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151.
Surface mining in the Elk Valley, British Columbia, involves removing vegetation, soil, and rock to access underlying metallurgical coal. Subsequent waste rock is placed into adjacent valleys, frequently burying headwater streams. Due to their coarse texture, waste rock piles increase infiltration and percolation, increasing solute transport and concentration of geochemicals in downstream surface waters. Previous research suggests that weathering solutes are transport limited, and it is hypothesized that revegetation will enhance evapotranspiration (ET) and reduce percolation through the waste rock, potentially reducing loading. This study examined the surface‐atmosphere water and energy exchanges using the eddy covariance technique for three waste rock surfaces with different levels of reclamation: (a) an ~25‐year‐old mixed coniferous forest, (b) a grass site, and (c) bare waste rock. Measurements were taken from May to October in 2013 and 2014. Soil moisture and matric suction were measured to 1‐m depth. Sap flow at the forested site was measured to partition transpiration from total ET. In all years, ET rates were greatest at the forested site, followed by the grass cover and lowest at the bare waste rock site. Growing season ET rates at the forest were 56% higher than grass in 2013 and 35% higher in 2014. At the vegetated sites, climate was the main driver of ET, with high radiation, and warm and dry conditions enhancing fluxes. Maximum ET at these sites corresponded with peak growing season, with vegetation increasing both transpiration and rainfall interception. At the bare rock site, ET was weakly related to atmospheric conditions, and ET rates briefly increased during periods following rainfall when near‐surface soil moisture was enhanced. Transpiration comprised 29% of overall ET at the forest site from late July to early October. Results suggest that vegetation establishment can be incorporated into mine reclamation plans to enhance ET rates and limit percolation, potentially reducing downstream geochemical loads.  相似文献   
152.
The Mangala Valles is a 900-km long outflow channel system in the highlands adjacent to the south-eastern flank of the Tharsis bulge. This work was intended to answer the following two questions unresolved in previous studies: (1) Was there only one source of water (Mangala Fossa at the valley head which is one of the Medusae Fossae troughs or graben) or were other sources also involved in the valley-carving water supply, and (2) Was there only one episode of flooding (maybe with phases) or were there several episodes significantly separated in time. The geologic analysis of HRSC image 0286 and mapping supported by analysis of MOC and THEMIS images show that Mangala Valles was carved by water released from several sources. The major source was Mangala Fossa, which probably formed in response to magmatic dike intrusion. The graben cracked the cryosphere and permitted the release of groundwater held under hydrostatic pressure. This major source was augmented by a few smaller-scale sources at localities in (1) two mapped heads of magmatic dikes, (2) heads of two clusters of sinuous channels, and (3) probably several large knob terrain locals. The analysis of results of crater counts at more than 60 localities showed that the first episode of formation of Mangala Valles occurred ~3.5 Ga ago and was followed by three more episodes, one occurred ~1 Ga ago, another one ~0.5 Ga ago, and the last one ~0.2 Ga ago. East of the mapped area there are extended and thick lava flows whose source may be the eastern continuation of the Mangala source graben. Crater counts in 10 localities on these lava flows correlate with those taken on the Mangala valley elements supporting the idea that the valley head graben was caused by dike intrusions. Our observations suggest that the waning stage of the latest flooding episode (~0.2 Ga ago) led to the formation at the valley head of meander-like features sharing some characteristics with meanders of terrestrial rivers. If this analogy is correct this could suggest a short episode of global warming in Late Amazonian time.  相似文献   
153.
Depth profiles in the sediment porewaters of the Chattahoochee River (Georgia, USA) show that iron oxides scavenge arsenate in the water column and settle to the sediment-water interface (SWI) where they are reduced by iron-reducing bacteria. During their reduction, these particles seem to release arsenic to the porewaters in the form of arsenate only. Sediment slurry incubations were conducted to determine the effect of low concentrations of arsenic (?10 μM) on biogeochemical processes in these sediments. Experiments confirm that any arsenate (As(V)) added to these sediments is immediately adsorbed in oxic conditions and released in anoxic conditions during the microbial reduction of authigenic iron oxides. Incubations in the presence of ?1 μM As(V) reveal that arsenate is released but not concomitantly reduced during this process. Simultaneously, microbial iron reduction is enhanced significantly, spurring the simultaneous release of arsenate into porewaters and secondary formation of crystalline iron oxides. Above 1 μM As(V), however, the microbial reductive dissolution of iron oxides appears inhibited by arsenate, and arsenite is produced in excess in the porewaters. These incubations show that even low inputs of arsenic to riverine sediments may affect microbial processes, the stability of iron oxides and, indirectly, the cycling of arsenic. Possible mechanisms for such effects on iron reduction are proposed.  相似文献   
154.
