Fe2+-Ti4+ charge transfer in stoichiometric Fe2+,Ti4+-minerals     

Stephanie M. Mattson  George R. Rossman 《Physics and Chemistry of Minerals》1988,16(1):78-82

Optical absorption spectra are presented for taramellite, traskite and neptunite, all of which have both Fe²⁺ and Ti⁴⁺ as major elements. The spectra of each of these minerals are dominated by a single, intense absorption band in the 415 to 460 nm region with 7000 to 9000 cm^?1 halfwidth. These transitions, assigned to Fe²⁺-Ti⁴⁺ intervalence charge transfer, showed little difference in intensity at 80 and 300 K and have molar absorptivities which range from ～100 to ～1300 M^?1 cm^?1. The Fe²⁺-Ti⁴⁺ absorptions in these standards generally compare well to other mineral spectra in which Fe²⁺ — Ti⁴⁺ intervalence absorption has previously been proposed with the exception of the most cited example, blue corundum.  相似文献   

Surface inhomogeneity effects on convective diffusion     

Gary A. Briggs 《Boundary-Layer Meteorology》1988,45(1-2):117-135

It is suggested that convective scaling, with appropriate extensions, provides the most useful framework for estimating the effects of urban-scale surface inhomogeneities on diffusion in convective conditions. Strong contrasts in surface heat flux exist between cropland, forests, urban areas, and water or marshland surfaces. It is argued that a typical fetch for convective turbulence to readjust to changed heat (or buoyancy) input from the surface below is 2(U/w ^*)h, where U is the mean wind speed in the mixing layer, w ^* is the convective scaling velocity, and h is the mixing depth. In contrast, the fetch required for wind speed to readjust to new underlying surface roughness is of the order (U/u ^*)²h/2, where u ^* is the friction velocity.The ratio w ^*/U is the best index of diffusion rates in moderately to very unstable conditions. General urban effects on heat flux, h, and U are discussed separately, then their combined effects on w ^*/U are estimated. While this ratio can double over a large city during light winds, its increase is much less for small cities, or during moderate winds. Finally, some examples of heat flux in- homogeneities causing stationary convective features are presented. Steady downdrafts associated with these features are of the order of 0.4w ^*, and could significantly increase surface concentrations from elevated sources.On assignment from the National Oceanic and Atmospheric Administration, U.S. Department of Commerce.This paper is based on a presentation made at the AMS Specialty Conference on Air Quality Modeling of the Urban Boundary Layer, in Baltimore, late 1983.  相似文献   

On the determination of the closure parameters in higher-order closure models     

Marion Wichmann  Eberhard Schaller 《Boundary-Layer Meteorology》1986,37(4):323-341

In higher-order closure models at least the pressure redistribution and the dissipation of the turbulent kinetic energy and the temperature variance have to be parameterized. Due to this, the introduction of proportionality coefficients — the so-called closure parameters — is forced, which have to be determined before the model is used. We compare a group of models which use the return-to-isotropy hypothesis (Rotta, 1951) to describe the pressure redistribution and assume local isotropy for the smallest eddies in order to parameterize the dissipation. Special concern is given to the method of Mellor and Yamada (1982). Some of the closure parameters are re-derived on the basis of sensitivity studies requiring that both shear production and buoyancy behave in a realistic way if pressure redistribution or dissipation is changed by varying the closure parameters. This set of parameters is compared with those obtained by fitting to experimental data, by use of the Monin-Obukhov similarity theory and by considering ratios of variances, covariances and mean flow gradients, respectively. It is shown that the various sets of closure parameters are at least of the same order. The differences give some insight into the advantages and disadvantages of the various determination procedures. However, the general accordance of the different parameter sets supports the assumption of universal constants.  相似文献   

Similarity forms for ground-source surface-layer diffusion     

Gary A. Briggs 《Boundary-Layer Meteorology》1982,23(4):489-502

Past work on analyzing ground-source diffusion data in terms of surface-layer similarity theory is reviewed; these analyses assume that _z /L orh/L is a function of u ^* x/L (where h = Q/ dy). It is argued that an alternative scaling, h ^*/L versus x/L, is nearly as universal in that it is very weakly influenced by surface roughness, except for a modest influence in the free convective case (h ^* = Q/u ^* dy); the advantage of this scaling is that it eliminates the need to reassess as vertical diffusion progresses. The Prairie Grass data set is adjusted for the difference in source and sampling heights, and is plotted with this scaling. Simple analytic equations are suggested that fit the resultant data plots for stable and unstable conditions, and suggestions are made towards practical application of these results.On assignment from the National Oceanic and Atmospheric Administration, U.S. Department of Commerce.  相似文献   

Inverted-polarity electrical structures in thunderstorms in the Severe Thunderstorm Electrification and Precipitation Study (STEPS)     

W. David Rust  Donald R. MacGorman  Eric C. Bruning  Stephanie A. Weiss  Paul R. Krehbiel  Ronald J. Thomas  William Rison  Timothy Hamlin  Jeremiah Harlin 《Atmospheric Research》2005,76(1-4):247

