Calcium promotes cadmium elimination as vaterite grains by tobacco trichomes   总被引：1，自引：0，他引：1  

Marie-Pierre Isaure  Géraldine Sarret  Yong-Eui Choi  Sirine C. Fakra  Sébastien Pairis  Stephan Clemens  Alain Manceau 《Geochimica et cosmochimica acta》2010,74(20):5817-5834

In tobacco plants, elimination of Zn and Cd via the production of Ca-containing grains at the top of leaf hairs, called trichomes, is a potent detoxification mechanism. This study examines how Cd is incorporated in these biominerals, and how calcium growth supplement modifies their nature. Scanning electron microscopy coupled with energy dispersive X-ray microanalysis (SEM-EDX), microfocused X-ray diffraction (μ-XRD), and microfocused X-ray absorption near edge structure (μ-XANES) spectroscopy were used to image the morphology of the grains, identify the crystallized mineral phases, and speciate Cd, respectively. The mineralogy of the grains and chemical form of Cd varied with the amount of Ca. When tobacco plants were grown in a nutrient solution containing 25 μM Cd and low Ca supplement (Ca/Cd = 11 mol ratio), most of the grains were oblong-shaped and low-Cd-substituted calcite. When exposed to the same amount of Cd and high Ca supplement (Ca/Cd = 131 mol ratio), grains were more abundant and diverse in compositions, and in total more Cd was eliminated. Most grains in the high Ca/Cd experiment were round-shaped and composed predominantly of Cd-substituted vaterite, a usually metastable calcium carbonate polymorph, and subordinate calcite. Calcium oxalate and a Ca amorphous phase were detected occasionally in the two treatments, but were devoid of Cd. The biomineralization of cadmium and implications of results for Cd exposure of smokers and phytoremediation are discussed.  相似文献   

Simulations of accidental coal immersion     

Jaffrennou C  Giamarchi P  Cabon JY  Stephan L  Burel-Deschamps L  Bautin F  Thomas A  Dumont J  Le Floch S 《Marine pollution bulletin》2007,54(12):1932-1939

Coal is currently becoming an increasingly interesting fossil energy resource and that is the reason why its maritime transport, and hence the risk of collier accidents, increase. In this work, the environmental impact of an accidental coal immersion at sea is studied: the physicochemical effects are estimated using innovative experimental setups – a laboratory seawater canal called “polludrome” is used to evaluate the behaviour of coal particles submitted to a seawater flow, and a specifically designed tub is used to study the physicochemical consequences induced when coal is introduced into continuously renewed seawater. When coal is introduced into seawater, the most easily visible consequences are physical: fine coal particles reduce the daylight penetration up to 100% and move along with the flow, and coal chunks accumulate on the floor. Chemical effects are also measured: humic matters are dissolved from coal into seawater (up to 2 mg L⁻¹), but no release of polycyclic aromatic hydrocarbons is evidenced. Some inorganic compounds are dissolved, among which manganese, whose concentrations can reach 1 μg L⁻¹. Fortunately, the results show that the environmental impact of this type of accident would remain limited.  相似文献   

Determination of particulate organic carbon (POC) in seawater: The relative methodological importance of artificial gains and losses in two glass-fiber-filter-based techniques   总被引：1，自引：0，他引：1  

Robert Turnewitsch  Barbara M. Springer  Konstadinos Kiriakoulakis  Juan Carlos Vilas  Javier Arístegui  George Wolff  Florian Peine  Stephan Werk  Gerhard Graf  Joanna J. Waniek 《Marine Chemistry》2007,105(3-4):208-228

Particulate matter in aquatic systems is an important vehicle for the transport of particulate organic carbon (POC). Its accurate measurement is of central importance for the understanding of marine carbon cycling. Previous work has shown that GF/F-filter-based bottle-sample-derived concentration estimates of POC are generally close to or higher than large-volume in-situ-pump-derived values (and in some rare cases in subzero waters are up to two orders of magnitude higher). To further investigate this phenomenon, water samples from the surface and mid-water Northeast Atlantic and the Baltic Sea were analyzed. Our data support a bias of POC concentration estimates caused by adsorption of nitrogen-rich dissolved organic material onto GF/F filters. For surface-ocean samples the mass per unit area of exposed filter and composition of adsorbed material depended on the filtered volume. Amounts of adsorbed OC were enhanced in the surface ocean (typically 0.5 μmol cm^− 2 of exposed filter) as compared to the deep ocean (typically 0.2 μmol cm^− 2 of exposed filter). These dependencies should be taken into account for future POC methodologies. Bottle/pump differences of samples that were not corrected for adsorption were higher in the deep ocean than in the surface ocean. This discrepancy increased in summer. It is shown that POC concentration estimates that were not corrected for adsorption depend not only on the filtered volume, true POC concentration and mass of adsorbed OC, but also on the filter area. However, in all cases we studied, correction for adsorption was important, but not sufficient, to explain bottle/pump differences. Artificial formation of filterable particles and/or processes leading to filterable material being lost from and/or missed by sample-processing procedures must be considered. It can be deduced that the maximum amounts of POC and particulate organic nitrogen (PON) that can be artificially formed per liter of filtered ocean water are  3–4 μM OC (5–10% of dissolved OC) and  0.2–0.5 μM ON (2–10% of dissolved ON), respectively. The relative sensitivities of bottle and pump procedures, and of surface- and deep-ocean material, to artificial particle formation and the missing/losing of material are evaluated. As present procedures do not exist to correct for all possible biasing effects due to artificial particle formation and/or miss/loss of filterable material, uncertainties of filtration-based estimates of POC concentrations need further testing. The challenge now is to further constrain the magnitude of the biasing effects that add to the adsorption effect to reduce the uncertainties of estimates of POC concentrations, inventories and fluxes in the ocean.  相似文献   

