Garnet and spinel in fertile and depleted mantle: insights from thermodynamic modelling   总被引：2，自引：1，他引：1  

Luca Ziberna  Stephan Klemme  Paolo Nimis 《Contributions to Mineralogy and Petrology》2013,166(2):411-421

We performed thermodynamic calculations based on model and natural peridotitic compositions at pressure and temperature conditions relevant to the Earth’s upper mantle, using well-established free energy minimization techniques. The model is consistent with the available experimental data in Cr-bearing peridotitic systems and can therefore be used to predict phase relations and mineral compositions in a wide range of realistic mantle compositions. The generated phase diagrams for six different bulk compositions, representative of fertile, depleted and ultra-depleted peridotitic mantle, shown that the garnet + spinel stability field is always broad at low temperatures and progressively narrows with increasing temperatures. In lithospheric sections with hot geotherms (ca. 60 mW/m²), garnet coexists with spinel across an interval of 10–15 km, at ca. 50–70 km depths. In colder, cratonic, lithospheric sections (e.g. along a 40 mW/m² geotherm), the width of the garnet–spinel transition strongly depends on bulk composition: In fertile mantle, spinel can coexist with garnet to about 120 km depth, while in an ultra-depleted harzburgitic mantle, it can be stable to over 180 km depth. The formation of chromian spinel inclusions in diamonds is restricted to pressures between 4.0 and 6.0 GPa. The modes of spinel decrease rapidly to less than 1 vol % when it coexists with garnet; hence, spinel grains can be easily overlooked during the petrographical characterization of small mantle xenoliths. The very Cr-rich nature of many spinels from xenoliths and diamonds from cratonic settings may be simply a consequence of their low modes in high-pressure assemblages; thus, their composition does not necessarily imply an extremely refractory composition of the source rock. The model also shows that large Ca and Cr variations in lherzolitic garnets in equilibrium with spinel can be explained by variations of pressure and temperature along a continental geotherm and do not necessarily imply variations of bulk composition. The slope of the Cr# [i.e. Cr/(Cr + Al)mol] isopleths in garnet in equilibrium with spinel changes significantly at high temperatures, posing serious limitations to the applicability of empirical geobarometric methods calibrated on cratonic mantle xenoliths in hotter, off-craton, lithospheric mantle sections.  相似文献   

Early Palaeozoic deep subduction of continental crust in the Kyrgyz North Tianshan: evidence from Lu–Hf garnet geochronology and petrology of mafic dikes     

Yamirka Rojas-Agramonte  Daniel Herwartz  Antonio García-Casco  Alfred Kröner  Dmitriy V. Alexeiev  Reiner Klemd  Stephan Buhre  Matthias Barth 《Contributions to Mineralogy and Petrology》2013,166(2):525-543

High-pressure and ultrahigh-pressure (UHP) eclogite-bearing metamorphic assemblages in the North Tianshan of Kyrgyzstan are known from the Aktyuz and Makbal areas, where eclogites and garnet amphibolites are associated with continental rocks such as granitoid gneisses in Aktyuz and shallow-water clastic (passive margin?) metasediments in Makbal. We present the first Lu–Hf isotope data for an eclogite and two garnet amphibolite samples from the two metamorphic terranes which, combined with petrological analysis, tightly constrain the age of high-pressure metamorphism in the Kyrgyz North Tianshan. A five-point isochron for an Aktyuz eclogite sample provides a Lu–Hf age of 474.3 ± 2.2 Ma, and a four-point isochron on a Makbal sample corresponds to 470.1 ± 2.5 Ma. A prograde, subduction-related path is inferred for both samples with peak P–T conditions ranging from 1.4 to 1.6 GPa and 610–620 °C. A further Makbal sample provided a significantly older Lu–Hf age of 486 ± 5.4 Ma, most likely due to late alteration in the sample (late addition of unradiogenic Hf). We conclude that garnet growth in all three samples occurred around ca. 474 Ma and that these rocks likely experienced UHP metamorphism contemporaneously. Our results support previous geochronological evidence for an Early Ordovician collision belt in the North Tianshan and allow refinement of a tectonic model involving subduction of thinned continental crust to considerable depth along the margin of a small microcontinent.  相似文献   