Balloon-borne electric field soundings and lightning mapping data have been analyzed for three of the storms that occurred in the Severe Thunderstorm Electrification and Precipitation Study field program in 2000 to determine if the storms had inverted-polarity electrical structures. The polarities of all or some of the vertically stacked charge regions in such storms are opposite to the polarities observed at comparable heights in normal storms. Analyses compared the charge structures inferred from electric field soundings in the storms with charges inferred from three-dimensional lightning mapping data. Charge structures were inferred from electric field profiles by combining the one-dimensional approximation of Gauss's law with additional information from three-dimensional patterns in the electric field vectors. The three different ways of inferring the charge structure in the storms were found to complement each other and to be consistent overall. Charge deposition by lightning possibly occurred and increased the charge complexity of one of the storms.Many of the cloud flashes in each case were inverted-polarity flashes. Two storms produced ground flash activity comprised predominantly of positive ground flashes. One storm, which was an isolated thunderstorm, produced inverted-polarity cloud flashes, but no flashes to ground. The positive and negative thunderstorm charge regions were found at altitudes where, respectively, negative and positive charge would be found in normal-polarity storms. Thus, we conclude that these storms had anomalous and inverted-polarity electrical structures. Collectively, these three cases (along with the limited cases in the refereed literature) provide additional evidence that thunderstorms can have inverted-polarity electrical structures.  相似文献   

Time-Relative Positioning with a Single Civil GPS Receiver     

Stephanie Michaud  Rock Santerre 《GPS Solutions》2001,5(2):71-77

Time-relative positioning is a recent method for processing GPS phase observations. The operational method undertaken in this paper consists of the following steps: first, recording phase observations at a station of known coordinates; second, moving the GPS receiver to an unknown station (which can be located up to a few hundred meters away, dependint on what type of transportation – e. g., walking, motorcycle – is available) while continuously observing carrier phases; and, third, recording phase observations at a second station of unknown coordinates with a single GPS receiver. To obtain the position of the unknown station relative to the first (known) station, the processing method uses combined observations taken at two different epochs and two different stations with the same receiver. For this reason, the errors that vary between two epochs must be taken into account in an appropriate way, especially errors in satellite clock corrections and ephemerides, and errors related to tropospheric and ionospheric delays. Ionospheric modeling using IONEX files (the ionospheric maps calculated by the International GPS Service) was also tested to correct L1 phase observations. This method has been used to calculate short vectors with an accuracy of a few centimeters (for a processing interval of 30 s) using a single civil GPS receiver. ? 2001 John Wiley & Sons, Inc.  相似文献   

Ozone Production Efficiency in Savanna and Forested Areas during the EXPRESSO Experiment     

T. Marion  P. E. Perros  R. Losno  E. Steiner 《Journal of Atmospheric Chemistry》2001,38(1):3-30

NO, NO_x, NO_y and O₃ have been measuredduring the airborne EXPRESSO experiment, November 96,which took place near Bangui (Central Africa) at thebeginning of the dry season. This period correspondsto an intense burning activity. Chemical andphotochemical characteristics of the planetaryboundary layer, which corresponds most of the time tothe monsoon layer, and the Harmattan layer, which issituated above the latter, have been studied forsavanna as well as rain forest areas. These two layersare very different when considering the chemicalcomposition (especially for ozone and NO_z) andthe photochemical age.The relationship of photochemical ozone productionversus photochemical NO_x oxidation products hasbeen investigated. Results indicate an ozoneproduction efficiency (OPE) ranging from 6.3 to 14.8in the planetary boundary layer. Thus, this layer ischaracteristic of a photochemically young and activeair mass. In this layer, the ozone potentialproduction increases with the air mass photochemicalage. On the other hand, the Harmattan layer shows anOPE ranging from 4.6 to 7.4. These values arecharacteristic of photochemically well-aged airmasses. In this layer, the ozone potential productionseems to be exhausted with values around 4.0 (i.e., 4ozone molecules produced for each NO_x moleculeemitted).  相似文献   

Earth science,F. M. Brown and W. Bailey. Silver Burdett Co., Morristown,New Jersey, 1978. No. of pages: 530. Price: £10.25     

David J. Briggs 《地球表面变化过程与地形》1979,4(2):204-204

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The Chemical Quality of Self-Supplied Domestic Well Water in the United States     

Michael J. Focazio  Deborah Tipton  Stephanie Dunkle Shapiro  Linda H. Geiger 《Ground Water Monitoring & Remediation》2006,26(3):92-104

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Perspectives on present-day sea level change: a tribute to Christian le Provost     

Alix Lombard  Anny Cazenave  Pierre Yves Le Traon  Stephanie Guinehut  Cécile Cabanes 《Ocean Dynamics》2006,56(5-6):445-451

In this paper, we first discuss the controversial result of the work by Cabanes et al. (Science 294:840–842, 2001), who suggested that the rate of past century sea level rise may have been overestimated, considering the limited and heterogeneous location of historical tide gauges and the high regional variability of thermal expansion which was supposed to dominate the observed sea level. If correct, this conclusion would have solved the problem raised by the IPCC third assessment report [Church et al, Cambridge University Press, Cambridge, pp 881, 2001], namely, the factor two difference between the 20th century observed sea level rise and the computed climatic contributions. However, recent investigations based on new ocean temperature data sets indicate that thermal expansion only explains part (about 0.4 mm/year) of the 1.8 mm/year observed sea level rise of the past few decades. In fact, the Cabanes et al.’s conclusion was incorrect due to a contamination of abnormally high ocean temperature data in the Gulf Stream area that led to an overestimate of thermal expansion in this region. In this paper, we also estimate thermal expansion over the last decade (1993–2003), using a new ocean temperature and salinity database. We compare our result with three other estimates, two being based on global gridded data sets, and one based on an approach similar to that developed here. It is found that the mean rate of thermosteric sea level rise over the past decade is 1.5±0.3 mm/year, i.e. 50% of the observed 3 mm/year by satellite altimetry. For both time spans, past few decades and last decade, a contribution of 1.4 mm/year is not explained by thermal expansion, thus needs to be of water mass origin. Direct estimates of land ice melt for the recent years account for about 1 mm/year sea level rise. Thus, at least for the last decade, we have moved closer to explaining the observed rate of sea level rise than the IPCC third assessment report.  相似文献