Results from the first ballast water sampling study in the Mediterranean Sea - the Port of Koper study     

David M  Gollasch S  Cabrini M  Perkovic M  Bosnjak D  Virgilio D 《Marine pollution bulletin》2007,54(1):53-65

The ongoing transfer of harmful organisms by shipping, especially via ballast water transport, may result in a change of biodiversity, alteration of ecosystems, negative impacts on human health and economic loss. Species introductions which cause irreversible consequences to receiving environments and economies call for particular attention. One critical issue is a need to evaluate the quantities and processes of species introductions. Consequently ballast water was sampled on 15 ships calling at the Port of Koper, Slovenia. This was the first ballast water sampling study in the Mediterranean Sea. This paper summarises the sampling results. Samples were analysed for all types of aquatic organisms including bacteria. The results may be considered as background information for an initial risk assessment of future species introductions - an important tool for the implementation of ballast water management measures.  相似文献   

Geology of Mars after the first 40 years of exploration     

Angelo Pio Rossi  Stephan van Gasselt 《中国天文和天体物理学报》2010,10(7)

The knowledge of Martian geology has increased enormously in the last 40 yr. Several missions orbiting or roving Mars have revolutionized our understanding of its evolution and geological features, which in several ways are similar to Earth, but are extremely different in many respects. The impressive dichotomy between the two Martian hemispheres is most likely linked to its impact cratering history, rather than internal dynamics such as on Earth. Mars' volcanism has been extensive, very long-lived and rather constant in its setting. Water was available in large quantities in the distant past of Mars, when a magnetic field and more vigorous tectonics were active.Exogenic forces have been shaping Martian landscapes and have led to a plethora of landscapes shaped by wind, water and ice. Mars' dynamical behavior continues, with its climatic variation affecting climate and geology until very recent times. This paper tries to summarize major highlights in Mars' Geology, and points to deeper and more extensive sources of important scientific contributions and future exploration.  相似文献   

Eocene fauna of Messel Pit Fossil Site, Germany     

Stephan Schaal 《东北亚地学研究》2005,(Z1)

The paper reports sunthetically the Cocene fauna of the Messel Pit Fossil site of Germany, in detail, including its rich taxanomic compositions, geological and paleogeographic backgroud, and the studying and applying history.  相似文献   

The retention of ammonia and sulfur dioxide during riming of ice particles and dendritic snow flakes: laboratory experiments in the Mainz vertical wind tunnel     

Nadine v. Blohn  Karoline Diehl  Anke Nölscher  Alexander Jost  Subir K. Mitra  Stephan Borrmann 《Journal of Atmospheric Chemistry》2013,70(2):131-150

Laboratory experiments were carried out in the Mainz vertical wind tunnel to determine the retention of the trace gases ammonia and sulfur dioxide dissolved in supercooled cloud droplets during riming. The conditions during riming were similar to the ones in atmospheric mixed phase clouds: temperatures from ?18 °C to ?5 °C, liquid water contents between 1 and 1.5 g m^?3, liquid drop radii between 10 and 20 μm, liquid phase concentrations from 1 to 22 mg/l. As collectors, floating ice particles and snow flakes with diameters between 6 mm and 1.5 cm were used. After riming the retention coefficients, i.e. the fractions of the species which remained in the ice phase after freezing were determined. Retention coefficients lying between 0.1 and 1.0 were measured depending on the solubility and dissociation of the trace gas, liquid phase concentration, ambient air temperature, and shape of rimed collector. This can be explained from the chemists’ point of view by the effective Henry’s law constant of the species and physically with the rate of latent heat removal from the rimed collector during freezing. Parameterizations derived from the different experimental cases describe the retention coefficients as a function of temperature. In general, an average retention of ammonia of 92?±?21 % was determined independently of liquid phase concentration while mean values for sulfur dioxide were 53?±?10 % at low liquid phase concentrations and 29?±?7 % at high liquid phase concentrations.  相似文献   

