557-573

The problem of zonal jet formation and cyclone–anticyclone asymmetry in decaying rotating turbulence is addressed using both laboratory experiments and numerical simulations with a high-resolution shallow water model in a spherical geometry. Experiments are performed at different Rossby and Froude numbers and applying a rigid wall as meridional boundary in the numerical scheme to mimic the experimental apparatus. The formation of a zonally banded flow pattern, i.e. meridionally confined easterly/westerly jets, has observed; both experimental and numerical results confirmed that this tendency is favoured by high-planetary vorticity gradients. Also, in the experiments characterized by large rotation speeds and small Rossby deformation radius, an initial symmetric distribution of relative vorticity is found to evolve towards a dominance of anticyclonic structures, indicating a breaking of the cyclone–anticyclone symmetry. This aspect has deepened by numerically analysing the sensitivity of the temporal variations of the asymmetry index with respect to the position of the meridional confinement as well as the effect of relaxing the divergence of the fluid (i.e. non-divergent case) to zero. Results suggested that experiments characterized by the higher rotation speed and the lower fluid thickness are better reproduced by a divergent model with a high-latitude meridional boundary.  相似文献