Transfer of organic carbon (OC) from the terrestrial to the oceanic carbon pool is largely driven by riverine and aeolian transport. Before transport, however, terrigenous organic matter can be retained in intermediate terrestrial reservoirs such as soils. Using compound-specific radiocarbon analysis of terrigenous biomarkers their average terrestrial residence time can be evaluated.Here we show compound-specific radiocarbon (14C) ages of terrigenous biomarkers and bulk 14C ages accompanied by geochemical proxy data from core top samples collected along transects in front of several river mouths in the Black Sea. 14C ages of long chain n-alkanes, long chain n-fatty acids and total organic carbon (TOC) are highest in front of the river mouths, correlating well with BIT (branched and isoprenoid tetraether) indices, which indicates contribution of pre-aged, soil-derived terrigenous organic matter. The radiocarbon ages decrease further offshore towards locations where organic matter is dominated by marine production and aeolian input potentially contributes terrigenous organic matter. Average terrestrial residence times of vascular plant biomarkers deduced from n-C29+31 alkanes and n-C28+30 fatty acids ages from stations directly in front of the river mouths range from 900 ± 70 years to 4400 ± 170 years. These average residence times correlate with size and topography in climatically similar catchments, whereas the climatic regime appears to control continental carbon turnover times in morphologically similar drainage areas of the Black Sea catchment. Along-transect data imply petrogenic contribution of n-C29+31 alkanes and input via different terrigenous biomarker transport modes, i.e., riverine and aeolian, resulting in aged biomarkers at offshore core locations. Because n-C29+31 alkanes show contributions from petrogenic sources, n-C28+30 fatty acids likely provide better estimates of average terrestrial residence times of vascular plant biomarkers. Moreover, sedimentary n-C28 and n-C30 fatty acids appear clearly much less influenced by autochthonous sources than n-C24 and n-C26 fatty acids as indicated by increasing radiocarbon ages with increasing chain-length and are, thus, more representative as vascular plant biomarkers.  相似文献   
155.
Heavy minerals of twenty sediment samples, belonging to polar ice sheet, lake, mainland area and shelf region of Schirmacher Oasis, east Antarctica, have been studied for their textural characteristics, abundance and provenance determination. The heavy crop is represented by zircon, tourmaline, rutile, garnet, hypersthene, hornblende, chlorite, enstatite, lawsonite, kyanite, sillimanite, zoisite, andalusite, spinel, topaz and opaques. The assemblage, in general, is dominated by hornblende-hypersthene-garnet assemblage, followed by kyanite-sillimanite-andalusite and zircontourmaline-rutile. The high concentration of specific minerals of metamorphic origin reveals high-grade metamorphic terrain as the primary source. The ZTR ratio is low showing low mineralogical maturity. An attempt has also been made to compare the trends of heavy minerals of various sub glacial regions with those of the average values of entire area.  相似文献   
156.
Synthetic data have long been employed in hydrology for model development and testing. The objective of this study was to generate a synthetic dataset of hydrologic response with higher spatial and temporal resolution than could presently be obtained in the field, spanning a longer period than the typical duration of monitoring campaigns in experimental catchments. The synthetic dataset was generated for a rangeland catchment with the Integrated Hydrology Model (InHM), and is presented for future use by the community. The InHM boundary‐value problem is based upon the previously reported hypothetical reality of Tarrawarra‐like hydrologic response. Whereas the emphasis in developing the hypothetical reality was on parameterising InHM to reproduce observations from the Tarrawarra catchment, the emphasis in generating the synthetic dataset is on developing an internally valid hydrologic‐response dataset that extends well beyond the period of observations at Tarrawarra. The synthetic dataset spans 11 years of continuous forcing and response data (e.g. integrated response, distributed fluxes, state variable dynamics). The dataset should be useful for a wide range of problems including evaluation of simple rainfall runoff modelling techniques, design of measurement networks, development of data‐assimilation algorithms, and studies on information theory. The dataset is available at: ftp://pangea.stanford.edu/pub/loague/ . Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
157.