Local and regional minimum 1D models for earthquake location and data quality assessment in complex tectonic regions: application to Switzerland   总被引：1，自引：0，他引：1  

Stephan Husen  Edi Kissling  John F. Clinton 《Swiss Journal of Geoscience》2011,104(3):455-469

One-dimensional (1D) velocity models are still widely used for computing earthquake locations at seismological centers or in regions where three-dimensional (3D) velocity models are not available due to the lack of data of sufficiently high quality. The concept of the minimum 1D model with appropriate station corrections provides a framework to compute initial hypocenter locations and seismic velocities for local earthquake tomography. Since a minimum 1D model represents a solution to the coupled hypocenter-velocity problem it also represents a suitable velocity model for earthquake location and data quality assessment, such as evaluating the consistency in assigning pre-defined weighting classes and average picking error. Nevertheless, the use of a simple 1D velocity structure in combination with station delays raises the question of how appropriate the minimum 1D model concept is when applied to complex tectonic regions with significant three-dimensional (3D) variations in seismic velocities. In this study we compute one regional minimum 1D model and three local minimum 1D models for selected subregions of the Swiss Alpine region, which exhibits a strongly varying Moho topography. We compare the regional and local minimum 1D models in terms of earthquake locations and data quality assessment to measure their performance. Our results show that the local minimum 1D models provide more realistic hypocenter locations and better data fits than a single model for the Alpine region. We attribute this to the fact that in a local minimum 1D model local and regional effects of the velocity structure can be better separated. Consequently, in tectonically complex regions, minimum 1D models should be computed in sub-regions defined by similar structure, if they are used for earthquake location and data quality assessment.  相似文献   

Chemical modelling of the groundwater composition in aquifers affected by lignite mine dumps discharge (surface mine Inden,Germany)     

Stephan Lenk  Frank Wisotzky 《Environmental Earth Sciences》2011,62(3):581-591

The oxidation of pyrite results in sulphate concentrations from 1,300 to 2,000 mg/l in the dump water of the open cast mine Inden, which is located in Germany. Under near-neutral pH and reduced redox conditions, precipitation of siderite (FeCO₃) retains up to 85% of the pre-liberated ferrous iron, so that iron concentrations in the dump water are relatively low as compared to the concentrations of sulphate. The highly mineralised dump water will enter the aquifer system northwards of Inden during the next centuries. This area is used intensely for water extraction. Model calculations show that there will be no problem of acidification in the adjacent aquifer system and, therefore, no problem of high heavy metal concentrations during the next centuries. The most important problem will be high sulphate concentrations in the groundwater. Besides dispersion and diffusion, there are no chemical mechanisms that lower the sulphate concentrations downstream. On the basis of the simulations, sulphate plumes of about 1–2 km in width and up to 15 km in length are expected. Within the core of these plumes, sulphate concentrations will be above the drinking water limits.  相似文献   

Structure and evolution of a passive margin in a compressive environment: Example of the south-western Alps-Ligurian basin junction during the Cenozoic     

F. Sage  M.-O. BeslierI. Thinon  C. LarroqueJ.-X. Dessa  S. MigeonJ. Angelier  P. GuennocD. Schreiber  F. MichaudJ.-F. Stephan  L. Sonnette 《Marine and Petroleum Geology》2011,28(7):1263-1282

We focus on the northern Ligurian margin, at the geological junction of the subalpine domain and the Ligurian oceanic basin, in order (1) to identify the location of the southern limit of the Alpine compressive domain during the Cenozoic, and (2) to study the influence of a compressive environment on the tectonic and sedimentary evolution of a passive margin.Based on published onshore and offshore data, we first propose a chronology of the main extensional and compressional regional tectonic events.High-resolution seismic data image the margin structure down to ∼3 km below seafloor. These data support that past rifting processes control the present-day margin structure, and that 2800-4000 m of synrift sediment was deposited on this segment of the margin in two steps. First, sub-parallel reflectors indicate sediment deposition within a subsident basin showing a low amount of extension. Then, a fan-shaped sequence indicates block tilting and a higher amount of extension. We do not show any influence of the Miocene Alpine compression on the present-day margin structure at our scale of investigation, despite the southern subalpine relief formed in the close hinterland at that time. The southern front of the Miocene Alps was thus located upslope from the continental margin.Finally, a comparison with the Gulf of Lions margin suggests that the tectonic influence of the Alpine compression on the rifting processes is restrited to an increase of the subsidence related to flexure ahead of the Alpine front, explaining abnormally high synrift thicknesses in the study area. The Alpine environment, however, has probably controlled the sedimentary evolution of the margin since the rifting. Indeed, sediment supply and distribution would be mainly controlled by the permanent building of relief in the hinterland and by the steep basin morphology, rather than by sea-level fluctuations, even during the Messinian sea-level low-stand.  相似文献