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61.
Surface-structure-controlled sectoral zoning of the rare earth elements in fluorite from Long Lake, New York, and Bingham, New Mexico, USA 总被引:1,自引:0,他引:1
Stephanie BoszeJohn Rakovan 《Geochimica et cosmochimica acta》2002,66(6):997-1009
The concentration and distribution of rare earth elements (REE) in sectorally zoned fluorite crystals from Long Lake, New York, and the Hansonburg Mining District, Bingham, New Mexico, have been studied using cathodoluminescence and synchrotron X-ray fluorescence microanalysis (SXRFMA). In cubo-octahedral samples from Long Lake, New York, Ce, Nd, Gd, Dy, Ho, Er, and Tm are preferentially partitioned into the |111| sector relative to the |100| sector. Partition coefficients (Kd = concentration in |111| sector/concentration in |100| sector) range between 3.5 for Ce, to 1.4 for Tm, with a general decrease in Kd as elements deviated from the ionic radius of Ca2+, for which REE substitute in fluorite. Diffusion of the REE has occurred, as evidenced by gradual changes in composition over distances of 0.2 to 0.3 mm at sector boundaries.In Bingham samples, three different partition coefficients were determined for Dy: Kd|100|/|111| = 2.83, Kd |100|/|110| = 1.77, and Kd |110|/|111| = 1.60. These are mean Kd values for a 95% confidence interval. In another sample from the same deposit, Dy, Er, and Gd were found to be preferentially incorporated into the |100| sector relative to the |210| sector with average Kd |100|/|210| of 3.1, 2.4, and 2.9, respectively. In a third sample, Nd was found to be preferentially incorporated into the |110| sector relative to the |321| sector with an average Kd |110|/|321| value of 2.3.Compositional heterogeneities in a given sector (concentric zoning) have been resolved using SXRFMA but are significantly less than the concentration difference across sector boundaries. Often fluorite exists in a wide variety of morphologies, as is the case in the Hansonburg Mining District of Bingham. We suggest caution when using the REE as petrogenetic indicators because fluorite trace element chemistry can vary greatly among crystals within a deposit depending on the internal morphology of a particular crystal. 相似文献
62.
A.B. Galvin C.M.S. Cohen F.M. Ipavich R. von Steiger J. Woch U. Mall 《Planetary and Space Science》1993,41(11-12)
During the inbound segment of the Ulysses flyby of Jupiter, there were multiple incursions into the dawnside low-latitude boundary layer, as identified by Bame et al. (Science257, 1539–1542, 1992) using plasma electron data. In the present study, ion composition and spectral measurements provide independent collaborative evidence for the existence of distinct boundary layer regions. Measurements are taken in the energy-per-charge range of 0.6–60 keV/e and involve mass as well as mass-per-charge identification by the Ulysses/SWICS experiment. Ion species of Jovian magnetospheric origin (including O+, O2+, S2+, S3+) and sheath origin (including He2+ and high charge state CNO) have been directly identified for the first time in the Jovian magnetospheric boundary layer. Protons of probably mixed origin and He+ of possibly sheath (ultimately interstellar pickup) origin were also observed in the boundary layer. Sheath-like ions are observed throughout the boundary layer; however, the Jovian ions are depleted or absent for portions of two boundary layer cases studied. Ions of solar wind origin are observed within the outer magnetosphere. and ions of magnetospheric origin are found within the sheath, indicating that transport across the magnetopause boundary can work both ways, at least under some conditions. Although their source cannot be uniquely identified, the proton energy spectrum in the boundary layer suggests a sheath origin for the lower energy protons. 相似文献
63.
Jim Cohen 《Astrophysics and Space Science》2005,295(1-2):27-36
Magnetic field strengths and directions can be estimated using many different observational techniques that span a wide range of wavelengths. Each observational method favours different regimes of scale size, density and other physical conditions. The available techniques and their ranges of applicability are briefly described and the current status of observations is reviewed, with particular emphasis on high-resolution observations of star-forming regions. 相似文献
64.
Phase-referenced observations of 13 star-forming regions in the 2 Π1/2 , J = 1/2 transition of rotationally excited OH at 4765 MHz have been carried out using MERLIN. Two of the regions were also observed at 4750 MHz and one at 4660 MHz. There were 10 maser detections at 4765 MHz and three non-detections. There were no detections at 4750 and 4660 MHz. The 4765-MHz masers have brightness temperatures of ∼107 K at MERLIN resolution (∼50 mas). Several cases of 4765-MHz masers overlapping in position and velocity with 1720- and 1665-MHz masers are reported. There are also isolated 4765-MHz masers with peak flux densities ≥30 times that of any ground-state counterpart. Most of the 4.7-GHz maser spots are unresolved at 50-mas angular resolution, but in four of the nearest sources the maser spots are resolved, indicating a characteristic size for 4765-MHz maser regions of ∼100 au. In W3(OH) we discovered that 20 per cent of the 4765-MHz emission comes from a narrow low-brightness filament that stretches north–south for ∼1.0 arcec (∼2200 au) between two previously known 4765-MHz maser spots. The filament appears in projection against the H ii region and has a brightness temperature of ∼4 × 105 K . There are matching absorption features in mainline transitions of highly excited OH. The filament may trace a shock front in a rotating disc. 相似文献
65.
66.
67.
A solution to the orbital motion of an Earth satellite at the critical inclination and with near-zero eccentricity is developed by the von Zeipel method to the first order in the eccentricity, and to the first order in the higher gravitational harmonics, using elements which do not degenerate at zero eccentricity. 相似文献
68.
69.
A. Niezurawska M. Szymczak A. M. S. Richards R. J. Cohen 《Astrophysics and Space Science》2005,295(1-2):37-42
Two star-forming regions Cepheus A and W75N, were searched for the 4765-MHz OH maser emission using the multi-element radio linked interferometer network (MERLIN). The excited OH emission has an arc-like structure of 40 mas in Cep A and a linear structure of size 45 mas in W75N. We also found the 1720-MHz line in Cep A and Hutawarakorn [MNRAS 330 (2002) 349] reported the 1720-MHz emission in W75N. The 1720- and 4765-MHz OH spots coincided in space within 60 mas and in velocity within 0.3 km s–1 in both targets implying that both maser transitions arise from the same region. According to the modelling by Gray [MNRAS 252 (1991) 30] the 1720/4765-MHz co-propagation requires a low density, warm environment. The masers lie at the edges of H II regions where such conditions are expected. 相似文献
70.
Sources of Enterococcus faecalis isolates from Pensacola Beach, FL. were identified using a library-based approach by applying the statistical method of average similarity to single and composite data sets generated from separate analyses. Data sets included antibiotic resistance analysis (ARA), rep-fingerprints, and fatty acid methyl ester (FAME) profiles. Use of a composite data set composed of ARA and rep-fingerprints, added to the confidence of the identifications. The addition of FAME data to composite data sets did not add to the confidence of identifications. Source identification was performed to better understand risk associated with higher densities of enterococci found in swash zone interstitial water (SZIW) as compared to adjacent bathing water on Pensacola Beach, FL. The "swash zone" is that area of the beach continually washed over by waves. As the potential sources of enterococci were limited in this environment, only two library units, sea gull and human, were constructed. Identification of the beach isolates using a composite data set indicated a sea gull origin. The clonality of the beach isolates suggested that the beach environment selects certain subspecies of E. faecalis. 相似文献