158.
In this study, we use records of nitrogen isotope ratios (δ15N), UK’37 temperature estimates, organic carbon and opal percentages from high-resolution sediment cores located in the eastern equatorial Pacific (EEP) to explore the mechanisms linking millennial-scale changes in low-latitude sea surface temperature, water column denitrification and surface productivity to the timing of northern or southern polar climate during the last 100,000 yr. Our results support a hypothesis that the Southern Hemisphere, and its connection to the low latitudes via shallow subsurface ocean circulation, has a primary influence on the biogeochemistry of the EEP. In addition, our results suggest that, during the last glacial stage, denitrification rates fluctuated on millennial timescales in response to water-column ventilation rather than upstream oxidant demand in intermediate-depth waters.However, due to the poor age constraints available for Marine Isotopic Stage (MIS) 3, the EEP sedimentary data presented here could support two conflicting mechanisms, one driven by enhanced intermediate overturning circulation in the Southern Ocean during Heinrich Events/Antarctic Warm Events, implying that subsurface flow rates control thermocline ventilation, and a second one consistent with more sluggish intermediate circulation during Antarctic Warm Events and giving a central role to the temperature control on oxygen solubility in Southern Ocean surface waters.  相似文献   
159.
The Alps are often referred to as the ‘water tower of Europe’. In Switzerland, many branches of the economy, especially the hydropower industry, are closely linked to and dependent on the availability of water. Assessing the impact of climate change on streamflow runoff is, thus, of great interest. Major efforts have already been made in this respect, but the analyses often focus on individual catchments and are difficult to intercompare. In this article, we analysed nine high‐alpine catchments spread over the Swiss Alps, selected for their relevance to a wide range of morphological characteristics. Runoff projections were carried out until the end of the current century by applying the Glacier Evolution Runoff Model (GERM) and climate scenarios generated in the framework of the ENSEMBLES project. We focused on assessing the uncertainty induced by the unknown climate evolution and provided general, statistically based statements, which should be useful as a ‘rule of thumb’ for analyses addressing questions related to water management. Catchments with a high degree of glacierization will undergo the largest changes. General statements about absolute variations in discharge are unreliable, but an overall pattern, with an initial phase of increased annual discharge, followed by a phase with decreasing discharge, is recognizable for all catchments with a significant degree of glacierization. In these catchments, a transition from glacial and glacio‐nival regime types to nival will occur. The timing of maximal annual runoff is projected to occur before 2050 in all basins. The time of year with maximal daily discharges is expected to occur earlier at a rate of 4·4 ± 1·7 days per decade. Compared to its present level, the contribution of snow‐ and icemelt to annual discharge is projected to drop by 15 to 25% until the year 2100. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
160.
An innovative micro‐extraction of aqueous samples coupled with gas chromatography/mass spectrometry in selected ion‐monitoring mode (GC/MS‐SIM) was developed to selectively analyze for 1,4‐dioxane with low part‐per‐billion detection sensitivity. Recoveries of 1,4‐dioxane ranged from 93% to 117% for both spiked laboratory reagent water and natural groundwater matrices, the later having elevated organic carbon content (8.34 ± 0.31 mg/L as total organic carbon). We observed that freezing the aqueous sample along with the extraction solvent enhanced the extraction efficiency, minimized physical interferences, and improved sensitivity resulting in a limit of detection for 1,4‐dioxane to approximately 1.6 μg/L. This method substantially reduces the labor, time, reagents and cost, and uses instruments that are commonly found in analytical laboratories. This method requires a relatively small sample volume (200 μL), and can be considered a green analytical method as it minimizes the use of toxic solvents and the associated laboratory wastes.  相似文献   
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