Growing of Tibetan Plateau: From Inside Out     

WANG Chengshan  DAI Jingen  ZHAO Xixi  LI Yalin  A. Graham Stephan  HE Dengf  RAN Bo  MEN Jun 《《地质学报》英文版》2013,87(Z1):76-76

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用电子束CT作冠状动脉血管造影     

Stephan Achenbach  Dieter Ropers  Werner G. Daniel  Werner Moshage 《CT理论与应用研究》2000,9(1):45-48

本文介绍用电子束ＣＴ作冠状动脉可视化造影的方法,说明本项成就的特征和在应用这项技术的局限性,并指出这种技术在临床上,可能成为新无创伤性的诊断工具。  相似文献   

Ceres’ spectral link to carbonaceous chondrites—Analysis of the dark background materials          下载免费PDF全文

Michael Schäfer  Tanja Schäfer  Matthew R. M. Izawa  Edward A. Cloutis  Stefan E. Schröder  Thomas Roatsch  Frank Preusker  Katrin Stephan  Klaus‐Dieter Matz  Carol A. Raymond  Christopher T. Russell 《Meteoritics & planetary science》2018,53(9):1925-1945

Ceres’ surface has commonly been linked with carbonaceous chondrites (CCs) by ground‐based telescopic observations, because of its low albedo, flat to red‐sloped spectra in the visible and near‐infrared (VIS/NIR) wavelength region, and the absence of distinct absorption bands, though no currently known meteorites provide complete spectral matches to Ceres. Spatially resolved data of the Dawn Framing Camera (FC) reveal a generally dark surface covered with bright spots exhibiting reflectance values several times higher than Ceres’ background. In this work, we investigated FC data from High Altitude Mapping Orbit (HAMO) and Ceres eXtended Juling (CXJ) orbit (~140 m/pixel) for global spectral variations. We found that the cerean surface mainly differs by spectral slope over the whole FC wavelength region (0.4–1.0 μm). Areas exhibiting slopes ?1 constitute only ~3% of the cerean surface and mainly occur in the bright material in and around young craters, whereas slopes ≥?10% μm^?1 occur on more than 90% of the cerean surface; the latter being denoted as Ceres’ background material in this work. FC and Visible and Infrared Spectrometer (VIR) spectra of this background material were compared to the suite of CCs spectrally investigated so far regarding their VIS/NIR region and 2.7 μm absorption, as well as their reflectance at 0.653 μm. This resulted in a good match to heated CI Ivuna (heated to 200–300 °C) and a better match for CM1 meteorites, especially Moapa Valley. This possibly indicates that the alteration of CM2 to CM1 took place on Ceres.  相似文献   

Late Quaternary solifluction sheets in the British uplands     

Stephan Harrison  Leanne Hughes  Neil Glasser  Oliver Kuras 《第四纪科学杂志》2021,36(7):1162-1173

Solifluction sheets are large-scale and extensive valley-floor and valley-side landforms developed widely in the British Isles from mass-wasting of glacial and periglacial sediments during late-glacial times. We describe their geographical distribution and review the processes that have led to their development. We use data from the Cheviot Hills, the one site in the British Isles where sedimentology and optically stimulated luminescence dating have been combined, to assess their age and nature of deposition. We also present data from central Wales where a new mapping and resistivity survey has reconstructed the nature of valley-side solifluction sheets. We explore the relative lack of recent research on these landforms and argue that solifluction sheets represent a clear example of how upland geomorphological systems have responded to late-glacial climate change. We end by identifying a number of areas where research on these enigmatic features could be focussed, including better understanding of their distribution, sedimentology and age.  相似文献   

The pre-weichselian glaciations of North-West Europe     

Jürgen Ehlers  Klaus-Dieter Meyer  Hans-Jürgen Stephan 《Quaternary Science Reviews》1984,3(1):1-40

In North-West Europe no evidence has been found for glaciations older than the Elsterian. The Elsterian seems to consist of at least two separate ice advances with a minor interval in between. During the Elsterian in the area south of the Baltic Sea over 400 m deep channels were cut into the underlying substratum by a combination of glacial erosion and meltwater activity. The channels were active until the Late Elsterian and were subsequently filled with meltwater deposits and glaciolacustrine silt and clay. During the Saalian no comparative channels were being formed. Three different ice advances can be distinguished within the Saalian, the stratigraphical correlation of which is to be discussed. No convincing evidence was found for any interglacial within the Saalian sequence. There are good reasons to assume that the ice advances were only separated from each other by minor ice-free intervals.  相似文献   

