High-pressure metamorphism of stratiform sulphide deposits from the Diahot region,New Caledonia     

R. M. Briggs  H. W. Kobe  P. M. Black 《Mineralium Deposita》1977,12(3):263-279

Stratiform Cu-Pb-Zn (-Au-Ag) mineralization associated with black carbonaceous schists and acid metatuffs is restricted to distinct horizons within the Cretaceous sequence of the Diahot region. The sulphides occur in sharply bounded lenses which show varying degrees of compositional banding conformable with the foliation of the country schists. The deposits are sedimentary-exhalative of the Rio Tinto-type and have been modified by mid-Tertiary high-pressure metamorphism (lawsonite-albite and glaucophanitic greenschist facies). The ores are not strongly deformed by the metamorphism and sedimentary structures, pyrite framboids and atoll structures are preserved in some deposits. With increasing metamorphic grade sphalerite becomes more iron-rich, pyrrhotite becomes more abundant, and the sulphides show a general increase in grain-size which parallels that of the silicates in the enclosing rocks. In the more highly metamorphosed deposits the sulphide associations are retrograde assemblages. There is no evidence of large-scale metamorphic remobilization of sulphides. No differences were observed in either the sulphide assemblages or in the composition of the sulphides to indicate that the metamorphism was of the high pressure rather than the low pressure type.  相似文献   

Does upward seepage of river water and storm water runoff determine water quality of urban drainage systems in lowland areas? A case study for the Rhine–Meuse delta     

Kim Vermonden  Marion A. A. Hermus  Marije van Weperen  Rob S. E. W. Leuven  Gerard van der Velde  Alfons J. P. Smolders  Jan G. M. Roelofs  A. Jan Hendriks 《水文研究》2009,23(21):3110-3120

The water quality of urban drainage ditches in lowlands in the Rhine‐Meuse delta was analysed with principal component analysis (PCA) during a dry period and a rain storm, and related to the seepage of polluted river water and effective impervious area (EIA). This was done in order to test the hypothesis that seepage of river water and storm water runoff from impervious areas strongly determine the water quality of urban drainage systems along large lowland rivers. Our analysis revealed that upward seepage of groundwater originating from rivers Rhine and Meuse was positively correlated with nitrate, potassium, sodium and chloride and negatively correlated with alkalinity, calcium, magnesium and iron. EIA was correlated with very few environmental variables (i.e. phosphate, pH and iron in the dry period and iron during the rain storm). Nickel and zinc concentrations generally exceeded the maximum allowable concentrations (MAC), while lead and phosphorus concentrations were just above the nutrient standards and MAC in a few locations during the rain storm. To optimize water quality in urban water systems, attention should be paid to all sources of pollution and not only to EIA. The impact of local groundwater seepage originating from large rivers in lowlands on the chemistry of urban water systems is often underestimated and should be taken into account when assessing water quality and improving water quality status. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Hyperspectral mapping of alteration assemblages within a hydrothermal vug at the Haughton impact structure,Canada          下载免费PDF全文

Rebecca N. Greenberger  John F. Mustard  Gordon R. Osinski  Livio L. Tornabene  Alexandra J. Pontefract  Cassandra L. Marion  Roberta L. Flemming  Janette H. Wilson  Edward A. Cloutis 《Meteoritics & planetary science》2016,51(12):2274-2292

Meteorite impacts on Earth and Mars can generate hydrothermal systems that alter the primary mineralogies of rocks and provide suitable environments for microbial colonization. We investigate a calcite–marcasite‐bearing vug at the ~23 km diameter Haughton impact structure, Devon Island, Nunavut, Canada, using imaging spectroscopy of the outcrop in the field (0.65–1.1 μm) and samples in the laboratory (0.4–2.5 μm), point spectroscopy (0.35–2.5 μm), major element chemistry, and X‐ray diffraction analyses. The mineral assemblages mapped at the outcrop include marcasite; marcasite with minor gypsum and jarosite; fibroferrite and copiapite with minor gypsum and melanterite; gypsum, Fe³⁺ oxides, and jarosite; and calcite, gypsum, clay, microcline, and quartz. Hyperspectral mapping of alteration phases shows spatial patterns that illuminate changes in alteration conditions and formation of specific mineral phases. Marcasite formed from the postimpact hydrothermal system under reducing conditions, while subsequent weathering oxidized the marcasite at low temperatures and water/rock ratios. The acidic fluids resulting from the oxidation collected on flat‐lying portions of the outcrop, precipitating fibroferrite + copiapite. That assemblage then likely dissolved, and the changing chemistry and pH resulting from interaction with the calcite‐rich host rock formed gypsum‐bearing red coatings. These results have implications for understanding water–rock interactions and habitabilities at this site and on Mars.  相似文献   

Surface radiation climatology for Ny-Ålesund,Svalbard (78.9° N), basic observations for trend detection     

Marion Maturilli  Andreas Herber  Gert König-Langlo 《Theoretical and Applied Climatology》2015,120(1-2):331-339

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Evaluating techniques for sampling stream crayfish (Paranephrops planifrons)     

Charles F. Rabeni  Kevin J. Collier  Stephanie M. Parkyn  Brendan J. Hicks 《新西兰海洋与淡水研究杂志》2013,47(5):693-700

We evaluated several capture and analysis techniques for estimating abundance and size structure of freshwater crayfish (Paranephrops planifrons) (koura) from a forested North Island, New Zealand stream to provide a methodological basis for future population studies. Direct observation at night and collecting with baited traps were not considered useful. A quadrat sampler was highly biased toward collecting small individuals. Handnetting at night and estimating abundances using the depletion method were not as efficient as handnetting on different dates and analysing by a mark‐recapture technique. Electrofishing was effective in collecting koura from different habitats and resulted in the highest abundance estimates, and mark‐recapture estimates appeared to be more precise than depletion estimates, especially if multiple recaptures were made. Handnetting captured more large crayfish relative to electrofishing or the quadrat sampler.  相似文献   

The role of dissolved molecular oxygen in abiotic pyrite oxidation under acid pH conditions – Experiments with O-enriched molecular oxygen     

Claudia Heidel  Marion Tichomirowa 《Applied Geochemistry》2010

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Thermochronometric constraints on the tectonic evolution of the Serifos detachment, Aegean Sea, Greece   总被引：1，自引：0，他引：1  

Stephanie Brichau  Stuart Thomson  Uwe Ring 《International Journal of Earth Sciences》2010,99(2):379-393

We constrain the timing and kinematics of the Serifos detachment in the southwestern Cyclades, Greece, using low-temperature thermochronometry. Fission-track dating shows that the Serifos detachment was active between ~13 and 6 Ma and that the Serifos granodiorite in its footwall intruded at or before ~12–11 Ma into the extensional shear zone and initially cooled very rapidly at rates >180°C per million year. The mylonite zone at the top of the granodiorite and mylonitic structures in its country rocks record a consistent top-SSW shear sense in the ductile crust. In the brittle regime top-NNE shear-sense indicators occur as well. Conjugate top-SSW and top-NNE high-angle normal faults are the youngest deformational features and cut across the detachment. Age–distance relationships for the fission-track data display a relatively flat pattern. We discuss a model advocating initial top-SSW movement on the Serifos detachment before and during emplacement of the granodiorite. Updoming of the detachment during exhumation and cooling caused subsequent bivergent extension in the brittle crust.  相似文献   

Introducing the decile concept for studying the spatiotemporal characteristics and variability of long-lasting dry and wet periods     

Stephanie Hänsel 《Theoretical and Applied Climatology》2014,118(1-2):223-235

Changes in the persistence of dry and wet periods are of particular interest for many sectors, as long-term deviations from normal precipitation strongly affect the water availability. Here, an indicator is introduced to explore variability and trends of long-lasting dry and wet periods by using decile based thresholds. The test of three different thresholds for ending those periods revealed only slight influences of the chosen threshold on the spatiotemporal pattern and trends. The methodology of the deciles indicator is illustrated and studied exemplarily for a spatially highly resolved data set for Saxony, Germany within 1901–2010. Within that region decile wet and dry periods, respectively, occur approximately four times within 10 years, last on average 11 months and cover on average more than 35 % of the stations. Several years to decades long periods with particularly frequent and/or long decile dry or wet periods were identified. The computed trends strongly depend upon the analysis period, as frequency, duration and spatial coverage of decile periods show strong variations up to multi-decadal time scales. Nonetheless, there is some indication that dry period coverage increased within the 20th century, while wet period coverage decreased. However, in the most recent decades the long-term trends reversed.  相似文献   

Seasonal controls on stream chemical export across diverse coastal watersheds in the USA     

Janet Barco  Stephanie Gunawan  Terri S. Hogue 《水文研究》2013,27(10):1440-1453

The current study focuses on understanding key factors controlling geochemical export in eight diverse coastal watersheds at seasonal and annual time scales. Geochemical, atmospheric and hydrologic data across a range of hydro‐climatic regimes and varying land uses were investigated and relationships analysed. A hyperbolic dilution model was fitted for each watershed system to evaluate discharge–concentration relationships. Nitrate concentration effects were observed in watersheds exposed to high atmospheric deposition rates as well as agricultural watersheds, whereas urban watersheds showed nitrate dilution effects. Dilution patterns were observed for calcium, magnesium and sulfate for almost all watersheds. Seasonal loads for almost all constituents were noted to be mainly driven by hydrologic seasonality, but are also dependent on inputs (atmospheric deposition and land use sources). Understanding the primary controls on hydro‐chemical interactions is critical for developing and refining predictive water quality models, especially in coastal watersheds where sensitive downstream ecosystems act as receiving waters for upstream pollutant loads. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

In pursuit of procedural justice: Lessons from an analysis of 56 forest carbon project designs     

Kimberly R. Marion Suiseeya  Susan Caplow 《Global Environmental Change》2013,23(5):968-979

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