40Ar-39Ar Ages of Types 3 and 4, L and H Chondrites from Antarctica     

Thomas Stephan  Elmar K. Jessberger 《Meteoritics & planetary science》1988,23(4):373-377

Abstract— This is a report on ⁴⁰Ar-³⁹Ar studies of 7 low petrographic type L and H chondrites from Antarctica. From petrographic similarities it has been argued that the L3 chondrites ALHA77015, ?77167, ?77249, and ?77260 are pieces from a common fall (McKinley et al., 1981). Our results now confirm this supposition: The four meteorites have identical characteristic Ar-degassing patterns, very similar K, Ca, Cl, and ³⁶Ar_trapped contents, and similar ⁴⁰Ar-³⁹Ar ages of <4 Ga which are rather unusual for ordinary chondrites and might be due to shock. The undulating age patterns could be due to weathering or to ³⁹Ar recoil. The L4 chondrite ALHA77230 shows no age plateau and only a lower limit for the time of a severe degassing, 4.0 Ga, can be given. ALHA77226 and RKPA78002, two H4 chondrites, exhibit reasonably well defined age plateaus at about 4.3 and 4.4 Ga. Two individual chondrules from RKPA78002 have the same age as the whole rock sample.  相似文献   

The provenance of Australian uranium ore concentrates by elemental and isotopic analysis     

Elizabeth Keegan  Stephan Richter  Ian Kelly  Henri Wong  Patricia Gadd  Heinz Kuehn  Adolfo Alonso-Munoz 《Applied Geochemistry》2008

Elemental and isotopic ratio analyses of U ore concentrate samples, from the 3 operating U mining facilities in Australia, were carried out to determine if significant variations exist between their products, thereby allowing the U ore concentrate’s origin to be identified. Elemental analyses were conducted using inductively coupled plasma mass spectrometry (ICP-MS) and X-ray fluorescence spectrometry (XRF). Lead isotope ratios were measured using ICP-MS and U isotope analyses were conducted using thermal ionisation mass spectrometry (TIMS). Minute quantities of sample, such as that obtained from a swipe, were also examined for elemental concentrations using secondary ion mass spectrometry (SIMS). The results of multivariate statistical analysis show clear patterns in the trace elemental composition of the processed U ores, indicating that it is possible to use this feature as a unique identifier of an Australian U ore concentrate’s source. Secondary ion mass spectrometry analyses also allow individual particles to be differentiated using this ‘fingerprinting’ technique. Isotope ratios determined using TIMS reveal that there is a significant difference in the n(²³⁴U)/n(²³⁸U) isotope ratio between the U ore concentrate from each mine.  相似文献   

Changes of cloud microphysical properties during the transition from supercooled to mixed-phase conditions during CIME     

Stephan Mertes  Alfons Schwarzenbck  Paolo Laj  Wolfram Wobrock  Jean-Marc Pichon  Giordano Orsi  Jost Heintzenberg 《Atmospheric Research》2001,58(4)

A ground-based seeding experiment using carbon dioxide and propane sprayed from pressurized bottles was carried out under supercooled cloud conditions on a small spatial and short time scale. Water vapor deposition on the artificially generated dry ice and propane ice germs as the main ice formation process (nucleation and growth) is consistent with the experimental results. After nucleation, diffusional growth of the ice particles, partly at the expense of evaporating small droplets, was identified during the mixing of the seeding line with the ambient supercooled cloud. Within the seeding plume, ice water contents up to 80% of the total condensed water are observed, although the size of the formed ice particles did not exceed 25 μm. From the changes of the ice and supercooled liquid phase with time under mixed-phase conditions, liquid water content (LWC) evaporation, ice water content (IWC) formation, and ice crystal growth rates are estimated, which are not affected by the artificial nucleation process. Thus, these rates are assessed to be applicable for a growing ice phase of small ice particles in a young mixed-phase cloud, where other growth mechanisms, like riming or aggregation, are negligible.  相似文献